N. D. Luong, N. T. Binh, L. D. Duong, D. O. Kim, D. S. Kim et al., An eco-friendly and efficient route of lignin extraction from black liquor and a lignin-based copolyester synthesis, Polymer Bulletin, vol.68, pp.879-890, 2012.

A. Gandini, M. N. Belgacem, B. M. Naceur, and G. Alessandro, Monomers, Polymers and Composites from Renewable Resources, pp.1-16, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00511686

G. Taylor, Biofuels and the biorefinery concept, Energy Policy, vol.36, pp.4406-4409, 2008.
DOI : 10.1016/j.enpol.2008.09.069

, Sustainable biofuels: prospects and challenges, 2008.

J. Marton, Lignin Structure and Reactions, 1966.

M. Phillips, The chemistry of lignin, Chemical Reviews, vol.14, pp.103-170, 1934.

F. Schulze, Beitrage zur Kenntniss des Lignins. Chem. Zentr, vol.1857, pp.321-325

K. V. Sarkanen and C. H. Ludwig, Lignins: Occurrence, formation, structure and reactions, 1971.

R. Benedikt and M. Bamberger, Über eine quantitative Reaction des Lignins, Monatshefte für Chemie, vol.1890, pp.260-267
DOI : 10.1007/bf01540738

E. Adler, Lignin chemistry-past, Science and Technology, vol.11, pp.169-218, 1977.

J. L. Mccarthy and A. Islam, ACS Symposium Series, pp.2-66, 1999.

G. Brunow, , pp.89-99, 2004.

K. Freudenberg, Biosynthesis and constitution of lignin, Nature, vol.183, pp.1152-1155, 1959.

K. Freudenberg, Zur Kenntis der Cellulose. Ber. Dtsch. Chem. Ges, pp.767-773, 1921.

F. S. Chakar and A. J. Ragauskas, Review of current and future softwood kraft lignin process chemistry, Industrial Crops and Products, vol.20, pp.131-141, 2004.

K. Freudenberg, Lignin: Its Constitution and Formation from p-Hydroxycinnamyl Alcohols, Science, vol.48, pp.595-600, 1965.

C. H. Ludwig, B. J. Nist, and J. L. Mccarthy, The High Resolution Nuclear Magnetic Resonance Spectroscopy of Protons in Compounds Related to Lignin, Lignin. XII.1, vol.86, pp.1186-1196, 1964.

H. Nimz, Beech Lignin-Proposal of a Constitutional Scheme, Angewandte Chemie International Edition in English, issue.13, pp.313-321, 1974.

J. J. Lindberg, A. Tuula, and K. Levon, Lignin, pp.190-204, 1989.

H. Hatakeyama and T. Hatakeyama, , pp.1-63, 2010.

J. H. Lora and W. G. Glasser, Recent industrial applications of lignin: A sustainable alternative to nonrenewable materials, Journal of Polymers and the Environment, issue.10, pp.39-48, 2002.

P. K. Swain, L. M. Das, and S. N. Naik, Biomass to liquid: A prospective challenge to research and development in 21st century, Renewable and Sustainable Energy Reviews, vol.15, pp.4917-4933, 2011.

P. Mckendry, Energy production from biomass, Conversion technologies, vol.83, pp.47-54, 2002.

M. Hamaguchi, M. Cardoso, and E. Vakkilainen, Alternative technologies for biofuels production in kraft pulp mills-potential and prospects, Energies, vol.5, pp.2288-2309, 2012.

J. Zakzeski, P. C. Bruijnincx, A. L. Jongerius, and B. M. Weckhuysen, The catalytic valorization of lignin for the production of renewable chemicals, Chem. Rev, vol.110, pp.3552-3599, 2010.

J. Zakzeski and B. Weckhuysen, Lignin solubilization and aqueous phase reforming for the production of aromatic chemicals and hydrogen, ChemSusChem, vol.4, pp.369-378, 2011.

D. J. Nowakowski, A. V. Bridgwater, D. C. Elliott, D. Meier, and P. De-wild, Lignin fast pyrolysis: Results from an international collaboration, Journal of Analytical and Applied Pyrolysis, vol.88, pp.53-72, 2010.
DOI : 10.1016/j.jaap.2010.02.009

URL : https://publications.tno.nl/publication/34633421/18CQb2/w10026.pdf

D. Mohan, C. U. Pittman, and P. H. Steele, Pyrolysis of wood/biomass for bio-oil: A critical review, Energy and Fuels, vol.20, pp.848-889, 2006.

A. Leonowicz, A. Matuszewska, J. Luterek, D. Ziegenhagen, M. Wojta?-wasilewska et al., Biodegradation of Lignin by White Rot Fungi. Fungal Genetics and Biology, vol.27, pp.175-185, 1999.

M. Brebu and I. Spiridon, Co-pyrolysis of LignoBoost® lignin with synthetic polymers, Polymer Degradation and Stability, vol.97, pp.2104-2109, 2012.

A. Van-der-drift and H. Boerrigter, Synthesis gas from biomass for fuels and chemicals, 2006.

D. Choi, D. C. Chipman, S. C. Bents, and R. C. Brown, A techno-economic analysis of polyhydroxyalkanoate and hydrogen production from syngas fermentation of gasified biomass, Applied Biochemistry and Biotechnology, vol.160, pp.1032-1046, 2010.

J. D. Araújo, C. A. Grande, and A. E. Rodrigues, Vanillin production from lignin oxidation in a batch reactor, Chemical Engineering Research and Design, vol.88, pp.1024-1032, 2010.

J. C. Villar, A. Caperos, and F. García-ochoa, Oxidation of hardwood kraft-lignin to phenolic derivatives with oxygen as oxidant, Wood Science and Technology, vol.35, pp.245-255, 2001.

E. A. Silva, M. Zabkova, J. D. Araújo, C. A. Cateto, M. F. Barreiro et al., An integrated process to produce vanillin and ligninbased polyurethanes from Kraft lignin, Chemical Engineering Research and Design, vol.87, pp.1276-1292, 2009.

M. B. Hocking, Vanillin: Synthetic Flavoring from Spent Sulfite Liquor, Journal of Chemical Education, vol.79, pp.1055-1059, 1997.

V. E. Tarabanko, N. V. Koropatchinskaya, A. V. Kudryashev, and B. N. Kuznetsov, Influence of lignin origin on the efficiency of the catalytic oxidation of lignin into vanillin and syringaldehyde, Russian Chemical Bulletin, vol.44, pp.367-371, 1995.

R. Isroi, S. Millati, C. Syamsiah, M. N. Niklasson, K. Cahyanto et al., Biological pretreatment of lignocelluloses with white-rot fungi and its applications: A review, BioResources, issue.6, pp.5224-5259, 2011.

D. W. Wong, Structure and action mechanism of ligninolytic enzymes, Applied Biochemistry and Biotechnology, vol.157, pp.174-209, 2009.

Y. Liu and K. Li, Preparation and characterization of demethylated ligninpolyethylenimine adhesives, Journal of Adhesion, vol.82, pp.593-605, 2006.

P. Truter, A. Pizzi, and H. Vermaas, Cold-setting wood adhesives from kraft hardwood lignin, Journal of Applied Polymer Science, vol.51, pp.1319-1322, 1994.

A. R. Gonçalves and P. Benar, Hydroxymethylation and oxidation of Organosolv lignins and utilization of the products, Bioresource Technology, vol.79, pp.103-111, 2001.

L. Hu, H. Pan, Y. Zhou, and M. Zhang, Methods to improve lignin's reactivity as a phenol substitute and as replacement for other phenolic compounds: A brief review, BioResources, issue.6, pp.3515-3525, 2011.

Y. B. Mu, C. P. Wang, L. W. Zhao, and F. X. Chu, Study on Composite Adhesive of Hydroxymethylated Lignosulfonate/Phenol-formaldehyde Resin with Low Free Formaldehyde, Chemistry and Industry of Forest Products, vol.29, pp.38-42, 2009.

N. E. Mansouri, A. Pizzi, and J. Salvado, Lignin-based polycondensation resins for wood adhesives, Journal of Applied Polymer Science, vol.103, pp.1690-1699, 2007.
URL : https://hal.archives-ouvertes.fr/hal-01194987

H. R. Mansouri, P. Navarrete, A. Pizzi, S. Tapin-lingua, B. Benjelloun-mlayah et al., Synthetic-resin-free wood panel adhesives from mixed low molecular mass lignin and tannin, European Journal of Wood and Wood Products, pp.1-9, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00594484

N. E. Mansouri, Q. Yuan, and F. Huang, Study of chemical modification of alkaline lignin by the glyoxalation reaction, BioResources, issue.6, pp.4523-4536, 2011.

P. Navarrete, A. Pizzi, H. Pasch, and L. Delmotte, Study on lignin-glyoxal reaction by MALDI-TOF and CP-MAS 13C-NMR, vol.26, pp.1069-1082, 2012.

N. E. Mansouri, A. Pizzi, and J. Salvadó, Lignin-based wood panel adhesives without formaldehyde. Holz als Roh-und Werkstoff, vol.65, pp.65-70, 2007.

M. H. Schneider, Furfuryl alcohol lignin adhesive. Industrial Bioprocessing, p.10, 2004.

C. G. Silva, S. Grelier, F. Pichavant, E. Frollini, and A. Castellan, Adding value to lignins isolated from sugarcane bagasse and Miscanthus, Industrial Crops and Products, vol.42, pp.87-95, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00932349

E. C. Ramires, J. D. Megiatto, C. Gardrat, A. Castellan, and E. Frollini, Biobased composites from glyoxal-phenolic resins and sisal fibers, Bioresource Technology, vol.101, pp.1998-2006, 2010.
DOI : 10.1016/j.biortech.2009.10.005

URL : https://hal.archives-ouvertes.fr/hal-00679326

S. Cheng, Z. Yuan, M. Anderson, M. Leitch, and C. Xu, Synthesis of biobased phenolic resins/adhesives with methylolated wood-derived bio-oil, Journal of Applied Polymer Science, vol.126, pp.430-440, 2012.

W. Zhang, Y. Ma, C. Wang, S. Li, M. Zhang et al., Preparation and properties of lignin-phenol-formaldehyde resins based on different biorefinery residues of agricultural biomass, Industrial Crops and Products, issue.43, pp.326-333, 2013.

M. Arend, B. Westermann, and N. Risch, Modern Variants of the Mannich Reaction, Angewandte Chemie International Edition, vol.37, pp.1044-1070, 1998.

Y. Matsushita and S. Yasuda, Reactivity of a condensed-type lignin model compound in the Mannich reaction and preparation of cationic surfactant from sulfuric acid lignin, Journal of Wood Science, vol.49, pp.166-171, 2003.

X. Yue, F. Chen, and X. Zhou, Improved interfacial bonding of PVC/Wood-flour composites by lignin amine modification, BioResources, issue.6, pp.2022-2034, 2011.

S. P. Huo, M. C. Nie, Z. W. Kong, G. M. Wu, and J. Chen, Crosslinking kinetics of the formation of lignin-aminated polyol-based polyurethane foam, Journal of Applied Polymer Science, vol.125, pp.152-157, 2012.

T. Kudanga, E. N. Prasetyo, J. Sipilä, G. M. Guebitz, and G. S. Nyanhongo, Reactivity of long chain alkylamines to lignin moieties: Implications on hydrophobicity of lignocellulose materials, Journal of Biotechnology, vol.149, pp.81-87, 2010.

L. Zhang and J. Huang, Effects of nitrolignin on mechanical properties of polyurethane-nitrolignin films, Journal of Applied Polymer Science, vol.80, pp.1213-1219, 2001.

J. Huang and L. Zhang, Effects of NCO/OH molar ratio on structure and properties of graft-interpenetrating polymer networks from polyurethane and nitrolignin, Polymer, vol.43, pp.2287-2294, 2002.

L. Zhang and J. Huang, Effects of hard-segment compositions on properties of polyurethane-nitrolignin films, Journal of Applied Polymer Science, vol.81, pp.3251-3259, 2001.

T. Hu, A. Gandini, M. Belgacem, Z. Guo, and S. Montanari, Chemical Modification, Properties, and Usage of Lignin, pp.57-80, 2002.

M. Nahmany and A. Melman, Chemoselectivity in reactions of esterification, Organic and Biomolecular Chemistry, issue.2, pp.1563-1572, 2004.

Z. Guo, A. Gandini, and F. Pla, Polyesters from lignin. 1. The reaction of kraft lignin with dicarboxylic acid chlorides, Polymer International, vol.27, pp.17-22, 1992.

