I. and .. .. ,

I. 1. Intérêt-scientifique-d'électrofilage and .. .. ,

, Généralité et description du procédé de filage électrostatique

, Deuxième région d'instabilité

, Autres Instabilités : fibres branchées et fibres perlées

, Viscosité de la solution

, Masse molaire moléculaire du polymère

, La conductivité de la solution

, La tension de surface/densité de charges de surface

, Débit d'alimentation en solution

, Distance entre l'extrémité de l'aiguille et le collecteur

, Diamètre de la buse d'électrofilage

, Applications potentielles

, Unités de construction Secondaires (SBU)

, 3. 1. MOF-5: Metal organic framework n°5

, ZIF-8: Zeolitic Imidazolate Framework n° 8?

, membranes et les films à base

, 2. 2. Les membranes à matrice mixte (MMM)

, 3. 2. 1. La croissance in situ sur des supports non modifiés

R. Jaeger, M. M. Bergshoef, and C. M. Batlle, Electrospinning of ultra-thin polymer fibers

I. Schönherr, H. Et, J. Vancso, and G. , Macromolecular Symposia, pp.141-150, 1998.

S. Almuhamed, M. Bonne, N. Khenoussi, J. Brendle, and L. Schacher, Electrospinning composite nanofibers of polyacrylonitrile/synthetic Na montmorillonite

B. Lebeau and D. C. Et-adolphe, Industrial and Engineering Chemistry, vol.35, pp.146-152, 2016.

. Khenoussi-nabyl, Contribution à l'étude et à la caractérisation de nanofibres obtenues par électrofilage «application aux domaines medical et composite », p.47, 2010.

A. L. Yarin, S. Koombhongse, and D. H. Et-reneker, Taylor cone and jetting from liquid droplets in electrospinning of nanofibers, Applied Physics, vol.90, issue.9, pp.4836-4846, 2001.

M. Cloupeau and B. Et-prunet-foch, Electrostatic spraying of liquids in cone-jet mode, Electrostatics, vol.22, issue.2, pp.135-159, 1989.

, A fundamental investigation of the formation and properties of electrospun fibers

S. B. Warner, A. Buer, S. C. Ugbolue, G. C. Rutledge, and M. Y. Shin, National Textile Center Annual Report, pp.83-90, 1998.

E. Reneker, D. H. Et-yarin, and A. L. , Polymer, vol.49, issue.10, pp.2387-2425, 2008.

G. Taylor, Disintegration of water drops in an electric field, Proceedings of the Royal Society of London A: Mathematical, Physical and Engineering Sciences. The Royal Society, pp.383-397, 1964.

A. L. Yarin and S. Koombhongse, Bending instability in electrospinning of nanofibers

D. H. Reneker, Applied Physics, vol.89, issue.5, pp.3018-3026, 2001.

P. Electrospun, X. M. Mo, C. Y. Xu, and M. Kotaki, nanofiber: a biomimetic extracellular matrix for smooth muscle cell and endothelial cell proliferation

S. Ramakrishna, Biomaterials, vol.25, issue.10, pp.1883-1890, 2004.

O. S. Yördem, M. Papila, and Y. Z. Et-mencelo?lu, Effects of electrospinning parameters on polyacrylonitrile nanofiber diameter: An investigation by response surface methodology, Materials & Design, vol.29, issue.1, pp.34-44, 2008.

. Electrically and G. Taylor, In: Proceedings of the Royal Society of London A: Mathematical, Physical and Engineering Sciences, pp.453-475, 1969.

C. Yuan and X. , Study on morphology of electrospun poly (vinyl alcohol) mats. Zhang

L. Wu, Y. Han, and J. Et-sheng, European Polymer, vol.41, issue.3, pp.423-432, 2005.

C. J. Buchko, L. C. Chen, Y. Shen, and D. C. Et-martin, Processing and microstructural characterization of porous biocompatible protein polymer thin films, Polymer, vol.40, issue.26, pp.7397-7407, 1999.

N. Kizildag, Y. Beceren, M. Kazanci, and D. Et-cukul, RMUTP. Proceedings of The International Conference: Textiles & Fashion, pp.3-4, 2012.

E. D. Boland, G. E. Wnek, D. G. Simpson, K. J. Pawlowski, and G. L. Bowlin, Tailoring tissue engineering scaffolds using electrostatic processing techniques: a study of poly (glycolic acid), vol.38, pp.1231-1243, 2001.

A. Theron, E. Zussman, and A. L. Et-yarin, Electrostatic field-assisted alignment of electrospun nanofibres, Nanotechnology, vol.12, issue.3, pp.384-390, 2001.

