, Article en préparation: Method comparison to estimate Submarine Groundwater Discharge fluxes from karstic coastal aquifers: Application to Côte Bleue

, Article en préparation: Method comparison to estimate Submarine Groundwater Discharge fluxes from karstic coastal aquifers: Application to Côte Bleue

, Activités de radium des échantillons collectés en surface

, Nous avons échantillonnés trois puits, vol.20

, Nous avons également prélevé de l'eau de la Nam Theun et de la Nam On, les deux principales rivières alimentant le réservoir (60 L ; NTH2 et NON1), NAK1308, NAK1901 et NAK1915), les deux sorties du réservoir

, Des profils verticaux (6 profondeurs ; 80 L) ont été réalisés aux stations Res2, Res3, Res6 et in (ns) October ; ns December

, Estimation of nutrient fluxes (mol d -1 ) driven by SGD, the Huveaune River and the, Tableau, vol.6

, DSi and NO 3 d -1, Rhône River in April, 2016.

B. Tableau, 1: Date, heure et volume des échantillons prélevés sur le plateau de Nakaï et sur le réservoir e Nam Theun

, Bibliographie Agence des aires Marines Protégées, 2007.

M. P. Anderson, Heat as a Ground Water Tracer, Ground Water, vol.43, pp.951-968, 2005.

L. Aquilina, B. Ladouche, N. Doerfliger, J. L. Seidel, M. Bakalowicz et al., Origin, evolution and residence time of saline thermal fluids (Balaruc springs, southern France): implications for fluid transfer across the continental shelf, Chem. Geol, vol.192, pp.1-21, 2002.
URL : https://hal.archives-ouvertes.fr/hal-00676776

B. Arfib, T. Cavalera, and E. Gilli, Influence de l'hydrodynamique sur l'intrusion saline en aquifère karstique côtier, Comptes Rendus Geosci, vol.338, pp.757-767, 2006.

,

M. Bakalowicz, Karst groundwater: a challenge for new resources, Hydrogeol. J, vol.13, pp.148-160, 2005.

T. H. Bakken, F. Ruden, and L. E. Mangset, Submarine groundwater: a new concept for the supply of drinking water, Water Resour. Manag, vol.26, pp.1015-1026, 2012.

P. Baudron, S. Cockenpot, F. Lopez-castejon, O. Radakovitch, J. Gilabert et al., Combining radon, short-lived radium isotopes and hydrodynamic modeling to assess submarine groundwater discharge from an anthropized semiarid watershed to a Mediterranean lagoon, J. Hydrol, vol.525, pp.55-71, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01296493

A. J. Beck, J. K. Cochran, and S. A. Sañudo-wilhelmy, Temporal Trends of Dissolved Trace Metals in Jamaica Bay, NY: Importance of Wastewater Input and Submarine Groundwater Discharge in an Urban Estuary, Estuaries Coasts, vol.32, pp.535-550, 2009.

A. J. Beck and M. A. Cochran, Controls on solid-solution partitioning of radium in saturated marine sands, Mar. Chem, vol.156, pp.38-48, 2013.

A. J. Beck, J. P. Rapaglia, J. K. Cochran, and H. J. Bokuniewicz, Radium mass-balance in Jamaica Bay, NY: Evidence for a substantial flux of submarine groundwater, Mar. Chem, vol.106, pp.419-441, 2007.

A. J. Beck, J. P. Rapaglia, J. K. Cochran, H. J. Bokuniewicz, and S. Yang, Submarine groundwater discharge to Great South Bay, NY, estimated using Ra isotopes, 2008.

. Chem, Measurement of Radium and Actinium Isotopes in the marine environment, vol.109, pp.279-291

S. Bejannin, P. Van-beek, T. Stieglitz, M. Souhaut, and J. Tamborski, Combining airborne thermal infrared images and radium isotopes to study submarine groundwater discharge along the French Mediterranean coastline, J. Hydrol. Reg. Stud, vol.13, pp.72-90, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01765611

A. Béoutis, P. Jean, and S. Colas, , 2009.

A. H. Beusen, C. P. Slomp, and A. F. Bouwman, Global land-ocean linkage: direct inputs of nitrogen to coastal waters via submarine groundwater discharge, Environ. Res. Lett, vol.8, p.34035, 2013.

F. J. Black, A. Paytan, K. L. Knee, N. R. De-sieyes, P. M. Ganguli et al., Submarine Groundwater Discharge of Total Mercury and Monomethylmercury to Central California Coastal Waters, Environ. Sci. Technol, vol.43, pp.5652-5659, 2009.

F. J. Black, A. Paytan, K. L. Knee, N. R. Sieyes, P. M. Ganguli et al., Submarine Groundwater Discharge of Total Mercury and Monomethylmercury to Central California Coastal Waters, ResearchGate, vol.43, pp.5652-5661, 2009.

A. C. Blanco, A. Watanabe, K. Nadaoka, S. Motooka, E. C. Herrera et al., Estimation of nearshore groundwater discharge and its potential effects on a fringing coral reef, Mar. Pollut. Bull, vol.62, pp.770-785, 2011.

S. E. Bone, M. A. Charette, C. H. Lamborg, and M. E. Gonneea, Has Submarine Groundwater Discharge Been Overlooked as a Source of Mercury to Coastal Waters?, Environ. Sci. Technol, vol.41, pp.3090-3095, 2007.

T. Boschetti, P. González-hernández, R. Hernández-díaz, G. Naclerio, and F. Celico, ): effects on karst development and water isotope composition, Environ. Earth Sci, vol.73, pp.5703-5719, 2015.

W. S. Broecker and T. H. Peng, Tracers in the Sea, 690 pp. Lamont-Doherty Geol, Obs. Palisades NY, 1982.

B. Burnett, Offshore springs and seeps are focus of working group, Eos Trans. Am. Geophys. Union, vol.80, pp.13-15, 1999.

