Supramolecular Coordination: Self-Assembly of Finite Two-and Three-Dimensional Ensembles, Chem. Rev, vol.111, issue.11, pp.6810-6918, 2011. ,
Ditopic Complexation and Release of Neutral Guest Molecules by a Hydrogen-Bonded "Endo-Exo" Receptor, Angew. Chem. Int. Ed, vol.44, issue.21, pp.3248-3253, 2005. ,
Molecular Basis for the Recognition of Higher Fullerenes into Ureidopyrimidinone-Cyclotriveratrylene Self-Assembled Capsules, Chem. Eur. J, vol.22, issue.38, pp.13496-13505, 2016. ,
Combining coordination and hydrogen-bonds to form arene ruthenium metalla-assemblies, J. Organomet. Chem, vol.824, pp.80-87, 2016. ,
Porous organic cages: soluble, modular and molecular pores, Nature Reviews Materials, vol.1, p.16053, 2016. ,
Porous organic cages, Nature Materials, vol.8, p.973, 2009. ,
A Permanent Mesoporous Organic Cage with an Exceptionally High Surface Area, Angew. Chem, issue.6, pp.1542-1546, 2014. ,
Coupling Metaloid-Directed SelfAssembly and Dynamic Covalent Systems as a Route to Large Organic Cages and Cyclophanes, Inorg. Chem, vol.57, issue.7, pp.3486-3496, 2018. ,
Structure relationships between bis-monodentate ligands and coordination driven self-assemblies, Coord. Chem. Rev, vol.374, pp.1-14, 2018. ,
Strategies for reversible guest uptake and release from metallosupramolecular architectures, Chem. Eur. J, vol.24, issue.56, pp.14878-14890, 2018. ,
Recent advances in the construction and applications of heterometallic macrocycles and cages, Coord. Chem. Rev, vol.344, pp.323-344, 2017. ,
Coordination-driven Nanostructures with Polyaromatic Shells ,
, Chem. Lett, vol.46, issue.2, pp.163-171, 2017.
Chiral metal-organic cages/containers (MOCs): From structural and stereochemical design to applications, Coord. Chem. Rev, 2017. ,
, Metallacyclic assembly of interlocked superstructures
, Coord. Chem. Rev, vol.333, pp.1-26, 2017.
Integrative self-sorting of coordination cages based on 'naked' metal ions, Chem. Commun, vol.53, issue.61, pp.8506-8516, 2017. ,
Structural design principles for self-assembled coordination polygons and polyhedra, Chem. Commun, issue.14, pp.1354-1379, 2013. ,
Preparation of a macrocyclic polynuclear complex ,
, NO3)8 (en = ethylenediamine, bpy = bipyridine), which recognizes an organic molecule in aqueous media, JACS, vol.1990, issue.14, pp.5645-5647
Transition Metal Based Cationic Molecular Boxes. Self-Assembly of Macrocyclic Platinum(II) and Palladium(II) Tetranuclear Complexes, JACS, vol.116, issue.11, pp.4981-4982, 1994. ,
The rational design of high symmetry coordination clusters, J. Chem. Soc, issue.8, pp.1185-1200, 1999. ,
Stepwise Construction of Heterobimetallic Cages by an Extended Molecular Library Approach, Inorg. Chem, vol.123, issue.37, pp.3507-3515, 2001. ,
Metal-directed self-assembly of two-and three-dimensional synthetic receptors ,
, Chem. Soc. Rev, vol.27, issue.6, pp.417-425, 1998.
Coordination Assemblies from a Pd(II)-Cornered Square Complex, Acc. Chem. Res, vol.38, issue.4, pp.369-378, 2005. ,
A Porphyrin Prism: Structural Switching Triggered by Guest Inclusion, Angew. Chem. Int. Ed, vol.40, issue.9, pp.1718-1721, 2001. ,
, , pp.12-12
, Heterometallic Open Molecular Box Containing Six Porphyrin Walls, Angew. Chem. Int. Ed, vol.47, issue.44, pp.8455-8459, 2008.
Strategies for the Construction of Supramolecular Compounds through Coordination Chemistry, Angew. Chem. Int. Ed, vol.40, issue.11, pp.2022-2043, 2001. ,
Development of a Coordination Chemistry-Based Approach for Functional Supramolecular Structures, Acc. Chem. Res, vol.38, issue.11, pp.825-837, 2005. ,
Heteroligated Supramolecular Coordination Complexes Formed via the Halide-Induced Ligand Rearrangement Reaction, Acc. Chem. Res, issue.12, pp.1618-1629, 2008. ,
The coordination behaviour of large natural bite angle diphosphine ligands towards methyl and 4-cyanophenylpalladium(ii) complexes, J. Chem. Soc, issue.11, pp.2308-2317, 2002. ,
A Novel Triangular Macrocyclic Compound, [(tmeda)Pt(azpy)]3(PF6)6·13H2O (tmeda: Tetramethylethylenediamine, azpy: 4,4?-Azopyridine), Chem. Lett, vol.42, issue.4, pp.374-376, 2013. ,
Self-assembled Pd6L4 cage and Pd4L4 square using hydrazide based ligands: synthesis, characterization and catalytic activity in Suzuki-Miyaura coupling reactions, RSC Advances, vol.6, issue.15, pp.12453-12460, 2016. ,
Coordination-Driven Self-Assembly of 2D-Metallamacrocycles Using a New Carbazole-Based Dipyridyl Donor: Synthesis, Characterization, and C60 Binding Study, Inorg. Chem, vol.2012, issue.8, pp.4817-4823 ,
New Insights into the Factors That Govern the Square/Triangle Equilibria of Pd(II) and Pt(II) Supramolecules. Unexpected Participation of a Mononuclear Species in the Equilibrium, Inorg. Chem, issue.20, pp.9438-9449, 2010. ,
On the structure of transition-metal-linked molecular squares, Chem. Commun, issue.13, pp.1535-1536, 1996. ,
Synthetic and Computational Studies on Factors Controlling Structures of Molecular Triangles and Squares and Their Equilibrium in Solutions, Inorg. Chem, issue.4, pp.2008-2015, 2010. ,
Cavity-promoted Diels-Alder Reactions of Unsubstituted Naphthalene: Fine Reactivity Tuning by Cavity Shrinkage, Chem. Lett, issue.8, pp.1095-1097, 2015. ,
Room-Temperature and Solution-State Observation of the Mixed-Valence Cation Radical Dimer of Tetrathiafulvalene, [(TTF)2]+?, within a Self-Assembled Cage, JACS, vol.127, issue.39, pp.13456-13457, 2005. ,
Self-organization of dipyridylcalix[4]pyrrole into a supramolecular cage for dicarboxylates, vol.6, pp.19794-19796, 2016. ,
Self-assembly of metal-organic hybrid nanoscopic rectangles ,
, Dalton Transactions, issue.24, pp.2542-2546, 2007.