E. Zussman, A. Theron, and A. L. Et-yarin, Applied Physics Letters, vol.82, issue.6, pp.973-975, 2003.

, A novel electrospinning target to improve the yield of uniaxially aligned fibers

V. P. Secasanu, C. K. Giardina, and Y. Wang, Biotechnology Progress, vol.25, issue.4, pp.1169-1175, 2009.

C. L. Casper, J. S. Stephens, and N. Tassi, Controlling surface morphology of electrospun polystyrene fibers: effect of humidity and molecular weight in the electrospinning process

G. Chase, D. B. Et-rabolt, and J. F. , Macromolecules, vol.37, issue.2, pp.573-578, 2004.

C. Mit-uppatham, M. Nithitanakul, and P. Et-supaphol, Ultrafine electrospun polyamide-6 fibers: effect of solution conditions on morphology and average fiber diameter, Macromolecular Chemistry and Physics, vol.205, issue.17, pp.2327-2338, 2004.

D. Li and Y. Et-xia, Electrospinning of nanofibers: reinventing the wheel?, Advanced Materials, vol.16, issue.14, pp.1151-1170, 2004.

. Electrospinning, T. Subbiah, G. S. Bhat, R. W. Tock, S. Parameswaran et al., Applied Polymer Science, vol.96, issue.2, pp.557-569, 2005.

, Principles of tissue engineering and reconstruction using polymer-cell constructs

D. J. Mooney, L. Cima, R. Langer, L. Johnson, L. K. Hansen et al., Proceedings, vol.252, 1991.

R. Langer and J. P. Vacanti, Tissue Engineering, vol.260, pp.920-926, 1993.

, Electrospinning materials for energy-related applications and devices. Dong, Z

S. J. Kennedy and Y. Wu, , vol.196, pp.4886-4904, 2011.

I. D. Norris, M. M. Shaker, F. K. Ko, and A. G. Et-macdiarmid, Electrostatic fabrication of ultrafine conducting fibers: polyaniline/polyethylene oxide blends, Synthetic Metals, vol.114, issue.2, pp.109-114, 2000.

, Palladium nanoparticles by electrospinning from poly (acrylonitrile-co-acrylic acid

, PdCl 2 solutions. Relations between preparation conditions, particle size, and catalytic activity

M. M. Demir, M. A. Gulgun, Y. Z. Menceloglu, B. Erman, S. S. Abramchuk et al.,

E. , K. A. Matveeva, V. G. Et-sulman, and M. G. , Macromolecules, vol.37, issue.5, pp.1787-1792, 2004.

. Beitrag-zur-konstitution-anorganischer-verbindungen and A. Werner, Polymer Science, 1893, vol.3, pp.267-330

S. Kitagawa, R. Kitaura, and S. I. Et-noro, Functional porous coordination polymers

, Angewandte Chemie International Edition, vol.43, issue.18, pp.2334-2375, 2004.

H. Li, M. Eddaoudi, M. O'keeffe, and O. M. Et-yaghi, Design and synthesis of an exceptionally stable and highly porous metal-organic framework, Nature, vol.402, pp.276-279, 1999.

O. M. Yaghi, M. O'keeffe, N. W. Ockwig, H. K. Chae, M. Eddaoudi et al., Reticular synthesis and the design of new materials, vol.423, pp.705-714, 2003.

M. Moler, D. B. Li, H. Chen, B. Reineke, T. M. O'keeffe et al., Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal-Organic Carboxylate Frameworks, Accounts of Chemical Research, vol.34, pp.319-330, 2001.

H. C. Zhou, J. R. Long, and O. M. Et-yaghi, Chemical Reviews, vol.112, pp.673-674, 2012.

H. Wu, W. Zhou, and T. Et-yildirim, High-capacity methane storage in metal? organic frameworks M2 (dhtp): the important role of open metal sites, vol.131, pp.4995-5000, 2009.

. Ab-initio, Fully Periodic Characterization of MOF-74-M (M= Mg

E. Structures, . Of-adsorption, L. Valenzano, B. Civalleri, and W. F. Et-perger, MRS Online Proceedings Library Archive, vol.1366, 2011.