W. C. Burnett, P. K. Aggarwal, A. Aureli, H. Bokuniewicz, J. E. Cable et al., Quantifying submarine groundwater discharge in the coastal zone via multiple methods, Sci. Total Environ, vol.367, pp.498-543, 2006.

W. C. Burnett, H. Bokuniewicz, M. Huettel, W. S. Moore, and M. Taniguchi, Groundwater and pore water inputs to the coastal zone, Biogeochemistry, vol.66, pp.3-33, 2003.

W. C. Burnett and H. Dulaiova, Radon as a tracer of submarine groundwater discharge into a boat basin in Donnalucata, Sicily. Cont. Shelf Res, vol.26, pp.862-873, 2006.

W. C. Burnett and H. Dulaiova, Estimating the dynamics of groundwater input into the coastal zone via continuous radon-222 measurements, J. Environ. Radioact, vol.69, pp.21-35, 2003.

W. C. Burnett, M. Lambert, and H. Dulaiova, Tracing groundwater discharge into the ocean via continuous radon-222 measurements, MTS/IEEE Oceans 2001. An Ocean Odyssey. Conference Proceedings (IEEE Cat. No.01CH37295), vol.1, pp.251-255, 2001.

W. C. Burnett, M. Taniguchi, and J. Oberdorfer, Measurement and significance of the direct discharge of groundwater into the coastal zone, J. Sea Res, vol.46, pp.109-116, 2001.

J. E. Cable, G. C. Bugna, W. C. Burnett, and J. P. Chanton, Application of 222Rn and CH4 for assessment of groundwater discharge to the coastal ocean, Limnol. Oceanogr, vol.41, pp.1347-1353, 1996.

J. E. Cable and J. B. Martin, Submarine groundwater discharge studies along the Ubatuba coastal area in south-eastern Brazil, Brazil. Estuar. Coast. Shelf Sci, vol.76, pp.473-483, 2008.

W. Cai, Y. Wang, J. Krest, and W. S. Moore, The geochemistry of dissolved inorganic carbon in a surficial groundwater aquifer in North Inlet, South Carolina, and the carbon fluxes to the coastal ocean, Geochim. Cosmochim. Acta, vol.67, pp.631-639, 2003.

G. Cauwet, HTCO method for dissolved organic carbon analysis in seawater: influence of catalyst on blank estimation, Mar. Chem, vol.47, issue.94, pp.90013-90015, 1994.

T. Cavalera, Etude du fonctionnement et du bassin d'alimentation de la source sousmarine de Port Miou, 2007.
URL : https://hal.archives-ouvertes.fr/tel-00789232

V. Chanudet, P. Guédant, W. Rode, A. Godon, F. Guérin et al., Evolution of the physico-chemical water quality in the Nam Theun 2 Reservoir and downstream rivers for the first 5 years after impoundment, Hydroécologie Appliquée, vol.19, pp.27-61, 2016.

M. A. Charette and K. O. Buesseler, Submarine groundwater discharge of nutrients and copper to an urban subestuary of Chesapeake Bay (Elizabeth River), Limnol. Oceanogr, vol.49, pp.376-385, 2004.

M. A. Charette, K. O. Buesseler, and J. E. Andrews, Utility of radium isotopes for evaluating the input and transport of groundwater-derived nitrogen to a Cape Cod estuary, Limnol. Oceanogr, vol.46, pp.465-470, 2001.

M. A. Charette, M. E. Gonneea, P. J. Morris, P. Statham, G. Fones et al., Radium isotopes as tracers of iron sources fueling a Southern Ocean phytoplankton bloom, Deep Sea Res. Part II Top. Stud. Oceanogr, vol.54, 1989.

M. A. Charette, W. S. Moore, and W. C. Burnett, Chapter 5 Uranium-and Thorium-Series Nuclides as Tracers of Submarine Groundwater Discharge, in: Radioactivity in the Environment, pp.155-191, 2008.

M. A. Charette and E. R. Sholkovitz, Oxidative precipitation of groundwater-derived ferrous iron in the subterranean estuary of a coastal bay, Geophys. Res. Lett, vol.29, pp.85-86, 2006.

J. B. Christensen, D. L. Jensen, and T. H. Christensen, Effect of dissolved organic carbon on the mobility of cadmium, nickel and zinc in leachate polluted groundwater, Water Res, vol.30, pp.91-98, 1996.

T. M. Church, An underground route for the water cycle, Nature, vol.380, pp.579-580, 1996.

S. L. Colbert and D. E. Hammond, Temporal and spatial variability of radium in the coastal ocean and its impact on computation of nearshore cross-shelf mixing rates, Cont. Shelf Res, vol.27, pp.1477-1500, 2007.

M. Colette-bregand, A. James, C. Munshy, and G. Bocquené, Contamination des milieux aquatiques par les substances pharmaceutiques et cosmétiques -Etat des lieux et perspectives, 2009.

M. Condomines, E. Gourdin, D. Gataniou, and J. Seidel, Geochemical behaviour of Radium isotopes and Radon in a coastal thermal system (Balaruc-les-Bains, South of France), Geochim. Cosmochim. Acta, vol.98, pp.160-176, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00795512

,

P. G. Cook, C. Wood, T. White, C. T. Simmons, T. Fass et al., Groundwater inflow to a shallow, poorly-mixed wetland estimated from a mass balance of radon, J. Hydrol, vol.354, pp.213-226, 2008.

T. Cyronak, I. R. Santos, D. V. Erler, D. T. Maher, and B. D. Eyre, Drivers of pCO2 variability in two contrasting coral reef lagoons: The influence of submarine groundwater discharge, 2014.