Tripodal oxazoline-based homochiral coordination cages with internal binding sites, Chem. Commun, issue.10, pp.1136-1138, 2006. ,
A Self-Assembled Homooxacalix[3]arene-based Dimeric Capsule Constructed by a PdII?Pyridine Interaction Which Shows a Novel Chiral Twisting Motion in Response to Guest Inclusion, JACS, vol.123, issue.17, pp.3872-3877, 2001. ,
Cation-Anion Arrangement Patterns in Self-Assembled Pd2L4 and Pd4L8 Coordination Cages, Acc. Chem. Res, vol.50, issue.9, pp.2233-2243, 2017. ,
Supramolecular exofunctionalized palladium cages: fluorescent properties and biological activity, Dalton Transactions, vol.45, issue.20, pp.8556-8565, 2016. ,
Self-Assembly of a Pd4L8 Double-Walled Square Partly Takes Place Through the Formation of Kinetically Trapped Species, Eur. J. Inorg. Chem, issue.10, pp.1192-1197, 2018. ,
Adaptive self-assembly and inducedfit transformations of anion-binding metal-organic macrocycles, Nature Communications, vol.8, p.15898, 2017. ,
Polyaromatic molecular peanuts, Nature Communications, vol.8, p.15914, 2017. ,
SelfAssembly of M30L60 Icosidodecahedron, Chem, vol.2016, issue.1, pp.91-101 ,
,
, Metallosupramolecular Cages: Synthesis, Structures and Guest-Encapsulation Studies, Chem. Eur. J, vol.2017, issue.60, pp.15089-15097
Giant hollow MnL2n spherical complexes: structure, functionalisation and applications, Chem. Commun, issue.60, pp.6703-6712, 2013. ,
The use of dimetal building blocks in convergent syntheses of large arrays, Proceedings of the National Academy of Sciences, issue.8, pp.4810-4813, 2002. ,
Self-assembly and anion sensing of metalorganic [M6L2] cages from fluorescent triphenylamine tri-pyrazoles with dipalladium ,
, Dalton Transactions, 2017.
Construction of half-sandwich rhodium-and iridium-based metallamacrocycles with different space conformations via isomeric pyridyl-substituted ligands, J. Coord. Chem, vol.2018, pp.1-12 ,
Arene Ruthenium Cages: Boxes Full of Surprises, Eur. J. Inorg. Chem, issue.17, pp.2445-2453, 2009. ,
Coordination-driven self-assembly of ruthenium(II) architectures: Synthesis, characterization and cytotoxicity studies, Dalton Transactions, vol.47, pp.8466-8475, 2018. ,
Self-Assembly of Chiral Metallacycles and Metallacages from a Directionally Adaptable BINOL-Derived Donor, JACS, vol.2015, issue.37, pp.11896-11899 ,
Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages, JACS, vol.140, issue.22, pp.7005-7011, 2018. ,
Platinum(II)-Based Convex Trigonal-Prismatic Cages via Coordination-Driven SelfAssembly and C60 Encapsulation, Inorg. Chem, vol.2017, issue.20, pp.12498-12504 ,
Covalent Organic Frameworks and Cage Compounds: Design and Applications of Polymeric and Discrete Organic Scaffolds, Angew. Chem. Int. Ed, vol.57, issue.18, pp.8285-8289, 2018. ,
Donor-sitedirected Rational Assembly of Heteroleptic cis-[Pd2L2L?2] Coordination Cages from Picolyl Ligands, Chem. Eur. J, vol.24, issue.49, pp.12976-12982, 2018. ,
The nature of the mechanical bond : from molecules to machines, 2017. ,
Switching Devices Based on Interlocked Molecules, Acc. Chem. Res, vol.34, issue.6, pp.433-444, 2001. ,
Light powered molecular machines, Chem. Soc. Rev, vol.38, issue.6, pp.99-122, 2009. ,
Interlocking of molecular threads: from the statistical approach to the templated synthesis of catenands, Chem. Rev, vol.87, issue.4, pp.795-810, 1987. ,
Active metal template synthesis of rotaxanes, catenanes and molecular shuttles, Chem. Soc. Rev, vol.38, issue.6, pp.1530-1541, 2009. ,
Topologically complex molecules obtained by transition metal templation: it is the presentation that determines the synthesis strategy, New J. Chem, vol.37, issue.1, pp.49-57, 2013. ,
Template routes to interlocked molecular structures and orderly molecular entanglements, Coord. Chem. Rev, pp.5-52, 0202. ,
A Quadruply Stranded Metallohelicate and Its Spontaneous Dimerization into an Interlocked Metallohelicate, Angew. Chem. Int. Ed, vol.47, issue.4, pp.706-710, 2008. ,
Anion-Directed Formation and Degradation of an Interlocked Metallohelicate, JACS, vol.2012, issue.26, pp.10987-10997 ,