D. Saha and S. Et-deng, Hydrogen adsorption on metal-organic framework MOF-177, vol.15, pp.363-376, 2010.

J. L. Rowsell and O. Et-yaghi, Metal-organic frameworks: a new class of porous materials

M. Microporous and M. Materials, , vol.73, pp.3-14, 2004.

K. Khaletskaya, Functional Metal-Organic Frameworks: From Bulk to Surface Engineered Properties, p.9, 2014.

M. Kim, J. Rosi, N. Vodak, D. Wachter, and J. , Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage

M. O'keeffe and O. M. Et-yaghi, Science, vol.295, issue.5554, pp.469-472, 2002.

B. Civalleri, F. Napoli, Y. Noël, C. Roetti, R. Et-dovesi et al., Ab-initio prediction of materials properties with crystal: MOF-5 as a case study, vol.8, pp.364-371, 2006.

M. Eddaoudi, H. Li, and O. M. Et-yaghi, Highly porous and stable metal-organic frameworks: structure design and sorption properties, vol.122, pp.1391-1397, 2000.

, A chemically functionalizable nanoporous material

Y. Lo, S. M. Charmant, J. P. Orpen, A. G. Williams, and I. D. , Science, vol.283, issue.5405, pp.1148-1150, 1999.

L. Alaerts, M. Maes, and M. A. Van-der-veen, Metalorganic frameworks as high-potential adsorbents for liquid-phase separations of olefins, alkylnaphthalenes and dichlorobenzenes

P. A. Jacobs and D. E. De-vos, Physical Chemistry Chemical Physics, vol.11, pp.2903-2911, 2009.

. Peralta-david, Evaluation des Metal-Organic Frameworks en adsorption et séparation des hydrocarbures, vol.84, p.70, 2011.

, Probing the Lewis acidity and catalytic activity of the Metal-Organic Framework, Cu, vol.3

L. Alaerts, E. Séguin, H. Poelman, F. Thibaultstarzyk, P. A. Jacobs et al., Chemistry-A European, vol.12, pp.7353-7363, 2006.

K. Kratzke, T. Et-kaskel, and S. , Improved synthesis, thermal stability and catalytic properties of the metal-organic framework compound Cu 3 (BTC) 2 . Schlichte, Microporous and Mesoporous Materials, vol.73, issue.1, pp.81-88, 2004.

K. S. Park, Z. Ni, A. P. Cote, J. Y. Choi, R. D. Huang et al., Exceptional chemical and thermal stability of Zeolitic Imidazolate Frameworks

O. M. Yaghi, Proceedings of the National Academy of Sciences of the United States of

, America, vol.103, pp.10186-10191, 2006.

Y. Liu, Y. Zeng, G. Zhao, L. Lai, and Z. , Rapid synthesis of Zeolitic Imidazolate Framework-8 (ZIF-8) nanocrystals in an aqueous system. Pan, vol.47, pp.2071-2073, 2011.

H. Wu, W. Zhou, and T. Et-yildirim, Hydrogen storage in a prototypical Zeolitic Imidazolate Framework-8, vol.129, pp.5314-5315, 2007.

M. P. Suh, H. J. Park, T. K. Prasad, and D. W. Lim, Hydrogen storage in Metal-Organic Frameworks, vol.112, pp.782-835, 2011.

J. R. Li, R. J. Kuppler, and H. C. Zhou, Selective gas adsorption and separation in metal-organic frameworks, Chemical Society Reviews, vol.38, issue.5, pp.1477-504, 2009.

J. Lee, O. K. Farha, and J. Roberts, Metal-organic framework materials as catalysts

K. A. Scheidt, S. T. Nguyen, and J. T. Et-hupp, Chemical Society Reviews, vol.38, pp.1450-1459, 2009.

A. Morozan and F. Et-jaouen, Metal organic frameworks for electrochemical applications, Energy & Environmental Science, vol.5, issue.11, pp.9269-9290, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00738818

R. Campesi, Sciences Ingénierie et Environnement)

, Synthèse, caractérisation et étude des propriétés thermodynamiques d'hydrogénation de nanocomposites matériaux poreux/métaux alliages, pp.22-23, 2008.

N. L. Rosi and J. Eckert, Hydrogen storage in microporous Metal-Organic Frameworks

M. Eddaoudi, D. T. Vodak, J. Kim, M. O'keeffe, and O. M. Et-yaghi, Science, vol.300, pp.1127-1129, 2003.

B. Panella, M. Hirscher, H. Pütter, and U. Et-müller, Hydrogen adsorption in Metal-Organic Frameworks: Cu-MOFs and Zn-MOFs compared, vol.16, pp.520-524, 2006.

M. Kramer, M. Sabo, R. Kunschke, H. Fröde, and S. Et-kaskel, Advanced Engineering Materials, vol.8, pp.293-296, 2006.

H. Furukawa, M. A. Miller, and O. M. Et-yaghi, Materials Chemistry, vol.17, pp.3197-3204, 2007.

. Seyedali-emami, Synthesis of Peptide-based Porous Materials, p.10, 2013.