A. Dai and K. E. Trenberth, Estimates of Freshwater Discharge from Continents: Latitudinal and Seasonal Variations, J. Hydrometeorol, vol.3, pp.660-687, 2002.

S. Descloux, P. Guedant, D. Phommachanh, and R. Luthi, Main features of the Nam Theun 2 hydroelectric project (Lao PDR) and the associated environmental monitoring programmes, Hydroécologie Appliquée, vol.19, pp.5-25, 2016.

C. Deshmukh, F. Guérin, C. Delon, S. Pighini, A. Vongkhamsao et al., The net GHG (CO2, CH4 and N2O) footprint of a newly impounded subtropical hydroelectric reservoir: Nam Theun 2, pp.2013-10815, 2013.

C. Deshmukh, D. Serça, C. Delon, R. Tardif, M. Demarty et al., Physical controls on CH4 emissions from a newly flooded subtropical freshwater hydroelectric reservoir: Nam Theun 2, Biogeosciences, vol.11, pp.4251-4269, 2014.
URL : https://hal.archives-ouvertes.fr/hal-00965382

, Direction Générale des Entreprise, 2016.

H. Dulai, J. Kamenik, C. A. Waters, J. Kennedy, J. Babinec et al., Autonomous long-term gamma-spectrometric monitoring of submarine groundwater discharge trends in Hawaii, J. Radioanal. Nucl. Chem, vol.307, pp.1865-1870, 2016.

H. Dulaiova, R. Peterson, W. C. Burnett, and D. Lane-smith, A multi-detector continuous monitor for assessment of <Superscript>222</Superscript>Rn in the coastal ocean, J. Radioanal. Nucl. Chem, vol.263, pp.361-363, 2005.

F. Elbaz-poulichet, J. Seidel, and C. Othoniel, Occurrence of an anthropogenic gadolinium anomaly in river and coastal waters of Southern France, Water Res, vol.36, pp.1102-1105, 2002.

A. A. El-gamal, R. N. Peterson, and W. C. Burnett, Detecting Freshwater Inputs via Groundwater Discharge to Marina Lagoon, Estuaries Coasts, vol.35, pp.1486-1499, 2012.

R. J. Elsinger and W. S. Moore, 226Ra behavior in the Pee Dee River-Winyah Bay estuary, Earth Planet. Sci. Lett, vol.48, pp.90187-90196, 1980.

D. V. Erler, I. R. Santos, Y. Zhang, D. R. Tait, K. M. Befus et al., Nitrogen transformations within a tropical subterranean estuary, Mar. Chem, vol.164, pp.38-47, 2014.

A. T. Fisher, Marine hydrogeology: recent accomplishments and future opportunities, Hydrogeol. J, vol.13, pp.69-97, 2005.

P. Fleury, M. Bakalowicz, and G. De-marsily, Submarine springs and coastal karst aquifers: A review, J. Hydrol, vol.339, pp.79-92, 2007.

. Franceagrimer, Les filières pêche et aquaculture, 2017.

J. Garcia-orellana, J. K. Cochran, H. Bokuniewicz, J. W. Daniel, V. Rodellas et al., Evaluation of 224 Ra as a tracer for submarine groundwater discharge in Long Island Sound (NY), Geochim. Cosmochim. Acta, vol.141, pp.314-330, 2014.
URL : https://hal.archives-ouvertes.fr/hal-01818178

E. Garcia-solsona, J. Garcia-orellana, P. Masqué, and H. Dulaiova, Uncertainties associated with 223Ra and 224Ra measurements in water via a Delayed Coincidence Counter (RaDeCC), Mar. Chem, vol.109, pp.198-219, 2008.

,

E. Garcia-solsona, J. Garcia-orellana, P. Masqué, E. Garcés, O. Radakovitch et al., An assessment of karstic submarine groundwater and associated nutrient discharge to a Mediterranean coastal area, Spain) using radium isotopes. Biogeochemistry, vol.97, pp.211-229, 2009.
URL : https://hal.archives-ouvertes.fr/hal-01061558

E. Garcia-solsona, J. Garcia-orellana, P. Masqué, V. Rodellas, M. Mejías et al., Groundwater and nutrient discharge through karstic coastal springs (Castello;, Spain), Biogeosciences, vol.7, pp.2625-2638, 2010.

E. Garcia-solsona, P. Masqué, J. Garcia-orellana, J. Rapaglia, A. J. Beck et al., Estimating submarine groundwater discharge around Isola La Cura, northern Venice Lagoon (Italy), by using the radium quartet, Mar. Chem, vol.109, pp.292-306, 2008.

J. Gassend, B. Liou, and S. Ximénès, L'épave 2 de l'anse des Laurons, Archaeonautica, vol.4, pp.75-105, 1984.

J. C. Gattacceca, A. Mayer, A. Cucco, C. Claude, O. Radakovitch et al., Submarine groundwater discharge in a subsiding coastal lowland: A 226Ra and 222Rn investigation in the Southern Venice lagoon, Appl. Geochem, vol.26, pp.907-920, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00799576

C. Giffin, A. Kaufman, and W. Broecker, Delayed coincidence counter for the assay of actinon and thoron, J. Geophys. Res, vol.68, pp.1749-1757, 1963.

,

E. Gilli, Compilation d'anciennes mesures de débit à Port-Miou. Apport à l'hydrogéologie de la Basse Provence, Presented at the 7th Conference on Limestone Hydrology and fissured Media, 2001.

F. Giorgi, Climate change hot-spots, Geophys. Res. Lett, vol.33, p.8707, 2006.

C. Gobler and S. Sañudo-wilhelmy, Effects of organic carbon, organic nitrogen, inorganic nutrients, and iron additions on the growth of phytoplankton and bacteria during a brown tide bloom, Mar. Ecol. Prog. Ser, vol.209, pp.19-34, 2001.

