, J. Phys. Chem. B, p.110, 2006.
, Energy Environ. Sci, 2008.
, Jpn. J. Appl. Phys. Part, vol.2, p.731, 2005.
, Thin Solid Films, vol.351, p.290, 1999.
, Acta Part A, Mol. Biomol. Spectrosc, vol.96, issue.72, p.305, 2008.
, J. Am. Chem. Soc, vol.115, p.1705, 1993.
, Angew. Chem. Int. Ed, vol.47, issue.8910, p.4375, 2011.
, Adv. Funct. Mater, p.17, 2007.
, Electrochim. Acta, vol.19, issue.4, p.4006, 2007.
, Sol. Energy Mater. Sol. Cells, vol.90, p.105, 2001.
, J. Phys. Chem. C, vol.112, p.1819, 2008.
, J. Am. Chem. Soc, vol.115, p.13144, 1993.
, Chem. Lett, vol.32, p.28, 2003.
, J. Mater. Chem, 2011.
, Appl. Phys. Lett, p.103515, 2007.
, Eur. J. Org. Chem, p.2903, 2009.
, Chem. Eur. J, vol.19, p.5220, 2013.
, Chem. Soc. Rev, vol.43, issue.7520, p.253, 2009.
, Chem. Rev, p.6503, 2010.
Villoria de la Mano, Eur. J. Org. Chem, vol.31, p.2891, 2007. ,
, Chem. Soc. Rev, vol.45, p.9, 2016.
, Chem. Rev, vol.256, p.2503, 2012.
, Chem. Soc. Rev, vol.42, p.2294, 2013.
, J. Phys. Chem. Lett, p.189, 2013.
, Am. Mineral, vol.85, p.543, 2000.
, J. Mater. Chem. A, 2016.
, J. Mater. Chem. A, issue.2, p.3344, 2014.
, Energy Environ. Sci, vol.7, p.3808, 2014.
, Natl. Acad. Sci, vol.108, 2011.
, J. Photocatal. Photobiol. A, p.45, 2015.
, J. Am. Chem. Soc, vol.138, p.407, 2014.
, Chem. Phys
, Z. Int. J. Hydrogen Energ, vol.400, issue.520, p.6484, 2004.
, J.R. Chem. Sci, vol.6, p.4855, 2015.
, J. Chem. Soc. Rev, vol.38, p.185, 2009.
, , vol.20, p.267, 2015.
, J. Phys. Chem. A, vol.101, p.2583, 1997.
, Chem. Mater, vol.16, p.1806, 2004.
, Chem. Mater, p.22, 1915.
, Science, vol.334, p.629, 2011.
, J. Am. Chem. Soc, p.135, 1961.
, Tetrahedron, p.4726, 2009.
, Eur. J. Org. Chem, p.5248, 2012.
, Chem. Eur. J, p.1193, 2010.
, Int. J. Quantum Chem, vol.5, p.3214, 2003.
, J. Comput. Chem, p.839, 2008.
, Inorg. Chim. Acta, p.431, 0197.
, J. Polym. Adv. Technol, vol.21, p.27, 2010.
, J. Control. Release, vol.23, p.258, 2002.
, Chem. Asian J, 1709.
, Biomaterials, vol.26, p.587, 2005.
, , p.181, 2010.
, J. Tissue Eng. Regen. Med, vol.9, p.1225, 2007.
, Biomaterials, vol.30, p.6151, 2009.
, J. Mater. Chem. B, vol.2, p.5319, 2014.
, Z. Adv. Drug. Del. Rev, vol.60, p.958, 2008.
, Eur. Polym. J, vol.72, p.602, 2015.
, J. Am .Chem. Soc, vol.58, p.15046, 1190.
, , p.613, 2005.
, ACS Appl. Mater. Inter, vol.7, p.24023, 2015.
, Biomaterials, vol.33, p.1281, 2012.
, Angew. Chem. Int. Ed, p.40, 2001.
, Z. Biomaterials, vol.35, p.4969, 2014.
, Polym. Int, vol.67, p.627, 2018.
, Chem. Soc. Rev, p.6195, 2012.
, Chem. Rev, p.3479, 2010.
, , vol.25, p.8442, 2009.
, J. Am. Chem. Soc, vol.133, p.13922, 2003.
, Nature, vol.463, p.895, 2008.
Comprehensive Supramolecular Chemistry, 1996. ,
, J. Chem. Soc. Rev, p.909, 2012.
, J. Control. Release, vol.127, p.22, 2008.
