A. H. Zacher, D. C. Elliott, M. V. Olarte, D. M. Santosa, F. Preto et al., Pyrolysis of Woody Residue Feedstocks: Upgrading of Bio-oils from Mountain-Pine-Beetle-Killed Trees and Hog Fuel, Energy Fuels, vol.28, pp.7510-7516, 2014.

S. Zhan, W. Chenguang, B. Kang, Z. Xinghua, Y. Chiling et al., Guangzhou 510640, China, 3. Key Laboratory of Clean Production and Utilization of Renewable Energy, Ministry of Agriculture, Chinese Academy of Sciences, vol.1, 2017.

, Biol. Eng, vol.10, pp.214-225

H. Zhang, T. R. Carlson, R. Xiao, and G. W. Huber, Catalytic fast pyrolysis of wood and alcohol mixtures in a fluidized bed reactor, Green Chem, vol.14, pp.98-110, 2012.

H. Zhang, Y. Cheng, T. P. Vispute, R. Xiao, and G. W. Huber, Catalytic conversion of biomass-derived feedstocks into olefins and aromatics with ZSM-5: the hydrogen to carbon effective ratio, Energy Environ. Sci, vol.4, 2011.

H. Zhang, R. Xiao, B. Jin, G. Xiao, and R. Chen, Biomass catalytic pyrolysis to produce olefins and aromatics with a physically mixed catalyst, Bioresour. Technol, vol.140, pp.256-262, 2013.

J. Zhang, K. Wang, M. W. Nolte, Y. S. Choi, R. C. Brown et al., Catalytic Deoxygenation of Bio-Oil Model Compounds over Acid-Base Bifunctional Catalysts, ACS Catal, vol.6, pp.2608-2621, 2016.

X. Zhao, L. Wei, S. Cheng, Y. Cao, J. Julson et al., Catalytic cracking of carinata oil for hydrocarbon biofuel over fresh and regenerated Zn/Na-ZSM-5, Appl. Catal. Gen, vol.507, pp.44-55, 2015.

K. H. Esbensen, D. Guyot, F. Westad, and L. P. Houmoller, Multivariate Data Analysis: In Practice :?an?Introduction?to?Multivariate?Data?Analysis and Experimental Design, 2002.

J. R. García, M. Bertero, M. Falco, and U. Sedran, Catalytic cracking of bio-oils improved by the formation of mesopores by means of Y zeolite desilication, Appl. Catal. Gen, vol.503, pp.1-8, 2015.

E. M. Gucho, K. Shahzad, E. A. Bramer, N. A. Akhtar, and G. Brem, Experimental Study on Dry Torrefaction of Beech Wood and Miscanthus, vol.8, pp.3903-3923, 2015.

G. Jiang, D. J. Nowakowski, and A. V. Bridgwater, A systematic study of the kinetics of lignin pyrolysis, Thermochim. Acta, vol.498, pp.61-66, 2010.

J. Lehto, A. Oasmaa, and Y. Solantausta, Fuel oil quality and combustion of fast pyrolysis bio-oils, 2013.

C. Liu, H. Wang, A. M. Karim, J. Sun, and Y. Wang, Catalytic fast pyrolysis of lignocellulosic biomass, Chem. Soc. Rev, vol.43, pp.7594-7623, 2014.

C. Mohabeer, L. Abdelouahed, S. Marcotte, and B. Taouk, Comparative analysis of pyrolytic liquid products of beech wood, flax shives and woody biomass components, J. Anal, 2017.
URL : https://hal.archives-ouvertes.fr/hal-02138615

, Appl. Pyrolysis, vol.127, pp.269-277

P. Patwardhan, Understanding the product distribution from biomass fast pyrolysis, 2010.

C. Quan, N. Gao, and Q. Song, Pyrolysis of biomass components in a TGA and a fixed-bed reactor: Thermochemical behaviors, kinetics, and product characterization, J. Anal. Appl. Pyrolysis, vol.121, pp.84-92, 2016.