M. A. Goñi and I. R. Gardner, Seasonal Dynamics in Dissolved Organic Carbon Concentrations in a Coastal Water-Table Aquifer at the Forest-Marsh Interface, Aquat. Geochem, vol.9, pp.209-232, 2003.

M. E. Gonneea and M. A. Charette, Hydrologic Controls on Nutrient Cycling in an Unconfined Coastal Aquifer, Environ. Sci. Technol, vol.48, pp.14178-14185, 2014.

M. E. Gonneea, P. J. Morris, H. Dulaiova, and M. A. Charette, Measurement of Radium and Actinium Isotopes in the marine environment, Mar. Chem, vol.109, pp.250-267, 2008.

,

F. Guérin, C. Deshmukh, D. Labat, S. Pighini, A. Vongkhamsao et al., Effect of sporadic destratification, seasonal overturn and artificial mixing on CH 4 emissions at the surface of a subtropical hydroelectric reservoir, Lao PDR). Biogeosciences Discuss, vol.12, 2015.

G. J. Hancock, I. T. Webster, and T. C. Stieglitz, Horizontal mixing of Great Barrier Reef waters: Offshore diffusivity determined from radium isotope distribution, J. Geophys. Res, vol.111, 2006.

F. G. Hoefel and R. L. Evans, Impact of Low Salinity Porewater on Seafloor Electromagnetic Data: A Means of Detecting Submarine Groundwater Discharge?, Estuar. Coast. Shelf Sci, vol.52, pp.179-189, 2001.

D. P. Horn, Measurements and modelling of beach groundwater flow in the swash-zone: a review, Swash-Zone Processes1st International Workshop on Swash-Zone Processes, vol.26, pp.622-652, 2006.

D. Hwang, G. Kim, Y. Lee, and H. Yang, Estimating submarine inputs of groundwater and nutrients to a coastal bay using radium isotopes, Mar. Chem, vol.96, pp.61-71, 2005.

D. Hwang, Y. Lee, and G. Kim, Large submarine groundwater discharge and benthic eutrophication in Bangdu Bay on volcanic Jeju Island, Korea. Limnol. Oceanogr, vol.50, pp.1393-1403, 2005.

M. Ivanovich and R. S. Harmon, Uranium series disequilibrium: applications to environmental problems, 1982.

A. Jensen, K. Collins, and A. P. Lockwood, Artificial Reefs in European Seas, 2012.

J. Jeong, G. Kim, and S. Han, Influence of trace element fluxes from submarine groundwater discharge (SGD) on their inventories in coastal waters off volcanic island, Korea. Appl. Geochem, vol.27, pp.37-43, 2012.

R. E. Johannes, Ecological significance of the submarine discharge of groundwater, Mar. ECOL-PROG SER, vol.3, pp.365-373, 1980.

A. G. Johnson, C. R. Glenn, W. C. Burnett, R. N. Peterson, and P. G. Lucey, Aerial infrared imaging reveals large nutrient-rich groundwater inputs to the ocean, Geophys. Res. Lett, vol.35, p.15606, 2008.

J. Jouvenel, F. Bachet, J. Harmenin, and D. Bellan-santini, Suivi biologique d'une réserve marine de la Côte Bleue, Colloque «Importance de La Recherche Dans Les Aires Protégées: Des Fondements à La Gestion, pp.5-7, 2002.

M. H. Kara and J. Quignard, Les poissons des lagunes et des estuaires de Méditerranée 3A: Les poissons migrateurs. ISTE Editions, 2018.

A. Kaufman, R. M. Trier, W. S. Broecker, and H. W. Feely, Distribution of 228Ra in the world ocean, J. Geophys. Res, vol.78, pp.8827-8848, 1973.

J. L. Kelly, C. R. Glenn, and P. G. Lucey, High-resolution aerial infrared mapping of groundwater discharge to the coastal ocean, Limnol Ocean. Methods, vol.11, pp.262-277, 2013.

M. G. Khublaryan, A. P. Frolov, and I. O. Yushmanov, Seawater intrusion into coastal aquifers, Water Resour, vol.35, pp.274-286, 2008.

J. Klassen and D. M. Allen, Assessing the risk of saltwater intrusion in coastal aquifers, J. Hydrol, vol.551, pp.730-745, 2017.

K. Knee and A. Paytan, 4.08 Submarine groundwater discharge: A source of nutrients, metals, and pollutants to the coastal ocean, Treatise Estuar Coast Sci, vol.4, pp.205-234, 2011.

K. L. Knee, E. Garcia-solsona, J. Garcia-orellana, A. B. Boehm, and A. Paytan, Using radium isotopes to characterize water ages and coastal mixing rates: A sensitivity analysis, Limnol. Oceanogr. Methods, vol.9, pp.380-395, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00985400

K. L. Knee, J. H. Street, E. E. Grossman&gt;, A. B. Boehm, and A. Paytan, Nutrient inputs to the coastal ocean from submarine groundwater discharge in a groundwater-dominated system: Relation to land use, Limnol. Oceanogr, vol.55, pp.1105-1122, 2010.

F. Kohout, Submarine springs: a neglected phenomenon of coastal hydrology, Hydrology, vol.26, pp.391-413, 1966.

K. D. Kroeger, P. W. Swarzenski, W. J. Greenwood, and C. Reich, Submarine groundwater discharge to Tampa Bay: Nutrient fluxes and biogeochemistry of the coastal aquifer, Mar. Chem, vol.104, pp.85-97, 2007.

C. D. Langevin, Simulation of Submarine Ground Water Discharge to a Marine Estuary, Ground Water, vol.41, pp.758-771, 2003.