, Adv. Drug. Del. Rev, vol.53, p.321, 2001.
, Adv. Drug Del. Rev, vol.64, p.223, 2012.
, Soft Matter, vol.10, p.1462, 2014.
, Chem. Commun, p.350, 2004.
, J. Phys. Chem. B, vol.107, issue.593, p.53, 2003.
, J. Adv. Res, issue.6, p.105, 2015.
, Int. J. Pharm, vol.235, p.1, 2002.
, , vol.12, p.4881, 2016.
, J. Mater. Chem. B, p.3654, 2015.
Synthetic polymers, principles of regenerative medicine, Radiat. Phys. Chem, vol.58, p.2583, 1032. ,
, Adv. Mater, vol.15, p.1155, 2003.
, Z.; Xu, F. Sci. China Technol. Sc, vol.15, p.2241, 2004.
, Development of Polyamidoamine Hydrogels: Towards New Stimuli-Responsive Materials -Chapter, vol.44, 2011.
, J. Polym. Sci. Pol. Phys, p.49, 1246.
, Macromolecules, pp.44-5776, 2011.
, Soft Matter, 2011.
, Adv. Mater, p.4499, 1920.
, Adv. Funct. Mater, vol.44, issue.2, p.518, 2011.
, Adv. Mater, p.4171, 2013.
, JSME Int. J. A-Solid M, issue.7, p.163, 2013.
, J. Phys. Chem. B, vol.1, p.914, 2005.
, Kobunshi Ronbunshu, vol.65, p.707, 2008.
, J. Biomed. Nanotechnol, vol.111, p.40, 2014.
, Polym. J, vol.38, p.171, 2006.
, ACS Nano, vol.9, p.4686, 2015.
Nanocomposites: Synthesis, Characterization and Applications, Mater. Sci. Technol, vol.3, issue.105, p.787, 2006. ,
, Nanotechnology in Therapeutics: Current Technology and Applications, 2007.
, Macromol. Mater. Eng, vol.292, p.620, 2007.
, J. Control. Release, vol.130, p.246, 2008.
, Adv. Mater, 2008.
, Adv. Mater, vol.16, p.1074, 2004.
, Prog. Polym. Sci, vol.38, p.672, 2013.
, J. Cell Sci, p.255, 2008.
, J.A. Proc. Natl. Acad. Sci, vol.100, p.5413, 2003.
, Biomaterials, vol.21, p.4521, 1590.
In-Situ Gelling Polymers: For Biomedical Applications, 2015. ,
Integrated Biomaterials for Biomedical Technology, 2012. ,
, , vol.35, p.598, 2014.
, Macromol. Biosci, p.563, 2010.
, Adv. Mater, vol.26, p.85, 2014.
, Eur. J. Pharm. Biopharm, vol.27, p.1173, 2000.
, Sci. Eng. R, vol.93, issue.1, p.54, 2015.
, Drug. Deliv, vol.23, p.748, 2016.
Hydrogel biomaterials, Biomedical Engineering -Frontiers and Challenges, vol.124, p.4132, 1653. ,
, Drug Discov. Today, vol.7, p.25, 1955.
Hydrogels for actuators, Hydrogel Sensors and Actuators, 2010. ,
, Biomaterials, p.5440, 2006.
Shape-memory polymers and shape-changing polymers" in "Shape-Memory Polymers, 2010. ,
, Polym. Chem, 1048.
, Drug Deliv. Rev, vol.64, p.49, 2012.
Hydrogels: Properties, Preparation, Characterization and Biomedical, Applications in Tissue Engineering, Drug, Delivery and Wound Care" in "Advanced Healthcare Materials, Sci. Transl. Med, vol.9, issue.1, p.47, 2014. ,
, J. Biomater. Sci. Polym, vol.31, p.305, 1993.
, , p.544, 2002.
, Macromolecules, vol.36, p.9929, 2003.
Rheology Essentials of Foods and Cosmetics, Des. Monomers Polym, vol.12, p.125, 0197. ,
, Adv. Healthc. Mater, vol.7, p.673, 2001.
, Biomacromolecules, vol.8, p.1109, 2007.
, J. Pharm. Res, vol.11, p.3350, 2012.
Handbook of vibrational spectroscopy, vol.2, 2002. ,
, Eur. Polym. J, p.877, 2007.
, Eur. J. Pharm. Sci, vol.33, p.76, 2000.
, Thermochim. Acta, p.28, 2015.
, Biomaterials, vol.8, p.323, 1987.
