.. .. Discussions,

.. .. Conclusions,

M. W. Barsoum, Prog. Solid State Chem, vol.28, pp.201-281, 2000.

M. Radovic and M. W. Barsoum, Am. Ceram. Soc. Bull, vol.92, pp.20-27, 2013.

M. W. Barsoum, Physical properties of the MAX phases, Encyclopedia of Materials: Science and Technology, pp.1-11, 2006.

M. W. Barsoum, D. Brodkin, and T. El-raghy, Scr. Mater, vol.36, pp.535-541, 1997.

W. K. Pang, I. M. Low, B. H. O'connor, A. J. Studer, V. K. Peterson et al., Iop, Int. Conference Neutron Scattering, p.4, 2009.

Z. M. Sun, Int. Mater. Rev, vol.56, pp.143-166, 2011.

S. Basu, N. Obando, A. Gowdy, I. Karaman, and M. Radovic, J. Electrochem. Soc, vol.159, pp.90-96, 2012.

J. L. Smialek, Corros. Sci, vol.91, pp.281-286, 2015.

V. Gauthier-brunet, T. Cabioc'h, P. Chartier, M. Jaouen, and S. Dubois, J. Eur. Ceram. Soc, vol.29, pp.187-194, 2009.

X. H. Wang, Y. C. Zhou, and Z. Metallk, Solid-liquid reaction synthesis and simultaneous densification of polycrystalline Ti2AlC, Z. Metallk, vol.93, pp.66-71, 2002.

Y. L. Bai, H. X. Zhang, X. D. He, C. C. Zhu, R. G. Wang et al., Int. J. Refract. Met. Hard Mat, vol.45, pp.58-63, 2014.

V. T. Witusiewicz, B. Hallstedt, A. A. Bondar, U. Hecht, S. V. Sleptsov et al., J. Alloy. Compd, vol.623, pp.480-496, 2015.

R. E. Loehman and A. P. Tomsia, Am. Ceram. Soc. Bull, vol.67, pp.375-380, 1988.

N. F. Gao and Y. Miyamoto, J. Mater. Res, vol.17, pp.52-59, 2002.

X. H. Yin, M. S. Li, and Y. C. Zhou, J. Mater. Res, vol.21, pp.2415-2421, 2006.

D. J. Tallman, J. Yang, L. Pan, B. Anasori, and M. W. Barsoum, J. Nucl. Mater, vol.460, pp.122-129, 2015.

O. Dezellus, R. Voytovych, A. P. Li, G. Constantin, F. Bosselet et al., J. Mater. Sci, vol.45, pp.2080-2084, 2010.

J. Zhang, G. C. Wang, Y. M. Hea, Y. Sun, and X. D. He, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process, vol.567, pp.58-64, 2013.

B. C. Mei, W. B. Zhou, J. Q. Zhu, and X. O. Hong, J. Mater. Sci, vol.39, pp.1471-1472, 2004.

D. Q. Chen, G. Y. Zhou, Z. P. Liu, and S. T. Tu, Procedia Eng, vol.130, pp.652-661, 2015.

J. Cao, J. K. Liu, X. G. Song, X. T. Lin, and J. C. Feng, Mater. Des, vol.56, pp.115-121, 2014.

J. K. Liu, J. Cao, X. T. Lin, H. Y. Chen, J. Wang et al., Vacuum, vol.102, pp.16-25, 2014.

O. Dezellus, B. Gardiola, J. Andrieux, and S. Lay, Scr. Mater, vol.104, pp.17-20, 2015.

A. Kothalkar, A. Cerit, G. Proust, S. Basu, M. Radovic et al., Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process, vol.622, pp.168-177, 2015.

S. L. Shang, Y. Wang, D. E. Kim, and Z. K. Liu, Comput. Mater. Sci, vol.47, pp.1040-1048, 2010.

J. K. Liu, J. Cao, X. G. Song, Y. F. Wang, and J. C. Feng, Mater. Des, vol.57, pp.592-597, 2014.

M. W. Barsoum, M. Ali, and T. El-raghy, Metall. Mater. Trans. A-Phys. Metall. Mater. Sci, vol.31, pp.1857-1865, 2000.

Y. Wang, Z. K. Liu, and L. Q. Chen, Acta Mater, vol.52, pp.2665-2671, 2004.

M. W. Barsoum, The M n+1 AX n phases: a new class of solids; thermodynamically stable nanolaminates, Prog Solid State Chem, vol.28, pp.201-281, 2000.

M. W. Barsoum, D. Brodkin, and T. El-raghy, Layered machinable ceramics for high temperature applications, Scripta Mater, vol.36, pp.535-541, 1997.

M. Radovic and M. W. Barsoum, MAX phases: bridging the gap between metals and ceramics, Am Ceram Soc Bull, vol.92, pp.20-27, 2013.

Z. M. Sun, Progress in research and development on MAX phases: a family of layered ternary compounds, Int Mater Rev, vol.56, pp.143-166, 2011.

M. Sundberg, G. Malmqvist, A. Magnusson, and T. El-raghy, Alumina forming high temperature silicides and carbides, Ceram Int, vol.30, pp.1899-1904, 2004.

S. Basu, N. Obando, A. Gowdy, I. Karaman, and M. Radovic, Long-term oxidation of Ti 2 AlC in air and water vapor at 1000-1300°C temperature range, J Electrochem Soc, vol.159, pp.90-96, 2012.

J. L. Smialek, Kinetic aspects of Ti 2 AlC MAX phase oxidation, Oxid Met, vol.83, pp.351-366, 2015.

T. A. Prikhna, A. V. Starostina, and D. Lizkendorf, Studies of the oxidation stability, mechanical characteristics of materials based on max phases of the Ti-Al-(C, N) systems, and of the possibility of their use as tool bonds and materials for polishing, J Superhard Mater, vol.36, pp.9-17, 2014.

S. Gupta, D. Filimonov, V. Zaitsev, T. Palanisamy, and M. W. Barsoum, Ambient and 550°C tribological behavior of select MAX phases against Ni-based superalloys, Wear, vol.264, pp.270-278, 2008.

S. Gupta, D. Filimonov, T. Palanisamy, and M. W. Barsoum, Tribological behavior of select MAX phases against Al 2 O 3 at elevated temperatures, Wear, vol.265, pp.560-565, 2008.

X. H. Wang and Y. C. Zhou, Layered machinable and electrically conductive Ti 2 AlC and Ti 3 AlC 2 ceramics: a review, J Mater Sci Technol, vol.26, pp.385-416, 2010.

Y. L. Bai, X. D. He, C. C. Zhu, and G. Q. Chen, Microstructures, electrical, thermal, and mechanical properties of bulk Ti 2 AlC synthesized by self-propagating high-temperature combustion synthesis with pseudo hot isostatic pressing, J Am Ceram Soc, vol.95, pp.358-364, 2012.

C. Dhakal, S. Aryal, R. Sakidja, and W. Ching, Approximate lattice thermal conductivity of MAX phases at high temperature, J Eur Ceram Soc, vol.35, pp.3203-3212, 2015.

E. N. Hoffman, D. W. Vinson, R. L. Sindelar, D. J. Tallman, G. Kohse et al., MAX phase carbides and nitrides: properties for future nuclear power plant in-core applications and neutron transmutation analysis, Nucl Eng Des, vol.244, pp.17-24, 2012.

W. K. Pang, I. M. Low, O. Connor, and B. H. , Comparison of thermal stability in MAX 211 and 312 phases. Int Conf Neutron Scatter, vol.251, p.4, 2009.

J. Y. Wang, Y. C. Zhou, T. Liao, J. Zhang, and Z. J. Lin, A first-principles investigation of the phase stability of Ti 2 AlC with Al vacancies, Scripta Mater, vol.58, pp.227-230, 2008.

B. Cui, D. D. Jayaseelan, and W. E. Lee, Microstructural evolution during high-temperature oxidation of Ti 2 AlC ceramics, Acta Mater, vol.59, pp.4116-4125, 2011.

J. Zhang, G. C. Wang, Y. M. Hea, Y. Sun, and X. D. He, Effect of joining temperature and holding time on microstructure and shear strength of Ti 2 AlC/Cu joints brazed using Ag-Cu filler alloy, Mater Sci Eng A-Struct Mater Prop Microstruct Process, vol.567, pp.58-64, 2013.

G. C. Wang, G. H. Fan, J. Zhang, T. P. Wang, and X. W. Liu, Microstructure evolution and brazing mechanism of Ti 2 AlC-Ti 2 AlC joint by using pure-silver filler metal, Ceram Int, vol.41, pp.8203-8210, 2015.

L. F. Hu, A. Kothalkar, G. Proust, I. Karaman, and M. Radovic, Fabrication and characterization of NiTi/Ti 3 SiC 2 and NiTi/Ti 2 AlC composites, J Alloy Compd, vol.610, pp.635-644, 2014.

Z. J. Lin, M. J. Zhuo, Y. C. Zhou, M. S. Li, and J. Y. Wang, Microstructural characterization of layered ternary Ti 2 AlC, Acta Mater, vol.54, pp.1009-1015, 2006.

C. Lu, G. Wang, G. Yang, G. Fan, J. Zhang et al., Substitution behavior of Ag atoms in the Ti 2 AlC ceramic, Journal of the American Ceramic Society, vol.100, pp.732-738, 2017.