Stepwise Halide-Triggered Double and Triple Catenation of Self-Assembled Coordination Cages, Angew. Chem. Int. Ed, vol.54, issue.9, pp.2796-2800, 2015. ,
Coordination-Driven Self-Assembly Using Ditopic Pyridyl-Pyrazolyl Donor and p-Cymene Ru(II) Acceptors: [2]Catenane Synthesis and Anticancer Activities, Inorg. Chem, vol.2017, issue.14, pp.8430-8438 ,
Template-Free Synthesis of a Molecular Solomon Link by Two-Component Self-Assembly, Angew. Chem. Int. Ed, vol.55, issue.6, pp.2007-2011, 2016. ,
,
, Metallosupramolecular Cages: Synthesis, Structures and Guest-Encapsulation Studies, Chem. Eur. J, vol.2017, issue.60, pp.15089-15097
Preparation of Highly Fluorescent Host-Guest Complexes with Tunable Color upon Encapsulation, JACS, vol.2015, issue.29, pp.9266-9269 ,
Selective Co-Encapsulation Inside an M6L4 Cage, Chem. Eur. J, vol.22, issue.43, pp.15468-15474, 2016. ,
Highly selective CO2vs. N2 adsorption in the cavity of a molecular coordination cage, Chem. Commun, vol.2017, issue.31, pp.4398-4401 ,
Excellent Correlation between Drug Release and Portal Size in Metalla-Cage Drug-Delivery Systems, Chem. Eur. J, vol.17, issue.35, pp.9669-9677, 2011. ,
Reversible guest exchange mechanisms in supramolecular hostguest assemblies, Chem. Soc. Rev, vol.36, issue.2, pp.161-171, 2007. ,
Multiaddressable molecular rectangles with reversible host-guest interactions: Modulation of pH-controlled guest release and capture, Proceedings of the National Academy of Sciences, vol.112, issue.3, pp.690-695, 2015. ,
Light-Triggered Crystallization of a Molecular Host?Guest Complex, JACS, vol.2010, issue.29, pp.9973-9975 ,
Light-Controlled Interconversion between a Self-Assembled Triangle and a Rhombicuboctahedral Sphere, Angew. Chem. Int. Ed, vol.55, issue.1, pp.445-449, 2016. ,
LightTriggered Guest Uptake and Release by a Photochromic Coordination Cage, Angew. Chem. Int. Ed, vol.52, issue.4, pp.1319-1323, 2013. ,
, Stepwise Assembly
, Nanoscale Rhombododecahedral Metal-Organic Cages via Metalloligand Strategy for Guest Trapping and Protection, JACS, vol.2014, issue.12, pp.4456-4459
Alkane Oxidation via Photochemical Excitation of a Self-Assembled Molecular Cage, JACS, vol.126, issue.30, pp.9172-9173, 2004. ,
The Promise of Self-Assembled 3D Supramolecular Coordination Complexes for Biomedical Applications, Inorg. Chem, vol.56, issue.24, pp.14715-14729, 2017. ,
The "Complex-ina-Complex" Cations [(acac)2M?Ru6(p-iPrC6H4Me)6(tpt)2(dhbq)3]6+: A Trojan Horse for Cancer Cells, Angew. Chem. Int. Ed, vol.47, issue.20, pp.3773-3776, 2008. ,
Stimuli-responsive Pd2L4 metallosupramolecular cages: towards targeted cisplatin drug delivery, Chemical Science, vol.2012, issue.3, pp.778-784 ,
Bioconjugation strategies to couple supramolecular exo-functionalized palladium cages to peptides for biomedical applications, Chem. Commun, vol.2017, issue.8, pp.1405-1408 ,
Ruthenium(II) p-cymene complexes of naphthoquinone derivatives as antitumor agents: A structure?activity relationship study, J. Organomet. Chem, vol.822, pp.211-220, 2016. ,
Cytotoxic double arene ruthenium metalla-cycles that overcome cisplatin resistance, J. Organomet. Chem, vol.803, pp.39-44, 2016. ,
, Anticancer Activity and Autophagy Involvement of Self-Assembled Arene-Ruthenium Metallacycles, vol.2015, pp.4507-4514
Self-assembled metalla-rectangles bearing azodipyridyl ligands: synthesis, characterization and antitumor activity, Dalton Transactions, vol.42, issue.2, pp.466-475, 2013. ,
, Biomedical and Biochemical Applications of Self-Assembled Metallacycles and Metallacages. Acc. Chem. Res, vol.46, issue.11, pp.2464-2474, 2013.
Coordination-Driven Self-Assembly of Ionic Irregular Hexagonal Metallamacrocycles via an Organometallic Clip and Their Cytotoxicity Potency, Inorg. Chem, vol.57, issue.7, pp.3615-3625, 2018. ,
Biologically active [Pd2L4]4+ quadruply-stranded helicates: stability and cytotoxicity, Dalton Transactions, vol.44, issue.24, pp.11129-11136, 2015. ,
,
, Ionic Hexagonal Macrocycle and Its Antiproliferative Activity. Frontiers in Chemistry, vol.6, p.87, 2018.
