, Lifecycle Greenhouse Gas Emissions of Various Electricity Generation Sources

R. Davies, Uranium 2016: Resources, Production and Demand, NEA No. 7301, Nature, vol.203, issue.4950, pp.1110-1115, 1964.

. Energy, Electricity and Nuclear Power Estimates for the Period up to 2050. IAEA-RDS-1/36, 2016.

D. S. Sholl and R. P. Lively, Seven chemical separations: to change the world: purifying mixtures without using heat would lower global energy use, emissions and pollution--and open up new routes to resources, Nature, vol.532, issue.7600, pp.435-438, 2016.

A. Saxena, Experiments for recovery of uranium from seawater by harnessing tidal energy, BARC Newsl, vol.249, pp.226-232, 2004.

J. Kim, Recovery of uranium from seawater: a review of current status and future research needs. Separation Science and Technology, vol.48, pp.367-387, 2013.

N. Kabay, Preparation of amidoxime-fiber adsorbents based on poly (methacrylonitrile) for recovery of uranium from seawater. Separation science and technology, vol.29, pp.375-384, 1994.

M. Kanno, Present status of study on extraction of uranium from sea water, Journal of Nuclear Science and Technology, vol.21, issue.1, pp.1-9, 1984.

R. Van-reis and A. Zydney, Membrane separations in biotechnology, Current Opinion in Biotechnology, vol.12, issue.2, pp.208-211, 2001.

F. Fan, Sorption of uranium (VI) from aqueous solution onto magnesium silicate hollow spheres, Journal of Radioanalytical and Nuclear Chemistry, vol.289, issue.2, pp.367-374, 2011.

G. A. Brennecka, Uranium isotope fractionation during adsorption to Mn-oxyhydroxides. Environmental science & technology, vol.45, pp.1370-1375, 2011.

S. Sadeghi and E. Sheikhzadeh, Solid phase extraction using silica gel modified with murexide for preconcentration of uranium (VI) ions from water samples, Journal of Hazardous Materials, vol.163, issue.2-3, pp.861-868, 2009.

G. Lefevre, S. Noinville, and M. Fédoroff, Study of uranyl sorption onto hematite by in situ attenuated total reflection-infrared spectroscopy, Journal of colloid and interface science, vol.296, issue.2, pp.608-613, 2006.

K. Lieser and B. Thybusch, Sorption of uranyl ions on hydrous titanium dioxideSorption von Uranylionen an wasserhaltigem Titandioxid. Fresenius' Zeitschrift für analytische Chemie, vol.332, pp.351-357, 1988.

T. Hori, M. Yamawaki, and M. Kanno, Uranium adsorption properties of hydrous titanium oxides in seawater, Journal of Nuclear Science and Technology, vol.24, issue.5, pp.377-384, 1987.

H. Yamashita, The collection of uranium from sea water with hydrous metal oxide. II. The mechanism of uranium adsorption on hydrous titanium (IV) oxide, Bulletin of the Chemical Society of Japan, vol.53, issue.1, pp.1-5, 1980.

H. Yamashita, The Collection of Uranium from Sea Water with Hydrous Metal Oxide. IV. Physical Properties and Uranium Adsorption of Hydrous Titanium (IV) Oxide, Bulletin of the Chemical Society of Japan, vol.53, issue.11, pp.3050-3053, 1980.

H. Yamashita, The collection of uranium from sea water with hydrous metal oxide. III. The effects of diverse ions in sea water on uranium adsorption by hydrous titanium (IV) oxide, Bulletin of the Chemical Society of Japan, vol.53, issue.5, pp.1331-1334, 1980.

M. J. Comarmond, Uranium sorption on various forms of titanium dioxide-influence of surface area, surface charge, and impurities. Environmental science & technology, vol.45, pp.5536-5542, 2011.

N. Das, Remediation of radionuclide pollutants through biosorption-an overview, CLEAN-Soil, Air, Water, vol.40, issue.1, pp.16-23, 2012.

J. Kim, Binding of uranyl ion by a DNA aptamer attached to a solid support, Bioorganic & medicinal chemistry letters, vol.21, issue.13, pp.4020-4022, 2011.