D. R. Lee, A device for measuring seepage flux in lakes and estuaries1, Limnol. Oceanogr, vol.22, pp.140-147, 1977.

E. Lee, Y. Hyun, and K. Lee, Sea level periodic change and its impact on submarine groundwater discharge rate in coastal aquifer, Estuar. Coast. Shelf Sci. 121, vol.122, pp.51-60, 2013.

E. Lee, K. Kang, S. P. Hyun, K. Lee, H. Yoon et al., Submarine groundwater discharge revealed by aerial thermal infrared imagery: a case study on Jeju Island, Korea. Hydrol. Process, vol.30, pp.3494-3506, 2016.

Y. Lee, D. Hwang, G. Kim, W. Lee, and H. Oh, Nutrient inputs from submarine groundwater discharge (SGD) in Masan Bay, an embayment surrounded by heavily industrialized cities, Human Impacts on Urban Subsurface Environments, vol.407, pp.3181-3188, 2009.

,

Y. Lee and G. Kim, Linking groundwater-borne nutrients and dinoflagellate red-tide outbreaks in the southern sea of Korea using a Ra tracer, Sedimentological and ecohydrological processes of Asian deltas: The Yangtze and the Mekong, vol.71, pp.309-317, 2007.

K. Leleu, Suivi et évaluation de la pêche professionnelle au sein d'une Aire Marine Protégée : protocoles d'enquêtes et indicateurs de pression et d'impact, 2012.

K. Leleu, D. Pelletier, E. Charbonnel, Y. Letourneur, F. Alban et al., Métiers, effort and catches of a Mediterranean small-scale coastal fishery: The case of the Côte Bleue Marine Park, Fish. Res, vol.154, pp.93-101, 2014.

C. Li and W. Cai, On the calculation of eddy diffusivity in the shelf water from radium isotopes: High sensitivity to advection, J. Mar. Syst, vol.86, pp.28-33, 2011.

W. Ludwig, E. Dumont, M. Meybeck, and S. Heussner, River discharges of water and nutrients to the Mediterranean and Black Sea: Major drivers for ecosystem changes during past and future decades?, Prog. Oceanogr, vol.80, pp.199-217, 2009.

,

F. T. Manheim, D. E. Krantz, and J. F. Bratton, Studying ground water under Delmarva coastal bays using electrical resistivity, Ground Water, vol.42, pp.1052-1068, 2004.

M. Mejías, B. J. Ballesteros, C. Antón-pacheco, J. A. Domínguez, J. Garcia-orellana et al., Methodological study of submarine groundwater discharge from a karstic aquifer in the Western Mediterranean Sea, J. Hydrol, vol.464, issue.465, pp.27-40, 2012.

H. A. Michael, A. E. Mulligan, and C. F. Harvey, Seasonal oscillations in water exchange between aquifers and the coastal ocean, Nature, vol.436, pp.1145-1148, 2005.

,

B. Mijatovi?, The groundwater discharge in the Mediterranean karst coastal zones and freshwater tapping: set problems and adopted solutions. Case studies, Environ. Geol, vol.51, pp.737-742, 2006.

C. Millot and L. Wald, The effect of Mistral wind on the Ligurian current near Provence, Oceanol. Acta, vol.3, pp.399-402, 1980.
URL : https://hal.archives-ouvertes.fr/hal-00463850

W. S. Moore, Inappropriate attempts to use distributions of 228Ra and 226Ra in coastal waters to model mixing and advection rates, Cont. Shelf Res, vol.105, pp.95-100, 2015.

W. S. Moore, The Effect of Submarine Groundwater Discharge on the Ocean, Annu. Rev. Mar. Sci, vol.2, pp.59-88, 2010.

W. S. Moore, Fifteen years experience in measuring 224Ra and 223Ra by delayedcoincidence counting, Mar. Chem, vol.109, pp.188-197, 2008.

,

W. S. Moore, Ages of continental shelf waters determined from 223Ra and 224Ra, J. Geophys. Res. Oceans, vol.105, pp.22117-22122, 2000.

W. S. Moore, Determining coastal mixing rates using radium isotopes, Cont. Shelf Res, vol.20, 1993.

W. S. Moore, The subterranean estuary: a reaction zone of ground water and sea water, Mar. Chem, vol.65, pp.14-20, 1999.

W. S. Moore, High fluxes of radium and barium from the mouth of the Ganges-Brahmaputra River during low river discharge suggest a large groundwater source, Earth Planet. Sci. Lett, vol.150, pp.83-89, 1997.

W. S. Moore, Using the radium quartet for evaluating groundwater input and water exchange in salt marshes, Geochim. Cosmochim. Acta, vol.60, pp.4645-4652, 1996.

W. S. Moore, Radium 228 in the South Atlantic Bight, J. Geophys. Res. Oceans, vol.92, pp.5177-5190, 1987.

W. S. Moore, Sampling 228Ra in the deep ocean, Deep Sea Res. Oceanogr. Abstr, vol.23, pp.90007-90010, 1976.

W. S. Moore and R. Arnold, Measurement of 223Ra and 224Ra on coastal waters using a delayed coincidence counter, J. Geophys. Res. Oceans, vol.101, pp.1321-1329, 1996.

W. S. Moore and P. Cai, Calibration of RaDeCC systems for 223Ra measurements, Mar. Chem, vol.156, pp.130-137, 2013.

W. S. Moore and D. F. Reid, Extraction of radium from natural waters using manganeseimpregnated acrylic fibers, J. Geophys. Res, vol.78, pp.8880-8886, 1973.

,

W. S. Moore, J. L. Sarmiento, and R. M. Key, Submarine groundwater discharge revealed by 228 Ra distribution in the upper Atlantic Ocean, Nat. Geosci, vol.1, pp.309-311, 2008.

