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, ?????????????????? ????????????? ??????? ???????? ????, p.153

, ???????????? ???????????? ???????? ? ???????????? ?????? ?????? ???????????

. .. ???-????????-????????-????, , p.164

.. .. ??????????,

.. .. ??????,

, ?????????? ????????? ?????? ???????????? ? ??????? 10 ??????? 2.22, ? ????? ??? ????????? ????? ?????????? (040)

, ????????? ???????????? ?????????????? ????????????? ????????? (100) ? (001) ???????? 32 S 16 O 18 O (? ?? ?1 )

, ???????? ??????? (I ? III) ????? 2 1 , 2 3 ? 1 + 3 ???????? 32 S 16 O 18 O ??????? 32 S 16 O 18 O ??? ??????? ? ??? ?????. ?? ?????? ????? ??????? ???? ?????????? ??????: 1. ?????????? ??????????, ???????????? ???????????? ? ????????????? ??????????????? ?????? 2 ??????????? ????????, ? ????? ?? ?????? ?????????????????? ??????? ???????? ???????? ???????? 4 ?????????? ???????????? ?????????? ???????

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, 2 3 bands of 32 S 16 O 18 O. The inverse spectroscopic the IPF. Key words: Ro-vibrational spectra, sulfur dioxide, isotopologues, effective Hamilto nian

, Les spectres FTIR expérimentaux de nombreux isotopologues du dioxyde de soufre, 32 S 16 O 2 , 34 S 16 O 2 , 32 S 18 O 2 et 32 S 16 O 18 O, ontété enregistrés pour la première fois dans les régions des bandes fondamentales, «chaudes», harmoniques et de combinaison. La grande variabilité des conditions expérimentales a permis d'observer et d'identi?er pour la première fois des transitions appartenant aux ban des rovibrationnelles suivantes : 3 2 , 3 2 ? 2 , 2 2 ? 2 bandes de 32 S 16 O 2, Titre : Analyse spectrale FTIRà haute résolution des isotopologues du dioxyde de soufre. Résumé : Dans cette thèse, nous avons examiné les propriétés spectrales de l'anhydride sulfureux