Z. Guo and A. Gandini, Polyesters from lignin 2. The copolyesterification of kraft lignin and polyethylene glycols with dicarboxylic acid chlorides, European Polymer Journal, vol.27, pp.1177-1180, 1991.

R. Fang, X. S. Cheng, and W. S. Lin, Preparation and application of dimer acid/lignin graft copolymer, BioResources, issue.6, pp.2874-2884, 2011.

M. Firdaus and M. A. Meier, Renewable co-polymers derived from vanillin and fatty acid derivatives, European Polymer Journal, 2012.
DOI : 10.1016/j.eurpolymj.2012.10.017

S. Thiebaud and M. E. Borredon, Solvent-free wood esterification with fatty acid chlorides, Bioresource Technology, vol.52, pp.169-173, 1995.
DOI : 10.1016/0960-8524(95)00018-a

S. Thiebaud, M. E. Borredon, G. Baziard, and F. Senocq, Properties of wood esterified by fatty-acid chlorides, Bioresource Technology, vol.59, pp.103-107, 1997.
DOI : 10.1016/s0960-8524(96)00160-5

T. Saito, R. H. Brown, M. A. Hunt, D. L. Pickel, J. M. Pickel et al., Turning renewable resources into value-added polymer: Development of lignin-based thermoplastic, Green Chemistry, vol.14, pp.3295-3303, 2012.
DOI : 10.1039/c2gc35933b

G. Sivasankarapillai and A. G. Mcdonald, Synthesis and properties of lignin-highly branched poly (ester-amine) polymeric systems, Biomass and Bioenergy, vol.35, pp.919-931, 2012.
DOI : 10.1016/j.biombioe.2010.11.002

G. Sivasankarapillai, A. G. Mcdonald, and H. Li, Lignin valorization by forming toughened lignin-co-polymers: Development of hyperbranched prepolymers for crosslinking, Biomass and Bioenergy, vol.47, pp.99-108, 2012.
DOI : 10.1016/j.biombioe.2012.09.057

R. R. Sailaja and M. V. Deepthi, Mechanical and thermal properties of compatibilized composites of polyethylene and esterified lignin, Materials and Design, pp.4369-4379, 2010.

B. Xiao, X. F. Sun, and R. Sun, Chemical modification of lignins with succinic anhydride in aqueous systems, Polymer Degradation and Stability, vol.71, pp.223-231, 2001.
DOI : 10.1016/s0141-3910(00)00133-6

B. Doczekalska, M. Bartkowiak, and R. Zakrzewski, Modification of sawdust from pine and beech wood with the succinic anhydride, vol.65, pp.187-191, 2007.
DOI : 10.1007/s00107-006-0152-6

W. Thielemans and R. P. Wool, Lignin esters for use in unsaturated thermosets: Lignin modification and solubility modeling, Biomacromolecules, issue.6, pp.1895-1905, 2005.
DOI : 10.1021/bm0500345

B. Ahvazi, O. Wojciechowicz, T. M. Ton-that, and J. Hawari, Preparation of lignopolyols from wheat straw soda lignin, Journal of Agricultural and Food Chemistry, vol.59, pp.10505-10516, 2011.
DOI : 10.1021/jf202452m

A. Effendi, H. Gerhauser, and A. V. Bridgwater, Production of renewable phenolic resins by thermochemical conversion of biomass: A review, Renewable and Sustainable Energy Reviews, vol.12, pp.2092-2116, 2008.

T. That, Cardanol-lignin-based polyurethanes, Polymer International, vol.41, pp.13-16, 1996.

H. Sadeghifar, C. Cui, and D. S. Argyropoulos, Toward Thermoplastic Lignin Polymers; Part I: Selective Masking of Phenolic Hydroxyl Groups in Kraft Lignins via Methylation & Oxypropylation Chemistries, Industrial & Engineering Chemistry Research, 2012.

L. C. Wu and W. G. Glasser, Engineering Plastics From Lignin. I. Synthesis of hydroxypropyl lignin, Journal of Applied Polymer Science, vol.29, pp.1111-1123, 1984.

S. Fernandes, C. S. Freire, C. P. Neto, and A. Gandini, The bulk oxypropylation of chitin and chitosan and the characterization of the ensuing polyols, Green Chemistry, issue.10, pp.93-97, 2008.
URL : https://hal.archives-ouvertes.fr/hal-01600492

M. Evtiouguina, A. Margarida-barros, J. J. Cruz-pinto, C. Neto, N. Belgacem et al., The oxypropylation of cork residues: preliminary results, Bioresource Technology, vol.73, pp.187-189, 2000.
DOI : 10.1016/s0960-8524(99)00158-3

M. Evtiouguina, A. Gandini, C. P. Neto, and N. M. Belgacem, Urethanes and polyurethanes based on oxypropylated cork: 1. Appraisal and reactivity of products, Polymer International, vol.50, pp.1150-1155, 2001.

A. De-menezes, D. Pasquini, A. Curvelo, and A. Gandini, Self-reinforced composites obtained by the partial oxypropylation of cellulose fibers. 2. Effect of catalyst on the mechanical and dynamic mechanical properties, Cellulose, vol.16, pp.239-246, 2009.

C. Pavier and A. Gandini, Oxypropylation of sugar beet pulp. 1. Optimisation of the reaction, Industrial Crops and Products, vol.12, pp.1-8, 2000.
DOI : 10.1016/s0926-6690(99)00039-4

C. Pavier and A. Gandini, Oxypropylation of sugar beet pulp. 2. Separation of the grafted pulp from the propylene oxide homopolymer, Carbohydrate Polymers, vol.42, pp.13-17, 2000.

C. Pavier and A. Gandini, Urethanes and polyurethanes from oxypropylated sugar beet pulp. I. Kinetic study in solution, European Polymer Journal, vol.36, pp.1653-1658, 2000.
DOI : 10.1016/s0014-3057(99)00245-1

J. P. Aniceto, I. Portugal, and C. M. Silva, Biomass-based polyols through oxypropylation reaction, ChemSusChem, vol.5, pp.1358-1368, 2012.

L. C. Wu and W. G. Glasser, Engineering Plastics from Lignin. I. Synthesis of hydroxypropyl lignin, Journal of Applied Polymer Science, vol.29, pp.1111-1123, 1984.

M. Ionescu, Chemistry and technology of polyols for polyurethanes, 2005.

D. S. Argyropoulos, Quantitative Phosphorus-31 NMR Analysis of Lignins, a New Tool for the Lignin Chemist, Journal of Wood Chemistry and Technology, vol.14, pp.45-63, 1994.

D. S. Argyropoulos, Quantitative Phosphorus-31 NMR Analysis of Six Soluble Lignins, Journal of Wood Chemistry and Technology, vol.14, pp.65-82, 1994.

D. S. Argyropoulos, 31P NMR in wood chemistry: A review of recent progress, Research on Chemical Intermediates, vol.21, pp.373-395, 1995.

H. Nadji, C. Bruzzese, M. N. Belgacem, A. Benaboura, and A. Gandini, Oxypropylation of lignins and preparation of rigid polyurethane foams from the ensuing polyols, Macromolecular Materials and Engineering, vol.290, pp.1009-1016, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00196909

C. A. Cateto, M. F. Barreiro, A. E. Rodrigues, and M. N. Belgacem, Optimization study of lignin oxypropylation in view of the preparation of polyurethane rigid foams, Industrial and Engineering Chemistry Research, vol.48, pp.2583-2589, 2009.

Y. Li and A. J. Ragauskas, Ethanol organosolv lignin-based rigid polyurethane foam reinforced with cellulose nanowhiskers, pp.3347-3351, 2012.

Y. Li and A. J. Ragauskas, Kraft Lignin-Based Rigid Polyurethane Foam, Journal of Wood Chemistry and Technology, vol.32, pp.210-224, 2012.

S. S. Kelley, W. G. Glasser, and T. C. Ward, Engineering plastics from lignin. XV. Polyurethane films from chain-extended hydroxypropyl lignin, Journal of Applied Polymer Science, vol.36, pp.759-772, 1988.

H. Hatakeyama, A. Hirogaki, H. Matsumura, and T. Hatakeyama, Glass transition temperature of polyurethane foams derived from lignin by controlled reaction rate, Journal of Thermal Analysis and Calorimetry, vol.2013, pp.1-8

R. W. Thring, P. Ni, and S. M. Aharoni, Molecular weight effects of the soft segment on the ultimate properties of lignin-derived polyurethanes, International Journal of Polymeric Materials, vol.53, pp.507-524, 2004.

R. W. Thring, M. N. Vanderlaan, and S. L. Griffin, Polyurethanes from Alcell® lignin. Biomass and Bioenergy, vol.13, pp.125-132, 1997.

M. N. Vanderlaan and R. W. Thring, Polyurethanes from Alcell® lignin fractions obtained by sequential solvent extraction, Biomass and Bioenergy, vol.14, pp.525-531, 1998.

C. A. Cateto, M. F. Barreiro, and A. E. Rodrigues, Monitoring of lignin-based polyurethane synthesis by FTIR-ATR, Industrial Crops and Products, vol.27, pp.168-174, 2008.

E. Delebecq, J. P. Pascault, B. Boutevin, and F. Ganachaud, On the versatility of urethane/urea bonds: Reversibility, blocked isocyanate, and non-isocyanate polyurethane, Chemical Reviews, issue.113, pp.80-118, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00825156

S. Sarkar and B. Adhikari, Thermal stability of lignin-hydroxy-terminated polybutadiene copolyurethanes, Polymer Degradation and Stability, vol.73, pp.169-175, 2001.

S. Sarkar and B. Adhikari, Synthesis and characterization of lignin-HTPB copolyurethane, European Polymer Journal, vol.37, pp.1391-1401, 2001.

C. Bonini, M. D'auria, L. Emanuele, R. Ferri, R. Pucciariello et al., Polyurethanes and polyesters from lignin, Journal of Applied Polymer Science, vol.98, pp.1451-1456, 2005.

H. Hatakeyama, S. Hirose, T. Hatakeyama, and I. Lignin, , pp.205-218, 1989.

H. Hatakeyama, S. Hirose, S. Yano, K. Nakamura, and T. Hatakeyama, Cellulose sources and exploitation: industrial utilization, biotechnology and physico-chemical properties, pp.466-471, 1990.

L. Kouisni, Y. Fang, M. Paleologou, B. Ahvazi, J. Hawari et al., Kraft lignin recovery and its use in the preparation of lignin-based phenol formaldehyde resins for plywood, Cellulose Chemistry and Technology, vol.45, pp.515-520, 2011.

N. E. Mansouri, Q. Yuan, and F. Huang, Synthesis and characterization of kraft lignin-based epoxy resins, BioResources, issue.6, pp.2492-2503, 2011.

Q. Yin, W. Yang, C. Sun, and M. Di, Preparation and properties of lignin-epoxy resin composite, BioResources, vol.7, pp.5737-5748, 2012.

G. Sun, H. Sun, Y. Liu, B. Zhao, N. Zhu et al., Comparative study on the curing kinetics and mechanism of a lignin-based-epoxy/anhydride resin system, Polymer, vol.48, pp.330-337, 2007.

T. N. Ismail, H. A. Hassan, S. Hirose, Y. Taguchi, T. Hatakeyama et al., Synthesis and thermal properties of ester-type crosslinked epoxy resins derived from lignosulfonate and glycerol, Polymer International, vol.59, pp.181-186, 2010.

O. Faruk and M. Sain, Continuous extrusion foaming of lignin enhanced thermoplastic polyurethane (TPU), Journal of Biobased Materials and Bioenergy, issue.7, pp.309-314, 2013.

P. Cinelli, I. Anguillesi, and A. Lazzeri, Green synthesis of flexible polyurethane foams from liquefied lignin, European Polymer Journal, vol.49, pp.1174-1184, 2013.

X. Pan and J. N. Saddler, Effect of replacing polyol by organosolv and kraft lignin on the property and structure of rigid polyurethane foam, p.12, 2013.

C. Ciobanu, M. Ungureanu, L. Ignat, D. Ungureanu, and V. I. Popa, Properties of lignin-polyurethane films prepared by casting method, Ind. Crop. Pro, p.231, 2004.

Y. S. Kim and J. F. Kadla, Preparation of a thermoresponsive lignin-based biomaterial through atom transfer radical polymerization, Biomacromolecules, vol.11, pp.981-988, 2010.