Advantages of Catalysis in Self-Assembled Molecular Capsules ,
, Chem. Eur. J, vol.22, issue.27, pp.9060-9066, 2016.
Functional Capsules via Subcomponent SelfAssembly, Acc. Chem. Res, vol.51, issue.10, pp.2423-2436, 2018. ,
Nucleophilic Substitution Catalyzed by a Supramolecular Cavity Proceeds with Retention of Absolute Stereochemistry, JACS, vol.2014, issue.41, pp.14409-14412 ,
Assembly of Encapsulated Transition Metal Catalysts, Angew. Chem. Int. Ed, vol.40, issue.22, pp.4271-4274, 2001. ,
Terpene cyclization catalysed inside a self-assembled cavity, Nature Chemistry, vol.7, 0197. ,
Acid Catalysis in Basic Solution: A Supramolecular Host Promotes Orthoformate Hydrolysis, Science, issue.5821, pp.85-88, 2007. ,
Self-Assembled Molecular Capsule Catalyzes a Diels?Alder Reaction, JACS, vol.120, issue.29, pp.7389-7390, 1998. ,
A Self-Organizing Chemical Assembly Line, JACS, vol.2013, issue.51, pp.19143-19146 ,
A supramolecular approach to combining enzymatic and transition metal catalysis, Nature Chemistry, issue.5, p.100, 2013. ,
Metal-driven self-assembly: the case of redox-active discrete architectures, Chem. Commun, issue.34, pp.7275-7289, 2015. ,
URL : https://hal.archives-ouvertes.fr/hal-01390940
In Situ Spectroscopic, Electrochemical, and Theoretical Studies of the Photoinduced Host?Guest Electron Transfer that Precedes Unusual Host-Mediated Alkane Photooxidation, JACS, vol.131, issue.13, pp.4764-4768, 2009. ,
Encapsulation of Pt(iv) prodrugs within a Pt(ii) cage for drug delivery, Chemical Science, vol.6, issue.2, pp.1189-1193, 2015. ,
Synthesis and Electrochemical Behavior of a Zwitterion-Bridged Metalla-Cage, Organometallics, vol.33, issue.18, pp.5043-5045, 2014. ,
A New Macrocyclic Polylactam-Type Neutral Receptor for Anions ? Structural Aspects of Anion Recognition, Eur. J. Org. Chem, issue.21, pp.4031-4039, 2001. ,
Self-Assembly of Ferrocene-Functionalized Perylene Bisimide Bridging Ligands with Pt(II) Corner to Electrochemically Active Molecular Squares, JACS, vol.125, issue.32, pp.9716-9725, 2003. ,
Fluorescent and Electroactive Cyclic Assemblies from Perylene Tetracarboxylic Acid Bisimide Ligands and Metal Phosphane Triflates, Chem. Eur. J, vol.7, issue.4, pp.894-902, 2001. ,
Giant Electroactive M4L6 Tetrahedral Host SelfAssembled with Fe(II) Vertices and Perylene Bisimide Dye Edges, JACS, vol.2013, issue.41, pp.15656-15661 ,
Bioorganometallic Chemistry of Ferrocene, Chem. Rev, vol.104, issue.12, pp.5931-5986, 2004. ,
Construction of multiferrocenyl metallacycles and metallacages via coordination-driven self-assembly: from structure to functions, Chem. Soc. Rev, vol.44, issue.8, pp.2148-2167, 2015. ,
Synthesis of a New Family of Hexakisferrocenyl Hexagons and Their Electrochemical Behavior, The Journal of Organic Chemistry, vol.73, issue.21, pp.8553-8557, 2008. ,
A New Family of Multiferrocene Complexes with Enhanced Control of Structure and Stoichiometry via Coordination-Driven Self-Assembly and Their Electrochemistry, JACS, vol.130, issue.3, pp.839-841, 2008. ,
Facile Self-Assembly of Supramolecular Hexakisferrocenyl Triangles via CoordinationDriven Self-Assembly and Their Electrochemical Behavior, Organometallics, vol.30, issue.13, pp.3637-3642, 2011. ,
Construction of Multifunctional Cuboctahedra via Coordination-Driven Self-Assembly, JACS, vol.131, issue.19, pp.6695-6697, 2009. ,
Design and Construction of EndoFunctionalized Multiferrocenyl Hexagons via Coordination-Driven Self-Assembly and Their Electrochemistry, The Journal of Organic Chemistry, vol.2012, issue.2, pp.1148-1153 ,
Self-assembly of metallomacrocycles with dipyrazole ligands and anion sensing of [Pd4Fe2] macrocycle with ferrocene-based dipyrazole ligand, Dalton Transactions, vol.42, issue.10, pp.3447-3454, 2013. ,
Self-Assembly of Heterobimetallic Neutral Macrocycles Incorporating Ferrocene Spacer Groups: Spectroelectrochemical Analysis of the Double Two-Electron Oxidation of a Molecular Rectangle, Inorg. Chem, issue.16, pp.5798-5804, 2005. ,
Synthesis and Anion Sensing of WaterSoluble Metallomacrocycles, Inorg. Chem, issue.13, pp.6055-6062, 2011. ,
Combining Ferrocenes and Molecular Squares: Self-Assembly of Heterobimetallic Macrocyclic Squares Incorporating Mixed Transition Metal Systems and a Main Group Element. Single-Crystal X-ray Structure of, Organometallics, vol.15, issue.3, pp.904-908, 1996. ,
Self-assembled molecular squares containing metal-based donor: synthesis and application in the sensing of nitro-aromatics, Dalton Transactions, vol.40, issue.13, pp.3112-3115, 2011. ,