, R: A Language and Environment for Statistical Computing, 2014.

J. T. Scanlon and D. E. Willis, Calculation of Flame Ionization Detector Relative Response Factors Using the Effective Carbon Number Concept, J. Chromatogr. Sci, vol.23, pp.333-340, 1985.

Y. Cheng, J. Jae, J. Shi, W. Fan, and G. W. Huber, Production of Renewable Aromatic Compounds by Catalytic Fast Pyrolysis of Lignocellulosic Biomass with Bifunctional Ga, 2012.

, Catalysts. Angew. Chem, vol.124, pp.1416-1419

R. C. Deka, Acidity in zeolites and their characterization by different spectroscopic methods, Indian J. Chem. Technol, vol.5, pp.109-123, 1998.

T. Dickerson and J. Soria, Catalytic Fast Pyrolysis: A, Review. Energies, vol.6, pp.514-538, 2013.

F. Dumeignil, K. Sato, M. Imamura, N. Matsubayashi, E. Payen et al., Characterization and hydrodesulfurization activity of CoMo catalysts supported on sol-gel prepared Al2O3, Appl. Catal. Gen, vol.287, pp.135-145, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00098375

K. H. Esbensen, D. Guyot, F. Westad, and L. P. Houmoller, Multivariate Data Analysis, Practice :?an?Introduction?to?Multivariate?Data?Analysis?and?Experimental?Design.?Multivariate? Data Analysis, 2002.

R. French and S. Czernik, Catalytic pyrolysis of biomass for biofuels production, Fuel Process. Technol, vol.91, pp.25-32, 2010.

L. Garcia, M. L. Salvador, J. Arauzo, and R. Bilbao, Influence of catalyst weight/biomass flow rate ratio on gas production in the catalytic pyrolysis of pine sawdust at low temperatures, Ind. Eng. Chem. Res, vol.37, pp.3812-3819, 1998.

A. G. Gayubo, A. T. Aguayo, A. Atutxa, R. Aguado, M. Olazar et al., Transformation of Oxygenate Components of Biomass Pyrolysis Oil on a HZSM-5 Zeolite, II. Aldehydes, Ketones, and Acids. Ind. Eng. Chem. Res, vol.43, pp.2619-2626, 2004.

D. A. Gunawardena and S. D. Fernando, Methods and Applications of Deoxygenation for the Conversion of Biomass to Petrochemical Products, 2013.

Z. Guo, S. Wang, Y. Zhu, Z. Luo, and K. Cen, Separation of acid compounds for refining biomass pyrolysis oil, J. Fuel Chem. Technol, vol.37, issue.09, pp.60010-60014, 2009.

A. A. Imran, E. A. Bramer, K. Seshan, and G. Brem, Catalytic Flash Pyrolysis of Biomass Using Different Types of Zeolite and Online Vapor Fractionation, vol.9, 2016.

Y. Jannot, Isothermes de sorption: Modèles et détermination, 2008.

L. Jia, M. Raad, S. Hamieh, J. Toufaily, T. Hamieh et al., Catalytic fast pyrolysis of biomass: superior selectivity of hierarchical zeolite to aromatics, 2017.

H. Li, Y. Yan, and Z. Ren, Online upgrading of organic vapors from the fast pyrolysis of biomass, J. Fuel Chem. Technol, vol.36, pp.60002-60007, 2008.

L. J. Lobree, I. Hwang, J. A. Reimer, and A. T. Bell, Investigations of the State of Fe in H-ZSM-5, J. Catal, vol.186, pp.242-253, 1999.

, Appl. Pyrolysis, vol.127, pp.269-277

P. M. Mortensen, J. Grunwaldt, P. A. Jensen, K. G. Knudsen, and A. D. Jensen, A review of catalytic upgrading of bio-oil to engine fuels, Appl. Catal. Gen, vol.407, pp.1-19, 2011.

C. Mukarakate, J. D. Mcbrayer, T. J. Evans, S. Budhi, D. J. Robichaud et al., Catalytic fast pyrolysis of biomass: the reactions of water and aromatic intermediates produces phenols, Green Chem, vol.17, pp.4217-4227, 2015.