K. Chauhan and G. S. Chauhan, Separation of uranyl ions on starch-based functional hydrogels: mechanism and kinetics. Separation Science and Technology, vol.46, pp.172-178, 2010.

C. Acharya, D. Joseph, and S. Apte, Uranium sequestration by a marine cyanobacterium, Synechococcus elongatus strain BDU/75042, Bioresource technology, vol.100, issue.7, pp.2176-2181, 2009.

R. Yang, Synthesis of poly (4-vinylpyridine) and block copoly (4-vinylpyridine-b-styrene) by atom transfer radical polymerization using 5, vol.5, pp.2029-2033, 2003.

N. V. Tsarevsky, Rational selection of initiating/catalytic systems for the copper-mediated atom transfer radical polymerization of basic monomers in protic media: ATRP of 4-vinylpyridine, Macromolecules, vol.39, issue.20, pp.6817-6824, 2006.

G. T. Lewis, V. Nguyen, and Y. Cohen, Synthesis of poly (4-vinylpyridine) by reverse atom transfer radical polymerization, Journal of Polymer Science Part A: Polymer Chemistry, vol.45, issue.24, pp.5748-5758, 2007.

H. Chen, Reverse ATRP of 4-vinylpyridine with Diethyl 2, 3-Dicyano-2, 3-Diphenylsuccinate/CuCl 2/5, Materials Science and Engineering: C, vol.5, issue.5, pp.1604-1608, 2009.

J. Xia, X. Zhang, and K. Matyjaszewski, Atom transfer radical polymerization of 4-vinylpyridine, Macromolecules, vol.32, issue.10, pp.3531-3533, 1999.

W. Wang, Favorable hydrogen bonding in room-temperature Cu (0)-mediated controlled radical polymerization of 4-vinylpyridine, Polymer Chemistry, vol.3, issue.10, pp.2731-2734, 2012.

J. Qiu, Synthesis and antibacterial activity of copper-immobilized membrane comprising grafted poly (4-vinylpyridine) chains, Journal of colloid and interface science, vol.354, issue.1, pp.152-159, 2011.

T. Zhang, Surface-initiated Cu (0) mediated controlled radical polymerization (SI-CuCRP) using a copper plate, Polymer Chemistry, vol.6, issue.14, pp.2726-2733, 2015.

B. Lepoittevin, Hydrophilic PET surfaces by aminolysis and glycopolymer brushes chemistry, Journal of Polymer Science Part A: Polymer Chemistry, vol.54, issue.17, pp.2689-2697, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01822439

L. Jiang, Y. Jin, and R. K. Marcus, Polyethylenimine modified poly (ethylene terephthalate) capillary channeled-polymer fibers for anion exchange chromatography of proteins, Journal of Chromatography A, pp.200-209, 1410.

F. Lang, Surface analysis of polyethyleneterephthalate by ESCA and TOF-SIMS. Fresenius' journal of analytical chemistry, vol.358, pp.251-254, 1997.

Z. Ademovic, Surface modification of PET films using pulsed AC plasma polymerisation aimed at preventing protein adsorption. Plasma Processes and Polymers, vol.2, pp.53-63, 2005.

T. Mouhib, C60 molecular depth profiling of bilayered polymer films using ToF-SIMS. Surface and Interface Analysis, vol.43, pp.175-178, 2011.

I. Haller, Covalently attached organic monolayers on semiconductor surfaces, Journal of the American Chemical Society, vol.100, issue.26, pp.8050-8055, 1978.

J. R. Falsey, Peptide and small molecule microarray for high throughput cell adhesion and functional assays, Bioconjugate chemistry, vol.12, issue.3, pp.346-353, 2001.

N. S. Gunda, Optimization and characterization of biomolecule immobilization on silicon substrates using (3-aminopropyl) triethoxysilane (APTES) and glutaraldehyde linker, Applied Surface Science, vol.305, pp.522-530, 2014.