Supramolecular Assemblies with Symmetrical Octahedral Structures -Synthesis, Characterization, and Electrochemical Properties, Eur. J. Inorg. Chem, issue.3, pp.375-380, 2013. ,
An M2L4 Molecular Capsule with a Redox Switchable Polyradical Shell, Angew. Chem. Int. Ed, vol.55, issue.48, pp.15031-15034, 2016. ,
Tuning the Redox Properties of Fullerene Clusters within a Metal-Organic Capsule, JACS, vol.2017, issue.32, pp.11008-11011 ,
Zweistufige, reversible redoxsysteme mit stabilem radikalkation, Tetrahedron Lett, issue.27, pp.2271-2274, 1969. ,
Condensation of carbon disulfide with dimethyl acetylenedicarboxylate, Tetrahedron Lett, vol.1970, issue.30, pp.2633-2636 ,
Bis-1,3-dithiolium chloride: an unusually stable organic radical cation, Journal of the Chemical Society D: Chemical Communications, issue.21, pp.1453-1454, 1970. ,
Electrical conductivity by the bis(1,3-dithiole)-bis(1,3-dithiolium) system, JACS 1972, vol.94, pp.670-672 ,
Electron transfer in a new highly conducting donor-acceptor complex, JACS, vol.1973, issue.3, pp.948-949 ,
Tetrathiafulvalene: the advent of organic metals, Chem. Commun, issue.63, pp.7025-7027, 2013. ,
Tetrathiafulvalenes as building-blocks in supramolecular chemistry, Chem. Soc. Rev, vol.23, issue.1, pp.41-51, 1994. ,
Functionalised tetrathiafulvalenes: new applications as versatile ?-electron systems in materials chemistry, J. Mater. Chem, vol.10, issue.3, pp.589-598, 2000. ,
New Concepts in Tetrathiafulvalene Chemistry, Angew. Chem. Int. Ed, vol.40, issue.8, pp.1372-1409, 2001. ,
Magnetic Molecular Conductors, Chem. Rev, vol.104, issue.11, pp.5419-5448, 2004. ,
Tetrathiafulvalene (TTF) derivatives: key building-blocks for switchable processes, Chem. Commun, issue.17, pp.2245-2269, 2009. ,
Linearly extended ?-donors: when tetrathiafulvalene meets conjugated oligomers and polymers, J. Mater. Chem, vol.7, issue.12, pp.2307-2321, 1997. ,
Salts of extended tetrathiafulvalene analogues: relationships between molecular structure, electrochemical properties and solid state organisation, Chem. Soc. Rev, vol.34, issue.1, pp.69-98, 2005. ,
?-Extended TTF: a versatile molecule for organic electronics, J. Mater. Chem, vol.2012, issue.10, pp.4188-4205 ,
Supramolecular chemistry of ?-extended analogues of TTF and carbon nanostructures, New J. Chem, vol.33, issue.2, pp.228-234, 2009. ,
A BPTTF-based selfassembled electron-donating triangle capable of C60 binding, Chem. Commun, vol.2012, issue.25, pp.3106-3108 ,
A self-assembled bis(pyrrolo)tetrathiafulvalene-based redox active square, New J. Chem, vol.35, issue.1, pp.165-168, 2011. ,
A Metal-Directed SelfAssembled Electroactive Cage with Bis(pyrrolo)tetrathiafulvalene (BPTTF) Side Walls, JACS, vol.2012, issue.29, pp.11968-11970 ,
Self-Assembled Cages from the Electroactive Bis(pyrrolo)tetrathiafulvalene (BPTTF) Building Block, Eur. J. Inorg. Chem, issue.14, pp.2440-2448, 2014. ,
Self-Assembled Containers Based on Extended Tetrathiafulvalene, JACS, vol.2013, issue.27, pp.10018-10021 ,
Reversible Guest Uptake/Release by Redox-Controlled Assembly/Disassembly of a Coordination Cage, Angew. Chem. Int. Ed, vol.55, issue.5, pp.1746-1750, 2016. ,
Neutral versus polycationic coordination cages: a comparison regarding neutral guest inclusion, Chem. Commun, vol.52, issue.65, pp.10012-10015, 2016. ,
URL : https://hal.archives-ouvertes.fr/hal-01416415
Controlling the Host-Guest Interaction Mode through a Redox Stimulus, Angew. Chem. Int. Ed, vol.2017, issue.51, pp.16272-16276 ,
Straightforward access to aryl-substituted tetrathiafulvalenes by palladium-catalysed direct C-H arylation and their photophysical and electrochemical properties, Chemical Science, vol.2, issue.10, pp.2017-2021, 2011. ,
Electron-Rich Arene-Ruthenium Metalla-architectures Incorporating TetrapyridylTetrathiafulvene Donor Moieties, Organometallics, vol.33, issue.7, pp.1651-1658, 2014. ,
A Pyrrolo-Tetrathiafulvalene Belt and Its TCNQ Complex: Syntheses and X-ray Crystal Structures, Org. Lett, issue.8, pp.1327-1330, 2002. ,
Glycoluril-tetrathiafulvalene molecular clips: on the influence of electronic and spatial properties for binding neutral accepting guests, Beilstein Journal of Organic Chemistry, vol.11, pp.1023-1036, 2015. ,
URL : https://hal.archives-ouvertes.fr/hal-01301844
The metallic state of the organic conductor TMTSF-DMTCNQ at low temperature under pressure, Journal de Physique Lettres, vol.40, issue.15, pp.381-383, 1979. ,
URL : https://hal.archives-ouvertes.fr/jpa-00231649
Molecular recognition and switching via radical dimerization, In Pure Appl. Chem, vol.82, p.2281, 2010. ,