M. W. Barsoum, The M n+1 AX n phases: a new class of solids, Prog. Solid State Chem, vol.28, issue.1-4, pp.201-281, 2000.

M. Radovic and M. W. Barsoum, MAX phases: bridging the gap between metals and ceramics, vol.92, pp.20-27, 2013.

Z. M. Sun, Progress in research and development on MAX phases: a family of layered ternary compounds, vol.56, pp.143-166, 2011.

Y. L. Bai, X. D. He, C. C. Zhu, and G. Q. Chen, Microstructures, electrical, thermal, and mechanical properties of bulk Ti 2 AlC synthesized by self-propagating high-temperature combustion synthesis with pseudo hot isostatic pressing, J. Am. Ceram. Soc, vol.95, issue.1, pp.358-364, 2012.

S. Gupta, D. Filimonov, T. Palanisamy, and M. W. Barsoum, Tribological behavior of select MAX phases against Al 2 O 3 at elevated temperatures, Wear, vol.265, issue.3-4, pp.560-565, 2008.

T. Thomas and C. R. Bowen, Thermodynamic predictions for the manufacture of Ti 2 AlC MAX-phase ceramic by combustion synthesis, J. Alloy. Compd, vol.602, pp.72-77, 2014.

S. R. Kulkarni and A. Wu, Synthesis of Ti 2 AlC by spark plasma sintering of TiAl-carbon nanotube powder mixture, J. Alloy. Compd, vol.490, issue.1-2, pp.155-159, 2010.

T. Thomas and C. R. Bowen, Effect of particle size on the formation of Ti 2 AlC using combustion synthesis, Ceram. Int, vol.42, issue.3, pp.4150-4157, 2016.

V. T. Witusiewicz, B. Hallstedt, A. A. Bondar, U. Hecht, S. V. Sleptsov et al., Thermodynamic description of the Al-C-Ti system, J. Alloy. Compd, vol.623, pp.480-496, 2015.

A. Ganguly, M. W. Barsoum, and R. D. Doherty, Interdiffusion between Ti 3 SiC 2 -Ti 3 GeC 2 and Ti 2 AlC-Nb 2 AlC diffusion couples, J. Am. Ceram. Soc, vol.90, issue.7, pp.2200-2204, 2007.

X. H. Yin, M. S. Li, T. P. Li, and Y. C. Zhou, Diffusion bonding of Ti 3 AlC 2 ceramic via a Si interlayer, J. Mater. Sci, vol.42, issue.17, pp.7081-7085, 2007.

W. K. Pang, I. M. Low, B. H. O'connor, A. J. Studer, V. K. Peterson et al., Iop, Comparison of thermal stability in MAX 211 and 312 phases, Int. Conf. Neutron Scatt, p.251, 2009.

G. C. Wang, G. H. Fan, J. Zhang, T. P. Wang, and X. W. Liu, Microstructure evolution and brazing mechanism of Ti 2 AlC-T 2 AlC joint by using pure-silver filler metal, Ceram. Int, vol.41, issue.6, pp.8203-8210, 2015.

C. Lu, G. Wang, G. Yang, G. Fan, J. Zhang et al., Substitution behavior of Ag atoms in the Ti 2 AlC ceramic, J. Am. Ceram. Soc, 2016.

W. K. Pang, I. M. Low, B. H. O'connor, V. K. Peterson, A. J. Studer et al., In situ diffraction study of thermal decomposition in Maxthal Ti 2 AlC, J. Alloy. Compd, vol.509, issue.1, pp.172-176, 2011.

C. Lu, J. Zhang, T. Duan, and C. Liu, Microstructure evolution and brazing mechanisms of the Ti 2 AlC/Ni joints using nickel based filler alloy, J. Eur. Ceram. Soc, 2016.

M. W. Barsoum, M. Ali, and T. El-raghy, Processing and characterization of Ti 2 AlC, Ti 2 AlN, and Ti 2 AlC 0.5 N 0.5, Metall. Mater. Trans. A-Phys. Metall. Mater. Sci, vol.31, issue.7, pp.1857-1865, 2000.

L. Hu, M. O'neil, V. Erturun, R. Benitez, G. Proust et al., Highperformance metal/carbide composites with far-from-equilibrium compositions and controlled microstructures, Sci. Rep, vol.6, 2016.

C. Lu, Ceramics International, vol.43, pp.8579-8584, 2017.

M. W. Barsoum, The M nþ1 AX n phases: a new class of solids; thermodynamically stable nanolaminates, Prog. Solid State Chem, vol.28, issue.1e4, pp.201-281, 2000.

M. W. Barsoum, D. Brodkin, and T. El-raghy, Layered machinable ceramics for high temperature applications, Scr. Mater, vol.36, issue.5, pp.535-541, 1997.

M. W. Barsoum, Physical properties of the MAX phases, Encycl. Mater. Sci. Technol, vol.1, issue.1, pp.1-6, 2006.

M. Radovic and M. W. Barsoum, MAX phases: bridging the gap between metals and ceramics, vol.92, pp.20-27, 2013.

G. Hug, M. Jaouen, and M. W. Barsoum, X-ray absorption spectroscopy, EELS, and full-potential augmented plane wave study of the electronic structure of Ti 2 AlC, Ti 2 AlN, Nb 2 AlC, and (Ti, Nb) 2 AlC, Phys. Rev. B, vol.71, issue.2, p.12, 2005.

N. J. Lane, S. C. Vogel, E. N. Caspi, S. Dubois, V. Gauthier-brunet et al., A high-temperature neutron diffraction and first-principles study of Ti 3 AlC 2 and Ti 3 (Al, Sn)C 2, J. Am. Ceram. Soc, vol.97, issue.2, pp.570-576, 2014.

M. W. Barsoum, M. Ali, and T. El-raghy, Processing and characterization of Ti 2 AlC, Ti 2 AlN, and Ti 2 AlC 0.5 N 0.5, vol.31, pp.1857-1865, 2000.

H. B. Zhang, Y. C. Zhou, Y. W. Bao, and M. S. Li, Improving the oxidation resistance of Ti 3 SiC 2 by forming a Ti 3 (Si, Al)C 2 solid solution, Acta Mater, vol.52, issue.12, pp.3631-3637, 2004.

P. Eklund, J. Rosen, and P. O. Persson, Layered ternary M nþ1 AX n phases and their 2D derivative MXene: an overview from a thin-film perspective, J. Phys. D. Appl. Phys, vol.50, issue.11, p.113001, 2017.

S. Kerdsongpanya, K. Buchholt, O. Tengstrand, J. Lu, J. Jensen et al., Phase-stabilization and substrate effects on nucleation and growth of (Ti, V) nþ1 GeC n thin films, J. Appl. Phys, vol.110, issue.5, p.53516, 2011.

L. Zheng, J. Wang, X. Lu, F. Li, J. Wang et al., Ti 0.5 Nb 0.5 ) 5 AlC 4 : a new-layered compound belonging to MAX phases, vol.93, pp.3068-3071, 2010.

P. Eklund, M. Beckers, U. Jansson, H. Hogberg, and L. Hultman, The M nþ1 AX n phases: materials science and thin-film processing, Thin Solid Films, vol.518, issue.8, pp.1851-1878, 2010.

Z. M. Sun, Progress in research and development on MAX phases: a family of layered ternary compounds, vol.56, pp.143-166, 2011.

J. L. Smialek, Kinetic aspects of Ti 2 AlC MAX phase oxidation, Oxid. Met, vol.83, issue.3e4, pp.351-366, 2015.

S. Basu, N. Obando, A. Gowdy, I. Karaman, and M. Radovic, Long-term oxidation of Ti 2 AlC in air and water vapor at 1000-1300 C temperature range, J. Electrochem. Soc, vol.159, issue.2, pp.90-96, 2012.

H. J. Yang, Y. T. Pei, J. C. Rao, J. T. De-hosson, S. B. Li et al., High temperature healing of Ti 2 AlC: on the origin of inhomogeneous oxide scale, vol.65, pp.135-138, 2011.

H. J. Yang, Y. T. Pei, G. M. Song, and J. T. De-hosson, Healing performance of Ti 2 AlC ceramic studied with in situ microcantilever bending, J. Eur. Ceram. Soc, vol.33, issue.2, pp.383-391, 2013.

D. Bandyopadhyay, The Ti-Si-C system (titanium-silicon-carbon), J. phase equilibria diffusion, vol.25, issue.5, pp.415-420, 2004.

Y. Zhang, G. P. Ding, Y. C. Zhou, and B. C. Cai, Ti 3 SiC 2 -a self-lubricating ceramic, Mat. Lett, vol.55, issue.5, pp.285-289, 2002.

J. Xie, X. H. Wang, A. J. Li, F. Z. Li, and Y. C. Zhou, Corrosion behavior of selected M nþ1 AX n phases in hot concentrated HCl solution: effect of a element and MX layer, Corros. Sci, vol.60, issue.1, pp.129-135, 2012.

D. J. Tallman, E. N. Hoffman, E. N. Caspi, B. L. Garcia-diaz, G. Kohse et al., Effect of neutron irradiation on select MAX phases, Acta Mater, vol.85, issue.1, pp.132-143, 2015.