W. S. Moore and T. J. Shaw, Fluxes and behavior of radium isotopes, barium, and uranium in seven Southeastern US rivers and estuaries, Mar. Chem, vol.108, pp.236-254, 2008.

N. Moosdorf and T. Oehler, Societal use of fresh submarine groundwater discharge: An overlooked water resource, Earth-Sci. Rev, vol.171, pp.338-348, 2017.

,

S. Nakada, J. Yasumoto, M. Taniguchi, and T. Ishitobi, Submarine groundwater discharge and seawater circulation in a subterranean estuary beneath a tidal flat, Hydrol. Process, vol.25, pp.2755-2763, 2011.

J. Á. Navarro, P. C. López, and A. Perez-garcia, Evaluation of geothermal flow at the springs in Aragon (Spain), and its relation to geologic structure, Hydrogeol. J, vol.12, pp.601-609, 2004.

R. Nickson, J. Mcarthur, W. Burgess, K. M. Ahmed, P. Ravenscroft et al., Arsenic poisoning of Bangladesh groundwater, Nature, vol.395, pp.338-338, 1998.

L. F. Niencheski, H. L. Windom, W. S. Moore, and R. A. Jahnke, Submarine groundwater discharge of nutrients to the ocean along a coastal lagoon barrier, Southern Brazil, Mar. Chem, vol.106, pp.546-561, 2007.

P. Ollivier, C. Claude, O. Radakovitch, and B. Hamelin, TIMS measurements of 226Ra and 228Ra in the Gulf of Lion, an attempt to quantify submarine groundwater discharge, Mar. Chem, vol.109, pp.337-354, 2008.
URL : https://hal.archives-ouvertes.fr/hal-01061563

F. Orton and C. R. Tyler, Do hormone-modulating chemicals impact on reproduction and development of wild amphibians?, Biol. Rev, vol.90, pp.1100-1117, 2015.

,

H. W. Paerl, Coastal eutrophication and harmful algal blooms: Importance of atmospheric deposition and groundwater as "new" nitrogen and other nutrient sources, Limnol. Oceanogr, vol.42, pp.1154-1165, 1997.

R. J. Paulsen, C. F. Smith, D. O&apos;rourke, and T. F. Wong, Development and evaluation of an ultrasonic ground water seepage meter, Ground Water, vol.39, pp.904-911, 2001.

A. Pavlidou, V. P. Papadopoulos, I. Hatzianestis, N. Simboura, D. Patiris et al., Chemical inputs from a karstic submarine groundwater discharge (SGD) into an oligotrophic Mediterranean coastal area, Sci. Total Environ. 488, vol.489, pp.1-13, 2014.

A. Paytan, G. G. Shellenbarger, J. H. Street, M. E. Gonneea, K. Davis et al., Submarine groundwater discharge: An important source of new inorganic nitrogen to coral reef ecosystems, Limnol. Oceanogr, vol.51, pp.343-348, 2006.

F. Pearce and A. J. Crivelli, Characteristics of Mediterranean wetlands, Tour du Valat, 1994.

M. Polemio, D. Casarano, and P. P. Limoni, Karstic aquifer vulnerability assessment methods and results at a test site, Nat. Hazards Earth Syst. Sci, 2009.

D. Porcelli and P. W. Swarzenski, The Behavior of U-and Th-series Nuclides in Groundwater, Rev. Mineral. Geochem, vol.52, pp.317-361, 2003.

M. Pujo-pay, P. Conan, and P. Raimbault, Excretion of dissolved organic nitrogen by phytoplankton assessed by wet oxidation and 1 5 tr~acer procedures, Mar. Ecol. Prog. Ser, vol.153, pp.99-111, 1997.

M. Rama and W. S. , Using the radium quartet for evaluating groundwater input and water exchange in salt marshes, Geochim. Cosmochim. Acta, vol.60, pp.4645-4652, 1996.

J. Rapaglia, E. Di-sipio, H. Bokuniewicz, G. Maria-zuppi, L. Zaggia et al., Groundwater connections under a barrier beach: A case study in the Venice Lagoon, Cont. Shelf Res, vol.30, pp.119-126, 2010.

C. Robinson, L. Li, and H. Prommer, Tide-induced recirculation across the aquifer-ocean interface, Water Resour. Res, p.43, 2007.

C. Rocha, J. Wilson, J. Scholten, and M. Schubert, Retention and fate of groundwater-borne nitrogen in a coastal bay, Biogeochemistry, vol.125, pp.275-299, 2015.

V. Rocher, R. Mailler, J. Gaspéri, Y. Coquet, F. Nauleau et al., Élimination des polluants émergents dans les rejets de STEP 17, 2016.

V. Rodellas, J. Garcia-orellana, P. Masqué, M. Feldman, and Y. Weinstein, Submarine groundwater discharge as a major source of nutrients to the Mediterranean Sea, Proc. Natl. Acad. Sci, vol.112, pp.3926-3930, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01818173

V. Rodellas, J. Garcia-orellana, A. Tovar-sánchez, G. Basterretxea, J. M. López-garcia et al., Submarine groundwater discharge as a source of nutrients and trace metals in a Mediterranean bay, Mar. Chem, vol.160, pp.56-66, 2014.
URL : https://hal.archives-ouvertes.fr/hal-01818181

,

V. Rodellas, J. Garcia-orellana, G. Trezzi, P. Masqué, T. C. Stieglitz et al., Using the radium quartet to quantify submarine groundwater discharge and porewater exchange, Geochim. Cosmochim. Acta, vol.196, pp.58-73, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01765456

V. Rodellas, T. C. Stieglitz, A. Andrisoa, P. G. Cook, P. Raimbault et al., Groundwater-driven nutrient inputs to coastal lagoons: The relevance of lagoon water recirculation as a conveyor of dissolved nutrients, Sci. Total Environ, vol.642, pp.764-780, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01818604

T. Röper, J. Greskowiak, and G. Massmann, Detecting Small Groundwater Discharge Springs Using Handheld Thermal Infrared Imagery, vol.52, pp.936-942, 2014.