Dimerization of Conjugated Radical Cations: An Emerging Non-Covalent Interaction for Self-Assembly, Chemistry -An Asian Journal, vol.10, issue.1, pp.56-68, 2015. ,
Spectroelectrochemistry of Electrogenerated Tetrathiafulvalene-Derivatized Poly(thiophenes): Toward a Rational Design of Organic Conductors with Mixed Conduction, The Journal of Physical Chemistry B, issue.40, pp.7776-7781, 1998. ,
Do ?-dimers of tetrathiafulvalene cation radicals really exist at room temperature?, Chem. Commun, issue.24, pp.2736-2737, 2001. ,
Molecular and Electronic Structures of the Long-Bonded ?-Dimers of Tetrathiafulvalene Cation-Radical in Intermolecular Electron Transfer and in (Solid-State) Conductivity, JACS, vol.129, issue.4, pp.828-838, 2007. ,
Stable ?-dimer of a tetrathiafulvalene cation radical encapsulated in the cavity of cucurbit[8]uril, Chem. Commun, issue.7, pp.806-807, 2004. ,
Synthesis and electrochemistry of a tetrathiafulvalene (TTF)21-glycol dendrimer: intradendrimer aggregation of TTF cation radicals, Chem. Commun, issue.4, pp.509-510, 1998. ,
Monitoring the formation of TTF dimers by Na+ complexation, Chem. Commun, issue.21, pp.2233-2235, 2006. ,
URL : https://hal.archives-ouvertes.fr/hal-00084427
Palladium Induced Macrocyclic Preorganization for Stabilization of a Tetrathiafulvalene Mixed-Valence Dimer, Org. Lett, issue.18, pp.4902-4905, 2011. ,
Face-to-Face Dimeric Tetrathiafulvalenes and Their Cation Radical and Dication Species as Models of Mixed Valence and ?-Dimer States, Bull. Chem. Soc. Jpn, vol.2012, issue.1, pp.51-60 ,
, , vol.2, p.870, 2010.
Twisted ?-Electron System Electrooptic Chromophores. Structural and Electronic Consequences of Relaxing Twist-Inducing Nonbonded Repulsions, The Journal of Physical Chemistry C, issue.21, pp.8005-8015, 2008. ,
Diffusion NMR Spectroscopy in Supramolecular and Combinatorial Chemistry: An Old Parameter-New Insights, Angew. Chem. Int. Ed, vol.44, issue.4, pp.520-554, 2005. ,
, Multiple-Bridged Bis-Tetrathiafulvalenes: New Synthetic Protocols and Spectroelectrochemical Investigations, vol.122, pp.9486-9494, 2000.
,
,
,
Pyridinium Salts: Luminescent Spectroscopy and Photochemistry, Heterocycles, vol.26, issue.11, pp.2963-2982, 1987. ,
Self-Assembly of Ambidentate Pyridyl-Carboxylate Ligands with Octahedral Ruthenium Metal Centers: Self-Selection for a Single-Linkage Isomer and Anticancer-Potency Studies, Chem. Eur. J, vol.19, issue.21, pp.6709-6717, 2013. ,
Flexible arene ruthenium metalla-prisms, Inorg. Chim. Acta, vol.438, pp.5-9, 2015. ,
Self-assembly of an M6L12 coordination cube, Chem. Commun, issue.13, pp.1638-1640, 2009. ,
Scalable and Selective Dispersion of Semiconducting Arc-Discharged Carbon Nanotubes by Dithiafulvalene/Thiophene Copolymers for Thin Film Transistors, ACS Nano, vol.7, issue.3, pp.2659-2668, 2013. ,
The Interplay of Inverted Redox Potentials and Aromaticity in the Oxidized States of New ?-Electron Donors: 9-(1,3-Dithiol-2-ylidene)fluorene and 9-(1,3-Dithiol-2-ylidene)thioxanthene Derivatives, Chem. Eur. J, vol.12, issue.12, pp.3389-3400, 2006. ,
A Self-Assembled M2L4 Cage incorporating Electron-rich 9-(1,3-dithiol-2-ylidene)Fluorene Units, New J. Chem, vol.2017, issue.9, pp.3238-3241 ,
, The cavity volume has been estimated based on voidoo algorithm with ABSiCC (Automating Boring Stuff in Computational Chemistry), a homemade POVRAY-interfaced program designed by Thomas Cauchy and written by Yohann Morille
Combining High Electron Affinity and Intramolecular Charge Transfer in 1,3-Dithiole-Nitrofluorene Push-Pull Diads, Chem. -Eur. J, vol.14, issue.9, pp.2757-2770, 2008. ,
A M2L2 RedoxActive Metalla-Macrocycle Based on Electron, Fluorene. Inorganics, vol.6, issue.9, p.44, 2018. ,
Self-Assembly of Heterometallic Metallomacrocycles via Ditopic Fluoroaryl Gold(I) Organometallic Metalloligands, Organometallics, vol.2012, issue.4, pp.1533-1545 ,
Pillar height dependent formation of unprecedented Pd8 molecular swing and Pd6 molecular boat via multicomponent self-assembly, Chem. Commun, vol.2012, issue.17, pp.2298-2300 ,
Syntheses, electrochemical behaviors, spectral properties and DFT calculations of two 1,3-dithiole derivatives, Chem Res Chinese U, vol.30, issue.3, pp.425-430, 2014. ,
Review: Fullerene based acceptors for efficient bulk heterojunction organic solar cell applications, Sol. Energy Mater. Sol. Cells, vol.161, pp.102-148, 2017. ,
Redox-Driven Transformation of a Discrete Molecular Cage into an Infinite 3D Coordination Polymer, Chem. Eur. J, vol.24, issue.44, pp.11273-11277, 2018. ,
, , 2012.
