Etude de nanocomposites basés sur des alliages PLA/PA11

Abstract : Polylactic acid (PLA) is one of the biobased polymers that generates the most interest, but its thermomechanical properties need to be improved. To do that, the most used and studied methods consist of blending PLA with other polymers or adding nanoscaled mineral fillers (nanoparticles) to get a PLA based nanocomposite. This PhD work is dedicated to the elaboration and properties characterization of nanocomposites based on a filled PLA and polyamide 11 80/20 wt/wt blend. The aim is to obtain a biobased material with improved thermal, mechanical and fire reaction properties by controlling its morphology through the addition of nanoparticles and flame retardants additives. To achieve that, two compatibilization techniques, aiming to improve PLA-PA11 interfacial adhesion, were evaluated. The first one consisted of adding silica nanoparticles. Important changes of the blend morphology and rheological properties were noticed, depending on the localization of the two different silica nanoparticles used into the polymer blend phases. The second one consisted of introducing a reactive multifunctional epoxy copolymer, named Joncryl. The reactivity of this copolymer with PLA and PA11 allowed to compatibilize the blend, leading to a fine morphology and higher mechanical properties compared to those of the pristine blend. Samples of compatibilized blends obtained through this method were processed using FDM additive manufacturing process. A study of the influence of this process on the morphology and mechanical properties obtained for these samples was performed. Finally, a better fire reaction of compatibilized polymer blend with 3%wt Joncryl was obtained by the combined addition of phyllosilicates nanoparticles and flame retardants.
Document type :
Theses
Complete list of metadatas

Cited literature [332 references]  Display  Hide  Download

https://tel.archives-ouvertes.fr/tel-02273904
Contributor : Abes Star <>
Submitted on : Thursday, August 29, 2019 - 1:33:06 PM
Last modification on : Friday, August 30, 2019 - 10:43:22 AM

File

71681_RASSELET_2019_archivage....
Version validated by the jury (STAR)

Identifiers

  • HAL Id : tel-02273904, version 1

Collections

Citation

Damien Rasselet. Etude de nanocomposites basés sur des alliages PLA/PA11. Polymères. IMT - MINES ALES - IMT - Mines Alès Ecole Mines - Télécom, 2019. Français. ⟨NNT : 2019EMAL0001⟩. ⟨tel-02273904⟩

Share

Metrics

Record views

169

Files downloads

37