Synthèse et caractérisation de polyphosphates (Li/Na/K)(Y,La,Ln)(PO3)4 (Ln=Eu³⁺,Sm³⁺). Etude des propriétés de luminescence sous excitation VUV-UV

Abstract : This work is devoted to the development of phosphors based on polyphosphates of alkaline and rare earth ions, stoichiometric or activated with Eu3+ and Sm3+ ions, considered as light emitters under VUV excitation. These materials, with formula LixNa1-xY1-yEuy(PO3)4 (x = 0; 0.25; 0.5; 0.75; 1 and 0.01 ≤ y ≤ 1), LixNa1-xLa(PO3)4 : 5 % Eu3+ (x = 0; 0.1; 0.2; 0.8; 0.9; 1), NaxK1-xLa(PO3)4 : 5 % Eu3+ (x = 0; 0.1; 0.2; 0.8; 0.9; 1) and LixNa1-xSm(PO3)4 (x = 0; 0.5; 1), were synthesized in the solid state and characterized mainly by X-ray diffraction, infrared and Raman spectroscopies and thermal analysis. Physical-chemical and optical analyses, in particular using the Eu3+ ion as a structural probe, show that the cross-substitution of Li+, Na+ and K+ alkaline ions is possible only in a relatively small proportion, which is linked to the differences in crystallographic structures of these materials. The analysis of the Eu3+ ion spectroscopic data according to Judd and Ofelt theory confirms the close link between optical and structural properties in these materials. Excitation spectra are characterized by an intense band localized in the VUV domain, respectively due to the charge transfer mechanism Y3+-O2- and Eu3+-O2- for the Eu3+ doped yttrium materials and to the 4f-5d inter-configuration for the Sm3+ concentrated materials. Materials concentrated in Eu3+ and Sm3+ ions emit intense red and orange fluorescence respectively, demonstrating the absence of concentration quenching.
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Sihem Sebai. Synthèse et caractérisation de polyphosphates (Li/Na/K)(Y,La,Ln)(PO3)4 (Ln=Eu³⁺,Sm³⁺). Etude des propriétés de luminescence sous excitation VUV-UV. Matériaux. Université Clermont Auvergne; Université de Tunis El Manar, 2018. Français. ⟨NNT : 2018CLFAC067⟩. ⟨tel-02128368⟩

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