Studies of Potential Inversion in an Extended Tetrathiafulvalene, Langmuir, vol.22, issue.25, pp.10683-10688, 2006. ,
The Interplay of Inverted Redox Potentials and Aromaticity in the Oxidized States of New ?-Electron Donors: 9-(1,3-Dithiol-2-ylidene)fluorene and 9-(1,3-Dithiol-2-ylidene)thioxanthene Derivatives, Chem. Eur. J, vol.12, issue.12, pp.3389-3400, 2006. ,
Self-assembled M24L48 polyhedra and their sharp structural switch upon subtle ligand variation, Science, vol.2010, issue.5982, pp.1144-1151 ,
, The cavity volume has been estimated based on voidoo algorithm with ABSiCC (Automating Boring Stuff in Computational Chemistry), a homemade POVRAY-interfaced program designed by Thomas Cauchy and written by Yohann Morille
Controlling the Host-Guest Interaction Mode through a Redox Stimulus, Angew. Chem. Int. Ed, vol.2017, issue.51, pp.16272-16276 ,
Functional coordination polymers based on redox-active tetrathiafulvalene and its derivatives, Coord. Chem. Rev, vol.2017, pp.342-361 ,
Tuning the electronic properties and the planarity degree in the ?-extended TTF series: the prominent role of heteroatoms, Journal of Materials Chemistry C, vol.6, issue.48, pp.13190-13196, 2018. ,
Highly conjugated [?]-electron donors for organic metals: synthesis and redox chemistry of new 1,3-dithiole and 1,3-selenathiole derivatives, J. Chem. Soc., Perkin Trans. 1, vol.0, issue.1, pp.157-168, 1991. ,
Electrical and Magnetic Properties and X-Ray Structure of a Highly Conductive 4:1 Complex of Tetracyanoquinodimethane and a Tetrathiafulvalene Derivative, Angew. Chem. Int. Ed, vol.29, issue.12, pp.1450-1452, 1990. ,
p-Quinodimethane Analogues of Tetrathiafulvalene, Angew. Chem. Int. Ed, vol.28, issue.8, pp.1052-1053, 1989. ,
A new highly-conjugated TTF analogue: Synthesis, electrochemistry and a conducting TCNQ complex of 9, vol.10 ,
, Synth. Met, vol.25, issue.2, pp.203-205, 1988.
pi-Extended TTF: a versatile molecule for organic electronics, J. Mater. Chem, vol.2012, issue.10, pp.4188-4205 ,
Bis-and Tris-fused Tetrathiafulvalenes Extended with Anthracene-9,10-diylidene, Org. Lett, vol.18, issue.22, pp.5868-5871, 2016. ,
Highly [small pi]-extended tetrathiafulvalene analogues derived from pentacene-5, vol.7, pp.88821-88825, 2015. ,
Mixed valence radical cations and intermolecular complexes derived from indenofluorene-extended tetrathiafulvalenes, J. Mater. Chem. C, vol.2014, issue.48, pp.10428-10438 ,
Diindenothienoacene-tetrathiafulvalene redox systems, RSC Adv, vol.2015, issue.61, pp.49748-49751 ,
Expanded Indacene-Tetrathiafulvalene Scaffolds: Structural Implications for Redox Properties and Association Behavior, Chem. Eur. J, vol.2017, issue.53, pp.13120-13130 ,
Tetraceno[2,1,12,11-opqra]tetracene-extended tetrathiafulvalene -redox-controlled generation of a large PAH core, Org. Biomol. Chem, vol.2017, issue.4, pp.807-811 ,
Superextended Tetrathiafulvalene: Synthesis, Optoelectronic Properties, Fullerenes Complexation, and Photooxidation Study, J. Org. Chem, vol.80, issue.13, pp.6767-6775, 2015. ,
To bend or not to bend -are heteroatom interactions within conjugated molecules effective in dictating conformation and planarity? Mater. Horiz, vol.3, pp.333-339, 2016. ,
New vinylogous tetrathiafulvalene (TTF) ?-electron donors, Tetrahedron Lett, issue.10, pp.1373-1376, 1992. ,
Crystal structure of 9, Act. Cryst. E, vol.1, issue.9, pp.1475-1479 ,
URL : https://hal.archives-ouvertes.fr/hal-01486142
Donor-?-Acceptor Species Derived from Functionalised 1,3-Dithiol-2-ylidene Anthracene Donor Units Exhibiting Photoinduced Electron Transfer Properties: Spectroscopic, Electrochemical, XRay Crystallographic and Theoretical Studies, Chem. Eur. J, vol.4, issue.12, pp.2580-2592, 1998. ,
Intramolecular Electronic Interactions in Conjugated Ferrocene??-Extended-Tetrathiafulvalene Donor-?-Donor Molecular Hybrids, J. Org. Chem, issue.26, pp.9092-9102, 2000. ,
Nonplanar bis(1,3-dithiole) donors affording novel cation radical salts, Adv. Mater, vol.6, issue.4, pp.295-298, 1994. ,
Prediction of the stoichiometry of cation radical salts of organic metals by thin layer cyclic voltammetry, Adv. Mater, vol.5, issue.6, pp.445-447, 1993. ,
Redox-Driven Transformation of a Discrete Molecular Cage into an Infinite 3D Coordination Polymer, Chem. Eur. J, vol.24, issue.44, pp.11273-11277, 2018. ,