F. Sanchez and M. J. Rodriguez-alvarez, Effect of pH, temperature, conductivity and sediment size on thorium and radium activities along Jucar River (Spain), J. Radioanal. Nucl. Chem, vol.242, pp.671-681, 1999.

I. R. Santos, W. C. Burnett, T. Dittmar, I. G. Suryaputra, and J. Chanton, Tidal pumping drives nutrient and dissolved organic matter dynamics in a Gulf of Mexico subterranean estuary, Geochim. Cosmochim. Acta, vol.73, pp.1325-1339, 2009.

,

I. R. Santos, B. D. Eyre, and M. Huettel, The driving forces of porewater and groundwater flow in permeable coastal sediments: A review, Estuar. Coast. Shelf Sci, vol.98, pp.1-15, 2012.

I. R. Santos, W. C. Burnett, J. Chanton, B. Mwashote, I. G. Suryaputra et al., Nutrient biogeochemistry in a Gulf of Mexico subterranean estuary and groundwater-derived fluxes to the coastal ocean, Limnol. Oceanogr, vol.53, pp.705-718, 2008.

J. Sharples, J. J. Middelburg, K. Fennel, and T. D. Jickells, What proportion of riverine nutrients reaches the open ocean?, Glob. Biogeochem. Cycles, vol.31, pp.39-58, 2017.

G. G. Shellenbarger, S. G. Monismith, A. Genin, and A. Paytan, The importance of submarine groundwater discharge to the near shore nutrient supply in the Gulf of Aqaba, 2006.

, Limnol. Oceanogr, vol.51, pp.1876-1886

E. Sholkovitz, C. Herbold, and M. Charette, An automated dye-dilution based seepage meter for the time-series measurement of submarine groundwater discharge, Limnol. Oceanogr. Methods, vol.1, pp.16-28, 2003.

C. P. Slomp and P. Van-cappellen, Nutrient inputs to the coastal ocean through submarine groundwater discharge: controls and potential impact, J. Hydrol, vol.295, pp.64-86, 2004.

T. Stieglitz, J. Rapaglia, and H. Bokuniewicz, Estimation of submarine groundwater discharge from bulk ground electrical conductivity measurements, J. Geophys. Res. Oceans, vol.113, 2008.

T. C. Stieglitz, P. Van-beek, M. Souhaut, and P. G. Cook, Karstic groundwater discharge and seawater recirculation through sediments in shallow coastal Mediterranean lagoons, determined from water, salt and radon budgets, Mar. Chem., Radium and Radon Tracers in Aquatic Systems, vol.156, pp.73-84, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00984568

Y. Sun and T. Torgersen, The effects of water content and Mn-fiber surface conditions on 224Ra measurement by 220Rn emanation, Mar. Chem, vol.62, pp.299-306, 1998.

P. W. Swarzenski, U/Th series radionuclides as coastal groundwater tracers, Chem. Rev, vol.107, pp.663-674, 2007.

P. W. Swarzenski, W. C. Burnett, W. J. Greenwood, B. Herut, R. Peterson et al., Combined time-series resistivity and geochemical tracer techniques to examine submarine groundwater discharge at Dor Beach, Israel, Geophys. Res. Lett, vol.33, p.24405, 2006.

K. M. Talja, S. Kaukonen, J. Kilpi-koski, I. Malin, T. Kairesalo et al., Atrazine and Terbutryn Degradation in Deposits from Groundwater Environment within the Boreal Region in Lahti, Finland, J. Agric. Food Chem, vol.56, pp.11962-11968, 2008.

J. Tamborski, S. Bejannin, J. Garcia-orellana, M. Souhaut, C. Charbonnier et al., A comparison between water circulation and terrestriallydriven dissolved silica fluxes to the Mediterranean Sea traced using radium isotopes, Geochim. Cosmochim. Acta, vol.238, pp.496-515, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01986094

J. J. Tamborski, A. D. Rogers, H. J. Bokuniewicz, J. K. Cochran, and C. R. Young, Identification and quantification of diffuse fresh submarine groundwater discharge via airborne thermal infrared remote sensing, Remote Sens. Environ, vol.171, pp.202-217, 2015.

M. Taniguchi, W. C. Burnett, C. F. Smith, R. J. Paulsen, D. O&apos;rourke et al., Spatial and temporal distributions of submarine groundwater discharge rates obtained from various types of seepage meters at a site in the Northeastern Gulf of Mexico, Biogeochemistry, vol.66, pp.35-53, 2003.

M. Taniguchi and Y. Fukuo, Continuous Measurements of Ground-Water Seepage Using an Automatic Seepage Meter, Ground Water, vol.31, pp.675-679, 1993.

F. U. Tapia-gonzález, J. A. Herrera-silveira, and M. L. Aguirre-macedo, Water quality variability and eutrophic trends in karstic tropical coastal lagoons of the Yucatán Peninsula, Estuar. Coast. Shelf Sci, vol.76, pp.418-430, 2008.

,

T. J. Thrupp, T. J. Runnalls, M. Scholze, S. Kugathas, A. Kortenkamp et al., The consequences of exposure to mixtures of chemicals: Something from 'nothing' and 'a lot from a little' when fish are exposed to steroid hormones, Sci. Total Environ, vol.619, issue.620, pp.1482-1492, 2018.

Z. Top, L. E. Brand, R. D. Corbett, W. Burnett, and J. Chanton, Helium and Radon as Tracers of Groundwater Input into Florida Bay, J. Coast. Res, vol.17, pp.859-868, 2001.