E. N. Hoffman, D. W. Vinson, R. L. Sindelar, D. J. Tallman, G. Kohse et al., MAX phase carbides and nitrides: properties for future nuclear power plant in-core applications and neutron transmutation analysis, Nucl. Eng. Des, vol.244, issue.0, pp.17-24, 2012.

C. Lu, L. Sun, J. Zhang, Q. Qi, and G. Hug, Brazing mechanisms of the Ti 2 AlC joints using a pure Al filler metal, Ceram. Int, vol.43, issue.12, pp.8579-8584, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01706603

P. Hohenberg and W. Kohn, Inhomogeneous electron gas, Phys. Rev, vol.136, issue.3B, p.864, 1964.

P. E. , Bl? ochl, Projector augmented-wave method, Phys. Rev. B, vol.50, issue.24, p.17953, 1994.

J. P. Perdew, K. Burke, and M. Ernzerhof, Generalized gradient approximation made simple, Phys. Rev. Lett, vol.77, issue.18, pp.3865-3868, 1996.

T. Liao, J. Wang, and Y. Zhou, Ab initio modeling of the formation and migration of monovacancies in Ti 2 AlC, Scr. Mater, vol.59, issue.8, pp.854-857, 2008.

H. J. Monkhorst and J. D. Pack, Special points for Brillouin-zone integrations, Phys. Rev. B, vol.13, issue.12, p.5188, 1976.

C. Lu, J. Zhang, T. Duan, and C. Liu, Microstructure evolution and brazing mechanisms of the Ti 2 AlC/Ni joints using nickel based filler alloy, J. Eur. Ceram. Soc, vol.36, issue.14, pp.3319-3327, 2016.

M. Baben, L. Shang, J. Emmerlich, and J. M. Schneider, Oxygen incorporation in M 2 AlC, vol.60, pp.4810-4818, 2012.

J. Y. Wang, Y. C. Zhou, T. Liao, J. Zhang, and Z. J. Lin, A first-principles investigation of the phase stability of Ti 2 AlC with Al vacancies, Scr. Mater, vol.58, issue.3, pp.227-230, 2008.

V. J. Keast, S. Harris, and D. K. Smith, Prediction of the stability of the M nþ1 AX n phases from first principles, Phys. Rev. B, vol.80, issue.21, p.7, 2009.

A. Thore, M. Dahlqvist, B. Alling, and J. Rosen, Temperature dependent phase stability of nanolaminated ternaries from first-principles calculations, Comput. Mat. Sci, vol.91, issue.1, pp.251-257, 2014.

D. J. Tallman, J. Yang, L. Pan, B. Anasori, and M. W. Barsoum, Reactivity of Zircaloy-4 with Ti 3 SiC 2 and Ti 2 AlC in the 1100-1300 C temperature range, J. Nucl. Mater

M. W. Barsoum, D. Brodkin, and T. El-raghy, Scripta Mater, vol.36, issue.5, pp.535-541, 1997.

M. Radovic and M. W. Barsoum, Am. Ceram. Soc. Bull, vol.92, issue.3, pp.20-27, 2013.

M. W. Barsoum, Prog. Solid State Chem, vol.28, issue.1-4, pp.201-281, 2000.

Z. M. Sun, Int. Mater. Rev, vol.56, issue.3, pp.143-166, 2011.

J. L. Smialek, Oxid. Met, vol.83, issue.3-4, pp.351-366, 2015.

S. R. Kulkarni and A. Wu, J. Alloy. Compd, vol.490, issue.1-2, pp.155-159, 2010.

Y. L. Bai, H. X. Zhang, and X. D. He, Int. J. Refract. Met. Hard Mat, vol.45, pp.58-63, 2014.

R. E. Loehman and A. P. Tomsia, Am. Ceram. Soc. Bull, vol.67, issue.2, pp.375-380, 1988.

A. Ganguly, M. W. Barsoum, and R. D. Doherty, J. Am. Ceram. Soc, vol.90, issue.7, pp.2200-2204, 2007.

D. J. Tallman, J. Yang, and L. Pan, J. Nucl. Mater, vol.460, pp.122-129, 2015.

N. Eustathopoulos, M. G. Nicholas, and B. Drevet, Wettability at high temperatures, 1999.

W. K. Pang, I. M. Low, and B. H. O'connor, J. Alloy. Compd, vol.509, issue.1, pp.172-176, 2011.

S. K. Tung, L. C. Lim, and M. O. Lai, Scripta Mater, vol.34, issue.5, pp.763-769, 1996.

, Morphology of the Al/Ti 2 AlC sample: (a). cross-section; (b). triple line; (c). surface morphology of the reacted area; (d)

C. Lu, Materials Letters, vol.219, pp.240-242, 2018.

Z. W. Huang, Isothermal low-cycle fatigue and thermomechanical fatigue behavior of MCrAlY coated and uncoated nickel base superalloy, 2008.

X. Z. Bu, Research on laser welding of Inconel601 nickel based superalloy, 2011.

Z. Y. Pei, Study on K465 nickel-base superalloy, 2008.

W. Jeitschko, H. Nowotny, and F. Benesovsky, Carbon-containing ternary compounds (H-phase), Monatsh. Chem, vol.94, issue.4, pp.672-676, 1963.

W. Jeitschko, H. Nowotny, and F. Benesovsky, Ti2AlN, eine stickstoffhaltige H-phase, Monatsh. Chem, vol.94, issue.6, pp.1198-1200, 1963.

M. W. Barsoum, The Mn+1AXn phases: a new class of solids; thermodynamically stable nanollaminates, Progress in Solid State Chemistry, vol.28, issue.4, pp.201-281, 2000.

J. Y. Wang and Y. C. Zhou, Recent progress in theoretical prediction, preparation, and characterization of layered ternary transition-metal carbides, Annual Review of Materials Research, vol.39, pp.415-443, 2009.

Y. X. Mo, P. Rulis, and W. Y. Ching, Electronic structure and optical conductivities of 20 MAX-phase compounds, Physical Review B, vol.86, issue.16, p.165122, 2012.

M. Radovic and M. W. Barsoum, MAX phases: bridging the gap between metals and ceramics, American Ceramics Society Bulletin, vol.92, issue.3, pp.20-27, 2013.

M. W. Barsoum, D. Brodkin, and T. El-raghy, Layered machinable ceramics for high temperature applications, Scripta Materialia, vol.36, issue.5, pp.535-541, 1997.

W. K. Pang, I. M. Low, B. H. O'connor, A. J. Studer, V. K. Peterson et al., Comparison of thermal stability in MAX 211 and 312 phases, Journal of Physics: Conference Series, vol.251, issue.1, p.12025, 2010.

W. B. Zhou, B. C. Mei, J. Q. Zhu, and Y. L. Chen, Study on the machinable Ti2AlC ceramic, Journal of Wuhan University of Technology, vol.24, issue.9, pp.22-24, 2002.

X. H. Wang and Y. C. Zhou, Oxidation behavior of Ti3AlC2 at, pp.1000-1400

?. Air, Corrosion Science, p.45

S. Basu, N. Obando, A. Gowdy, I. Karaman, and M. Radovic, Long-term oxidation of Ti2AlC in air and water vapor at, pp.1000-1300

?. Range, Journal of the Electrochemical Society, vol.159, issue.2, pp.90-96, 2012.

G. M. Song, V. Schnabel, C. Kwakernaak, S. Van-der-zwaag, J. M. Schneider et al., High temperature oxidation behaviour of Ti2AlC, p.1200

?. C. , Materials at High Temperatures, vol.29, issue.3, pp.205-209, 2012.

D. J. Tallman, B. Anasori, and M. W. Barsoum, A critical review of the oxidation of Ti2AlC, Ti3AlC2 and Cr2AlC in air, Materials Research Letters, vol.1, issue.3, pp.115-125, 2013.

G. M. Song, S. B. Li, C. X. Zhao, W. G. Sloof, S. Van-der-zwaag et al., Ultra-high temperature ablation behavior of Ti2AlC ceramics under an oxyacetylene flame, Journal of the European Ceramic Society, vol.31, issue.5, pp.855-862, 2011.

Y. Chen, Thermodynamics, synthesis, oxidation properties of Ti2AlC and Cr2AlC ceramics, 2012.

Y. Zhou, Y. X. Li, X. K. Qian, and W. H. , Microstructure and adhesion of oxide scale formed on Ti3AlC2 after cyclic oxidation, Journal of Materials Engineering, vol.2, issue.9, pp.14-18, 2012.

Y. Zhou, Y. X. Li, X. K. Qian, and P. Zhou, Cyclic oxidation and residual stress within the scale of Ti3AlC2 at 1000

?. C. , Bulletin of the Chinese Ceramic Society, vol.12, issue.2, pp.403-410, 2012.

H. P. Zhu, X. K. Qian, H. Y. Wu, J. Lei, Y. C. Song et al., Cyclic oxidation of ternary layered Ti2AlC at, pp.600-1000

, ? C in airxidation of ternary layered, International Journal of Applied Ceramic Technology, vol.12, issue.2, pp.403-410, 2015.

H. J. Yang, Y. T. Pei, J. C. Rao, J. M. Th, S. B. De-hosson et al., High temperature healing of Ti2AlC: On the origin of inhomogeneous oxide scale, Scripta Materialia, vol.65, issue.2, pp.135-138, 2011.