R. T. Yang, Adsorbents: fundamentals and applications, p.4, 2003.

, Very large breathing effect in the first nanoporous chromium(III)-based solids, p.53

;. Or-cr, F. Millange, C. Thouvenot, M. Nogues, G. Marsolier et al., , vol.124, pp.13519-13526, 2002.

S. Bourrelly, P. L. Llewellyn, and . Serre, Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47

C. Millange, F. Loiseau, T. Férey, and G. , The, vol.127, pp.13519-13521, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00022800

D. Farrusseng and S. Aguado, Metal-Organic Frameworks: opportunities for catalysis
URL : https://hal.archives-ouvertes.fr/hal-00431148

C. Pinel and A. Chemie, , vol.48, pp.7502-7513, 2009.

Y. Lu, M. Tonigold, B. Bredenkötter, D. Volkmer, and J. Hitzbleck, II) containing Metal-Organic Framework showing catalytic activity in oxidation reactions

G. Langstein, . Zeitschrift, and . Chemie, , vol.634, pp.2411-2417, 2008.

S. T. Meek, J. A. Greathouse, and M. D. Et-allendorf, Metal-organic frameworks: A rapidly growing class of versatile nanoporous materials, vol.23, pp.249-267, 2011.

S. Henke, R. Schmid, J. D. Grunwaldt, and R. A. Fischer, Flexibility and sorption selectivity in rigid Metal-Organic Frameworks: The impact of ether-functionalised linkers, Chemistry-A European Journal, vol.16, issue.48, pp.14296-14306, 2010.

Z. Wang and S. M. Et-cohen, Postsynthetic modification of metal-organic frameworks, Chemical Society Reviews, vol.38, issue.5, pp.1315-1329, 2009.

T. Yamada and H. Et-kitagawa, Protection and deprotection approach for the introduction of functional groups into Metal? Organic Frameworks, vol.131, pp.6312-6313, 2009.

H. J. Choi and M. P. Suh, Inorganic Chemistry, vol.38, issue.26, pp.6309-6312, 1999.

Y. Yoo, Z. Lai, and H. K. Et-jeong, Fabrication of MOF-5 membranes using microwave-induced rapid seeding and solvothermal secondary growth, Microporous and Mesoporous Materials, vol.123, issue.1, pp.100-106, 2009.

Y. Liu, Z. Ng, E. A. Khan, H. K. Jeong, C. B. Ching et al., Synthesis of continuous MOF-5 membranes on porous ?-alumina substrates, vol.118, pp.296-301, 2009.

. Betard-angélique, Growth and Chemistry of Metal-Organic Framework Thin Films: Toward Functional Coatings, vol.8, pp.11-12, 2011.

D. Zacher, O. Shekhah, C. Wöll, and R. A. Fischer, Thin films of metal-organic frameworks, Chemical Society Reviews, vol.38, issue.5, pp.1418-1429, 2009.

O. Liu, J. Fischer, R. A. Et-wöll, and C. , MOF thin films: existing and future applications. Shekhah, vol.40, pp.1081-1106, 2011.

M. Böhringer, B. Jolly, M. Fischer, R. Et-kaskel, and S. , MOF processing by electrospinning for functional textiles. Rose, vol.13, pp.356-360, 2011.

O. Kozachuk, K. Yusenko, H. Noei, Y. Wang, S. Walleck et al., Solvothermal growth of a ruthenium metal-organic framework featuring HKUST-1 structure type as thin films on oxide surfaces, vol.47, pp.8509-8511, 2011.

E. Biemmi, A. Darga, N. Stock, and T. Et-bein, ) 2 (H 2 O) 3 · xH 2 O thin films on modified QCM-gold electrodes-Water sorption isotherms, Microporous and Mesoporous Materials, vol.114, issue.1, pp.380-386, 2008.

D. Zacher, A. Baunemann, S. Hermes, and R. A. Fischer, at alumina and silica surfaces modified with patterned self-assembled organic monolayers: evidence of surface selective and oriented growth, Materials Chemistry, vol.17, pp.2785-2792, 2007.

A. Centrone, Y. Yang, S. Speakman, L. Bromberg, G. C. Rutledge et al., , vol.132, pp.15687-15691, 2010.

J. Yao, D. Dong, D. Li, L. He, G. Xu et al., Contra-diffusion synthesis of ZIF-8 films on a polymer, vol.47, pp.2559-2561, 2011.