L. Cuvé, J. P. Pascault, G. Boiteux, and G. Seytre, Synthesis and properties of polyurethanes based on polyolefine: 1. Rigid polyurethanes and amorphous segmented polyurethanes prepared in polar solvents under homogeneous conditions, Polymer, vol.32, pp.343-352, 1991.

L. H. Peebles, Hard Block Length Distribution in Segmented Block Copolymers, Macromolecules, issue.9, pp.58-61, 1976.

G. Hinrichsen, Polyurethane handbook, vol.770, pp.398-398, 1993.

L. H. Peebles, Sequence Length Distribution in Segmented Block Copolymers. Macromolecules, vol.7, pp.872-882, 1974.

C. Prisacariu, Polyurethane Elastomers. From Morphology to Mechanical Aspects, pp.23-60, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00930142

J. K. Backus and H. G. Schmelzer, Encyclopedia of Polymer Science and Engineering, pp.243-303, 1988.

C. Prisacariu and E. Scortanu, Morphology of polyurethanes based on the chain extender ethylene glycol and aromatic flexible diisocyanates, as revealed by scanning electron microscopy, Revue Roumaine de Chimie, vol.53, pp.821-825, 2008.

T. G. Rials and W. G. Glasser, Engineering plastics from lignin. XIII: Effect of lignin structure on polyurethane network formation, Holzforschung, vol.40, pp.353-360, 1986.

C. A. Cateto, Lignin-Based Polyurethanes:Characterisation, Synthesis and Applications, FEUP, 2008.

H. Nadji, C. Bruzzèse, M. N. Belgacem, A. Benaboura, and A. Gandini, Oxypropylation of lignins and preparation of rigid polyurethane foams from the ensuing polyols, Macromolecular Materials and Engineering, vol.290, pp.1009-1016, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00196909

P. T. Anastas and J. C. Warner, Green Chemistry: Theory and Practice, 1998.

M. Vert, Y. Doi, K. H. Hellwich, M. Hess, P. Hodge et al., Terminology for biorelated polymers and applications (IUPAC recommendations 2012, vol.84, pp.377-410, 2012.
DOI : 10.1351/pac-rec-10-12-04

URL : https://hal.archives-ouvertes.fr/hal-00720283

D. K. Chattopadhyay and D. C. Webster, Thermal stability and flame retardancy of polyurethanes, Progress in Polymer Science, vol.34, pp.1068-1133, 2009.

G. Vázquez, G. Antorrena, J. González, and S. Freire, The influence of pulping conditions on the structure of acetosolv eucalyptus lignins, Journal of Wood Chemistry and Technology, vol.17, pp.147-162, 1997.

R. J. Gosselink, E. D. Jong, B. Guran, and A. Abächerli, Co-ordination network for lignin-Standardisation, production and applications adapted to market requirements (EUROLIGNIN), Industrial Crops and Products, vol.20, pp.121-129, 2004.
DOI : 10.1016/j.indcrop.2004.04.015

A. Vishtal and A. Kraslawski, Challenges in industrial applications of technical lignins, BioResources, issue.6, pp.3547-3568, 2011.

R. J. Gosselink, A. Abächerli, H. Semke, R. Malherbe, P. Käuper et al., Analytical protocols for characterisation of sulphur-free lignin, Industrial Crops and Products, vol.19, pp.271-281, 2004.

K. Wörmeyer, T. Ingram, B. Saake, G. Brunner, and I. Smirnova, Comparison of different pretreatment methods for lignocellulosic materials. Part II: Influence of pretreatment on the properties of rye straw lignin, Bioresource Technology, vol.102, pp.4157-4164, 2011.

F. G. Calvo-flores and J. A. Dobado, Lignin as renewable raw material, ChemSusChem, vol.3, pp.1227-1235, 2010.
DOI : 10.1002/cssc.201000157

A. Gandini, The irruption of polymers from renewable resources on the scene of macromolecular science and technology, Green Chemistry, issue.13, pp.1061-1083, 2011.

C. Pouteau, P. Dole, B. Cathala, L. Averous, and N. Boquillon, Antioxidant properties of lignin in polypropylene, Polymer Degradation and Stability, vol.81, pp.9-18, 2003.

N. Henry, D. Harper, and M. Dadmun, Optimizing noncovalent interactions between lignin and synthetic polymers to develop effective compatibilizers, Macromolecular Chemistry and Physics, vol.213, pp.1196-1205, 2012.
DOI : 10.1002/macp.201100633

S. Kubo and J. F. Kadla, Kraft lignin/poly(ethylene oxide) blends: Effect of lignin structure on miscibility and hydrogen bonding, Journal of Applied Polymer Science, vol.98, pp.1437-1444, 2005.

J. F. Kadla and S. Kubo, Lignin-based polymer blends: analysis of intermolecular interactions in lignin-synthetic polymer blends, Composites Part A: Applied Science and Manufacturing, vol.35, pp.395-400, 2004.

P. Song, Z. Cao, Q. Meng, S. Fu, Z. Fang et al., Effect of lignin incorporation and reactive compatibilization on the morphological, rheological, and mechanical properties of ABS resin, Journal of Macromolecular Science, Part B: Physics, vol.51, pp.720-735, 2012.

J. Li, Y. He, and Y. Inoue, Study on thermal and mechanical properties of biodegradable blends of poly(?-caprolactone) and lignin, Polymer Journal, vol.33, pp.336-343, 2001.

J. H. Lora and W. G. Glasser, Recent industrial applications of lignin: A sustainable alternative to nonrenewable materials, Journal of Polymers and the Environment, issue.10, pp.39-48, 2002.

W. D. Oliveira and W. G. Glasser, Multiphase materials with lignin. 11. Starlike copolymers with caprolactone, Macromolecules, vol.27, pp.5-11, 1994.

A. M. Nada, M. El-sakhawy, and S. M. Kamel, Infra-red spectroscopic study of lignins, Polymer Degradation and Stability, vol.60, pp.247-251, 1998.

S. Kubo and J. F. Kadla, Hydrogen bonding in lignin: A fourier transform infrared model compound study. Biomacromolecules, pp.2815-2821, 2005.

J. Li, Y. He, and Y. Inoue, Thermal and mechanical properties of biodegradable blends of poly(L-lactic acid) and lignin, Polymer International, vol.52, pp.949-955, 2003.

S. Hirose, T. Hatakeyama, Y. Izuta, and H. Hatakeyama, TG-FTIR studies on ligninbased polycaprolactones, Journal of Thermal Analysis and Calorimetry, vol.70, pp.853-860, 2002.

L. Averous, L. Moro, P. Dole, and C. Fringant, Properties of thermoplastic blends: Starch-polycaprolactone. Polymer, vol.41, pp.4157-4167, 2000.

S. C. Fox and A. G. Mcdonald, Chemical and thermal characterization of three industrial lignins and their corresponding lignin esters, BioResources, vol.5, pp.990-1009, 2010.

O. Persenaire, M. Alexandre, P. Degée, and P. Dubois, Mechanisms and Kinetics of Thermal Degradation of Poly(?-caprolactone), Biomacromolecules, issue.2, pp.288-294, 2001.

P. Karmalm, T. Hjertberg, A. Jansson, and R. Dahl, Thermal stability of poly(vinyl chloride) with epoxidised soybean oil as primary plasticizer, Polymer Degradation and Stability, vol.94, pp.2275-2281, 2009.

P. Karmalm, T. Hjertberg, A. Jansson, R. Dahl, and K. Ankner, Network formation by epoxidised soybean oil in plastisol poly(vinyl chloride), Polymer Degradation and Stability, vol.94, pp.1986-1990, 2009.

F. E. Okieimen, Studies in the utilisation of epoxidised vegetable oils as thermal stabiliser for polyvinyl chloride, Industrial Crops and Products, vol.15, pp.71-75, 2002.

A. Zlatani?, Z. S. Petrovi?, and K. Du?ek, Structure and Properties of Triolein-Based Polyurethane Networks, Biomacromolecules, vol.3, pp.1048-1056, 2002.

Z. S. Petrovi?, A. Guo, and W. Zhang, Structure and properties of polyurethanes based on halogenated and nonhalogenated soy-polyols, Journal of Polymer Science Part A: Polymer Chemistry, vol.38, pp.4062-4069, 2000.

Z. S. Petrovi?, L. Yang, A. Zlatani?, W. Zhang, and I. Javni, Network structure and properties of polyurethanes from soybean oil, Journal of Applied Polymer Science, vol.105, pp.2717-2727, 2007.

A. Köckritz and A. Martin, Oxidation of unsaturated fatty acid derivatives and vegetable oils, European Journal of Lipid Science and Technology, vol.110, pp.812-824, 2008.

N. Ramani, D. Graiver, K. W. Farminer, P. T. Tran, and T. Tran, , pp.603-604, 2010.

I. Cvetkovi?, J. Mili?, M. Ionescu, and Z. S. Petrovi?, Preparation of 9hydroxynonanoic acid methyl ester by ozonolysis of vegetable oils and its polycondensation, Hemijska Industrija, vol.62, pp.319-328, 2008.

Z. S. Petrovi?, W. Zhang, and I. Javni, Structure and Properties of Polyurethanes Prepared from Triglyceride Polyols by Ozonolysis, Biomacromolecules, issue.6, pp.713-719, 2005.

X. Kong and S. S. Narine, Physical properties of polyurethane plastic sheets produced from polyols from canola oil, Biomacromolecules, vol.8, pp.2203-2209, 2007.

A. Guo, D. Demydov, W. Zhang, and Z. S. Petrovic, Polyols and polyurethanes from hydroformylation of soybean oil, Journal of Polymers and the Environment, issue.10, pp.49-52, 2002.

C. K. Lyon, V. H. Garrett, and E. N. Frankel, Rigid urethane foams from hydroxymethylated castor oil, safflower oil, oleic safflower oil, and polyol esters of castor acids, Journal of the American Oil Chemists Society, vol.51, pp.331-334, 1974.

T. H. Khoe, F. Otey, E. N. Frankel, and J. C. Cowan, Polyurethane foams from hydroxymethylated fatty diethanolamides, Journal of the American Oil Chemists Society, vol.50, pp.331-333, 1973.

A. Guo, W. Zhang, and Z. Petrovic, Structure-property relationships in polyurethanes derived from soybean oil, Journal of Materials Science, vol.41, pp.4914-4920, 2006.

T. H. Khoe, F. H. Otey, and E. N. Frankel, Rigid urethane foams from hydroxymethylated linseed oil and polyol esters, Journal of the American Oil Chemists Society, vol.49, pp.615-618, 1972.

Z. S. Petrovic, Polyurethanes from vegetable oils, Polymer Reviews, pp.48-109, 2008.

M. Van-der-steen and C. V. Stevens, Undecylenic Acid: A Valuable and Physiologically Active Renewable Building Block from Castor Oil, ChemSusChem, issue.2, pp.692-713, 2009.

U. Biermann, W. Friedt, S. Lang, W. Lühs, G. Machmüller et al.,

. Gen, H. J. Klaas, M. P. Schäfer, and . Schneider, Biorefineries-Industrial Processes and Products, pp.253-289, 2008.

R. J. González-paz, C. Lluch, G. Lligadas, J. C. Ronda, M. Galià et al., A green approach toward oleic-and undecylenic acid-derived polyurethanes, Journal of Polymer Science, Part A: Polymer Chemistry, vol.49, pp.2407-2416, 2011.

O. Türünç and M. A. Meier, Fatty acid derived monomers and related polymers via thiol-ene (Click) additions, Macromolecular Rapid Communications, pp.1822-1826, 2010.

G. B. Bantchev, J. A. Kenar, G. Biresaw, and M. G. Han, Free Radical Addition of Butanethiol to Vegetable Oil Double Bonds, Journal of Agricultural and Food Chemistry, vol.57, pp.1282-1290, 2009.

J. Samuelsson, M. Jonsson, T. Brinck, and M. Johansson, Thiol-ene coupling reaction of fatty acid monomers, Journal of Polymer Science Part A: Polymer Chemistry, vol.42, pp.6346-6352, 2004.

A. Gandini, Polymers from renewable resources: A challenge for the future of macromolecular materials, Macromolecules, vol.41, pp.9491-9504, 2008.

D. K. Chattopadhyay and D. C. Webster, Thermal stability and flame retardancy of polyurethanes, Progress in Polymer Science, vol.34, pp.1068-1133, 2009.