Z. Zhou, S. Zhu, and D. Zhang, Grafting of thermo-responsive polymer inside mesoporous silica with large pore size using ATRP and investigation of its use in drug release, Journal of Materials Chemistry, vol.17, issue.23, pp.2428-2433, 2007.

R. B. Vasani, Stimulus-responsiveness and drug release from porous silicon films ATRP-grafted with poly (N-isopropylacrylamide), Langmuir, vol.27, issue.12, pp.7843-7853, 2011.

P. Pasetto, Mechanistic insight into surface-initiated polymerization of methyl methacrylate and styrene via ATRP from ordered mesoporous silica particles, Macromolecules, vol.42, issue.16, pp.5983-5995, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00411452

V. Deline, Mechanism of the SIMS matrix effect, Applied Physics Letters, vol.33, issue.9, pp.832-835, 1978.

F. Zhang, Chemical vapor deposition of three aminosilanes on silicon dioxide: surface characterization, stability, effects of silane concentration, and cyanine dye adsorption, Langmuir, vol.26, issue.18, pp.14648-14654, 2010.

J. Li, Y. Zhou, and Z. Luo, Smart fiber membrane for pH-induced oil/water separation, ACS applied materials & interfaces, vol.7, issue.35, pp.19643-19650, 2015.

M. Gilca, Chelidonium majus-an integrative review: traditional knowledge versus modern findings, Complementary Medicine Research, vol.17, issue.5, pp.241-248, 2010.

D. Kim, The therapeutic effect of chelidonic acid on ulcerative colitis, Biological and Pharmaceutical Bulletin, vol.35, issue.5, pp.666-671, 2012.

H. Jeong, Chelidonic acid evokes antidepressant-like effect through the up-regulation of BDNF in forced swimming test, Experimental Biology and Medicine, issue.14, pp.1559-1567, 2016.

G. Zhou, 3-D hydrogen-bonded frameworks of two metal complexes with chelidamic acid: Syntheses, structures and magnetism, Bulletin of the Korean Chemical Society, vol.25, issue.5, pp.676-680, 2004.

X. Su, A dipicolinic acid tag for rigid lanthanide tagging of proteins and paramagnetic NMR spectroscopy, Journal of the American Chemical Society, vol.130, issue.32, pp.10486-10487, 2008.

M. Kondo, Self-assembling construction of a novel nanoscale heptacobalt complex with an S-shaped folding, CrystEngComm, vol.10, issue.11, pp.1516-1519, 2008.

P. M. Cantos, S. J. Pope, and C. L. Cahill, An exploration of homo-and heterometallic UO 2 2+ hybrid materials containing chelidamic acid: synthesis, structure, and luminescence studies, CrystEngComm, vol.15, issue.44, pp.9039-9051, 2013.

Z. Derikvand, Solution and solid state studies of three new supramolecular compounds of zinc (II), nickel (II) and uranium (VI) with chelidamic acid and 9-aminoacridine, Inorganica Chimica Acta, vol.406, pp.256-265, 2013.

W. Yang, Synthesis, structures, and properties of uranyl hybrids constructed by a variety of monoand polycarboxylic acids. Inorganic chemistry, vol.52, pp.12394-12402, 2013.

H. C. Aspinall, Chiral lanthanide complexes: coordination chemistry and applications, Chemical reviews, vol.102, issue.6, pp.1807-1850, 2002.

G. Howáth, A new Efficient Method for the Preparation of 2, 6-Pyridinedihiethyl Ditosylates from Dimethyl 2, 60-Pyridinedicarboxylates. Synthetic communications, vol.29, pp.3719-3731, 1999.

S. Shi and Y. Zhang, Pd (OAc) 2-catalyzed fluoride-free cross-coupling reactions of arylsiloxanes with aryl bromides in aqueous medium. The Journal of organic chemistry, vol.72, pp.5927-5930, 2007.

T. Nakamura, Efficient Formation of Luminescent Lanthanide (III) Complexes by Solid-Phase Synthesis and On-Resin Screening, Chemistry-An Asian Journal, vol.8, issue.11, pp.2685-2690, 2013.