L. Xue, M. Kang, Z. Et-qiu, and S. , Synthesis of microporous membranes and films on various substrates by novel electrospinning method. Fan, vol.56, pp.459-464, 2013.

R. Ostermann, J. Cravillon, C. Weidmann, M. Wiebcke, and B. M. Et-smarsly, Metal-organic framework nanofibers via electrospinning, vol.47, pp.442-444, 2011.

N. Shah-miral, Synthesis and characterization of films and membranes of Metal-Organic Framework (MOF) for gas separation applications, p.55, 2012.

Z. Wang and S. M. Et-cohen, Postsynthetic modification of metal-organic frameworks, Chemical Society Reviews, vol.38, issue.5, pp.1315-1329, 2009.

A. Car, C. Stropnik, and K. V. Et-peinemann, Hybrid membrane materials with different metal-organic frameworks (MOFs) for gas separation, Desalination, vol.200, issue.1-3, pp.424-426, 2006.

S. Basu, A. Cano-odena, and I. F. Et-vankelecom, MOF-containing mixed-matrix membranes for CO 2 /CH 4 and CO 2 /N 2 binary gas mixture separations, Separation and Purification Technology, vol.81, issue.1, pp.31-40, 2011.

E. V. Perez, K. J. Balkus, J. P. Ferraris, and I. H. Et-musselman, Mixed-matrix membranes containing MOF-5 for gas separations, Membrane Science, vol.328, issue.1, pp.165-173, 2009.

J. Hu, H. Cai, H. Ren, Y. Wei, Z. Xu et al., Mixed-matrix membrane hollow fibers of Cu 3 (BTC) 2 MOF and polyimide for gas separation and adsorption, Industrial & Engineering Chemistry Research, vol.49, issue.24, pp.12605-12612, 2010.

A. Huang, H. Bux, F. Steinbach, and J. Caro, Molecular-sieve membrane with hydrogen permselectivity: ZIF-22 in LTA topology prepared with 3-aminopropyltriethoxysilane as covalent linker, Angewandte Chemie, vol.122, issue.29, pp.5078-5081, 2010.

H. Bux, F. Liang, Y. Li, J. Cravillon, M. Wiebcke et al., Zeolitic imidazolate framework membrane with molecular sieving properties by microwave-assisted solvothermal synthesis, vol.131, pp.16000-16001, 2009.

A. Huang and J. Caro, Covalent post-functionalization of zeolitic imidazolate framework ZIF-90 membrane for enhanced hydrogen selectivity, Angewandte Chemie International Edition, vol.50, issue.21, pp.4979-4982, 2011.

. Kuhn-philippe, Zéolithes et chimie organique : Elaboration de nouvelles voies de synthèses vertes, p.3, 2011.

Y. Liu, Z. Ng, E. A. Khan, H. K. Jeong, C. B. Ching et al., Synthesis of continuous MOF-5 membranes on porous ?-alumina substrates, vol.118, pp.296-301, 2009.

Y. Liu, E. Hu, E. A. Khan, and L. Et, Synthesis and characterization of ZIF-69 membranes and separation for CO 2 /CO mixture, Z., Membrane Science, vol.353, issue.1, pp.36-40, 2010.

S. Bertazzo and K. Et-rezwan, Control of ?-alumina surface charge with carboxylic acids, Langmuir, vol.26, issue.5, pp.3364-3371, 2009.

A. Huang, W. Dou, and J. Caro, Steam-stable zeolitic imidazolate framework ZIF-90 membrane with hydrogen selectivity through covalent functionalization, vol.132, pp.15562-15564, 2010.

. Synthetic, E. A. Flügel, A. Ranft, F. Haase, and B. V. Et-lotsch, Materials Chemistry, vol.22, issue.20, pp.10119-10133, 2012.

R. P. Mun, J. A. Byars, and D. V. Boger, The effects of polymer concentration and molecular weight on the breakup of laminar capillary jets, Non-Newtonian Fluid Mechanics, vol.74, issue.1, pp.285-297, 1998.

A. Koski, K. Yim, and S. Et-shivkumar, Effect of molecular weight on fibrous PVA produced by electrospinning, Materials Letters, vol.58, issue.3, pp.493-497, 2004.

, Effects of humidity and solution viscosity on electrospun fiber morphology

M. Eifert, M. B. Et-cosgriff-hernandez, and E. , Tissue Engineering Part C: Methods, vol.19, issue.10, pp.810-819, 2013.

. Khenoussi-nabyl, , p.97, 2010.

