Skip to Main content Skip to Navigation

Oxidation catalysis under green chemistry conditions

Abstract : In order to develop a chemistry more respectful of the environment, access to sustainable processes is mandatory. More specifically, in the field of oxidation chemistry, use of toxic oxidants has to be banished, use of solvents limited and reusable catalysts developed. In this context, two types of greener approaches have been explored. The first approach concerns removal or replacement of acetic acid, an additive - in association with H2O2, favoring exclusive formation of epoxides with Mn and Fe metal complexes as catalysts. For this objective, two strategies have been explored. The first one consists in introducing fluoroalcohol functions in the second coordination sphere of metal complexes with pyridinophane-based ligand to easily activate H2O2. Those complexes did not enhance the catalytic activity for cyclooctene oxidation reactions in comparison to analogous Mn(II) and Fe(III) complexes with unmodified ligands. However, Ni(II) and Co(II) metal complexes with unmodified ligands display interesting catalytic activity for H2 photoproduction. The second strategy aimed to replace acetic acid. Using silica beads functionalized with COOH pendant arms (SiO2@COOH) as additive and H2O2 as oxidant, catalytic epoxidation reactions catalyzed by Mn(II) and Fe(III) metal complexes with BPMEN ligand displayed significant selectivity towards epoxide. The second approach concerns organic-solvent free (ep)oxidation processes with catalysts based on polyoxometalates (POMs). Catalysts SiO2@PMo and SiO2@PW, respectively obtained by ionic grafting of H3PMo12O40 or H3PW12O40 on silica beads functionalized with NH2 pending functions (SiO2@NH2), have been fully characterized. With low catalyst loading, both catalysts displayed efficient oxidation activity and better selectivity than the free POMs. Moreover, recovered beads gave similar conversion and selectivity after two recycling processes.
Document type :
Complete list of metadatas

Cited literature [260 references]  Display  Hide  Download
Contributor : Abes Star :  Contact
Submitted on : Monday, October 5, 2020 - 12:41:42 PM
Last modification on : Tuesday, October 20, 2020 - 11:22:39 AM


Version validated by the jury (STAR)


  • HAL Id : tel-02957673, version 1



Yun Wang. Oxidation catalysis under green chemistry conditions. Coordination chemistry. Université Paul Sabatier - Toulouse III, 2019. English. ⟨NNT : 2019TOU30241⟩. ⟨tel-02957673⟩



Record views


Files downloads