, Biomaterials, Artificial Organs and Tissue Engineering, 2005.
, Int. J. Pharm. Pharm. Sci, issue.5, p.112, 2013.
, Biomaterials, p.1410, 2006.
, , p.2701, 2010.
, Biotechnol. Bioeng, vol.111, issue.1, p.441, 2008.
, J. Mater. Chem, vol.6, p.293, 2003.
, Drug Delivery Rev, vol.63, issue.789, p.1039, 2010.
, , vol.48, p.158, 2007.
, J. Phys. Chem. C, p.17206, 2011.
, J. R. Soc. Interface, vol.3, p.741, 2006.
Conductive Polymer Hydrogels, Springer Series on "Polymer and Composite Materials, vol.10, 2014. ,
, Chem. Commun, vol.578, p.11, 1977.
, Sci. Rev. Macromol. Chem. Phys. C, vol.39, p.665, 1999.
, Acc. Chem. Res, vol.18, p.309, 1985.
Intelligent macromolecules for smart devices: from materials synthesis to device applications, pp.41-80, 2004. ,
, Prog. Polym. Sci, vol.32, p.1, 2003.
, J. Tissue Eng. Regen. Med, vol.9, p.2477, 2004.
, J. Neural. Eng, vol.6, p.1, 2009.
, Biomed. Mater. Res, p.1056, 2010.
, Biomacromolecules, vol.10, p.2539, 2009.
, J. Mater. Sci. Mater. Med, vol.44, p.19, 1999.
, Adv. Funct. Mater, vol.17, p.79, 2007.
, Colloid. Polym. Sci, vol.282, p.1301, 2004.
, J. Colloid. Interf. Sci, p.488, 2004.
, Polymer, p.1597, 2006.
, Biomed. Mater. Res, p.221, 2010.
, Z. J. Biomed. Mater. Res, vol.87, p.332, 2008.
, Adv. Funct. Mater, vol.17, p.1645, 2007.
Conducting polymers in neural stimulation applications, Implantable neural prostheses, vol.2, p.217, 2010. ,
, J. Mater. Sci. Mater. Med, 1053.
, J. Appl. Phys, p.94501, 2008.
, Adv. Polym. Sci, vol.119, p.79, 1995.
, Int. J. Polym. Mater, p.531, 2010.
, J. Appl. Polym. Sci, p.1868, 2005.
, Polym. Adv. Technol, vol.21, p.615, 2010.
, Synth. Met, vol.152, p.173, 2005.
, J. Alloys Compd, vol.578, p.249, 2013.
, J. Polym. Sci., Polym. Lett. Ed, vol.9, p.9, 1087.
, J. Am. Chem. Soc, vol.113, p.5887, 1991.
, Adv. Mater, vol.12, p.222, 2000.
, Tissue Eng. A, p.423, 2008.
, J. Neural Eng, vol.4, p.6, 2007.
, Energy Environ. Sci, 2013.
, Biomaterials, vol.30, p.3637, 2009.
, Biomed. Mater. Res, vol.56, p.261, 2001.
, J.A. Synth. Met, vol.126, p.111, 2002.
, Synth. Met, p.193, 1988.
, Z. Proc. Natl. Acad. Sci. U.S.A, vol.132, p.9287, 1317.
, , p.7736, 2015.
, Z. Nat. Commun, vol.5, p.3002, 2014.
, Acc. Chem. Res, vol.50, p.1734, 2017.
, J. Am. Chem. Soc, p.7006, 2007.
, Macromol. Biosci, vol.12, p.494, 2012.
, Nano Lett, p.1146, 2015.
, Adv. Funct. Mater, p.1219, 2015.
, Acta Biomater, vol.11, p.144, 2010.
, ACS Appl. Mater. Interfaces, vol.9, issue.150, p.171, 2005.
, Electrochem. Commun, vol.7, p.717, 2005.
, Polym. Chem, vol.6, p.61, 2015.
, J.J. Mater. Sci.-Mater. El, vol.7, issue.2, p.6086, 2014.
, L. Sci. Rep, vol.5, p.18419, 2015.
, , 2015.
, Synthesis, vol.14, p.45, 2001.
, Compos. Sci. Technol, vol.21, p.498, 2008.
, J. Sci. Technol. Adv. Mater, p.14107, 2010.
, A. Sensor Actuat. B-Chem, vol.190, p.270, 2014.
, , vol.74, p.215, 2008.
, J. Sci.: Adv. Mater. Devices, vol.9, p.1, 2015.