C. A. Mullen and A. A. Boateng, Production of Aromatic Hydrocarbons via Catalytic Pyrolysis of Biomass over Fe-Modified HZSM-5 Zeolites, ACS Sustain. Chem. Eng, vol.3, pp.1623-1631, 2015.

C. A. Mullen and A. A. Boateng, Chemical Composition of Bio-oils Produced by Fast Pyrolysis of Two Energy Crops, Energy Fuels, vol.22, pp.2104-2109, 2008.

S. R. Naqvi, Y. Uemura, S. Yusup, Y. Sugiur, N. Nishiyama et al., The Role of Zeolite Structure and Acidity in Catalytic Deoxygenation of Biomass Pyrolysis Vapors. Energy Procedia, Clean, Efficient and Affordable Energy for a Sustainable Future, The 7th International Conference on Applied Energy (ICAE2015), vol.75, pp.793-800, 2015.

J. Payormhorm, K. Kangvansaichol, P. Reubroycharoen, P. Kuchonthara, and N. Hinchiranan, Pt/Al2O3-catalytic deoxygenation for upgrading of Leucaena leucocephala-pyrolysis oil, 2013.

, Bioresour. Technol, vol.139, pp.128-135

B. Puértolas, T. C. Keller, S. Mitchell, and J. Pérez-ramírez, Deoxygenation of bio-oil over solid base catalysts: From model to realistic feeds, Appl. Catal. B Environ, vol.184, pp.77-86, 2016.

K. A. Rogers and Y. Zheng, Selective Deoxygenation of Biomass-Derived Bio-oils within Hydrogen-Modest Environments: A Review and New Insights, ChemSusChem, vol.9, pp.1750-1772, 2016.

?. Topalo?lu?yaz?c?, ?. ?bilgiç, and . ?2010, ?Determining?the?surface?acidic properties of solid catalysts by amine titration using Hammett indicators and FTIR-pyridine adsorption methods, Surf. Interface Anal, vol.42, pp.959-962

C. Wang, Q. Hao, D. Lu, Q. Jia, G. Li et al., Production of Light Aromatic Hydrocarbons from Biomass by Catalytic Pyrolysis. Chin, J. Catal, vol.29, pp.907-912, 2008.

, , p.60073

J. W. Ward, Thermal decomposition of ammonium Y zeolite, J. Catal, vol.18, pp.90331-90334, 1970.

H. Yang, R. Yan, H. Chen, D. H. Lee, and C. Zheng, Characteristics of hemicellulose, cellulose and lignin pyrolysis, Fuel, vol.86, pp.1781-1788, 2007.

H. Yang, J. Yao, G. Chen, W. Ma, B. Yan et al., Overview of Upgrading of Pyrolysis Oil of Biomass, Energy Procedia, International Conference on Applied Energy, ICAE2014, vol.61, pp.1306-1309, 2014.

M. L. Yoo, Y. H. Park, Y. Park, and S. H. Park, Catalytic Pyrolysis of Wild Reed over a Zeolite-Based Waste Catalyst, vol.9, 0201.

J. Zhang, K. Wang, M. W. Nolte, Y. S. Choi, R. C. Brown et al., Catalytic Deoxygenation of Bio-Oil Model Compounds over Acid-Base Bifunctional Catalysts, ACS Catal, vol.6, pp.2608-2621, 2016.

A. Zheng, L. Jiang, Z. Zhao, Z. Huang, K. Zhao et al., Catalytic fast pyrolysis of lignocellulosic biomass for aromatic production: chemistry, catalyst and process, Interdiscip. Rev. Energy Environ, 2016.