H. J. Yang, Y. T. Pei, J. C. Rao, J. M. Th, and . De-hosson, Self-healing performance of Ti2AlC ceramic, Journal of Materials Chemistry, vol.22, issue.17, pp.8304-8313, 2012.

S. B. Li, G. M. Song, K. Kwakernaak, S. Van-der-zwaag, and W. G. Sloof, Multiple crack healing of a Ti2AlC ceramic, Journal of the European Ceramic Society, vol.32, issue.8, pp.1813-1820, 2012.

S. B. Li, L. Xiao, G. M. Song, X. M. Wu, W. G. Sloof et al., Oxidation and crack healing behavior of a fine-grained Cr2AlC ceramic, Journal of the American Ceramic Society, vol.96, issue.3, pp.892-899, 2013.

H. J. Yang, Y. T. Pei, J. M. Th, and . De-hosson, Oxide-scale growth on Cr2AlC ceramic and its consequence for self-healing, Scripta Materialia, vol.69, issue.2, pp.203-206, 2013.

H. J. Yang, Y. T. Pei, G. M. Song, J. M. Th, and . De-hosson, Healing performance of Ti2AlC ceramic studied with in situ microcantilever bending, Journal of the European Ceramic Society, vol.33, issue.2, pp.383-391, 2013.

X. H. Wang and Y. C. Zhou, Layered machinable and electrically conductive Ti2AlC and Ti3AlC2 ceramics: a review, Journal of Materials Science and Technology, vol.26, issue.5, pp.385-416, 2010.

M. A. Pietzka and J. C. Schuster, Summary of constitutional data on the aluminum-carbon-titanium system, Journal of Phase Equilibria, vol.15, issue.4, pp.392-400, 1994.

V. T. Witusiewicz, B. Hallstedt, A. A. Bondar, U. Hecht, S. V. Sleptsov et al., Thermodynamic description of the Al-C-Ti system, Journal of Alloys and Compounds, vol.623, pp.480-496, 2015.

W. B. Zhou, Study on the fabrication of Ti2AlC ceramics, 2003.

W. Ping, B. C. Mei, X. L. Hong, and W. B. Zhou, Synthesis of Ti2AlC by hot pressing and its mechanical and electrical properties, Transactions of Nonferrous Metals Society of China, vol.17, issue.5, pp.1001-1004, 2007.

C. H. Yang, F. Wang, T. T. Ai, and J. F. Zhu, Microstructure and mechanical properties of in situ TiAl/Ti2AlC composites prepared by reactive hot pressing, Ceramics International, vol.40, issue.6, pp.8165-8171, 2014.

M. W. Barsoum, T. El-raghy, and M. Ali, Processing and characterization of Ti2AlC, Ti2AlN, and Ti2AlC0.5N0.5. Metallurgical and Materials Transactions A, vol.31, pp.1857-1865, 2000.

N. V. Tzenov and M. W. Barsoum, Synthesis and characterization of Ti3AlC2, Journal of the American Ceramic Society, vol.83, issue.4, pp.825-832, 2000.

V. Gauthier-brunet, T. Cabioc'h, P. Chartier, M. Jaouen, and S. Dubois, Reaction synthesis of layered ternary Ti2AlC ceramic, Journal of the European Ceramic Society, vol.29, issue.1, pp.187-194, 2009.

L. Li, A. G. Zhou, L. Xu, Z. Y. Li, and L. B. Wang, Synthesis of high pure Ti3AlC2 and Ti2AlC powders from TiH2 powders as Ti source by tube furnace, Journal of Wuhan University of Technology-Mater. Sci. Ed, vol.28, issue.5, pp.882-887, 2013.

B. C. Mei, W. B. Zhou, J. Q. Zhu, and X. L. Hong, Synthesis of high-purity Ti2AlC by spark plasma sintering (SPS) of the elemental powders, Journal of materials science, vol.39, issue.4, pp.1471-1472, 2004.

S. R. Kulkarni, A. V. Datye-kuang-his, and . Wu, Synthesis of Ti2AlC by spark plasma sintering of TiAlcarbon nanotube powder mixture, Journal of Alloys and Compounds, vol.590, issue.1, pp.155-159, 2010.

T. Lapauw, K. Vanmeensel, K. Lambrinou, and J. Vleugels, A new method to texture dense Mn+1AXn ceramics by spark plasma deformation, Scripta Materialia, vol.111, pp.98-101, 2016.

S. Hashimoto, N. Nishina, K. Hirao, Y. Zhou, H. Hyuga et al., Formation mechanism of Ti2AlC under the self-propagating high-temperature synthesis (SHS) mode, Materials Research Bulletin, vol.47, issue.5, pp.1164-1168, 2012.

Y. L. Bai, H. X. Zhang, X. D. He, C. C. Zhu, R. G. Wang et al., Growth morphology and microstructural characterization of nonstoichiometric Ti2AlC bulk synthesized by selfpropagating high temperature combustion synthesis with pseudo hot isostatic pressing, International Journal of Refractory Metals and Hard Materials, vol.45, pp.58-63, 2014.

T. Thomas and C. R. Bowen, Thermodynamic predictions for the manufacture of Ti2AlC MAX-phase ceramic by combustion synthesis, Journal of Alloys and Compounds, vol.602, pp.72-77, 2014.

Z. J. Zhan, Y. Q. Lu, and W. K. Wang, Review of layered ternary compound MAX phases, Journal of Yanshan University, vol.36, issue.3, pp.189-195, 2012.

R. E. Loehman and A. P. Tomsia, Joining of ceramics, American Ceramic Society Bulletin, vol.67, issue.2, pp.375-380, 1988.

J. A. Fernie, R. Drew, and K. M. Knowles, Joining of engineering ceramics. International Materials Reviews, vol.54, issue.5, pp.283-331, 2009.

M. G. Nicholas, Joining processes, 1998.

L. W. Wang and F. Aldinger, Joining of advanced ceramics in green state, Materials Letters, vol.54, issue.2, pp.93-97, 2002.

J. Zheng and M. Akinc, Green state joining of sic without applied pressure, Journal of the American Ceramic Society, vol.84, issue.11, pp.2479-2483, 2001.

H. Gao, J. C. Liu, H. Y. Du, M. Liu, L. J. Wang et al., Effects of interlayer composition on joining of 25 % CePO4/ZrO2-ZrO2 ceramics on green state, Ceramics international, vol.30, issue.6, pp.823-827, 2004.

K. Ozturk, R. N. Basu, C. A. Randall, and M. J. Mayo, Diffusion bonding of rigid zirconia pieces using electrophoretically deposited particulate interlayers, Scripta materialia, vol.41, issue.11, pp.1191-1195, 1999.

M. Gopal, L. C. De-jonghe, and G. Thomas, Silicon nitride joining using rare-earth reaction sintering, Scripta materialia, vol.36, issue.4, pp.455-460, 1997.

T. Fukai, M. Naka, and J. C. Schuster, Interfacial microstructure and reaction phases of solid state bonded at SiC/V joints, Journal of Materials Synthesis and Processing, vol.6, issue.6, pp.387-392, 1998.

P. Miranzo, M. I. Osendi, and I. Vergara, Mechanical properties of the Ni filler metal layer in Si3N4 joints measured by nanoindentation, Surface and interface analysis, vol.36, issue.7, pp.649-653, 2004.

M. Vila, M. L. Martinez, C. Prieto, P. Miranzo, M. I. Osendi et al., Experimental determination of residual stress in silicon nitride diffusion bonds obtained by high-energy X-ray diffraction, Powder technology, vol.148, issue.1, pp.60-63, 2004.

J. Lemus and R. Drew, Diffusion bonding of silicon nitride to titanium, British ceramic transactions, vol.99, issue.5, pp.200-205, 2000.

J. Lemus and R. Drew, Joining of silicon nitride with a titanium foil interlayer, Materials Science and Engineering: A, vol.352, issue.1, pp.169-178, 2003.

A. Abed, P. Hussain, I. S. Jalham, and A. Hendry, Joining of sialon ceramics by a stainless steel interlayer, Journal of the European Ceramic Society, vol.21, issue.16, pp.2803-2809, 2001.

R. Polanco, A. De-pablos, P. Miranzo, and M. I. Osendi, Metal-ceramic interfaces: joining silicon nitridestainless steel, Applied surface science, vol.238, issue.1, pp.506-512, 2004.

W. Tillmann, J. Pfeiffer, and L. Wojarski, Influencing factors on the reactive wetting of Cu-Sn-Ti and AgCu-Ti alloys on silicon carbide-microstructural observations, effects and multivariate modelling, Advances in Science and Technology, vol.88, 2014.

G. Wang, P. Xiao, Z. J. Huang, and R. J. He, Brazing of ZrB2-SiC ceramic with amorphous CuTiNiZr filler, Ceramics International, vol.42, issue.4, pp.5130-5135, 2016.

H. P. Xiong, B. Chen, W. L. Guo, and L. Ye, Wettability of PdNi (Co)-Cr alloys on Si3N4 ceramic and joining of Si3N4 to Si3N4, Welding in the World, vol.59, issue.1, pp.33-44, 2015.

Y. Sun, J. Zhang, Y. P. Geng, K. Ikeuchi, and T. Shibayanagi, Microstructure and mechanical properties of an Si3N4/Si3N4 joint brazed with Au-Ni-Pd-V filler alloy, Scripta Materialia, vol.64, issue.5, pp.414-417, 2011.