Electrochemical impedance spectroscopy and its applications, Electrochemical Methods: Fundamentals and Applications, pp.143-248, 1947. ,
, Int. J. Photoenergy, p.851705, 2014.
, Analyst, vol.140, p.1466, 2015.
, Polymer, p.1783, 2000.
, J. Mater. Sci, vol.34, p.2733, 1999.
, Development of Polyamidoamine Hydrogels: Towards New Stimuli-Responsive Materials -Chapter, vol.96, p.4881, 1974.
, , vol.18, p.138, 2007.
, Org. Synth, vol.4, p.612, 1963.
,
, J. Synlett, p.79, 2013.
, Soft Matter, vol.12, p.2575, 2016.
, Beilstein J. Org. Chem, vol.48, p.9, 1474.
, J. Am. Chem. Soc, p.3502, 1968.
, J. Org. Chem, p.3129, 1967.
, Angew. Chem. Int. Ed, vol.42, p.4077, 2003.
Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, vol.87, 1985. ,
Conductive Polymer Hydrogels, Polymeric Hydrogels as Smart Biomaterials, vol.11, p.88, 1993. ,
, J. Electroanal. Chem, vol.354, p.605, 1989.
, J. Macromol. Sci. A, p.931, 2012.
, Adv. Mater, vol.29, p.1700974, 2017.
, J.P.; (b) Osada, Y. Macromolecules, vol.33, p.1232, 2000.
, ACS Appl. Mater. Interfaces, vol.9, p.1054, 1952.
Protective Groups in Organic Synthesis, 1999. ,
, J. Org. Chem, p.6317, 1990.
, Tetrahedron Lett, p.54, 2013.
, Org. Lett, vol.12, p.6334, 2010.
, J . Med. Chem, p.481, 1980.
, Monatsh. Chem, p.781, 2013.
, , vol.48, p.8090, 2012.
, Chem. Commun, p.1506, 2013.
, J. Chem. Soc. Perkin Trans. 1, 1986.
, J. Am. Chem. Soc, vol.128, p.2528, 2006.
Hydrogel functionalized with a polymerizable moiety and their uses as biosensors or bioreactors, p.738, 2008. ,
, J. Chem. Soc. Perkin Trans. 1, 1657.
, Biopolymers II, p.245, 1995.
Electrochemistry for Chemists, 1995. ,
, ) was dissolved in dry THF (45 mL) and cooled to 0°C in an ice bath under nitrogen atmosphere. Then, NaOH (aq.) 1 M (15 mL) and Boc2O (3.6 g, 16.6 mmol, 1.3 eq.) were added in this order, and the reaction mixture was stirred for 16h at room temperature. The solvent was removed by rotary evaporation and the aqueous phase was first diluted with water (60 mL) and then extracted with Et2O (3 × 60 mL). The combined organic phases were dried over Na2SO4 and
3.12 (q, J = 6.4 Hz, 2H), 1.61-1.32 (m, 17H). , 12.7 mmol, 1.0 eq.) and pyridine (1.50 g, 19.2 mmol, 1.5 eq.) in dry DCM (115 mL) at 0°C, under nitrogen atmosphere. After 1h, the mixture was allowed to slowly warm up to r.t., then stirred for 16h, concentrated under reduced pressure and diluted with Et2O (70 mL). The solution was then washed with water (3 × 70 mL) and, after that, the reunited organic phases were dried over Na2SO4 and concentrated under reduced pressure, CDCl3, 400 MHz): ? (ppm) 4.54 (bs, 1H), 3.62 (t, J = 6.4 Hz, 2H) ,
, IR (neat): ? = 3396, vol.3362, pp.1147-1148, 1516.
,
100 MHz): ? (ppm) 166.6, 166.6, 156.0, 78.9, p.25 ,
, Drug Delivery Rev, vol.53, p.321, 2001.
, Drug Delivery Rev, vol.63, p.339, 1257.
, Eur. Polym. J, vol.324, p.590, 2009.
, Adv. Mater, vol.26, p.85, 2014.
, , vol.25, p.8442, 2009.
, Chem. Mater, vol.27, p.5925, 2015.
, ACS Appl. Mater. Interfaces, vol.10, p.17408, 2017.
, Soft Matter, vol.13, p.7656, 2015.
, Angew. Chem. Int. Ed, vol.54, p.1219, 2015.
, J. Appl. Phys, vol.80, p.345, 1990.
, Polym. Degrad. Stabil, vol.156, p.228, 2018.
