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, Les difractogrammes ont été obtenus avec un diffractomètre Bruker D8 Advance. La source des rayons X est un tube à anode de cuivre, Cu K? de longueur d'onde ?=1, la plupart des cas, des palets miroir bas bruit de fond ont été utilisés, vol.5417

, la structure et les affinements finaux ont été réalisés avec SHELXL, 2016.

, Les images ont été obtenues avec un microscope électronique à balayage environnemental FEI Quanta 200 ESEM, équipé d'un détecteur d'électron secondaire (BSED) et d'un détecteur d'analyse dispersive en énergie EDX permettant l'acquisition d'analyses élémentaires quantitative et d'

. Icp-oes,

, Les analyses ont été effectuées sur un appareil Ametek Spectro Arcos. L'appareil, utilisant un système optique de détection, a été calibré avec une gamme d'étalonnage de 0 à 20 ppm préparées à partir d'étalons standarts certifiés (SCP Science). Tous les échantillons ont été dilués dans une matrice

, Les longueurs d'ondes des raies utilisées pour les différents éléments sont : Ni 221,648 ; 227,021 ; 231,604, vol.232, p.3

, Mn 257,611 ; 259,373 ; 260,569, vol.294, p.921

, Co 228,616, vol.230, p.892

, Al, vol.167, p.152, 0641.

, Cu 219,226 ; 224,700 ; 324,754, vol.327, p.396

, Li 323,261 ; 460,289, vol.670, p.780

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