M. Ali, K. M. Knowles, P. M. Mallinson, and J. A. Fernie, Microstructural evolution and characterisation of interfacial phases in Al2O3/Ag-Cu-Ti/Al2O3 braze joints, Acta Materialia, vol.96, pp.143-158, 2015.

M. Ali, K. M. Knowles, P. M. Mallinson, and J. A. Fernie, Interfacial reactions between sapphire and Ag-Cu-Ti based active braze alloys, Acta Materialia, vol.103, pp.859-869, 2016.

R. Voytovych, L. Y. Ljungberg, and N. Eustathopoulos, The role of adsorption and reaction in wetting in the CuAg-Ti/alumina system, Scripta materialia, vol.51, issue.5, pp.431-435, 2004.

M. Nomura, C. Iwamoto, and S. Tanaka, Nanostructure of wetting triple line in a Ag-Cu-Ti/Si3N4 reactive system, Acta materialia, vol.47, issue.2, pp.407-413, 1999.

C. Iwamoto and S. Tanaka, Interface nanostructure of brazed silicon nitride, Journal of the American Ceramic Society, vol.81, issue.2, pp.363-368, 1998.

A. Abed, I. S. Jalham, and A. Hendry, Wetting and reaction between ?'-sialon, stainless steel and Cu-Ag brazing alloys containing Ti, Journal of the European Ceramic Society, vol.21, issue.3, pp.283-290, 2001.

W. Tillmann, E. Lugscheider, K. Schlimbach, C. Manter, and J. E. Indacochea, Heat-resistant active brazing of silicon nitride part 1: mechanical evaluation of braze joints, Welding Journal, vol.76, issue.8, pp.300-304, 1997.

W. Tillmann, E. Lugscheider, K. Schlimbach, C. Manter, and J. E. Indacochea, Heat-resistant active brazing of silicon nitride part 2: metallurgical characterization of the braze joint, Welding Journal, vol.77, pp.103-108, 1998.

D. S. Duval, W. A. Owczarki, and D. F. Paulonic, TLP bonding-a new method for joining heat resistant alloy, Welding Journal, vol.53, pp.203-215, 1974.

Y. Iino, Partial transient liquid-phase metals layer technique of ceramic-metal bonding, Journal of materials science letters, vol.10, issue.2, pp.104-106, 1991.

M. R. Locatelli, B. J. Dalgleish, K. Nakashima, A. P. Tomsia, and A. M. Glaeser, New approaches to joining ceramics for high-temperature applications, Ceramics International, vol.23, issue.4, pp.313-322, 1997.

Z. M. Sun, R. Ahuja, and J. M. Schneider, Theoretical investigation of the solubility in (MxM 2?x)AlC (M and M =Ti, vol.68, p.224112, 2003.

A. Ganguly, T. Zhen, and M. W. Barsoum, Synthesis and mechanical properties of Ti3GeC2 and Ti3(SixGe1?x)C2 (x=0.5, 0.75) solid solutions, Journal of alloys and compounds, vol.376, issue.1, pp.287-295, 2004.

A. Ganguly, M. W. Barsoum, and R. D. Doherty, Interdiffusion between Ti3SiC2-Ti3GeC2 and Ti2AlC-Nb2AlC diffusion couples, Journal of the American Ceramic Society, vol.90, issue.7, pp.2200-2204, 2007.

X. H. Yin, M. S. Li, J. J. Xu, J. Zhang, and Y. C. Zhou, Direct diffusion bonding of Ti3SiC2 and Ti3AlC2, Materials Research Bulletin, vol.44, issue.6, pp.1379-1384, 2009.

X. H. Yin, M. S. Li, T. P. Li, and Y. C. Zhou, Diffusion bonding of Ti3AlC2 ceramic via a Si interlayer, Journal of materials science, vol.42, issue.17, pp.7081-7085, 2007.

X. H. Yin, M. S. Li, and Y. C. Zhou, Microstructure and mechanical strength of transient liquid phase bonded Ti3SiC2 joints using Al interlayer, Journal of the European Ceramic Society, vol.27, issue.12, pp.3539-3544, 2007.

E. Heikinheimo, I. Isomäki, A. A. Kodentsov, and F. J. Van-loo, Chemical interaction between Fe and silicon nitride ceramic, Journal of the European Ceramic Society, vol.17, issue.1, pp.25-31, 1997.

K. Bhanumurthy and R. Schmid-fetzer, Interface reactions between SiC/Zr and development of zirconium base composites by in-situ solid state reactions, Scripta materialia, vol.45, issue.5, pp.547-553, 2001.

J. Feng, D. Wang, H. Liu, and Z. Li, Finite element simulation of thermal stress during diffusion bonding of Al2O3 ceramic to aluminium. Science and technology of welding and joining, vol.8, pp.138-142, 2003.

N. F. Gao and Y. Miyamoto, Joining of Ti3SiC2 with Ti-6Al-4V alloy, Journal of materials research, vol.17, issue.1, pp.52-59, 2002.

X. H. Yin, M. S. Li, and Y. C. Zhou, Microstructure and mechanical strength of diffusion-bonded Ti3SiC2/Ni joints, Journal of materials research, vol.21, issue.9, pp.2415-2421, 2006.

X. H. Yin, M. S. Li, Y. Wang, and Y. C. Zhou, The effects of bonding temperature, pressure and holding time on the shear strength of diffusion bonded Ti3SiC2/Ni joints, Rare Metal Materials and Engineering, vol.36, pp.461-464, 2007.

D. J. Tallman, J. Yang, L. M. Pan, B. Anasori, and M. W. Barsoum, Reactivity of Zircaloy-4 with Ti3SiC2 and Ti2AlC in the, pp.1100-1300

?. Range, Journal of Nuclear Materials, vol.460, pp.122-129, 2015.

Z. Abdallah, M. T. Whittaker, and M. R. Bache, High temperature creep behaviour in the ? titanium aluminide Ti-45Al-2Mn-2Nb. Intermetallics, vol.38, pp.55-62, 2013.

H. Clemens and H. Kestler, Processing and applications of intermetallic ?-TiAl based alloys, Advanced engineering materials, vol.2, issue.9, pp.551-570, 2000.

Y. W. Kim, Ordered intermetallic alloys, part III: gamma titanium aluminides, JOM Journal of the Minerals, Metals and Materials Society, vol.46, issue.7, pp.30-39, 1994.

T. T. Ai, F. Wang, X. M. Feng, and M. M. Ruan, Microstructural and mechanical properties of dual Ti3AlC2-Ti2AlC reinforced TiAl composites fabricated by reaction hot pressing, Ceramics International, vol.40, issue.7, pp.9947-9953, 2014.

J. Cheng, F. Li, L. C. Fu, Z. H. Qiao, J. Yang et al., Dry-sliding tribological properties of TiAl/Ti2AlC composites, Tribology Letters, vol.53, issue.2, pp.457-467, 2014.

T. Kumagai and M. Nakamura, Effects of aluminum content and microstructure on tensile properties of TiAl alloys, Scripta materialia, vol.34, issue.7, pp.1147-1154, 1996.

S. C. Huang and E. L. Hall, The effects of Cr additions to binary TiAl-base alloys, Metallurgical Transactions A, vol.22, issue.11, pp.2619-2627, 1991.

X. B. Liu and H. M. Wang, Modification of tribology and high-temperature behavior of Ti-48Al-2Cr-2Nb intermetallic alloy by laser cladding, Applied surface science, vol.252, issue.16, pp.5735-5744, 2006.

A. R. Rastkar and T. Bell, Characterization and tribological performance of oxide layers on a gamma based titanium aluminide, Wear, vol.258, issue.11, pp.1616-1624, 2005.

X. J. Li, G. A. Cheng, W. B. Xue, R. T. Zheng, and Y. J. Cheng, Wear and corrosion resistant coatings formed by microarc oxidation on TiAl alloy, Materials Chemistry and Physics, vol.107, issue.1, pp.148-152, 2008.

L. F. Hu, A. Kothalkar, G. Proust, I. Karaman, and M. Radovic, Fabrication and characterization of NiTi/Ti3SiC2 and NiTi/Ti2AlC composites, Journal of Alloys and Compounds, vol.610, pp.635-644, 2014.

H. F. Sun, X. W. Li, P. Zhang, and W. B. Fang, The microstructure and tensile properties of the Ti2AlC reinforced TiAl composites fabricated by powder metallurgy, Materials Science and Engineering: A, vol.611, pp.257-262, 2014.

S. L. Shu, F. Qiu, S. J. Lv, S. B. Jin, and Q. C. Jiang, Phase transitions and compression properties of Ti2AlC/TiAl composites fabricated by combustion synthesis reaction, Materials Science and Engineering: A, vol.539, pp.344-348, 2012.

S. Basu, M. F. Ozaydin, A. Kothalkar, I. Karaman, and M. Radovic, Phase and morphology evolution in high-temperature Ti3SiC2-NiTi diffusion-bonded joints, Scripta Materialia, vol.65, issue.3, pp.237-240, 2011.