, Nat. Mater, vol.10, issue.183, p.7157, 2003.
, Chem. Rev, vol.103, p.351, 1685.
, Tetrahedron, vol.37, p.16, 1825.
, J. Biophotonics, vol.9, p.487, 1314.
, Methods Enzymol, p.20, 2000.
, Photochem. Photobiol, p.997, 2014.
, Nanoscale Res. Lett, p.40, 2017.
Fullerenes and Related Structures" in "Topics in Current Chemistry, M. J. Mater. Chem, vol.69, p.1097, 1993. ,
, J. Phys. Chem. A, p.7230, 1999.
, J. Phys. Chem. Chem. Phys, 1638.
, Environ. Sci. Technol, vol.42, p.4175, 2008.
, Bull. Chem. Soc. Jpn, vol.81, p.1584, 2008.
, , vol.12, p.4881, 2016.
, Chem. Rev, vol.68, p.449, 1968.
, Photochem. Photobiol. Sci, vol.12, p.4844, 2002.
, J. Am. Chem. Soc, vol.120, p.4439, 1998.
, Adv. Synth. Catal, vol.350, p.2815, 2008.
, Eur. Biophys. J, vol.40, p.339, 2011.
, J. Electroanal. Chem, vol.114, p.195, 1980.
, Chem. Commun, vol.52, p.12725, 2016.
, Org. Biomol. Chem, vol.13, p.25, 2015.
, Chem. Ber, vol.126, 1957.
, Angew. Chem. Int. Ed, p.2700, 2008.
, Nat. Chem, vol.8, p.50, 2016.
, Eur J. Org. Chem, vol.28, 2011.
Protective Groups in Organic Synthesis, 1999. ,
, , 2014.
, J. Am. Chem. Soc, vol.138, p.10766, 2016.
, Biopolymers II, p.245, 1995.
Aniline and pyrrole were freshly distilled over CaH2 under reduced pressure and stored under nitrogen, according to the reported procedures. 2 Triethylamine was distilled over CaH2 according to the reported procedure. 2 Triethylene glycol was kept for 2 days over 4 Å molecular sieves, then distilled under reduced pressure and stored under nitrogen over 4 Å molecular sieves in the drier, (THF) was distilled over metallic sodium in the presence of benzophenone ,
Petroleum ether was the 40-60 °C boiling fraction. Thin-layer chromatography was carried out on aluminum-supported Merck 60 F254 plates; detection was carried out using UV light (? = 254 and 365 nm) and permanganate followed by heating. Flash column chromatography was performed using Merck Kieselgel 60 (300-400 mesh) as the stationary phase. 1 H-NMR spectra were recorded at 300 or 400 MHz, ABA and all other chemicals employed were commercially available and used as received ,
Avance or Varian Mercury series instruments. Chemical shifts were referenced to the residual solvent peak (CDCl3, ? 7.26 ppm for 1 H-NMR and ? 77 ,
, FT-IR spectra were recorded with a Perkin-Elmer Spectrum BX instrument in the range 4000-400 cm -1 with a 2 cm -1 resolution. ESI-MS spectra were obtained by direct injection of the sample solution using a Thermo Scientific LCQ-FLEET instrument and are reported in the form m/z (intensity relative to base = 100). HRMS spectra were measured using a Thermo Scientific LTQ Orbitrap (FT-MS) instrument and are reported in the form m/z. UV-Vis spectra were recorded with a Varian Cary 400 spectrometer and a Shimadzu 2600 series spectrometer, and fluorescence spectra were recorded with a Varian Eclipse instrument, irradiating the sample at the wavelength corresponding to maximum absorption in the UV spectrum. UV-Vis spectra of the compounds on TiO2 were recorded in transmission mode after sensitization of thin, transparent semiconductor films. ATR-IR spectra of sensitized TiO2 powders were recorded with a Shimadzu model IRAffinity-1 in the range 4000-800 cm -1 . XPS experiments were carried out with a Thermo Scientific K-Alpha X-ray photoelectron spectrometer equipped with an aluminium X-ray source (energy 1486half maximum (FWHM) and the peak-area ratio of the spin-orbit components, C6D6, ? 7.16 ppm for 1 H-NMR, ? 128.06 ppm for 13 C-NMR)
The Manipulation of Air-Sensitive Compounds, 1986. ,
Purification of Laboratory Chemicals 5 th Editions, 2002. ,
, Tetrahedron, p.6285, 2014.
, ChemSusChem, vol.11, p.793, 2018.