, Robustesse de l'outil de diagnostic au vieillissement de la pile mesures de tension et d'impédance. La mise en oeuvre de modules de dégradation a permis au modèle de bon fonctionnement de suivre l'évolution de la tension pendant les 1000 heures. Le calcul de la résistance de membrane est adapté et permet de suivre l'évolution de la résistance hautes fréquences de la pile
, 63% pour des pressions faibles mais seulement de 20% pour une chute de température ou une augmentation d'humidité. Pour la tension, l'écart expérience-modèle commence à être trop important à partir de 900h de dégradations, le taux de fausses alarmes atteint 30%. On voit ici une limite de l'utilisation unique du taux de dégradation pour décrire la chute de la tension, Le taux de bonne isolation est de plus de 99% pour deux des défauts considérés dans l'étude (pressions élevées et humidités faibles)
, Ainsi la compréhension des mécanismes à l'oeuvre dans la chute de la résistance hautes fréquences doit être étudiée. Des expériences de caractérisations de la couche de diffusion sont nécessaire et un modèle de dégradation de celle-ci devrait être créé. Il doit permettre de suivre l'évolution de la résistance pendant le vieillissement de la pile. Les caractérisations expérimentales ont montré que le vieillissement rend la mesure de ré-sistance hautes fréquences moins sensible à l'apparition d'un défaut F 1 (chute de température) ou F 2 (augmentation de l'humidité relative). Pour améliorer les performances de diagnostic, il est possible de se focaliser sur l'obtention de nouveaux résidus. Ceux-ci devront permettre d'obtenir des indicateurs qui dépendent fortement de l'apparition de ces défauts, Le suivi et recalage de ces coefficients en boucle fermée permettrait de maintenir la précision du modèle pour décrire le comportement de la pile pendant le vieillissement
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