A. Gandini, The irruption of polymers from renewable resources on the scene of macromolecular science and technology, Green Chemistry, issue.13, pp.1061-1083, 2011.

C. P. Roger, The Chemistry of Solid Wood, pp.57-126, 1984.

E. Dorrestijn, L. J. Laarhoven, I. W. Arends, and P. Mulder, The occurrence and reactivity of phenoxyl linkages in lignin and low rank coal, Journal of Analytical and Applied Pyrolysis, vol.54, pp.153-192, 2000.

S. Laurichesse and L. Avérous, Synthesis, thermal properties, rheological and mechanical behaviors of lignins-grafted-poly(?-caprolactone), Polymer (United Kingdom), issue.54, pp.3882-3890, 2013.

R. Fang, X. S. Cheng, and W. S. Lin, Preparation and application of dimer acid/lignin graft copolymer, BioResources, issue.6, pp.2874-2884, 2011.

W. Thielemans and R. P. Wool, Lignin esters for use in unsaturated thermosets: Lignin modification and solubility modeling, Biomacromolecules, issue.6, pp.1895-1905, 2005.

S. Thiebaud and M. E. Borredon, Solvent-free wood esterification with fatty acid chlorides, Bioresource Technology, vol.52, pp.169-173, 1995.

S. Thiebaud, M. E. Borredon, G. Baziard, and F. Senocq, Properties of wood esterified by fatty-acid chlorides, Bioresource Technology, vol.59, pp.103-107, 1997.

D. V. Palaskar, A. Boyer, E. Cloutet, J. F. Le-meins, B. Gadenne et al., Original diols from sunflower and ricin oils: Synthesis, characterization, and use as polyurethane building blocks, Journal of Polymer Science, Part A: Polymer Chemistry, vol.50, pp.1766-1782, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00747662

A. S. More, B. Gadenne, C. Alfos, and H. Cramail, AB type polyaddition route to thermoplastic polyurethanes from fatty acid derivatives, Polymer Chemistry, vol.3, pp.1594-1605, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00818395

P. Mousavioun and W. O. Doherty, Chemical and thermal properties of fractionated bagasse soda lignin, Industrial Crops and Products, vol.31, pp.52-58

P. P. Kiatsimkul, G. J. Suppes, F. H. Hsieh, Z. Lozada, and Y. C. Tu, Preparation of high hydroxyl equivalent weight polyols from vegetable oils, Industrial Crops and Products, vol.27, pp.257-264, 2008.

A. Rybak, P. A. Fokou, and M. A. Meier, Metathesis as a versatile tool in oleochemistry, European Journal of Lipid Science and Technology, vol.110, pp.797-804, 2008.

X. Miao, C. Fischmeister, P. H. Dixneuf, C. Bruneau, J. L. Dubois et al., Polyamide precursors from renewable 10-undecenenitrile and methyl acrylate via olefin cross-metathesis, Green Chemistry, vol.14, pp.2179-2183, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00864808

M. Desroches, S. Caillol, V. Lapinte, R. Auvergne, and B. Boutevin, Synthesis of biobased polyols by thiol-ene coupling from vegetable oils, Macromolecules, vol.44, pp.2489-2500, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00587652

C. Lluch, J. C. Ronda, M. Galià, G. Lligadas, and V. Cádiz, Rapid approach to biobased telechelics through two one-pot thiol-ene click reactions, Biomacromolecules, vol.11, pp.1646-1653, 2010.

M. Szycher, Szycher's Handbook of Polyurethanes, 2012.

M. Ionescu, Chemistry and Technology of Polyols for Polyuerethanes, Rapra Technology, 2005.

M. A. Meier, J. O. Metzger, and U. S. Schubert, Plant oil renewable resources as green alternatives in polymer science, Chemical Society Reviews, vol.36, pp.1788-1802, 2007.

E. K. Pye, The alcell process a proven alternative to kraft pulping, Tappi Journal, p.74, 1991.

R. W. Thring, M. N. Vanderlaan, and S. L. Griffin, Polyurethanes from Alcell® lignin. Biomass and Bioenergy, vol.13, pp.125-132, 1997.

S. Baumberger, A. Abaecherli, M. Fasching, G. Gellerstedt, R. Gosselink et al., Molar mass determination of lignins by size-exclusion chromatography: Towards standardisation of the method, Holzforschung, vol.61, pp.459-468, 2007.

N. E. Mansouri and J. Salvadó, Structural characterization of technical lignins for the production of adhesives: Application to lignosulfonate, kraft, soda-anthraquinone, organosolv and ethanol process lignins, Industrial Crops and Products, pp.24-32, 2006.

E. A. Capanema, M. Y. Balakshin, and J. F. Kadla, A Comprehensive Approach for Quantitative Lignin Characterization by NMR Spectroscopy, Journal of Agricultural and Food Chemistry, vol.52, pp.1850-1860, 2004.

S. Caillol, M. Desroches, G. Boutevin, C. Loubat, R. Auvergne et al., Synthesis of new polyester polyols from epoxidized vegetable oils and biobased acids, European Journal of Lipid Science and Technology, vol.114, pp.1447-1459, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00778371

G. Lligadas, J. C. Ronda, M. Galià, U. Biermann, and J. O. Metzger, Synthesis and characterization of polyurethanes from epoxidized methyl oleate based polyether polyols as renewable resources, Journal of Polymer Science Part A: Polymer Chemistry, vol.44, pp.634-645, 2006.

R. W. Thring, P. Ni, and S. M. Aharoni, Molecular weight effects of the soft segment on the ultimate properties of lignin-derived polyurethanes, International Journal of Polymeric Materials, vol.53, pp.507-524, 2004.

Q. Ma, X. Liu, R. Zhang, J. Zhu, and Y. Jiang, Synthesis and properties of full biobased thermosetting resins from rosin acid and soybean oil: the role of rosin acid derivatives, Green Chemistry, issue.15, pp.1300-1310, 2013.

G. R. Palmese and R. L. Mccullough, Effect of epoxy-amine stoichiometry on cured resin material properties, Journal of Applied Polymer Science, vol.46, pp.1863-1873, 1992.

J. Huang and L. Zhang, Effects of NCO/OH molar ratio on structure and properties of graft-interpenetrating polymer networks from polyurethane and nitrolignin, Polymer, vol.43, pp.2287-2294, 2002.

T. Saito, R. H. Brown, M. A. Hunt, D. L. Pickel, J. M. Pickel et al., Turning renewable resources into value-added polymer: Development of lignin-based thermoplastic, Green Chemistry, vol.14, pp.3295-3303, 2012.

Y. Xu, Z. Petrovic, S. Das, and G. L. Wilkes, Morphology and properties of thermoplastic polyurethanes with dangling chains in ricinoleate-based soft segments, Polymer, vol.49, pp.4248-4258, 2008.

Z. S. Petrovi?, D. Hong, I. Javni, N. Erina, F. Zhang et al., Phase structure in segmented polyurethanes having fatty acid-based soft segments, Polymer, vol.54, pp.372-380, 2013.

C. Ciobanu, M. Ungureanu, L. Ignat, D. Ungureanu, and V. I. Popa, Properties of lignin-polyurethane films prepared by casting method, Ind. Crop. Pro, p.231, 2004.

M. Brebu and C. Vasile, Thermal degradation of lignin-A review, Cellulose Chemistry and Technology, vol.44, pp.353-363, 2010.

G. Lligadas, J. C. Ronda, M. Galiá, and V. Cádiz, Plant oils as platform chemicals for polyurethane synthesis: Current state-of-the-art, Biomacromolecules, vol.11, pp.2825-2835, 2010.

D. P. Pfister, Y. Xia, and R. C. Larock, Recent advances in vegetable oil-based polyurethanes, ChemSusChem, vol.4, pp.703-717, 2011.

A. B. Lowe, ;. Babu, K. O'connor, and R. Seeram, Thiol-ene "click" reactions and recent applications in polymer and materials synthesis, Progress in Biomaterials C7-8, vol.1, pp.1-16, 2010.

M. Szycher, Szycher's Handbook of Polyurethanes, 2012.

M. Ionescu, Chemistry and technology of polyols for polyurethanes, 2005.

L. J. Gibson, The hierarchical structure and mechanics of plant materials, Journal of the Royal Society Interface, vol.9, pp.2749-2766, 2012.

W. Boerjan, J. Ralph, and M. Baucher, Annual Review of Plant Biology, pp.519-546, 2003.

G. Brunow, , pp.89-99, 2004.

Y. R. Chen and S. Sarkanen, Macromolecular replication during lignin biosynthesis, Phytochemistry, vol.71, pp.453-462, 2010.

G. Vázquez, G. Antorrena, J. González, and S. Freire, The influence of pulping conditions on the structure of acetosolv eucalyptus lignins, Journal of Wood Chemistry and Technology, vol.17, pp.147-162, 1997.

H. Hatakeyama and T. Hatakeyama, , pp.1-63, 2010.

E. A. Silva, M. Zabkova, J. D. Araújo, C. A. Cateto, M. F. Barreiro et al., An integrated process to produce vanillin and ligninbased polyurethanes from Kraft lignin, Chemical Engineering Research and Design, vol.87, pp.1276-1292, 2009.

L. C. Wu and W. G. Glasser, Engineering plastics from lignin. I. Synthesis of hydroxypropyl lignin, Journal of Applied Polymer Science, vol.29, pp.1111-1123, 1984.

L. C. Wu and W. G. Glasser, Engineering Plastics From Lignin. I. Synthesis of hydroxypropyl lignin, Journal of Applied Polymer Science, vol.29, pp.1111-1123, 1984.

W. G. Glasser, C. A. Barnett, T. G. Rials, and V. P. Saraf, Engineering Plastics From Lignin-II Characterization of hydroxyalkyl derivatives, Journal of Applied Polymer Science, vol.29, pp.1815-1830, 1984.

S. Fernandes, C. S. Freire, C. P. Neto, and A. Gandini, The bulk oxypropylation of chitin and chitosan and the characterization of the ensuing polyols, Green Chemistry, issue.10, pp.93-97, 2008.
URL : https://hal.archives-ouvertes.fr/hal-01600492

M. Evtiouguina, A. Margarida-barros, J. J. Cruz-pinto, C. Neto, N. Belgacem et al., The oxypropylation of cork residues: preliminary results, Bioresource Technology, vol.73, pp.187-189, 2000.

M. Evtiouguina, A. Gandini, C. P. Neto, and N. M. Belgacem, Urethanes and polyurethanes based on oxypropylated cork: 1. Appraisal and reactivity of products, Polymer International, vol.50, pp.1150-1155, 2001.

A. De-menezes, D. Pasquini, A. Curvelo, and A. Gandini, Self-reinforced composites obtained by the partial oxypropylation of cellulose fibers. 2. Effect of catalyst on the mechanical and dynamic mechanical properties, Cellulose, vol.16, pp.239-246, 2009.

C. Pavier and A. Gandini, Oxypropylation of sugar beet pulp. 1. Optimisation of the reaction, Industrial Crops and Products, vol.12, pp.1-8, 2000.

C. Pavier and A. Gandini, Oxypropylation of sugar beet pulp. 2. Separation of the grafted pulp from the propylene oxide homopolymer, Carbohydrate Polymers, vol.42, pp.13-17, 2000.

C. Pavier and A. Gandini, Urethanes and polyurethanes from oxypropylated sugar beet pulp. I. Kinetic study in solution, European Polymer Journal, vol.36, pp.1653-1658, 2000.

A. Gandini, A. A. Da-silva-curvelo, D. Pasquini, and A. J. De-menezes, Direct transformation of cellulose fibres into self-reinforced composites by partial oxypropylation, Polymer, vol.46, pp.10611-10613, 2005.

A. Gandini, M. N. Belgacem, B. M. Naceur, and G. Alessandro, Monomers, Polymers and Composites from Renewable Resources, pp.273-288, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00511686

A. J. De-menezes, D. Pasquini, A. A. Curvelo, and A. Gandini, Novel thermoplastic materials based on the outer-shell oxypropylation of corn starch granules, Biomacromolecules, vol.8, pp.2047-2050, 2007.

H. Nadji, C. Bruzzese, M. N. Belgacem, A. Benaboura, and A. Gandini, Oxypropylation of lignins and preparation of rigid polyurethane foams from the ensuing polyols, Macromolecular Materials and Engineering, vol.290, pp.1009-1016, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00196909

A. Gandini and M. N. Belgacem, Recent contributions to the preparation of polymers derived from renewable resources, Journal of Polymers and the Environment, issue.10, pp.105-114, 2002.