C. P. Iglesias, Effect of a halogenide substituent on the stability and photophysical properties of lanthanide triple-stranded helicates with ditopic ligands derived from bis (benzimidazolyl) pyridine, Journal of the Chemical Society, issue.13, pp.2031-2043, 2000.

G. A. Molander and A. R. Brown, Suzuki? Miyaura Cross-Coupling Reactions of Potassium Vinyltrifluoroborate with Aryl and Heteroaryl Electrophiles. The Journal of organic chemistry, vol.71, pp.9681-9686, 2006.

A. Picot, Synthesis, structures, optical properties, and TD-DFT studies of donor-?-conjugated dipicolinic acid/ester/amide ligands, Tetrahedron, vol.64, issue.2, pp.399-411, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00369104

J. P. Mendes, Sulfolane: An efficient and universal solvent for copper-mediated atom transfer radical (co) polymerization of acrylates, methacrylates, styrene, and vinyl chloride, ACS Macro Letters, vol.3, issue.9, pp.858-861, 2014.

J. R. Góis, Improvement of the control over SARA ATRP of 2-(diisopropylamino) ethyl methacrylate by slow and continuous addition of sodium dithionite, Polymer Chemistry, vol.5, issue.16, pp.4617-4626, 2014.

G. Robil?, E. Buruian?, and A. Caraculacu, Determination of labile chlorine in PVC with the aid of phenolysis reaction, European Polymer Journal, vol.13, issue.1, pp.21-24, 1977.

Q. Yang, Synthesis of Eu (?) and Tb (?) complexes with novel pyridine dicarboxylic acid derivatives and their fluorescence properties, Journal of Central South University (Science and Technology), vol.4, p.20, 2007.

C. Tao, Pyridine-2, 6-dicarboxylic acid for the sensitization of europium (III) luminescence with very long lifetimes, vol.5, pp.58936-58942, 2015.

K. Binnemans, Interpretation of europium (III) spectra. Coordination Chemistry Reviews, vol.295, pp.1-45, 2015.

S. Lis, Luminescence spectroscopy of lanthanide (III) ions in solution, Journal of alloys and compounds, vol.341, issue.1-2, pp.45-50, 2002.

A. Barkleit, Americium (III) and europium (III) complex formation with lactate at elevated temperatures studied by spectroscopy and quantum chemical calculations, Dalton Transactions, vol.43, issue.29, pp.11221-11232, 2014.

T. Kimura, Comparative study on the hydration states of Cm (III) and Eu (III) in solution and in cation exchange resin, Journal of alloys and compounds, vol.271, pp.719-722, 1998.

J. Kim, A study of the carbonate complexation of CmIII and EuIII by time-resolved laser fluorescence spectroscopy, Journal of alloys and compounds, vol.213, pp.333-340, 1994.

C. Moulin, Uranium speciation in solution by time-resolved laser-induced fluorescence, Analytical Chemistry, vol.67, issue.2, pp.348-353, 1995.

I. Grenthe, Chemical thermodynamics of uranium, vol.1, 1992.

C. Xu, Complexation of U (VI) with dipicolinic acid: Thermodynamics and coordination modes. Inorganic chemistry, vol.52, pp.2750-2756, 2013.

V. Eliet, Characterisation of hydroxide complexes of uranium (VI) by time-resolved fluorescence spectroscopy, Journal of the Chemical Society, vol.91, issue.15, pp.2275-2285, 1995.

V. Eliet, I. Grenthe, and G. Bidoglio, Time-resolved laser-induced fluorescence of uranium (VI) hydroxocomplexes at different temperatures. Applied spectroscopy, vol.54, pp.99-105, 2000.

G. Meinrath, Lifetime and fluorescence quantum yield of uranium (VI) species in hydrolyzed solutions, Journal of alloys and compounds, vol.300, pp.107-112, 2000.

H. Burrows and T. Kemp, The photochemistry of the uranyl ion, Chemical Society Reviews, vol.3, issue.2, pp.139-165, 1974.

S. Sachs, V. Brendler, and G. Geipel, Uranium (VI) complexation by humic acid under neutral pH conditions studied by laser-induced fluorescence spectroscopy, Radiochimica Acta, vol.95, issue.2, pp.103-110, 2007.