C. Hongrojjanawiwat, W. Koombhongse, P. Supaphol, P. Jarusuwannapoo, T. Et-rangkupan et al., The influence of solvent properties and functionality on the electrospinnability of polystyrene nanofibers. Pattamaprom, vol.291, pp.840-847, 2006.

. Dmso and W. S. Macgregor, Annals of the New York Academy of Sciences, vol.141, issue.1, pp.3-12, 1967.

C. Yuan, X. Wu, L. Han, Y. Et-sheng, and J. , Study on morphology of electrospun poly (vinyl alcohol) mats. Zhang, vol.41, pp.423-432, 2005.

E. Atabey, Fluorescent electrospun polyvinyl alcohol/CdSe@ ZnS nanocomposite fibers

S. Wei, X. Zhang, H. Gu, X. Yan, Y. Huang et al., Composite Materials, vol.47, issue.25, pp.3175-3185, 2013.

W. Ding, S. Wei, J. Zhu, X. Chen, D. Rutman et al., Manipulated electrospun PVA nanofibers with inexpensive salts, Macromolecular Materials and Engineering, vol.295, issue.10, pp.958-965, 2010.

M. Böhringer, B. Jolly, M. Fischer, R. Et-kaskel, and S. , MOF processing by electrospinning for functional textiles. Rose, vol.13, pp.356-360, 2011.

S. S. Ojha, M. Afshari, R. Kotek, and R. E. Et-gorga, Morphology of electrospun nylon-6 nanofibers as a function of molecular weight and processing parameters, Applied Polymer Science, vol.108, issue.1, pp.308-319, 2008.

, A novel method to measure diffusion coefficients in porous metal-organic frameworks

O. Zybaylo, O. Shekhah, H. Wang, M. Tafipolsky, R. Schmid et al., Physical Chemistry Chemical Physics, vol.12, issue.28, pp.8093-8098, 2010.

C. Petit, J. Burress, and T. J. Et-bandosz, The synthesis and characterization of copper-based metal-organic framework/graphite oxide composites, Carbon, vol.49, issue.2, pp.563-572, 2011.

, A chemically functionalizable nanoporous material

Y. Lo, S. M. Charmant, J. P. Orpen, A. G. Williams, and I. D. , Science, vol.283, issue.5405, pp.1148-1150, 1999.

. Poly, Chains Grafted onto the Surface of Copper Oxide Nanoparticles: Application in Synthesis and Characterization of Novel Optically Active and Thermally Stable Nanocomposites Based on Poly (amide-imide) Containing

. Linkage, S. Mallakpour, M. Dinari, and E. Et-azadi, International Journal of Polymer Analysis and Characterization, vol.20, issue.1, pp.82-97, 2015.

. Electrochemical, S. Loera-serna, M. A. Oliver-tolentino, L. De, M. López-núñez et al., BTC) 2 ] metal-organic framework: the effect of the method of synthesis, Cu, vol.3, pp.113-120, 2012.

R. Sabouni, H. Kazemian, and S. Et-rohani, A novel combined manufacturing technique for rapid production of IRMOF-1 using ultrasound and microwave energies, Chemical Engineering Journal, vol.165, pp.966-973, 2010.

S. Hermes and F. Schröder, Loading of porous metal-organic open frameworks with organometallic CVD precursors: inclusion compounds of the type [LnM]a@MOF-5

S. Amirjalayer, R. Schmid, and R. A. Fischer, Materials Chemistry, vol.16, pp.2464-2472, 2006.

N. Iswarya, M. G. Kumar, K. S. Rajan, and J. B. Et-rayappan, Metal organic framework (MOF-5) for sensing of volatile organic compounds, vol.12, pp.1681-1685, 2012.

H. Li, M. Eddaoudi, M. O'keeffe, and O. M. Et-yaghi, Design and synthesis of an exceptionally stable and highly porous metal-organic framework, Nature, vol.402, issue.6759, pp.276-279, 1999.

S. Ullah, M. A. Bustam, A. M. Shariff, A. E. Elkhalifah, G. Murshid et al., Synthesis and CO 2 adsorption study of modified MOF-5 with multi-wall carbon nanotubes and expandable graphite, AIP Conference Proceedings, vol.1621, issue.1, pp.34-39, 2014.

X. Yang, C. Shao, H. Guan, X. Li, and J. Et-gong, Preparation and characterization of ZnO nanofibers by using electrospun PVA/zinc acetate composite fiber as precursor, Inorganic Chemistry Communications, vol.7, issue.2, pp.176-178, 2004.