J. P. Aniceto, I. Portugal, and C. M. Silva, Biomass-based polyols through oxypropylation reaction, ChemSusChem, vol.5, pp.1358-1368, 2012.

C. A. Cateto, M. F. Barreiro, A. E. Rodrigues, and M. N. Belgacem, Optimization study of lignin oxypropylation in view of the preparation of polyurethane rigid foams, Industrial and Engineering Chemistry Research, vol.48, pp.2583-2589, 2009.

S. Laurichesse and L. Avérous, Synthesis, thermal properties, rheological and mechanical behaviors of lignins-grafted-poly(?-caprolactone), Polymer (United Kingdom), issue.54, pp.3882-3890, 2013.

G. Lammers, E. J. Stamhuis, and A. A. Beenackers, Kinetics of the hydroxypropylation of potato starch in aqueous solution, Industrial & Engineering Chemistry Research, vol.32, pp.835-842, 1993.

C. A. Cateto, Lignin-Based Polyurethanes:Characterisation, Synthesis and Applications, FEUP, 2008.

H. Nadji, C. Bruzzèse, M. N. Belgacem, A. Benaboura, and A. Gandini, Oxypropylation of lignins and preparation of rigid polyurethane foams from the ensuing polyols, Macromolecular Materials and Engineering, vol.290, pp.1009-1016, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00196909

A. Gandini, M. N. Belgacem, B. M. Naceur, and G. Alessandro, Monomers, Polymers and Composites from Renewable Resources, pp.243-271, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00511686

D. S. Argyropoulos, Quantitative Phosphorus-31 NMR Analysis of Lignins, a New Tool for the Lignin Chemist, Journal of Wood Chemistry and Technology, vol.14, pp.45-63, 1994.

D. S. Argyropoulos, Quantitative Phosphorus-31 NMR Analysis of Six Soluble Lignins, Journal of Wood Chemistry and Technology, vol.14, pp.65-82, 1994.

D. S. Argyropoulos, 31P NMR in wood chemistry: A review of recent progress, Research on Chemical Intermediates, vol.21, pp.373-395, 1995.

A. Granata and D. S. Argyropoulos, 2dioxaphospholane, a reagent for the accurate determination of the uncondensed and condensed phenolic moieties in lignins, Journal of Agricultural and Food Chemistry, vol.2, issue.4, pp.1538-1544, 1995.

H. Sadeghifar, C. Cui, and D. S. Argyropoulos, Toward Thermoplastic Lignin Polymers; Part I: Selective Masking of Phenolic Hydroxyl Groups in Kraft Lignins via Methylation & Oxypropylation Chemistries, Industrial & Engineering Chemistry Research, 2012.

T. Saito, R. H. Brown, M. A. Hunt, D. L. Pickel, J. M. Pickel et al., Turning renewable resources into value-added polymer: Development of lignin-based thermoplastic, Green Chemistry, vol.14, pp.3295-3303, 2012.

R. W. Thring, M. N. Vanderlaan, and S. L. Griffin, Polyurethanes from Alcell® lignin. Biomass and Bioenergy, vol.13, pp.125-132, 1997.

R. W. Thring, P. Ni, and S. M. Aharoni, Molecular weight effects of the soft segment on the ultimate properties of lignin-derived polyurethanes, International Journal of Polymeric Materials, vol.53, pp.507-524, 2004.

Q. Ma, X. Liu, R. Zhang, J. Zhu, and Y. Jiang, Synthesis and properties of full biobased thermosetting resins from rosin acid and soybean oil: the role of rosin acid derivatives, Green Chemistry, issue.15, pp.1300-1310, 2013.

G. R. Palmese and R. L. Mccullough, Effect of epoxy-amine stoichiometry on cured resin material properties, Journal of Applied Polymer Science, vol.46, pp.1863-1873, 1992.

Y. Xu, Z. Petrovic, S. Das, and G. L. Wilkes, Morphology and properties of thermoplastic polyurethanes with dangling chains in ricinoleate-based soft segments, Polymer, vol.49, pp.4248-4258, 2008.

C. Prisacariu, Polyurethane Elastomers. From Morphology to Mechanical Aspects, pp.23-60, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00930142

S. Velankar and S. L. Cooper, Microphase separation and rheological properties of polyurethane melts. 2. Effect of block incompatibility on the microstructure, Macromolecules, vol.33, pp.382-394, 2000.

S. Velankar and S. L. Cooper, Microphase separation and rheological properties of polyurethane melts. 1. Effect of block length, Macromolecules, vol.31, pp.9181-9192, 1998.

S. Velankar and S. L. Cooper, Microphase separation and rheological properties of polyurethane melts. 3. Effect of block incompatibility on the viscoelastic properties, Macromolecules, vol.33, pp.395-403, 2000.

M. Brebu and C. Vasile, Thermal degradation of lignin-A review, Cellulose Chemistry and Technology, vol.44, pp.353-363, 2010.

T. Hatakeyama and H. Hatakeyama, Thermal Properties of Green Polymers and Biocomposites, 2005.

C. Cui, H. Sadeghifar, S. Sen, and D. S. Argyropoulos, Toward thermoplastic lignin polymers; Part II: Thermal & polymer characteristics of kraft lignin & derivatives, BioResources, issue.8, pp.864-886, 2013.

J. H. Saunders, The Reactions of Isocyanates and Isocyanate Derivatives at Elevated Temperatures. Rubber Chemistry and Technology, vol.32, pp.337-345, 1959.

I. Javni, Z. S. Petrovi?, A. Guo, and R. Fuller, Thermal stability of polyurethanes based on vegetable oils, Journal of Applied Polymer Science, vol.77, pp.1723-1734, 2000.

, Methoxyl Content of Pulp and Wood, TAPPI Test Methods, pp.209-72, 1972.

, Sustainable biofuels: prospects and challenges, 2008.

E. Adler, Lignin chemistry-past, Science and Technology, vol.11, pp.169-218, 1977.

B. Ahvazi, O. Wojciechowicz, T. M. Ton-that, and J. Hawari, Preparation of lignopolyols from wheat straw soda lignin, Journal of Agricultural and Food Chemistry, vol.59, pp.10505-10516, 2011.

A. S. Amarasekara, B. Wiredu, and A. Razzaq, Vanillin based polymers: I. An electrochemical route to polyvanillin, Green Chemistry, vol.14, pp.2395-2397, 2012.

C. Amen-chen, H. Pakdel, and C. Roy, Production of monomeric phenols by thermochemical conversion of biomass: a review, Bioresource Technology, vol.79, pp.277-299, 2001.

P. T. Anastas and J. C. Warner, Green Chemistry: Theory and Practice, 1998.

J. P. Aniceto, I. Portugal, and C. M. Silva, Biomass-based polyols through oxypropylation reaction, ChemSusChem, vol.5, pp.1358-1368, 2012.

C. Aouf, J. Lecomte, P. Villeneuve, E. Dubreucq, and H. Fulcrand, Chemo-enzymatic functionalization of gallic and vanillic acids: Synthesis of bio-based epoxy resins prepolymers, Green Chemistry, vol.14, pp.2328-2336, 2012.
URL : https://hal.archives-ouvertes.fr/hal-01506271

J. D. Araújo, C. A. Grande, and A. E. Rodrigues, Vanillin production from lignin oxidation in a batch reactor, Chemical Engineering Research and Design, vol.88, pp.1024-1032, 2010.

M. Arend, B. Westermann, and N. Risch, Modern Variants of the Mannich Reaction

, Angewandte Chemie International Edition, vol.37, pp.1044-1070, 1998.

D. S. Argyropoulos, Quantitative Phosphorus-31 NMR Analysis of Lignins, a New Tool for the Lignin Chemist, Journal of Wood Chemistry and Technology, vol.14, pp.45-63, 1994.

D. S. Argyropoulos, Quantitative Phosphorus-31 NMR Analysis of Six Soluble Lignins, Journal of Wood Chemistry and Technology, vol.14, pp.65-82, 1994.

D. S. Argyropoulos, 31P NMR in wood chemistry: A review of recent progress, Research on Chemical Intermediates, vol.21, pp.373-395, 1995.

R. Arshady and M. H. George, The allophanate link in polyurethane synthesis, Polymer communications, vol.31, pp.448-450, 1990.

L. Averous, L. Moro, P. Dole, and C. Fringant, Properties of thermoplastic blends: Starchpolycaprolactone, Polymer, vol.41, pp.4157-4167, 2000.

R. Babu, K. O'connor, and R. Seeram, Current progress on bio-based polymers and their future trends, Progress in Biomaterials C7-8, pp.1-16, 2013.

J. K. Backus and H. G. Schmelzer, Encyclopedia of Polymer Science and Engineering, pp.243-303, 1988.

G. B. Bantchev, J. A. Kenar, G. Biresaw, and M. G. Han, Free Radical Addition of Butanethiol to Vegetable Oil Double Bonds, Journal of Agricultural and Food Chemistry, vol.57, pp.1282-1290, 2009.

S. Baumberger, A. Abaecherli, M. Fasching, G. Gellerstedt, R. Gosselink et al., Molar mass determination of lignins by size-exclusion chromatography: Towards standardisation of the method, Holzforschung, pp.459-468, 2007.

R. Benedikt and M. Bamberger, Über eine quantitative Reaction des Lignins, Monatshefte für Chemie, vol.1890, pp.260-267

U. Biermann, W. Friedt, S. Lang, W. Lühs, G. Machmüller et al., Biorefineries-Industrial Processes and Products, pp.253-289, 2008.

A. Bismarck, -. Baltazar, A. Sarikakis, and K. , Green composites as Panacea? Socioeconomic aspects of green materials, Environment, Development and Sustainability, vol.8, pp.445-463, 2006.

W. Boerjan, J. Ralph, and M. Baucher, Annual Review of Plant Biology, pp.519-546, 2003.

C. Bonini, M. D'auria, L. Emanuele, R. Ferri, R. Pucciariello et al., Polyurethanes and polyesters from lignin, Journal of Applied Polymer Science, vol.98, pp.1451-1456, 2005.

J. Bouajila, P. Dole, C. Joly, and A. Limare, Some laws of a lignin plasticization, Journal of Applied Polymer Science, vol.102, pp.1445-1451, 2006.

M. Brebu and I. Spiridon, Co-pyrolysis of LignoBoost® lignin with synthetic polymers, Polymer Degradation and Stability, vol.97, pp.2104-2109, 2012.

M. Brebu and C. Vasile, Thermal degradation of lignin-A review, Cellulose Chemistry and Technology, vol.44, pp.353-363, 2010.

G. Brunow and . In-lignin, , pp.89-99, 2004.

S. Caillol, M. Desroches, G. Boutevin, C. Loubat, R. Auvergne et al., Synthesis of new polyester polyols from epoxidized vegetable oils and biobased acids, European Journal of Lipid Science and Technology, vol.114, pp.1447-1459, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00778371

F. G. Calvo-flores and J. A. Dobado, Lignin as renewable raw material, ChemSusChem, vol.3, pp.1227-1235, 2010.

Y. Camberlin, J. P. Pascault, J. M. Letoffe, and P. Claudy, Synthesis and DSC study of model hard segments from diphenyl methane diisocyanate and butane diol, Journal of Polymer Science: Polymer Chemistry Edition, vol.20, pp.383-392, 1982.

E. A. Capanema, M. Y. Balakshin, and J. F. Kadla, A Comprehensive Approach for Quantitative Lignin Characterization by NMR Spectroscopy, Journal of Agricultural and Food Chemistry, vol.52, pp.1850-1860, 2004.

C. A. Cateto, M. F. Barreiro, and A. E. Rodrigues, Monitoring of lignin-based polyurethane synthesis by FTIR-ATR, Industrial Crops and Products, vol.27, pp.168-174, 2008.

C. A. Cateto, M. F. Barreiro, A. E. Rodrigues, and M. N. Belgacem, Optimization study of lignin oxypropylation in view of the preparation of polyurethane rigid foams, Industrial and Engineering Chemistry Research, vol.48, pp.2583-2589, 2009.

C. A. Cateto, M. F. Barreiro, A. E. Rodrigues, and M. N. Belgacem, Kinetic study of the formation of lignin-based polyurethanes in bulk. Reactive and Functional Polymers, vol.71, pp.863-869, 2011.