10-dihydroanthracene System: Generation and Characterisation of the Radical Cation, Dication, and Derived Products, Photochemistry of the ?-Extended, vol.9, pp.973-978, 2001. ,
Synthesis, Optical Properties, and Electronic Structures of Fully Core-Modified Porphyrin Dications and Isophlorins, Chem. Eur. J, vol.2012, issue.42, pp.13361-13371 ,
THE STRUCTURES OF TWO DERIVATIVES OF THE 2-(1,3-DITHIOL-2-YLIDENEMETHYL)-1,3-DITHIOLIUM CATION. Phosphorus, Sulfur, and Silicon and the Related Elements, vol.122, pp.313-324, 1997. ,
Porphyrinoid Macrocycles Based on Thiophene-The Octaethyltetrathiaporphyrin Dication, Angew. Chem. Int. Ed, vol.35, pp.1520-1524, 1996. ,
2-(Thiopyran-4[prime or minute]-yliden)-1,3-dithioles fused with thiophene units: intramolecular S [three dots, centered] S interaction affecting the redox properties and molecular geometries, J. Chem. Soc., Chem. Commun, issue.12, pp.1431-1432, 1994. ,
Mono-, di-and tetra-nuclear pcymeneruthenium complexes containing oxalato ligands, J. Chem. Soc, vol.22, pp.4345-4350, 1997. ,
Designing the HostGuest Properties of Tetranuclear Arene Ruthenium Metalla-Rectangles to Accommodate a Pyrene Molecule, Eur. J. Inorg. Chem, issue.5, pp.725-728, 2010. ,
Vacuum-processable laddertype oligophenylenes for organic-inorganic hybrid structures: synthesis, optical and electrochemical properties upon increasing planarization as well as thin film growth, J. Mater. Chem, vol.2012, issue.10, pp.4383-4390 ,
, Spectroelectrochemistry for self-assembly ??1
, ? NMR for self-assembly ??2 in acetone-d6
, Annex 3.2. 1 ? NMR for self-assembly ??3 in DMSO-d6
, Annex 3.3. 1 ? NMR for self-assembly ??6 in CD2Cl2
, COSY NMR for self-assembly ??6
, COSY NMR for self-assembly ??6 -aromatic region
, Annex 3.6. 1 ? NMR for self-assembly ??4 in CD2Cl2
, C NMR for self-assembly ??4 in CD2Cl2
,
, COSY NMR for self-assembly ??8 in CD3OD
, Annex 3.10. 1 ? NMR for self-assembly ??10 in CD3OD
, Annex 3.11. COSY NMR for self-assembly ??10 in CD3OD
, Annex 3.12. ROESY NMR for self-assembly ??10 in CD3OD
, Annex 3.13. 1 ? NMR for self-assembly ??11 in CD3OD
, COSY NMR for self-assembly ??11 in CD3OD
, Annex 3.15. ROESY NMR for self-assembly ??11 in CD3OD
, Annex 3.16. 1 ? NMR for self-assembly ??12 in CD3CN
, Annex 3.17. COSY NMR for self-assembly ??12 in CD3CN
, Annex 3.18. ROESY NMR for self-assembly ??12 in CD3CN
, Annex 3.19. 1 ? NMR for self-assembly ??10 in different solvents
, Annex 3.20. Fit for association constant using NMR data for self-assembly ??11
, Annex 3.21. 1 ? NMR for self-assembly ??14 in CDCl3
, Annex 3.22. COSY NMR for self-assembly ??14 in CDCl3
, Annex 3.23. NOESY NMR for self-assembly ??14 in CDCl3
, Annex 3.24. 1 ? NMR for self-assembly ??15 in CDCl3
, Annex 3.25. COSY NMR for self-assembly ??15 in CDCl3
, Annex 3.26. NOESY NMR for self-assembly ??15 in CDCl3
, Annex 3, p.27
TEG with 4 eq. of AgBF4 in CD3CN ,
, Annex 3.28. DOSY NMR for ligand exTTF-TEG with 4 eq. of AgBF4 in CD3CN
, Annex 3.29. 1 ? NMR for compound 30 (S-exTTF) in CD2Cl2
, Annex 3.30. 13 ? NMR for compound 30 (S-exTTF) in CD2Cl2
, Annex 5.1. ESI-FTCIR for self-assembly ??7 in CH2Cl2
, ESI-FTCIR for self-assembly ??8 in methanol
, ESI-FTCIR for self-assembly ??10 in methanol
, ESI-FTCIR for self-assembly ??12 in methanol
Annex 6 ,
, Annex 6.1. X-ray data for self-assembly TTF(PhPy)
, Annex 6.2. X-ray data for self-assembly AA1
, X-ray data for ligand 25 (3Py-DTF-SHex)
, X-ray data for ligand 27 (3Py-DTF-SPr)
, Annex 6.5. X-ray data for self-assembly ??3
, Annex 6.6. X-ray data for self-assembly??4
, Annex 6.7. X-ray data for self-assembly??9
, X-ray data for self-assembly ??11, vol.8
, Annex 6.9. X-ray data for
, Annex 6.10. X-ray data for compound 29
, Annex 6.11. X-ray data for compound 31
180 in our case -for x-ray diffraction analysis. Main principle is based on the slow oxidation or reduction of the electro-active molecule and generation of corresponding charge particle. The later than crystalize with counter-ions, Annex 6.12. X-ray data for compound 30 ,
, ? NMR for self-assembly ??12 in CD3CN
, Annex 3.17. COSY NMR for self-assembly ??12 in CD3CN
, Annex 5.3. ESI-FTCIR for self-assembly ??10 in methanol
, ESI-FTCIR for self-assembly ??12 in methanol
, Final R indices
, Final R indices
, Largest diff. peak and hole 2.867 and -1