C. M. Rathi, M. Ahrenkiel, S. P. Koodali, R. T. Wang, and Z. , Facile synthesis of MOF-5 confined in SBA-15 hybrid material with enhanced hydrostability. Wu, vol.49, pp.1223-1225, 2013.

J. Tang, M. Yang, W. Dong, and M. Yang, Highly porous carbons derived from MOFs for shape-stabilized phase change materials with high storage capacity and thermal conductivity

H. Zhang, S. Fan, J. Wang, L. Tan, G. Wang et al., , vol.6, pp.40106-40114, 2016.

E. Reneker, D. H. Et-yarin, and A. L. , Polymer, vol.49, pp.2387-2425, 2008.

Y. Hu, H. Kazemian, S. Rohani, Y. Huang, and Y. Song, situ high pressure study of ZIF-8 by FTIR spectroscopy, vol.47, pp.12694-12696, 2011.

, Molecular sieving realized with ZIF-8/Matrimid® mixed-matrix membranes, Ordonez

M. J. Balkus, K. J. Ferraris, J. P. Et-musselman, and I. H. , Membrane Science, vol.361, issue.1, pp.28-37, 2010.

J. Li, Y. N. Wu, Z. Li, B. Zhang, M. Zhu et al., Zeolitic imidazolate framework-8 with high efficiency in trace arsenate adsorption and removal from water, Physical Chemistry C, vol.118, issue.47, pp.27382-27387, 2014.

J. Rémy, T. Van-hunskerken, V. Van-de-perre, S. Duerinck, T. Maes et al., Biobutanol Separation with the Metal-Organic Framework ZIF-8. Cousin Saint Remi, vol.4, pp.1074-1077, 2011.

G. Zhang, S. Hou, H. Zhang, W. Zeng, F. Yan et al., High Performance and Ultra Stable Lithium Ion Batteries Based on MOF Derived ZnO@ ZnO Quantum Dots/C Core-Shell Nanorod Arrays on a Carbon Cloth Anode, Advanced Materials, vol.27, issue.14, pp.2400-2405, 2015.

M. Amirilargani and B. Et-sadatnia, Poly (vinyl alcohol)/zeolitic imidazolate frameworks (ZIF-8) mixed matrix membranes for pervaporation dehydration of isopropanol, Membrane Science, vol.469, pp.1-10, 2014.

K. Kida, M. Okita, K. Fujita, S. Tanaka, and Y. Et-miyake, Formation of high crystalline ZIF-8 in an aqueous solution, CrystEngComm, vol.15, issue.9, pp.1794-1801, 2013.

A. F. Gross, E. Sherman, and J. J. Et-vajo, Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks, Dalton Transactions, vol.41, issue.18, pp.5458-5460, 2012.

S. Vairam and S. Et-govindarajan, New hydrazinium salts of benzene tricarboxylic and tetracarboxylic acids-preparation and their thermal studies, Thermochimica Acta, vol.414, issue.2, pp.263-270, 2004.

, Reactive adsorption of ammonia on Cu-based MOF/graphene composites. Petit

B. Mendoza, T. J. Et-bandosz, and . Langmuir, , vol.26, pp.15302-15309, 2010.

S. G. Anicuta, L. Dobre, M. Stroescu, and I. Et-jipa, Fourier transform infrared (FTIR) spectroscopy for characterization of antimicrobial films containing chitosan, Faculty Applied Chemistry and Material Science, pp.1234-1240, 2010.

S. K. Shakshooki, A. A. Elejmi, A. M. Hamassi, F. A. El-akari, and N. A. Et-masoud, Facile Synthesis of Poly (vinyl alcohol)/Fibrous Cerium Phosphate Nanocomposite Membranes, vol.2, pp.1-6, 2014.

H. Chhina, S. Campbell, and O. Kesler, An oxidation-resistant indium tin oxide catalyst support for proton exchange membrane fuel cells, vol.161, pp.893-900, 2006.

J. Herrero and C. Et-guillen, Improved ITO thin films for photovoltaic applications with a thin ZnO layer by sputtering, Thin Solid Films, vol.451, pp.630-633, 2004.

, Crystallinity in poly (vinyl alcohol). 1. An X-ray diffraction study of atactic PVOH

H. E. Assender and A. H. Et-windle, Polymer, vol.39, issue.18, pp.4295-4302, 1998.

. Electrospinning, T. Subbiah, G. S. Bhat, R. W. Tock, S. Parameswaran et al., Applied Polymer Science, vol.96, issue.2, pp.557-569, 2005.