C. A. Cateto, Faculdade de Engenharia da Universidade do Porto (FEUP), 2008.

G. Cazacu, M. Capraru, and V. Popa, Advances in Natural, pp.255-312, 2013.

F. S. Chakar and A. J. Ragauskas, Review of current and future softwood kraft lignin process chemistry, Industrial Crops and Products, vol.20, pp.131-141, 2004.

D. K. Chattopadhyay and D. C. Webster, Thermal stability and flame retardancy of polyurethanes, Progress in Polymer Science, vol.34, pp.1068-1133, 2009.

Y. R. Chen and S. Sarkanen, Macromolecular lignin replication: A mechanistic working hypothesis, Phytochemistry Reviews, vol.2, pp.235-255, 2003.

Y. R. Chen and S. Sarkanen, Macromolecular replication during lignin biosynthesis, Phytochemistry, vol.71, pp.453-462, 2010.

S. Cheng, Z. Yuan, M. Anderson, M. Leitch, and C. Xu, Synthesis of biobased phenolic resins/adhesives with methylolated wood-derived bio-oil, Journal of Applied Polymer Science, vol.126, pp.430-440, 2012.

D. Choi, D. C. Chipman, S. C. Bents, and R. C. Brown, A techno-economic analysis of polyhydroxyalkanoate and hydrogen production from syngas fermentation of gasified biomass, Applied Biochemistry and Biotechnology, vol.160, pp.1032-1046, 2010.

P. Cinelli, I. Anguillesi, and A. Lazzeri, Green synthesis of flexible polyurethane foams from liquefied lignin, European Polymer Journal, vol.49, pp.1174-1184, 2013.

C. Ciobanu, M. Ungureanu, L. Ignat, D. Ungureanu, and V. I. Popa, Properties of ligninpolyurethane films prepared by casting method, Ind. Crop. Pro, p.231, 2004.

J. H. Clark, R. Luque, and A. S. Matharu, Green chemistry, biofuels, and biorefinery, Annual Review of Chemical and Biomolecular Engineering, vol.3, pp.183-207, 2012.

C. Cui, H. Sadeghifar, S. Sen, and D. S. Argyropoulos, Toward thermoplastic lignin polymers; Part II: Thermal & polymer characteristics of kraft lignin & derivatives, BioResources, issue.8, pp.864-886, 2013.

L. Cuvé, J. P. Pascault, G. Boiteux, and G. Seytre, Synthesis and properties of polyurethanes based on polyolefine: 1. Rigid polyurethanes and amorphous segmented polyurethanes prepared in polar solvents under homogeneous conditions, Polymer, vol.32, pp.343-352, 1991.

I. Cvetkovi?, J. Mili?, M. Ionescu, and Z. S. Petrovi?, Preparation of 9-hydroxynonanoic acid methyl ester by ozonolysis of vegetable oils and its polycondensation, Hemijska Industrija, vol.62, pp.319-328, 2008.

C. G. Da-silva, S. Grelier, F. Pichavant, E. Frollini, and A. Castellan, Adding value to lignins isolated from sugarcane bagasse and Miscanthus, Industrial Crops and Products, vol.42, pp.87-95, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00932349

A. T. Dang-thi, Y. Camberlin, T. M. Lam, and J. P. Pascault, Synthèse et propriétés de polyuréthanes réticulés par des cycles isocyanurates. Die Angewandte Makromolekulare Chemie, vol.111, pp.29-51, 1983.

M. Dashtban, H. Schraft, T. A. Syed, and W. Qin, Fungal biodegradation and enzymatic modification of lignin, International Journal of Biochemistry and Molecular Biology, issue.1, pp.36-50, 2010.

A. De-chirico, M. Armanini, P. Chini, G. Cioccolo, F. Provasoli et al., Flame retardants for polypropylene based on lignin, Polymer Degradation and Stability, vol.79, pp.139-145, 2003.

A. De-menezes, D. Pasquini, A. Curvelo, and A. Gandini, Self-reinforced composites obtained by the partial oxypropylation of cellulose fibers. 2. Effect of catalyst on the mechanical and dynamic mechanical properties, Cellulose, vol.16, pp.239-246, 2009.

A. J. De-menezes, D. Pasquini, A. A. Curvelo, and A. Gandini, Novel thermoplastic materials based on the outer-shell oxypropylation of corn starch granules, Biomacromolecules, vol.8, pp.2047-2050, 2007.

W. De-oliveira and W. G. Glasser, Polymer Preprints, Division of Polymer Chemistry, Publ by ACS, pp.655-656, 1990.

D. Oliveira, W. Glasser, and W. G. , Multiphase materials with lignin. 11. Starlike copolymers with caprolactone, Macromolecules, vol.27, pp.5-11, 1994.

E. Delebecq, J. P. Pascault, B. Boutevin, and F. Ganachaud, On the versatility of urethane/urea bonds: Reversibility, blocked isocyanate, and non-isocyanate polyurethane, Chemical Reviews, issue.113, pp.80-118, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00825156

M. Delmas, Vegetal refining and agrichemistry, Chemical Engineering and Technology, vol.31, pp.792-797, 2008.

M. C. Delpech and F. M. Coutinho, Waterborne anionic polyurethanes and poly(urethaneurea)s: influence of the chain extender on mechanical and adhesive properties, Polymer Testing, vol.19, pp.939-952, 2000.

M. Desroches, S. Caillol, V. Lapinte, R. Auvergne, and B. Boutevin, Synthesis of biobased polyols by thiol-ene coupling from vegetable oils, Macromolecules, vol.44, pp.2489-2500, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00587652

B. Doczekalska, M. Bartkowiak, and R. Zakrzewski, Modification of sawdust from pine and beech wood with the succinic anhydride, vol.65, pp.187-191, 2007.

S. Domenek, A. Louaifi, A. Guinault, and S. Baumberger, Potential of Lignins as Antioxidant Additive in Active Biodegradable Packaging Materials, Journal of Polymers and the Environment, vol.2013, pp.1-10
URL : https://hal.archives-ouvertes.fr/hal-00987129

E. Dorrestijn, L. J. Laarhoven, I. W. Arends, and P. Mulder, The occurrence and reactivity of phenoxyl linkages in lignin and low rank coal, Journal of Analytical and Applied Pyrolysis, vol.54, pp.153-192, 2000.

A. Effendi, H. Gerhauser, and A. V. Bridgwater, Production of renewable phenolic resins by thermochemical conversion of biomass: A review, Renewable and Sustainable Energy Reviews, vol.12, pp.2092-2116, 2008.

R. El-hage, N. Brosse, L. Chrusciel, C. Sanchez, P. Sannigrahi et al., Characterization of milled wood lignin and ethanol organosolv lignin from miscanthus, Polymer Degradation and Stability, vol.94, pp.1632-1638, 2009.

N. E. El-mansouri, A. Pizzi, and J. Salvadó, Lignin-based wood panel adhesives without formaldehyde. Holz als Roh-und Werkstoff, vol.65, pp.65-70, 2007.

N. E. El-mansouri and J. Salvadó, Analytical methods for determining functional groups in various technical lignins, Industrial Crops and Products, vol.26, pp.116-124, 2007.

N. E. El-mansouri, Q. Yuan, and F. Huang, Synthesis and characterization of kraft ligninbased epoxy resins, BioResources, issue.6, pp.2492-2503, 2011.

X. Erdocia, A. Toledano, M. A. Corcuera, and J. Labidi, Organosolv black liquor hydrolysis to obtain low molecular weight phenolic compounds, Chemical Engineering Transactions, vol.29, pp.535-540, 2012.

M. Evtiouguina, A. Gandini, C. P. Neto, and N. M. Belgacem, Urethanes and polyurethanes based on oxypropylated cork: 1. Appraisal and reactivity of products, Polymer International, vol.50, pp.1150-1155, 2001.

M. Evtiouguina, A. Margarida-barros, J. J. Cruz-pinto, C. Neto, N. Belgacem et al., The oxypropylation of cork residues: preliminary results, Bioresource Technology, vol.73, pp.187-189, 2000.

S. I. Falkehag, Cellulose Conference, pp.247-257, 1975.

R. Fang, X. S. Cheng, and W. S. Lin, Preparation and application of dimer acid/lignin graft copolymer, BioResources, issue.6, pp.2874-2884, 2011.

O. Faruk and M. Sain, Continuous extrusion foaming of lignin enhanced thermoplastic polyurethane (TPU), Journal of Biobased Materials and Bioenergy, issue.7, pp.309-314, 2013.

S. Fernandes, C. S. Freire, C. P. Neto, and A. Gandini, The bulk oxypropylation of chitin and chitosan and the characterization of the ensuing polyols, Green Chemistry, issue.10, pp.93-97, 2008.
URL : https://hal.archives-ouvertes.fr/hal-01600492

S. Fernando, S. Adhikari, C. Chandrapal, and N. Murali, Biorefineries: Current status, challenges, and future direction, Energy and Fuels, vol.20, pp.1727-1737, 2006.

A. Ferrer, A. Vega, L. Rodríguez, and L. Jiménez, Acetosolv pulping for the fractionation of empty fruit bunches from palm oil industry, Bioresource Technology, vol.132, pp.115-120, 2013.

M. Firdaus and M. A. Meier, Renewable co-polymers derived from vanillin and fatty acid derivatives, European Polymer Journal, 2012.

S. C. Fox and A. G. Mcdonald, Chemical and thermal characterization of three industrial lignins and their corresponding lignin esters, BioResources, vol.5, pp.990-1009, 2010.

K. Freudenberg, Zur Kenntis der Cellulose, Ber. Dtsch. Chem. Ges, pp.767-773, 1921.

K. Freudenberg, Biosynthesis and constitution of lignin, Nature, vol.183, pp.1152-1155, 1959.

K. Freudenberg, Lignin: Its Constitution and Formation from p-Hydroxycinnamyl Alcohols, Science, vol.48, pp.595-600, 1965.

K. Freudenberg and A. C. Nash, Constitution and Biosynthesis of Lignin, 1968.

A. Gandini, Polymers from renewable resources: A challenge for the future of macromolecular materials, Macromolecules, vol.41, pp.9491-9504, 2008.

A. Gandini, The irruption of polymers from renewable resources on the scene of macromolecular science and technology, Green Chemistry, issue.13, pp.1061-1083, 2011.

A. Gandini and M. N. Belgacem, Recent contributions to the preparation of polymers derived from renewable resources, Journal of Polymers and the Environment, issue.10, pp.105-114, 2002.

A. Gandini, M. N. Belgacem, M. Naceur, B. Alessandro, and G. , Monomers, Polymers and Composites from Renewable Resources, pp.1-16, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00511686

A. Gandini, M. N. Belgacem, M. Naceur, B. Alessandro, and G. , Monomers, Polymers and Composites from Renewable Resources, pp.243-271, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00511686

A. Gandini, M. N. Belgacem, M. Naceur, B. Alessandro, and G. , Monomers, Polymers and Composites from Renewable Resources, pp.273-288, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00511686

A. Gandini, A. A. Da-silva-curvelo, D. Pasquini, and A. J. De-menezes, Direct transformation of cellulose fibres into self-reinforced composites by partial oxypropylation, Polymer, vol.46, pp.10611-10613, 2005.

G. Gao, J. I. Dallmeyer, and J. F. Kadla, Synthesis of lignin nanofibers with ionic-responsive shells: Water-expandable lignin-based nanofibrous mats, Biomacromolecules, issue.13, pp.3602-3610, 2012.

L. J. Gibson, The hierarchical structure and mechanics of plant materials, Journal of the Royal Society Interface, vol.9, pp.2749-2766, 2012.

W. G. Glasser, ACS Symposium Series, pp.216-238, 1999.

W. G. Glasser, C. A. Barnett, P. C. Muller, and K. V. Sarkanen, The chemistry of several novel bioconversion lignins, Journal of Agricultural and Food Chemistry, vol.31, pp.921-930, 1983.

W. G. Glasser, C. A. Barnett, T. G. Rials, and V. P. Saraf, Engineering Plastics From Lignin-II Characterization of hydroxyalkyl derivatives, Journal of Applied Polymer Science, vol.29, pp.1815-1830, 1984.

W. G. Glasser, R. A. Northey, and T. P. Schultz, Lignin: Historical, Biological, and Materials Perspectives, 1999.

A. R. Gonçalves and P. Benar, Hydroxymethylation and oxidation of Organosolv lignins and utilization of the products, Bioresource Technology, vol.79, pp.103-111, 2001.

R. J. González-paz, C. Lluch, G. Lligadas, J. C. Ronda, M. Galià et al., A green approach toward oleic-and undecylenic acid-derived polyurethanes, Journal of Polymer Science, Part A: Polymer Chemistry, vol.49, pp.2407-2416, 2011.

