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, Reaction rates of elementary steps (mol l -1 min -1 )
, Initial reaction rates of elementary steps (mol l -1 min -1 )
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, List of abbreviations Concentration of 4-iodoacetophenone in liquid phase (mol m -3 ) Concentration of 4-iodoacetophenone on the surface of the catalyst
, Total Pd concentration in the liquid pahse (mol m -3 )
, Active Pd concentration in the liquid pahse (mol m -3 )
, Concentration of total supported Pd on the solid (mol m -3 ) Concentration of active supported Pd on the solid
, Axial dispercion (m 2 s -1 )
, Effective diffusivity (m 2 s -1 ) Internal diameter of the reactor Kinetic constant of Pd adsorption (s -1 )
, Kinetic constant of Pd deactivation (s -1 )
, Kinetic constant of Pd leaching (mol -1 m 3 s -1 )
, Pd Pd mass inside the column (mg) ppm part per million (mg Pd /Kg solution)
, Q Liquid flow rate (ml min -1 )
, Rate of liquid Pd deactivation inside the column (mol 1 m -3 s -1 )
, Rate of liquid Pd deactivation inside the tube (mol 1 m -3 s -1 )
, Pd leaching reaction rate (mol m -3 s -1 )
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, In order to determine the value of axial dispersion coefficient and the liquid volume in the tracer experiment (uracil (Sigma Aldrich) as a tracer that is not adsorbed by the functionalized C18 Silica), then a dispersive packed bed reactor model was used to estimate the porosity and the axial dispersion, vol.1
, Optimized step response profile of normalized concentration at column outlet Conditions: Q L =0.46 ml/min, Column: length 5 cm
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