A. Tovar-sánchez, G. Basterretxea, V. Rodellas, D. Sánchez-quiles, J. García-orellana et al., Contribution of Groundwater Discharge to the Coastal Dissolved Nutrients and Trace Metal Concentrations in Majorca Island: Karstic vs Detrital Systems, Environ. Sci. Technol, vol.48, pp.11819-11827, 2014.

D. W. Townsend, N. R. Pettigrew, and A. C. Thomas, Offshore blooms of the red tide dinoflagellate, Alexandrium sp., in the Gulf of Maine, Cont. Shelf Res, vol.21, pp.347-369, 2001.

G. Trezzi, J. Garcia-orellana, V. Rodellas, P. Masqué, E. Garcia-solsona et al., Assessing the role of submarine groundwater discharge as a source of Sr to the Mediterranean Sea, Geochim. Cosmochim. Acta, vol.200, pp.42-54, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01765462

,

G. Trezzi, J. Garcia-orellana, V. Rodellas, J. Santos-echeandia, A. Tovar-sánchez et al., Submarine groundwater discharge: A significant source of dissolved trace metals to the North Western Mediterranean Sea, Mar. Chem, vol.186, pp.90-100, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01765491

G. Trezzi, J. Garcia-orellana, J. Santos-echeandia, V. Rodellas, E. Garcia-solsona et al., The influence of a metal-enriched mining waste deposit on submarine groundwater discharge to the coastal sea, Mar. Chem, vol.178, pp.35-45, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01818169

. Unep/map, State of the Mediterranean Marine and Coastal Environment, 2012.

, Submarine groundwater discharge: management implications, measurements and effects, UNESCO, 2004.

I. Valiela, J. Costa, K. Foreman, J. M. Teal, B. Howes et al., Transport of Groundwater-Borne Nutrients from Watersheds and Their Effects on Coastal Waters, Biogeochemistry, vol.10, pp.177-197, 1990.

P. Van-beek, M. Souhaut, B. Lansard, M. Bourquin, J. Reyss et al., LAFARA: a new underground laboratory in the French Pyrénées for ultra low-level gamma-ray spectrometry, J. Environ. Radioact, vol.116, pp.152-158, 2013.

,

P. Van-beek, M. Souhaut, and J. Reyss, Measuring the radium quartet (228Ra, 226Ra, 224Ra, 223Ra) in seawater samples using gamma spectrometry, J. Environ. Radioact, vol.101, pp.521-529, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00984570

C. Vella, M. Provansal, L. Long, and M. Bourcier, Contexte géomorphologique de trois ports antiques provençaux : Fos, Les Laurons, vol.94, pp.39-46, 2000.

G. Wang, S. Wang, Z. Wang, W. Jing, G. Wang et al., Significance of Submarine Groundwater Discharge in Nutrient Budgets in Tropical Sanya Bay, China. Sustainability, vol.10, 2018.

M. D. Webb and K. W. Howard, Modeling the Transient Response of Saline Intrusion to Rising Sea-Levels, Groundwater, vol.49, pp.560-569, 2011.

I. T. Webster, G. J. Hancock, and A. S. Murray, Modelling the effect of salinity on radium desorption from sediments, Geochim. Cosmochim. Acta, vol.59, pp.141-148, 1995.

Y. Weinstein, G. Less, U. Kafri, and B. Herut, Submarine groundwater discharge in the southeastern Mediterranean (Israel), pp.360-372, 2006.

Y. Weinstein, Y. Yechieli, Y. Shalem, W. C. Burnett, P. W. Swarzenski et al., What Is the Role of Fresh Groundwater and Recirculated Seawater in Conveying Nutrients to the Coastal Ocean?, Environ. Sci. Technol, vol.45, pp.5195-5200, 2011.

,

A. D. Werner, D. W. Alcoe, C. M. Ordens, J. L. Hutson, J. D. Ward et al., Current practice and future challenges in coastal aquifer management: flux-based and trigger-level approaches with application to an Australian case study, Water Resour. Manag, vol.25, pp.1831-1853, 2011.

A. M. Wilson, W. S. Moore, S. B. Joye, J. L. Anderson, and C. A. Schutte, , 2011.

A. M. Wilson and J. T. Morris, The influence of tidal forcing on groundwater flow and nutrient exchange in a salt marsh-dominated estuary, Biogeochemistry, vol.108, pp.27-38, 2012.

J. Wilson and C. Rocha, Regional scale assessment of Submarine Groundwater Discharge in Ireland combining medium resolution satellite imagery and geochemical tracing techniques, Remote Sens. Environ, vol.119, pp.21-34, 2012.

H. Windom and F. Niencheski, Biogeochemical processes in a freshwater-seawater mixing zone in permeable sediments along the coast of Southern Brazil, Mar. Chem, vol.83, pp.121-130, 2003.

H. L. Windom, W. S. Moore, L. F. Niencheski, and R. A. Jahnke, Submarine groundwater discharge: A large, previously unrecognized source of dissolved iron to the South Atlantic Ocean, Mar. Chem, vol.102, pp.252-266, 2006.

Z. Xu, B. X. Hu, and M. Ye, Numerical modeling and sensitivity analysis of seawater intrusion in a dual-permeability coastal karst aquifer with conduit networks, Hydrol. Earth Syst. Sci, vol.22, pp.221-239, 2018.

M. Zarroca, R. Linares, V. Rodellas, J. Garcia-orellana, C. Roqué et al., Delineating coastal groundwater discharge processes in a wetland area by means of electrical resistivity imaging, 224Ra and 222Rn, Hydrol. Process, vol.28, pp.2382-2395, 2014.
URL : https://hal.archives-ouvertes.fr/hal-01818187

I. S. Zektser, L. G. Everett, and R. G. Dzhamalov, Submarine Groundwater, 2006.