U. Gabriel, Uranyl surface speciation on silica particles studied by time-resolved laser-induced fluorescence spectroscopy, Journal of colloid and interface science, vol.239, issue.2, pp.358-368, 2001.

C. N. Watanabe and M. H. Gehlen, Luminescence quenching of uranyl ion adsorbed in nafion membrane by alcohols and vinyl monomers, Journal of Photochemistry and Photobiology A: Chemistry, vol.156, issue.1, pp.65-68, 2003.

H. D. Burrows, Mechanistic studies on uranyl ion initiated photopolymerization of acrylamide. Berichte der Bunsengesellschaft für physikalische Chemie, vol.96, pp.712-717, 1992.

A. S. Ivanov, Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater, Nature communications, vol.8, issue.1, p.1560, 2017.

G. Blasse, Quenching of the luminescent state of uranium in oxides by metal ions, Journal of Inorganic and Nuclear Chemistry, vol.39, issue.8, pp.1339-1341, 1977.

E. Rifi, F. Rastegar, and J. Brunette, Uptake of cesium, strontium and europium by a poly (sodium acrylateacrylic acid) hydrogel. Talanta, vol.42, pp.811-816, 1995.

F. Macá?ek, I. S. Shaban, and L. Mátel, Cesium, strontium, europium (III) and plutonium (IV) complexes with humic acid in solution and on montmorillonite surface, Journal of radioanalytical and nuclear chemistry, vol.241, issue.3, pp.627-636, 1999.

B. Sadhu, M. Sundararajan, and T. Bandyopadhyay, Water-mediated differential binding of strontium and cesium cations in fulvic acid, The Journal of Physical Chemistry B, vol.119, issue.34, pp.10989-10997, 2015.

E. Reinoso-maset, P. J. Worsfold, and M. J. Keith-roach, Characterization techniques VI.1.1. Nuclear magnetic resonance (NMR) NMR measurements were done using Bruker's DPX250, DRX300 and AV360 spectrometers. Sample concentrations were fixed at a 10 mg/mL for 1 H-NMR and at 40 mg, Chemosphere, vol.91, issue.7, p.13, 2013.

, Size exclusion chromatography (SEC)

, SEC analysis was performed in N,N-dimethylformamide (DMF) for P4VP using a Styragel column (HR 4E, 5 µm, p.4

P. Ps, VDPM) were analyzed with THF as eluent (1 mL/min) in a ViscoGELTM column (7.8 x 300 mm, GMHH R-H) provided by Viscotek and equipped with a Waters 410 refractive index detector, molar masses and dispersities were determined using polystyrene standards

, 1 g/L) at 60°C, at a flow rate of 0.8 mL/min and a polymer concentration from 2 to 5 mg/mL. The steric exclusion was carried out on two PSS GRAM 1000 Å columns (8 x 300 mm; separation limits: 1 to 1000 kg/mol) and one PSS GRAM, PVDPM samples were analyzed in DMF (+ LiBr

, x 300 mm; separation limits: 0.1 to 10 kg/mol) coupled with three detectors (Viscotek, TDA 305): a differential refractive index (RI) detector, a viscosimeter detector and a light scattering (LS) detector (laser ? = 670 nm at 7° and 90°)

, Static water contact angle measurements (WCA)

. Styrene, VDPM monomer (147 mg), TPMA (7.5 mg), CuCl2 (0.164 mg)

, VDPM monomer (147 mg), TPMA (15 mg), CuCl2 (0.164 mg)

, Cu 0 (2 cm) were placed in a 10 mL tube. 13.4 µL of the BnCl initiator was added and the tube closed and placed in an oil bath at 60 °C. Aliquots were periodically taken to determine the monomer conversion. The reaction solution was then diluted with DCM and the polymer precipitated in MeOH

/. Styrene and . Vdpm-/-bncl,

S. Noel, Quantification of primary amine groups available for subsequent biofunctionalization of polymer surfaces, Bioconjugate chemistry, vol.22, issue.8, pp.1690-1699, 2011.