A. Kothalkar, A. Cerit, G. Proust, S. Basu, M. Radovic et al., Interfacial study of NiTi-Ti3SiC2 solid state diffusion bonded joints, Materials Science and Engineering: A, vol.622, pp.168-177, 2015.

J. Cao, J. K. Liu, X. G. Song, X. T. Lin, and J. C. Feng, Diffusion bonding of TiAl intermetallic and Ti3AlC2 ceramic: Interfacial microstructure and joining properties, Materials & Design, vol.56, pp.115-121, 2014.

J. K. Liu, J. Cao, X. T. Lin, H. Y. Chen, J. Wang et al., Interfacial microstructure and joining properties of TiAl/Ti3AlC2 diffusion bonded joints using Zr and Ni foils as interlayer, Vacuum, vol.102, pp.16-25, 2014.

J. K. Liu, J. Cao, X. G. Song, Y. F. Wang, and J. C. Feng, Evaluation on diffusion bonded joints of TiAl alloy to Ti3SiC2 ceramic with and without Ni interlayer: interfacial microstructure and mechanical properties, Materials & Design, vol.57, pp.592-597, 2014.

J. K. Liu, J. L. Qi, J. Cao, X. T. Lin, Z. J. Wang et al., Study on vacuum brazing of DD3 Ni-base superalloy and Ti3AlC2. Transactions of the China Welding Institution, vol.35, pp.41-44, 2014.

O. Dezellus, R. Voytovych, A. P. Li, G. Constantin, F. Bosselet et al., Wettability of Ti3SiC2 by Ag-Cu and Ag-Cu-Ti melts, Journal of materials science, vol.45, issue.8, pp.2080-2084, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00423015

O. Dezellus, B. Gardiola, J. Andrieux, and S. Lay, Experimental evidence of copper insertion in a crystallographic structure of Ti3SiC2 MAX phase, Scripta Materialia, vol.104, pp.17-20, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01153723

Y. Zheng, Study on brazing process and its mechanism of Ti2AlC ceramic to copper, 2009.

J. Zhang, G. C. Wang, and Y. Zheng, Effect of Sn content on the microstructure, mechanical and electrical properties of Ti2AlC/Cu joints brazed with Cu-Sn-Ti filler alloy, Materials Science Forum, vol.762, pp.602-606, 2013.

G. C. Wang, G. H. Fan, J. Zhang, T. P. Wang, and X. W. Liu, Microstructure evolution and brazing mechanism of Ti2AlC-Ti2AlC joint by using pure-silver filler metal, Ceramics International, vol.41, issue.6, pp.8203-8210, 2015.

G. C. Wang, J. Zhang, and X. W. Liu, Characterizing the decomposition of Ti2AlC during its brazing with Cu by using Ag-Cu filler alloy, Materials Science Forum, vol.762, pp.607-611, 2013.

J. Zhang, G. C. Wang, Y. M. He, Y. Sun, and X. D. He, Effect of joining temperature and holding time on microstructure and shear strength of Ti2AlC/Cu joints brazed using Ag-Cu filler alloy, Materials Science and Engineering: A, vol.567, pp.58-64, 2013.

C. Lu, L. Sun, J. Zhang, Q. Qi, and G. Hug, Brazing mechanisms of the Ti2AlC joints using a pure Al filler metal, Ceramics International, vol.43, issue.12, pp.8579-8584, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01706603

A. J. Li, C. F. Hu, M. S. Li, and Y. C. Zhou, Joining of Ti-Al-C ceramics by oxidation at low oxygen partial pressure, Journal of the European Ceramic Society, vol.29, issue.12, pp.2619-2625, 2009.

M. Dahlqvist, B. Alling, and J. Rosén, Stability trends of max phases from first principles, Physical Review B, vol.81, p.220102, 2010.

A. Thore, M. Dahlqvist, B. Alling, and J. Rosen, Temperature dependent phase stability of nanolaminated ternaries from first-principles calculations, Computational Materials Science, vol.91, pp.251-257, 2014.

Y. C. Zhou and Z. M. Sun, Electronic structure and bonding properties of layered machinable Ti2AlC and Ti2AlN ceramics, Physical Review B, vol.61, issue.19, pp.12570-12573, 2000.

Y. C. Zhou and Z. M. Sun, Electronic structure and bonding properties in layered ternary carbide Ti3SiC2, Journal of Physics-Condensed Matter, vol.12, issue.28, pp.457-462, 2000.

Y. C. Zhou, X. H. Wang, Z. M. Sun, and S. Q. Chen, Electronic and structural properties of the layered ternary carbide Ti3AlC2, Journal of Materials Chemistry, vol.11, issue.9, pp.2335-2339, 2001.

J. M. Wang, J. Y. Wang, Y. C. Zhou, and C. F. Hu, Phase stability, electronic structure and mechanical properties of ternary-layered carbide Nb4AlC3: an ab initio study, Acta materialia, vol.56, issue.7, pp.1511-1518, 2008.

C. W. Zhang, Z. Zhang, P. J. Wang, Y. Wang, J. M. Dong et al., First-principles study of electronic structure of V2AlC and V2AlN, Solid State Communications, vol.144, issue.7, pp.347-351, 2007.

H. Y. Wu, X. K. Qian, H. P. Zhu, J. Lei, and X. D. He, First-principles study of the structural, electronic and elastic properties of ternary Zr2AN (A = Ga, In and Tl). Computational Materials Science, vol.84, pp.103-107, 2014.

M. Magnuson, J. P. Palmquist, M. Mattesini, S. Li, R. Ahuja et al., Electronic structure investigation of Ti3AlC2, Ti3SiC2, and Ti3GeC2 by soft x-ray emission spectroscopy, Physical Review B, vol.72, p.245101, 2005.

M. Magnuson, M. Mattesini, O. Wilhelmsson, J. Emmerlich, J. P. Palmquist et al., Electronic structure and chemical bonding in Ti4SiC3 investigated by soft x-ray emission spectroscopy and first-principles theory, Physical Review B, vol.74, p.205102, 2006.

M. Magnuson, O. Wilhelmsson, J. P. Palmquist, U. Jansson, M. Mattesini et al., Electronic structure and chemical bonding in Ti2AlC investigated by soft x-ray emission spectroscopy, Physical Review B, vol.74, 2006.

M. Magnuson, M. Mattesini, S. Li, C. Hoglund, M. Beckers et al., Bonding mechanism in the nitrides Ti2AlN and TiN: An experimental and theoretical investigation, Physical Review B, vol.76, p.195127, 2007.

T. Liao, J. Y. Wang, and Y. C. Zhou, Ab initio modeling of the formation and migration of monovacancies in Ti2AlC, Scripta Materialia, vol.59, pp.854-857, 2008.

K. Liu, Y. Qi, and J. Z. Duan, First-principles investigation of the vacancy effect on the electon properties in M2AlC(M = V and Nb, vol.4, p.107137, 2014.

J. J. Chen, J. Z. Duan, C. L. Wang, W. S. Duan, and L. Yang, The monovacancy formation energy and its effect on the electronic property, the lattice parameters and the hardness of the new found MAX phase, Nb2GeC. Computational Materials Science, vol.82, pp.521-524, 2014.

J. Y. Wang, Y. C. Zhou, T. Liao, J. Zhang, and Z. J. Lin, A first-principles investigation of the phase stability of Ti2AlC with Al vacancies, Scripta Materialia, vol.58, issue.3, pp.227-230, 2008.

S. C. Middleburgh, G. R. Lumpkin, and D. Riley, Accommodation, accumulation, and migration of defects in Ti3SiC2 and Ti3AlC2 MAX Phases, Journal of the American Ceramic Society, vol.96, issue.10, pp.3196-3201, 2013.

S. Kerdsongpanya, K. Buchholt, O. Tengstrand, J. Lu, J. Jensen et al., Phasestabilization and substrate effects on nucleation and growth of (Ti, V)n+1GeCn thin films, Journal of Applied Physics, vol.110, issue.5, p.53516, 2011.

F. L. Meng, Y. C. Zhou, and J. Y. Wang, Strengthening of Ti2AlC by substituting Ti with V, Scripta Materialia, vol.53, issue.12, pp.1369-1372, 2005.

Y. C. Zhou, H. B. Zhang, M. Y. Liu, J. Y. Wang, and Y. W. Bao, Preparation of TiC free Ti3SiC2 with improved oxidation resistance by substitution of Si with Al, Materials Research Innovations, vol.8, issue.2, pp.97-102, 2004.

Y. C. Zhou, J. X. Chen, and J. Y. Wang, Strengthening of Ti3AlC2 by incorporation of Si to form Ti3(Al, Si)C2 solid solutions, Acta Materialia, vol.54, issue.5, pp.1317-1322, 2006.

G. Hug and E. Fries, Full-potential electronic structure of Ti2AlC and Ti2AlN, Physical Review B, vol.65, issue.11, p.4, 2002.

G. Hug, M. Jaouen, and M. W. Barsoum, X-ray absorption spectroscopy, EELS, and full-potential augmented plane wave study of the electronic structure of Ti2AlC, Ti2AlN, Nb2AlC, and (Ti, Nb)2AlC, Physical Review B, vol.71, issue.2, p.12, 2005.

J. Y. Wang and Y. C. Zhou, First-principles study of equilibrium properties and electronic structure of Ti3(Si, Al)C2 solid solution, Journal of Physics-Condensed Matter, vol.15, issue.35, pp.5959-5968, 2003.