L. Abdelouahed, S. Leveneur, L. Vernieres-hassimi, L. Balland, and B. Taouk, Comparative investigation for the determination of kinetic parameters for biomass pyrolysis by thermogravimetric analysis, J. Therm. Anal. Calorim, vol.129, pp.1201-1213, 2017.
URL : https://hal.archives-ouvertes.fr/hal-02138398

H. S. Choi and D. Meier, Fast pyrolysis of Kraft lignin-Vapor cracking over various fixed-bed catalysts, J. Anal. Appl. Pyrolysis, vol.100, pp.207-212, 2013.

S. Farag, B. P. Mudraboyina, P. G. Jessop, and J. Chaouki, Impact of the heating mechanism on the yield and composition of bio-oil from pyrolysis of kraft lignin, Biomass Bioenergy, vol.95, pp.344-353, 2016.

A. V. Maldhure and J. D. Ekhe, Pyrolysis of purified kraft lignin in the presence of AlCl3 and ZnCl2, J. Environ. Chem. Eng, vol.1, pp.844-849, 2013.

C. A. Mullen and A. A. Boateng, Production of Aromatic Hydrocarbons via Catalytic Pyrolysis of Biomass over Fe-Modified HZSM-5 Zeolites, ACS Sustain. Chem. Eng, vol.3, pp.1623-1631, 2015.

P. Patwardhan, Understanding the product distribution from biomass fast pyrolysis, 2010.

H. Zhou, Y. Long, A. Meng, S. Chen, Q. Li et al., A novel method for kinetics analysis of pyrolysis of hemicellulose, cellulose, and lignin in TGA and macro-TGA, RSC Adv, vol.5, pp.26509-26516, 2015.

X. Zhu, Q. Lu, W. Li, D. Zhang, and . ;-m-=-fe, Fast and catalytic pyrolysis of xylan, Effects of temperature and M/HZSM-5, vol.4, pp.424-429, 2010.

J. D. Adjaye and N. N. Bakhshi, Production of hydrocarbons by catalytic upgrading of a fast pyrolysis bio-oil. Part I: Conversion over various catalysts, Fuel Process. Technol, vol.45, pp.161-183, 1995.

H. S. Cerqueira, G. Caeiro, L. Costa, and F. Ramôa-ribeiro, Deactivation of FCC catalysts, J. Mol. Catal. Chem, vol.292, pp.1-13, 2008.

S. J. Choi, S. H. Park, J. Jeon, I. G. Lee, C. Ryu et al., Catalytic conversion of particle board over microporous catalysts, Renew. Energy, AFORE, vol.54, pp.105-110, 2011.

C. Ellens, Design, optimization and evaluation of a free-fall biomass fast pyrolysis reactor and its products, 2009.

K. H. Esbensen, D. Guyot, F. Westad, and L. P. Houmoller, Multivariate Data Analysis:? In? Practice :? an? Introduction? to? Multivariate? Data? Analysis? and? Experimental? Design, 2002.

Y. Fan, Y. Cai, X. Li, N. Yu, and H. Yin, Catalytic upgrading of pyrolytic vapors from the vacuum pyrolysis of rape straw over nanocrystalline HZSM-5 zeolite in a two-stage fixed-bed reactor, J. Anal. Appl. Pyrolysis, vol.108, pp.185-195, 2014.

A. G. Gayubo, A. T. Aguayo, A. Atutxa, R. Aguado, M. Olazar et al., Transformation of Oxygenate Components of Biomass Pyrolysis Oil on a, 2004.

, Zeolite. II. Aldehydes, Ketones, and Acids. Ind. Eng. Chem. Res, vol.43, pp.2619-2626

C. Guizani, S. Valin, J. Billaud, M. Peyrot, and S. Salvador, Biomass fast pyrolysis in a drop tube reactor for bio oil production: Experiments and modeling, Fuel, vol.207, pp.71-84, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01581812

Z. Guo, S. Wang, Y. Zhu, Z. Luo, and K. Cen, Separation of acid compounds for refining biomass pyrolysis oil, J. Fuel Chem. Technol, vol.37, pp.49-52, 2009.