S. Almuhamed, N. Khenoussi, M. Bonne, L. Schacher, and B. Lebeau, Electrospinning of PAN nanofibers incorporating SBA-15-type ordered mesoporous silica particles

D. Adolphe and J. Et-brendlé, European Polymer Journal, vol.54, pp.71-78, 2014.

S. Zhao, X. Wu, L. Wang, and Y. Huang, Applied Polymer Science, vol.91, issue.1, pp.242-246, 2004.

R. Ameloot, F. Vermoortele, W. Vanhove, and M. B. Roeffaers, Interfacial synthesis of hollow metal-organic framework capsules demonstrating selective permeability

F. Et-de-vos and D. E. , Nature Chemistry, vol.3, issue.5, pp.382-387, 2011.

R. Syrlybaeva, N. Movsum-zade, I. Safiullina, Y. Puzin, and E. Et-movsumzade, Polymer-metal complexes of polyacrylonitrile and its copolymers: synthesis and theoretical study, Polymer Research, vol.22, issue.6, pp.100-108, 2015.

F. Alcántara, R. González, J. R. Tirado, and J. L. , , vol.159, pp.1028-1033, 2012.

M. Drobek, M. Vallicari, C. Chaaya, A. A. Julbe, A. Et-miele et al., Highly crystalline MOF-based materials grown on electrospun nanofibers. Bechelany, vol.7, pp.5794-5802, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01684626

H. M. Yang, L. I. Xian, X. L. Song, T. L. Yang, Z. H. Liang et al., situ electrochemical synthesis of MOF-5 and its application in improving photocatalytic activity of BiOBr, vol.25, pp.3987-3994, 2015.

. Interaction, ;. M. Pva-cu, K. Ono, and K. Et-murakami, II) complex: 1. Binding of a hydrophobic dye toward PVA-Cu (II) complex. Narisawa, vol.30, pp.1540-1545, 1989.

, Complex formation between poly (vinyl alcohol) and metallic ions in aqueous solution

N. Hojo, H. Shirai, and S. Et-hayashi, Polymer Science: Polymer Symposia, pp.299-307, 1974.

, Acétate de zinc dihydraté (Zn(OAc) 2 . 2H 2 O), acheté auprès de Fisher Scientific

, acheté auprès de Fisher Scientific

, ? L'acide 1, 4-benzène dicarboxilique ou l'acide téréphtalique (H 2 BDC), acheté auprès de Fisher Scientific

, ? 2-Méthyl imidazole (2-MeIm), acheté auprès d'Acros organic (France)

, ? 2, 6-diméthylpiridine ou la 2,6-Lutidine de pureté de 99%, achetée auprès de Fisher Scientific

?. Triethylamine, TEA) extra pure, achetée auprès de Fisher Scientific (France)

, ? Méthanol avec une pureté de 99,8%, extra séché sur tamis moléculaire, acheté auprès d'Acros organic (France)

, II. Synthèse classique des MOFs II. 1. HKUST-1

, La synthèse de MOF-5 a été effectuée en se basant sur des travaux publiés précédemment

. Ainsi, nous avons fait dissoudre 0,085 g de Zn(OAc) 2 . 2H 2 O dans 2 mL de DMSO

X. Song, S. Jeong, D. Kim, and M. S. Et-lah, Transmetalations in two metal-organic frameworks with different framework flexibilities: Kinetics and core-shell heterostructure, CrystEngComm, vol.14, issue.18, pp.5753-5756, 2012.

D. J. Hunt, J. R. Et-yaghi, and O. M. , MOF-177, MOF-199, and IRMOF-0. Tranchemontagne, Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, vol.64, pp.8553-8557, 2008.

M. Amirilargani and B. Et-sadatnia, Poly (vinyl alcohol)/zeolitic imidazolate frameworks (ZIF-8) mixed matrix membranes for pervaporation dehydration of isopropanol, Membrane Science, vol.469, pp.1-10, 2014.

. La-microscopie-Électronique-À-balayage, Principe et applications. Molon-Noblot

S. and S. , Rev. Fr. Histotechnol, vol.2, issue.1, pp.49-54, 1989.

O. Braissant and A. W. Decho, Exopolymeric substances of sulfate-reducing bacteria: Interactions with calcium at alkaline pH and implication for formation of carbonate minerals

C. Dupraz, C. Glunk, K. M. Przekop, and P. T. Visscher, Geobiology, vol.5, issue.4, pp.401-411, 2007.

R. Jenkins and R. L. Snyder, Introduction to X-ray Powder Diffractometry, éd, vol.138, pp.47-95, 1996.

J. I. Langford and D. Et-louer, Powder diffraction, Conclusions générales Et perspectives, vol.59, pp.131-234, 1996.