M. S. Li, G. Liu, Y. Zhang, and Y. C. Zhou, Influence of Al-La cocementation on the oxidation behavior of Ti3SiC2-base ceramic, Oxidation Of Metals, vol.60, issue.1, pp.179-193, 2003.

P. O. Persson, J. Rosen, D. R. Mckenzie, and M. M. Bilek, Formation of the MAX-phase oxycarbide Ti2Al(C, O) studied via electron energy-loss spectroscopy and first-principles calculations, Physical Review B, vol.80, issue.9, p.4, 2009.

J. Rosen, M. Dahlqvist, S. I. Simak, D. R. Mckenzie, and M. M. Bilek, Oxygen incorporation in Ti2AlC: Tuning of anisotropic conductivity, Applied Physics Letters, vol.97, issue.7, p.3, 2010.

M. Dahlqvist, B. Alling, I. A. Abrikosov, and J. Rosen, Phase stability of Ti2AlC upon oxygen incorporation: A first-principles investigation, Physical Review B, vol.81, issue.2, 2010.

M. Dahlqvist, Benefits of oxygen incorporation in atomic laminates, Journal of Physics-Condensed Matter, vol.28, issue.13, p.135501, 2016.

L. F. Hu, M. O'neil, V. Erturun, R. Benitez, G. Proust et al., High-performance metal/carbide composites with far-from-equilibrium compositions and controlled microstructures, Scientific Reports, vol.6, p.35523, 2016.

A. Penaloza and C. R. Houska, Refinements on the X-ray intensities from Ti3?2Al. Anales del Congreso Nacional de Metalurgia, vol.3, pp.54-59, 1983.

D. Q. Chen, G. Y. Zhou, Z. P. Liu, and S. T. Tu, Nanoindentation experimental study on mechanical properties of as-cast bni-2 solder alloy, Procedia Engineering, vol.130, pp.652-661, 2015.

P. K. Liao, K. E. Spear, and . B-ni, Phase Diagrams of Binary Nickel Alloys, vol.88, pp.31-36, 1991.

P. Nash and A. Nash, The Ni,àíSi system, Journal of Phase Equilibria, vol.8, issue.5, pp.417-417, 1987.

M. A. Arafin, M. Medraj, D. P. Turner, and P. Bocher, Transient liquid phase bonding of Inconel 718 and Inconel 625 with BNi-2: Modeling and experimental investigations, Materials Science and Engineering: A, vol.447, issue.1, pp.125-133, 2007.

J. Ruiz-vargas, N. Siredey-schwaller, N. Gey, P. Bocher, and A. Hazotte, Microstructure development during isothermal brazing of Ni/BNi-2 couples, Journal of Materials Processing Technology, vol.213, issue.1, pp.20-29, 2013.
URL : https://hal.archives-ouvertes.fr/hal-01501849

C. L. Ou, D. W. Liaw, Y. C. Du, and R. K. Shiue, Brazing of 422 stainless steel using the AWS classification BNi-2 Braze alloy, Journal Of Materials Science, vol.41, issue.19, pp.6353-6361, 2006.

A. C. Fischer-cripps, Factors affecting nanoindentation test data, 2000.

W. C. Oliver and G. M. Pharr, Nanoindentation in materials research: Past, present, and future, Mrs Bulletin, vol.35, issue.11, pp.897-907, 2010.

Z. G. Wang, H. Bei, E. P. George, and G. M. Pharr, Influences of surface preparation on nanoindentation pop-in in single-crystal Mo, Scripta Materialia, vol.65, issue.6, pp.469-472, 2011.

Y. Wang, Z. K. Liu, and L. Q. Chen, Thermodynamic properties of Al, Ni, NiAl, and Ni3Al from firstprinciples calculations, Acta Materialia, vol.52, issue.9, pp.2665-2671, 2004.

S. L. Shang, Y. Wang, D. E. Kim, and Z. K. Liu, First-principles thermodynamics from phonon and Debye model: Application to Ni and Ni3Al, Computational Materials Science, vol.47, issue.4, pp.1040-1048, 2010.

Y. L. Bai, X. D. He, R. G. Wang, Y. Sun, C. C. Zhu et al., High temperature physical and mechanical properties of large-scale Ti2AlC bulk synthesized by self-propagating high temperature combustion synthesis with pseudo hot isostatic pressing, Journal of the European Ceramic Society, vol.33, issue.13, pp.2435-2445, 2013.

R. F. Li, Z. S. Yu, and K. Qi, Vacuum Brazing of GH2132 Superalloy Using BNi-2+BNi-5 Composite Filler, Advanced Materials Research, vol.602, issue.3, pp.2087-2091, 2013.

Y. Sun, J. Liu, B. Li, H. Li, and T. Jin, Microstructure evolution of single crystal superalloy DD5 joints brazed using AWS BNi-2 filler alloy, Materials Research Innovations, vol.18, issue.1, pp.341-346, 2014.

S. K. Tung, L. C. Lim, and M. O. Lai, Solidification phenomena in nickel base brazes containing boron and silicon, Scripta Materialia, vol.34, issue.5, pp.763-769, 1996.

B. Huneau, P. Rogl, K. Zeng, R. Schmid-fetzer, M. Bohn et al., The ternary system Al-Ni-Ti Part I: Isothermal section at 900
URL : https://hal.archives-ouvertes.fr/hal-01007377

. ?-c;, Experimental investigation and thermodynamic calculation, Intermetallics, vol.7, issue.12, pp.1337-1345, 1999.

K. Zeng, R. Schmid-fetzer, B. Huneau, P. Rogl, and J. Bauer, The ternary system Al-Ni-Ti Part II: thermodynamic assessment and experimental investigation of polythermal phase equilibria, Intermetallics, vol.7, issue.12, pp.1347-1359, 1999.
URL : https://hal.archives-ouvertes.fr/hal-01007378

R. Yang, J. A. Leake, and R. W. Cahn, A microstructural study of a Ni2AlTi-Ni(Al, Ti)-Ni3(Al, Ti) three-phase alloy, Journal of materials research, vol.6, issue.2, pp.343-354, 1991.

S. Sonia, V. Filomena, S. R. Ana, T. Maria, and M. F. Vieira, TEM and HRTEM characterization of TiAl diffusion bonds using Ni/Al nanolayers, Microscopy and Microanalysis, vol.21, issue.1, pp.132-139, 2015.

W. Jeitschko, H. Nowotny, and F. Benesovsky, Carbon-containing ternary compounds (H-phase), Monatsh. Chem, vol.94, issue.4, p.672, 1963.

Z. J. Lin, M. J. Zhuo, Y. C. Zhou, M. S. Li, and J. Y. Wang, Microstructural characterization of layered ternary Ti2AlC, Acta Materialia, vol.54, issue.4, pp.1009-1015, 2006.

F. Birch, Finite elastic strain of cubic crystals, Physical Review, vol.71, issue.11, p.809, 1947.

F. Birch, Finite strain isotherm and velocities for single-crystal and polycrystalline NaCl at high pressures and 300 K, Journal of Geophysical Research: Solid Earth, vol.83, issue.B3, pp.1257-1268, 1978.

R. Yu, J. Zhu, and H. Q. Ye, Calculations of single-crystal elastic constants made simple, Computer physics communications, vol.181, issue.3, pp.671-675, 2010.

Y. C. Zhou, C. Zhao, F. Wang, Y. J. Sun, L. Y. Zheng et al., Theoretical prediction and experimental investigation on the thermal and mechanical properties of bulk ?-Yb2Si2O7, Journal of the American Ceramic Society, vol.96, issue.12, pp.3891-3900, 2013.

Y. L. Du, Z. M. Sun, and H. Hashimoto, First-principles study on phase stability and compression behavior of Ti2SC and Ti2AlC, vol.405, pp.720-723, 2010.

M. Born, On the stability of crystal lattices IX. Covariant theory of lattice deformations and the stability of some hexagonal lattices, Mathematical Proceedings of the Cambridge Philosophical Society, vol.36, 1940.

F. Mouhat and F. X. Coudert, Necessary and sufficient elastic stability conditions in various crystal systems, Physical Review B, vol.90, issue.22, p.224104, 2014.

Z. M. Sun and Y. C. Zhou, Ab initio calculation of titanium silicon carbide, Physical Review B, vol.60, issue.3, p.1441, 1999.

G. Hug and E. Fries, Full-potential study of Hägg phases, Physical Review B, vol.65, issue.1, p.113104, 2002.

J. Y. Wang and Y. C. Zhou, Dependence of elastic stiffness on electronic band structure of nanolaminate M2AlC (M=Ti,V ,Nb, and Cr) ceramics, Physical Review B, vol.69, issue.1, p.214111, 2004.

. Noël, E. Haddad, L. Garcia-caurel, M. W. Hultman, G. Barsoum et al., Dielectric properties of Ti2AlC and Ti2AlN MAX phases: The conductivity anisotropy, Journal of Applied Physics, vol.104, issue.2, p.23531, 2008.

V. Mauchamp, W. B. Yu, L. Gence, L. Piraux, T. Cobioch et al., Anisotropy of the resistivity and charge-carrier sign in nanolaminated Ti2AlC: Experiment and ab initio calculations, Physical Review B, vol.87, issue.1, p.235105, 2013.