, , pp.60010-60014

M. I. Jahirul, M. G. Rasul, A. A. Chowdhury, and N. Ashwath, Biofuels Production through Biomass Pyrolysis -A Technological Review. Energies, vol.5, pp.4952-5001, 2012.

J. Lehto, A. Oasmaa, and Y. Solantausta, Fuel oil quality and combustion of fast pyrolysis bio-oils, 2013.

H. Li, Y. Yan, and Z. Ren, Online upgrading of organic vapors from the fast pyrolysis of biomass, J. Fuel Chem. Technol, vol.36, issue.09, pp.60002-60007, 2008.

C. Mohabeer, L. Abdelouahed, S. Marcotte, and B. Taouk, Comparative analysis of pyrolytic liquid products of beech wood, flax shives and woody biomass components, J. Anal. Appl. Pyrolysis, vol.127, pp.269-277, 2017.
URL : https://hal.archives-ouvertes.fr/hal-02138615

C. Mukarakate, X. Zhang, A. Stanton, D. Robichaud, P. Ciesielski et al., Real-time monitoring of the deactivation of HZSM-5 during upgrading of pine pyrolysis vapors, Green Chem, vol.16, 2014.

K. Murata, Y. Liu, M. Inaba, and I. Takahara, Catalytic fast pyrolysis of jatropha wastes, J. Anal. Appl. Pyrolysis, vol.94, pp.75-82, 2012.

V. Paasikallio, C. Lindfors, E. Kuoppala, Y. Solantausta, A. Oasmaa et al., Product quality and catalyst deactivation in a four day catalytic fast pyrolysis production run, Green Chem, vol.16, p.3549, 2014.

H. J. Park, J. Dong, J. Jeon, K. Yoo, J. Yim et al., Conversion of the Pyrolytic Vapor of Radiata Pine over Zeolites, J. Ind. Eng. Chem, vol.13, pp.182-189, 2007.

H. J. Park, Y. Park, J. Kim, J. Jeon, K. Yoo et al., Bio-oil upgrading over Ga modified zeolites in a bubbling fluidized bed reactor, Studies in Surface Science and Catalysis, New Developments and Application in Chemical Reaction Engineering, pp.553-556, 2006.

S. Vitolo, B. Bresci, M. Seggiani, and M. G. Gallo, Catalytic upgrading of pyrolytic oils over HZSM-5 zeolite: behaviour of the catalyst when used in repeated upgradingregenerating cycles, Fuel, vol.80, pp.63-69, 2001.

S. Xiu and A. Shahbazi, Bio-oil production and upgrading research: A review, Renew. Sustain. Energy Rev, vol.16, pp.4406-4414, 2012.

A. Conclusion-and-perspectives-table, Molecules present in bio-oils and their chemical family Chemical family Molecules Identified Alcohols 1-Hexanol, 4-methyl-2-Propanol, 2-methyl-1-Butanol, vol.4, p.4

, 4-Benzenediol, vol.2, p.6

. Furancarboxaldehyde, , p.5

. Benzaldehyde, 2-hydroxy-6-methylBenzaldehyde, 2-methyl

. Cinnamaldehyde,

, Alkanes Nonane, 4-ethyl-5-methylDecane Aromatics 1,5-Heptadiene, 3-methyl

. Cyclopentene, , pp.1-1

, 3-tetramethyl-2-Butynamide, N-methylacid, 3,4-dimethylEsters 1,2,3-Propanetriol, monoacetate Butanoic acid, Naphthalene, vol.1, issue.2

, Methyl 2-furoate Benzoic acid, 3,4-dihydroxy-, methyl ester Methylparaben Furans 2,2'-Bifuran Benzofuran, vol.2

, Phenol, 2-methoxy-6-(1-propenyl)-Ketones 3-Penten-2-one

. Pentanone, 3-dimethyl-2-Cyclopenten-1-one, 3-methylCycloheptanone Ethanone, 1-(4-methylphenyl)-Phenols Phenol, 3-methylPhenol, 4-methylPhenol, 3-ethyl-5-methylPhenol, 3,5-dimethylPhenol, vol.2