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Réactivité et spectroscopie de systèmes moléculaires d'intérêt atmosphérique et biologique

Abstract : This thesis aims to study the photochemistry and reactivity in the gaseous phase of molecular systems which formulas are [S,S,X,O]q where X=N,O and q=-1, or 0, or +1 or +2, to understand those reactions at a molecular scale. We thus have studied the possibility of using the [S,S,N,O]- species as NO donors in therapeutic context. We also have identified the [O,S,S,O] species in Venus’ atmosphere. We have shown that the SS-XO species have a weak, low dissociation energy central bond which is origin of their reactivity
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Mohamed Cheraki. Réactivité et spectroscopie de systèmes moléculaires d'intérêt atmosphérique et biologique. Chimie théorique et/ou physique. Université Paris-Est, 2019. Français. ⟨NNT : 2019PESC2075⟩. ⟨tel-02894533⟩

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