D. A. Goring, Thermal softening of lignin, hemicelluloses and cellulose, Pulp Paper Mag. Can, vol.62, pp.517-527, 1963.

R. J. Gosselink, A. Abächerli, H. Semke, R. Malherbe, P. Käuper et al., Analytical protocols for characterisation of sulphur-free lignin, Industrial Crops and Products, vol.19, pp.271-281, 2004.

R. J. Gosselink, E. De-jong, B. Guran, and A. Abächerli, Co-ordination network for lignin-Standardisation, production and applications adapted to market requirements (EUROLIGNIN), Industrial Crops and Products, vol.20, pp.121-129, 2004.

R. J. Gosselink, M. H. Snijder, A. Kranenbarg, E. R. Keijsers, E. De-jong et al., Characterisation and application of NovaFiber lignin, Industrial Crops and Products, vol.20, pp.191-203, 2004.

A. Granata and D. S. Argyropoulos, 2-dioxaphospholane, a reagent for the accurate determination of the uncondensed and condensed phenolic moieties in lignins, Journal of Agricultural and Food Chemistry, vol.2, issue.4, pp.1538-1544, 1995.

A. Guo, D. Demydov, W. Zhang, and Z. S. Petrovic, Polyols and polyurethanes from hydroformylation of soybean oil, Journal of Polymers and the Environment, issue.10, pp.49-52, 2002.

A. Guo, W. Zhang, and Z. Petrovic, Structure-property relationships in polyurethanes derived from soybean oil, Journal of Materials Science, vol.41, pp.4914-4920, 2006.

Z. Guo and A. Gandini, Polyesters from lignin 2. The copolyesterification of kraft lignin and polyethylene glycols with dicarboxylic acid chlorides, European Polymer Journal, vol.27, pp.1177-1180, 1991.

Z. Guo, A. Gandini, and F. Pla, Polyesters from lignin. 1. The reaction of kraft lignin with dicarboxylic acid chlorides, Polymer International, vol.27, pp.17-22, 1992.

H. Nimz and H. , Wood Adhesives. Chemistry and Technology, 1983.

M. Hamaguchi, M. Cardoso, and E. Vakkilainen, Alternative technologies for biofuels production in kraft pulp mills-potential and prospects, Energies, vol.5, pp.2288-2309, 2012.

M. Hamaguchi, J. Kautto, and E. Vakkilainen, Effects of hemicellulose extraction on the kraft pulp mill operation and energy use: Review and case study with lignin removal, 2013.

H. Hatakeyama and T. Hatakeyama, , pp.1-63, 2010.

H. Hatakeyama, A. Hirogaki, H. Matsumura, and T. Hatakeyama, Glass transition temperature of polyurethane foams derived from lignin by controlled reaction rate, Journal of Thermal Analysis and Calorimetry, vol.2013, pp.1-8

H. Hatakeyama, S. Hirose, T. Hatakeyama, and . In-lignin, , pp.205-218, 1989.

H. Hatakeyama, S. Hirose, S. Yano, K. Nakamura, and T. Hatakeyama, Cellulose sources and exploitation: industrial utilization, biotechnology and physico-chemical properties, pp.466-471, 1990.

H. Hatakeyama, J. Nakano, A. Hatano, and N. Migita, Variation of infrared spectra with temperature for lignin and lignin model compounds, vol.52, pp.1724-1728, 1969.

T. Hatakeyama and H. Hatakeyama, Thermal Properties of Green Polymers and Biocomposites, 2005.

T. Hatakeyama, Y. Izuta, S. Hirose, and H. Hatakeyama, Phase transitions of lignin-based polycaprolactones and their polyurethane derivatives, Polymer, vol.43, pp.1177-1182, 2002.

N. Henry, D. Harper, and M. Dadmun, Optimizing noncovalent interactions between lignin and synthetic polymers to develop effective compatibilizers, Macromolecular Chemistry and Physics, vol.213, pp.1196-1205, 2012.

G. Hinrichsen, Polyurethane handbook, vol.770, pp.398-398, 1993.

S. Hirose, T. Hatakeyama, Y. Izuta, and H. Hatakeyama, TG-FTIR studies on lignin-based polycaprolactones, Journal of Thermal Analysis and Calorimetry, vol.70, pp.853-860, 2002.

M. B. Hocking, Vanillin: Synthetic Flavoring from Spent Sulfite Liquor, Journal of Chemical Education, vol.79, pp.1055-1059, 1997.

L. Hu, H. Pan, Y. Zhou, and M. Zhang, Methods to improve lignin's reactivity as a phenol substitute and as replacement for other phenolic compounds: A brief review, BioResources, issue.6, pp.3515-3525, 2011.

T. Hu, A. Gandini, M. Belgacem, Z. Guo, and S. Montanari, Chemical Modification, Properties, and Usage of Lignin, pp.57-80, 2002.

T. Q. Hu, Chemical Modification, Properties, and Usage of Lignin, 2002.

T. Q. Hu, Characterization of Lignocellulosic Materials Wiley-Blackwell, 2008.

J. Huang and L. Zhang, Effects of NCO/OH molar ratio on structure and properties of graftinterpenetrating polymer networks from polyurethane and nitrolignin, Polymer, vol.43, pp.2287-2294, 2002.

S. P. Huo, M. C. Nie, Z. W. Kong, G. M. Wu, and J. Chen, Crosslinking kinetics of the formation of lignin-aminated polyol-based polyurethane foam, Journal of Applied Polymer Science, vol.125, pp.152-157, 2012.

E. R. Inone-kauffmann, ARBOFORM®-A lignin-based thermoplastic, International Sugar Journal, vol.111, pp.10-11, 2009.

M. Ionescu, Chemistry and Technology of Polyols for Polyuerethanes, Rapra Technology, 2005.

M. Ionescu, Chemistry and technology of polyols for polyurethanes, 2005.

G. M. Irvine, The glass transitions of lignin and hemicellulose and their measurement by differential thermal analysis. Tappi, vol.67, pp.118-121, 1984.

T. N. Ismail, H. A. Hassan, S. Hirose, Y. Taguchi, T. Hatakeyama et al., Synthesis and thermal properties of ester-type crosslinked epoxy resins derived from lignosulfonate and glycerol, Polymer International, vol.59, pp.181-186, 2010.

M. Isroi, R. Syamsiah, S. Niklasson, C. Cahyanto, M. N. Lundquist et al., Biological pretreatment of lignocelluloses with white-rot fungi and its applications: A review, BioResources, issue.6, pp.5224-5259, 2011.

E. Jakab, O. Faix, F. Till, and T. Székely, Thermogravimetry/mass spectrometry study of six lignins within the scope of an international round robin test, Journal of Analytical and Applied Pyrolysis, vol.35, pp.167-179, 1995.

E. Jasiukaityte-grojzdek, M. Kunaver, and C. Crestini, Lignin structural changes during liquefaction in acidified ethylene glycol, Journal of Wood Chemistry and Technology, vol.32, pp.342-360, 2012.

I. Javni, Z. S. Petrovi?, A. Guo, and R. Fuller, Thermal stability of polyurethanes based on vegetable oils, Journal of Applied Polymer Science, vol.77, pp.1723-1734, 2000.

Y. Jin, X. Ruan, X. Cheng, and Q. Lü, Liquefaction of lignin by polyethyleneglycol and glycerol, Bioresource Technology, vol.102, pp.3581-3583, 2011.

J. F. Kadla and S. Kubo, Lignin-based polymer blends: analysis of intermolecular interactions in lignin-synthetic polymer blends, Composites Part A: Applied Science and Manufacturing, vol.35, pp.395-400, 2004.

J. F. Kadla, S. Kubo, R. A. Venditti, R. D. Gilbert, A. L. Compere et al., Ligninbased carbon fibers for composite fiber applications, Carbon, vol.40, pp.2913-2920, 2002.

P. Karmalm, T. Hjertberg, A. Jansson, and R. Dahl, Thermal stability of poly(vinyl chloride) with epoxidised soybean oil as primary plasticizer, Polymer Degradation and Stability, vol.94, pp.2275-2281, 2009.

P. Karmalm, T. Hjertberg, A. Jansson, R. Dahl, and K. Ankner, Network formation by epoxidised soybean oil in plastisol poly(vinyl chloride), Polymer Degradation and Stability, vol.94, pp.1986-1990, 2009.

S. S. Kelley, W. G. Glasser, and T. C. Ward, Engineering plastics from lignin. XV. Polyurethane films from chain-extended hydroxypropyl lignin, Journal of Applied Polymer Science, vol.36, pp.759-772, 1988.

L. Kham, Y. Le-bigot, M. Delmas, and G. Avignon, Delignification of wheat straw using a mixture of carboxylic acids and peroxoacids, Industrial Crops and Products, vol.21, pp.9-15, 2005.

F. B. Khambatta, F. Warner, T. Russell, and R. S. Stein, Small-angle x-ray and light scattering studies of the morphology of blends of poly(?-caprolactone) with poly(vinyl chloride), Journal of Polymer Science: Polymer Physics Edition, vol.14, pp.1391-1424, 1976.

T. H. Khoe, F. Otey, E. N. Frankel, and J. C. Cowan, Polyurethane foams from hydroxymethylated fatty diethanolamides, Journal of the American Oil Chemists Society, vol.50, pp.331-333, 1973.

T. H. Khoe, F. H. Otey, and E. N. Frankel, Rigid urethane foams from hydroxymethylated linseed oil and polyol esters, Journal of the American Oil Chemists Society, vol.49, pp.615-618, 1972.

P. P. Kiatsimkul, G. J. Suppes, F. H. Hsieh, Z. Lozada, and Y. C. Tu, Preparation of high hydroxyl equivalent weight polyols from vegetable oils, Industrial Crops and Products, vol.27, pp.257-264, 2008.

Y. S. Kim and J. F. Kadla, Preparation of a thermoresponsive lignin-based biomaterial through atom transfer radical polymerization, Biomacromolecules, vol.11, pp.981-988, 2010.

M. Kobayashi, T. Asano, M. Kajiyama, and B. Tomita, Analysis on residue formation during wood liquefaction with polyhydric alcohol, Journal of Wood Science, vol.50, pp.407-414, 2004.

A. Köckritz and A. Martin, Oxidation of unsaturated fatty acid derivatives and vegetable oils, European Journal of Lipid Science and Technology, vol.110, pp.812-824, 2008.

X. Kong and S. S. Narine, Physical properties of polyurethane plastic sheets produced from polyols from canola oil, Biomacromolecules, vol.8, pp.2203-2209, 2007.

A. L. Korich, K. M. Clarke, D. Wallace, and P. M. Iovine, Chemical modification of a lignin model polymer via arylboronate ester formation under mild reaction conditions, Macromolecules, vol.42, pp.5906-5908, 2009.

A. L. Korich, A. B. Fleming, A. R. Walker, J. Wang, C. Tang et al., Chemical modification of organosolv lignin using boronic acid-containing reagents, Polymer, vol.53, pp.87-93, 2012.

L. Kouisni, Y. Fang, M. Paleologou, B. Ahvazi, J. Hawari et al., Kraft lignin recovery and its use in the preparation of lignin-based phenol formaldehyde resins for plywood, Cellulose Chemistry and Technology, pp.45-515, 2011.

A. Kowalski, A. Duda, and S. Penczek, Kinetics and mechanism of cyclic esters polymerization initiated with tin(II) octoate, 1: Polymerization of ?-caprolactone, Macromolecular Rapid Communications, vol.19, pp.567-572, 1998.

S. Kubo and J. F. Kadla, Hydrogen bonding in lignin: A fourier transform infrared model compound study, Biomacromolecules, issue.6, pp.2815-2821, 2005.

S. Kubo and J. F. Kadla, Kraft lignin/poly(ethylene oxide) blends: Effect of lignin structure on miscibility and hydrogen bonding, Journal of Applied Polymer Science, vol.98, pp.1437-1444, 2005.

T. Kudanga, E. N. Prasetyo, J. Sipilä, G. M. Guebitz, and G. S. Nyanhongo, Reactivity of long chain alkylamines to lignin moieties: Implications on hydrophobicity of lignocellulose materials, Journal of Biotechnology, vol.149, pp.81-87, 2010.

M. Labet and W. Thielemans, Synthesis of polycaprolactone: A review, Chemical Society Reviews, vol.38, pp.3484-3504, 2009.