J. Hone, B. Batlogg, Z. Benes, A. T. Johnson, and J. E. Fischer, Quantized phonon spectrum of single-wall carbon nanotubes, Science, vol.289, issue.5485, pp.1730-1733, 2000.

A. Konar, R. K. Pandey, and T. Ethirajan, Carrier transport in layered nanolaminated films, ArXiv Preprint, vol.12, issue.1, p.4512, 2015.

A. Togo, L. Chaput, I. Tanaka, and G. Hug, First-principles phonon calculations of thermal expansion in Ti3SiC2, Ti3AlC2, and Ti3GeC2, Physical Review B, vol.81, issue.17, p.174301, 2010.

M. W. Barsoum, I. Salama, T. El-raghy, H. J. Golczewski, F. Seifert et al., Thermal and electrical properties of Nb2AlC, (Ti, Nb)2AlC and Ti2AlC, Metallurgical and Materials Transactions A, vol.33, issue.9, pp.2775-2779, 2002.

M. K. Drulis, H. Drulis, S. Gupta, M. W. Barsoum, and T. El-raghy, On the heat capacities of M2AlC (M= Ti, V, Cr) ternary carbides, Journal of Applied Physics, vol.99, issue.9, p.93502, 2006.

Y. L. Du, Z. M. Sun, H. Hashimoto, and W. B. Tian, First-principles study on thermodynamic properties of Ti2AlC and Ti2SC, Materials transactions, vol.50, issue.9, pp.2173-2176, 2009.

A. Zunger, S. H. Wei, L. G. Ferreira, and J. E. Bernard, Special quasirandom structures, Physical Review Letters, vol.65, issue.3, p.353, 1990.

F. A. Kröger and H. J. Vink, Relations between the concentrations of imperfections in crystalline solids, vol.3, pp.307-435, 1956.

O. Wilhelmsson, J. P. Palmquist, E. Lewin, J. Emmerlich, P. Eklund et al., Deposition and characterization of ternary thin films within the Ti-Al-C system by DC magnetron sputtering, Journal of crystal growth, vol.291, issue.1, pp.290-300, 2006.

S. G. Lee and K. J. Chang, Energetics and hydrogen passivation of carbon-related defects in InAs and In0.5Ga0.5As, Physical Review B, vol.53, issue.15, p.9784, 1996.

M. Baben, L. Shang, J. Emmerlich, and J. M. Schneider, Oxygen incorporation in M2AlC (M =

, Acta Materialia, vol.60, issue.1, pp.4810-4818, 2012.

B. Cui, D. D. Jayaseelan, and W. E. Lee, Microstructural evolution during high-temperature oxidation of Ti2AlC ceramics, Acta Materialia, vol.59, issue.1, pp.4116-4125, 2011.

J. C. Rao, Y. T. Pei, H. J. Yang, G. M. Song, S. B. Li et al., TEM study of the initial oxide scales of Ti2AlC, Acta Materialia, vol.59, issue.1, pp.5216-5223, 2011.

J. R. Xiao, T. F. Yang, C. X. Wang, J. M. Xue, and Y. G. Wang, Investigations on radiation tolerance of Mn+1AXn phases: study of Ti3SiC2, Ti3AlC2, Cr2AlC, Cr2GeC, Ti2AlC, and Ti2AlN, vol.98, pp.1323-1331, 2015.

D. J. Tallman, E. N. Hoffman, E. N. Caspi, B. L. Garcia-diaz, G. Kohse et al., Effect of neutron irradiation on select MAX phases, Acta Materialia, vol.85, issue.1, pp.132-143, 2015.

H. J. Yang, Y. T. Pei, G. M. Song, J. M. Th, and . De-hosson, Comments on "microstructural evolution during high-temperature oxidation of Ti2AlC ceramic, Scripta Materialia, vol.65, issue.1, pp.930-932, 2011.

M. Sonestedt, J. Frodelius, M. Sundberg, L. Hultman, and K. Stiller, Oxidation of Ti2AlC bulk and spray deposited coatings, Corrosion Science, vol.52, issue.1, pp.3955-3961, 2010.

W. K. Pang, I. M. Low, B. H. O'connor, V. K. Peterson, A. J. Studer et al., Insitu diffraction study of thermal decomposition in Maxthal Ti2AlC, Journal of Alloys and Compounds, vol.509, issue.1, pp.172-176, 2011.

B. Cui, D. D. Jayaseelan, and W. E. Lee, TEM study of the early stages of Ti2AlC oxidation at 900 ? C

, Scripta Materialia, vol.67, issue.10, pp.830-833, 2013.

T. Liao, J. Y. Wang, and Y. C. Zhou, Basal-plane slip systems and polymorphic phase transformation in Ti2AlC and Ti2AlN: a first-principles study, Journal of Physics: Condensed Matter, vol.18, issue.27, p.6183, 2006.

X. C. Li, L. L. Zheng, Y. H. Qian, J. J. Xu, and M. S. Li, Breakaway oxidation of Ti3AlC2 during long-term exposure in air at 1100

?. C. , Corrosion Science, vol.104, issue.1, pp.112-122, 2016.

Z. Dridi, B. Bouhafs, P. Ruterana, and H. Aourag, First-principles calculations of vacancy effects on structural and electronic properties of TiCx and TiNx, Journal of Physics: Condensed Matter, vol.14, issue.43, p.10237, 2002.

M. Guemmaz, A. Mosser, R. Ahujab, and B. Johansson, Elastic properties of sub-stoichiometric titanium carbides: comparison of FP-LMTO calculations and experimental results, Solid state communications, vol.110, issue.6, pp.299-303, 1999.

D. V. Shtansky, .. V. Ph, A. N. Kiryukhantsev-korneev, B. N. Sheveyko, C. Mavrin et al., TiCrAlC(N), and CrAlC(N) coatings deposited by sputtering of MAX phase targets, Comparative investigation of TiAlC(N), vol.203, pp.3595-3609, 2009.

J. Y. Wang and Y. C. Zhou, Ab initio elastic stiffness of nano-laminate (Mx, M2?x)AlC (M=Ti, V and Cr) solid solution, Journal of Physics: Condensed Matter, vol.16, issue.16, p.2819, 2004.

J. Halim, P. Chartier, T. Basyuk, T. Prikhna, N. C. El'ad et al., Structure and thermal expansion of (Crx, V1?x)n+1AlCn phases measured by X-ray diffraction, Journal of the European Ceramic Society, vol.37, issue.1, pp.15-21, 2017.

Z. F. Zhang, Z. M. Sun, H. Hashimoto, and T. Abe, Application of pulse discharge sintering (PDS) technique to rapid synthesis of Ti3SiC2 from Ti/Si/C powders, Journal of the European Ceramic Society, vol.22, issue.16, pp.2957-2961, 2002.

D. P. Riley, E. H. Kisi, T. C. Hansen, and A. W. Hewat, Self-Propagating High-Temperature Synthesis of Ti3SiC2: Ultra-High-Speed Neutron Diffraction Study of the Reaction Mechanism, Journal of the American Ceramic Society, vol.85, issue.10, pp.2417-2424, 2002.

Z. M. Sun, Z. F. Zhang, H. Hashimoto, and T. Abe, Ternary compound Ti3SiC2: Pulse discharge sintering synthesis, Materials Transactions, vol.43, issue.3, pp.428-431, 2002.

D. Bandyopadhyay, The Ti-Si-C system (titanium-silicon-carbon), Journal of phase equilibria and diffusion, vol.25, issue.5, pp.415-420, 2004.

M. L. Flem, X. M. Liu, S. Doriot, T. Cozzika, and I. Monnet, Irradiation damage in Ti3(Si, Al)C2: a TEM investigation, International Journal of Applied Ceramic Technology, vol.7, issue.6, pp.766-775, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00549388

X. M. Liu, M. L. Flem, J. L. Bechade, and I. Monnet, Nanoindentation investigation of heavy ion irradiated Ti3(Si, Al)C2, Journal of Nuclear Materials, vol.401, issue.1, pp.149-153, 2010.

V. J. Keast, S. Harris, and D. K. Smith, Prediction of the stability of the Mn+1AXn phases from first principles, Physical Review B, vol.80, issue.21, p.214113, 2009.

C. Lu, G. C. Wang, G. Yang, G. H. Fan, J. Zhang et al., Substitution behavior of ag atoms in the ti2alc ceramic, Journal of the American Ceramic Society, vol.100, issue.2, pp.732-738, 2017.

R. U. Vaidya and K. K. Chawla, Thermal expansion of metal-matrix composites, Composites Science and Technology, vol.50, issue.1, pp.13-22, 1994.

K. M. Shu and G. C. Tu, The microstructure and the thermal expansion characteristics of Cu/SiCp composites, Materials Science and Engineering: A, vol.349, issue.1, pp.236-247, 2003.

P. S. Turner, The problem of thermal-expansion stresses in reinforced plastics. National Advisory Committe for Aeronautics, pp.1-19, 1942.

E. Clementi, D. L. Raimondi, and R. W. , Atomic screening constants from SCF functions. II. Atoms with 37 to 86 electrons, The Journal of Chemical Physics, vol.47, issue.4, pp.1300-1307, 1967.

T. W. Clyne and P. J. Withers, An introduction to metal matrix composites, 1995.