G. Lammers, E. J. Stamhuis, and A. A. Beenackers, Kinetics of the hydroxypropylation of potato starch in aqueous solution, Industrial & Engineering Chemistry Research, vol.32, pp.835-842, 1993.

S. Laurichesse and L. Avérous, Synthesis, thermal properties, rheological and mechanical behaviors of lignins-grafted-poly(?-caprolactone), Polymer (United Kingdom), issue.54, pp.3882-3890, 2013.

W. J. Lee, K. C. Chang, and I. M. Tseng, Properties of phenol-formaldehyde resins prepared from phenol-liquefied lignin, Journal of Applied Polymer Science, vol.124, pp.4782-4788, 2012.

A. Leonowicz, A. Matuszewska, J. Luterek, D. Ziegenhagen, M. Wojtaå?-wasilewska et al., Biodegradation of Lignin by White Rot Fungi, Fungal Genetics and Biology, vol.27, pp.175-185, 1999.

A. Leonowicz, A. Matuszewska, J. Luterek, D. Ziegenhagen, M. Wojta?-wasilewska et al., Biodegradation of Lignin by White Rot Fungi, Fungal Genetics and Biology, vol.27, pp.175-185, 1999.

J. Li, Y. He, and Y. Inoue, Study on thermal and mechanical properties of biodegradable blends of poly(?-caprolactone) and lignin, Polymer Journal, vol.33, pp.336-343, 2001.

J. Li, Y. He, and Y. Inoue, Thermal and mechanical properties of biodegradable blends of poly(L-lactic acid) and lignin, Polymer International, vol.52, pp.949-955, 2003.

X. Li, Advanced Materials Research, pp.676-681, 2011.

Y. Li, Y. Han, T. Qin, and F. Chu, Preparation of polyurethane foams based on liquefied corn stalk enzymatic hydrolysis lignin, Journal of Biobased Materials and Bioenergy, vol.6, pp.51-58, 2012.

Y. Li, J. Mlynar, and S. Sarkanen, The first 85% kraft lignin-based thermoplastics, Journal of Polymer Science, Part B: Polymer Physics, vol.35, pp.1899-1910, 1997.

Y. Li and A. J. Ragauskas, Ethanol organosolv lignin-based rigid polyurethane foam reinforced with cellulose nanowhiskers, pp.3347-3351, 2012.

Y. Li and A. J. Ragauskas, Kraft Lignin-Based Rigid Polyurethane Foam, Journal of Wood Chemistry and Technology, vol.32, pp.210-224, 2012.

L. Lin, Y. Yao, M. Yoshioka, and N. Shiraishi, Molecular weights and molecular weight distributions of liquefied wood obtained by acid-catalyzed phenolysis, Journal of Applied Polymer Science, vol.64, pp.351-357, 1997.

N. Lin, D. Fan, P. R. Chang, J. Yu, X. Cheng et al., Structure and properties of poly(butylene succinate) filled with lignin: A case of lignosulfonate, Journal of Applied Polymer Science, pp.121-1717, 2011.

S. Y. Lin and C. W. Dence, Methods in Lignin Chemistry, 1992.

J. J. Lindberg, A. Kuusela-tuula, K. Levon, and . In-lignin, , pp.190-204, 1989.

Y. Liu and K. Li, Preparation and characterization of demethylated lignin-polyethylenimine adhesives, Journal of Adhesion, vol.82, pp.593-605, 2006.

G. Lligadas, J. C. Ronda, M. Galià, U. Biermann, and J. O. Metzger, Synthesis and characterization of polyurethanes from epoxidized methyl oleate based polyether polyols as renewable resources, Journal of Polymer Science Part A: Polymer Chemistry, vol.44, pp.634-645, 2006.

G. Lligadas, J. C. Ronda, M. Galiá, and V. Cádiz, Plant oils as platform chemicals for polyurethane synthesis: Current state-of-the-art, Biomacromolecules, vol.11, pp.2825-2835, 2010.

G. Lligadas, J. C. Ronda, M. Galià, and V. Cádiz, Monomers and polymers from plant oils via click chemistry reactions, Journal of Polymer Science, Part A: Polymer Chemistry, vol.51, pp.2111-2124, 2013.

C. Lluch, J. C. Ronda, M. Galià, G. Lligadas, and V. Cádiz, Rapid approach to biobased telechelics through two one-pot thiol-ene click reactions, Biomacromolecules, vol.11, pp.1646-1653, 2010.

J. Lora, B. Mohamed-naceur, and G. Alessandro, Monomers, Polymers and Composites from Renewable Resources, pp.225-241, 2008.

J. H. Lora and W. G. Glasser, Recent industrial applications of lignin: A sustainable alternative to nonrenewable materials, Journal of Polymers and the Environment, issue.10, pp.39-48, 2002.

A. B. Lowe, Thiol-ene "click" reactions and recent applications in polymer and materials synthesis, Polymer Chemistry, issue.1, pp.17-36, 2010.

C. H. Ludwig, B. J. Nist, J. L. Mccarthy, and . X. Lignin, 1 The High Resolution Nuclear Magnetic Resonance Spectroscopy of Protons in Compounds Related to Lignin, Journal of the American Chemical Society, vol.86, pp.1186-1196, 1964.

K. Lundquist, NMR study of lignin. 2 .Interpretation of the 1H NMR spectrum of acetylated birch lignin, Acta Chemica Scandinavica, vol.33, pp.27-30, 1979.

K. Lundquist and K. Stern, Analysis of lignin by 1H NMR spectroscopy, Nordic Pulp & Paper Research, vol.3, pp.210-213, 1989.

N. D. Luong, N. T. Binh, L. D. Duong, D. O. Kim, D. S. Kim et al., An eco-friendly and efficient route of lignin extraction from black liquor and a lignin-based copolyester synthesis, Polymer Bulletin, vol.68, pp.879-890, 2012.

C. K. Lyon, V. H. Garrett, and E. N. Frankel, Rigid urethane foams from hydroxymethylated castor oil, safflower oil, oleic safflower oil, and polyol esters of castor acids, Journal of the American Oil Chemists Society, vol.51, pp.331-334, 1974.

Q. Ma, X. Liu, R. Zhang, J. Zhu, and Y. Jiang, Synthesis and properties of full bio-based thermosetting resins from rosin acid and soybean oil: the role of rosin acid derivatives, Green Chemistry, issue.15, pp.1300-1310, 2013.

S. Malherbe and T. E. Cloete, Lignocellulose biodegradation: Fundamentals and applications, Reviews in Environmental Science and Biotechnology, issue.1, pp.105-114, 2002.

H. R. Mansouri, P. Navarrete, A. Pizzi, S. Tapin-lingua, B. Benjelloun-mlayah et al., Synthetic-resin-free wood panel adhesives from mixed low molecular mass lignin and tannin, European Journal of Wood and Wood Products, pp.1-9, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00594484

N. E. Mansouri, Q. Yuan, and F. Huang, Study of chemical modification of alkaline lignin by the glyoxalation reaction, BioResources, issue.6, pp.4523-4536, 2011.

N. E. Mansouri, A. Pizzi, and J. Salvado, Lignin-based polycondensation resins for wood adhesives, Journal of Applied Polymer Science, vol.103, pp.1690-1699, 2007.
URL : https://hal.archives-ouvertes.fr/hal-01194987

N. E. Mansouri and J. Salvadó, Structural characterization of technical lignins for the production of adhesives: Application to lignosulfonate, kraft, soda-anthraquinone, organosolv and ethanol process lignins, Industrial Crops and Products, vol.24, pp.8-16, 2006.

S. P. Maradur, C. H. Kim, S. Y. Kim, B. H. Kim, W. C. Kim et al., Preparation of carbon fibers from a lignin copolymer with polyacrylonitrile, Synthetic Metals, vol.162, pp.453-459, 2012.

J. Marton, Lignin Structure and Reactions, 1966.

J. Marton and T. Marton, Molecular weight of kraft lignin, vol.47, pp.471-476, 1964.

Y. Matsushita and S. Yasuda, Reactivity of a condensed-type lignin model compound in the Mannich reaction and preparation of cationic surfactant from sulfuric acid lignin, Journal of Wood Science, vol.49, pp.166-171, 2003.

K. Matyjaszewski, Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives, Macromolecules, vol.45, pp.4015-4039, 2012.
DOI : 10.1021/ma3001719

J. L. Mccarthy and A. Islam, ACS Symposium Series, pp.2-66, 1999.

P. Mckendry, Energy production from biomass, Conversion technologies, vol.83, pp.47-54, 2002.

M. A. Meier, J. O. Metzger, and U. S. Schubert, Plant oil renewable resources as green alternatives in polymer science, Chemical Society Reviews, vol.36, pp.1788-1802, 2007.
DOI : 10.1039/b703294c

L. Mialon, A. G. Pemba, and S. A. Miller, Biorenewable polyethylene terephthalate mimics derived from lignin and acetic acid, Green Chemistry, vol.12, pp.1704-1706, 2010.
DOI : 10.1039/c0gc00150c

L. Mialon, R. Vanderhenst, A. G. Pemba, and S. A. Miller, Polyalkylenehydroxybenzoates (PAHBs): Biorenewable aromatic/aliphatic polyesters from lignin, Macromolecular Rapid Communications, pp.32-1386, 2011.
DOI : 10.1002/marc.201100242

X. Miao, C. Fischmeister, P. H. Dixneuf, C. Bruneau, J. L. Dubois et al., Polyamide precursors from renewable 10-undecenenitrile and methyl acrylate via olefin cross-metathesis, Green Chemistry, vol.14, pp.2179-2183, 2012.
DOI : 10.1039/c2gc35648a

URL : https://hal.archives-ouvertes.fr/hal-00864808

D. Mohan, C. U. Pittman, and P. H. Steele, Pyrolysis of wood/biomass for bio-oil: A critical review, Energy and Fuels, vol.20, pp.848-889, 2006.

A. S. More, B. Gadenne, C. Alfos, and H. Cramail, AB type polyaddition route to thermoplastic polyurethanes from fatty acid derivatives, Polymer Chemistry, vol.3, pp.1594-1605, 2012.
DOI : 10.1039/c2py20123b

URL : https://hal.archives-ouvertes.fr/hal-00818395

P. Mousavioun and W. O. Doherty, Chemical and thermal properties of fractionated bagasse soda lignin, Industrial Crops and Products, pp.52-58, 2010.

Y. B. Mu, C. P. Wang, L. W. Zhao, and F. X. Chu, Study on Composite Adhesive of Hydroxymethylated Lignosulfonate/Phenol-formaldehyde Resin with Low Free Formaldehyde, Chemistry and Industry of Forest Products, vol.29, pp.38-42, 2009.

B. O. Myrvold, The polyelectrolyte behavior of randomly branched lignosulfonates, Tappi Journal, issue.6, pp.10-15, 2007.

B. O. Myrvold, A new model for the structure of lignosulphonates. Part 1. Behaviour in dilute solutions, Industrial Crops and Products, vol.27, pp.214-219, 2008.

A. M. Nada, M. El-sakhawy, and S. M. Kamel, Infra-red spectroscopic study of lignins, Polymer Degradation and Stability, vol.60, pp.247-251, 1998.
DOI : 10.1016/s0141-3910(97)00072-4

H. Nadji, C. Bruzzese, M. N. Belgacem, A. Benaboura, and A. Gandini, Oxypropylation of lignins and preparation of rigid polyurethane foams from the ensuing polyols, Macromolecular Materials and Engineering, vol.290, pp.1009-1016, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00196909

H. Nadji, C. Bruzzèse, M. N. Belgacem, A. Benaboura, and A. Gandini, Oxypropylation of lignins and preparation of rigid polyurethane foams from the ensuing polyols, Macromolecular Materials and Engineering, vol.290, pp.1009-1016, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00196909

M. Nahmany and A. Melman, Chemoselectivity in reactions of esterification, Organic and Biomolecular Chemistry, issue.2, pp.1563-1572, 2004.

M. Nassar and G. Mackay, Mechanism of Thermal Decomposition of Lignin, Wood and Fiber Science, vol.16, pp.441-453, 1984.

P. Navarrete, A. Pizzi, H. Pasch, and L. Delmotte, Study on lignin-glyoxal reaction by MALDI-TOF and CP-MAS 13C-NMR, Journal of Adhesion Science and Technology, vol.26, pp.1069-1082, 2012.

T. Nguyen, E. Zavarin, and E. M. , Thermal Analysis of Lignocellulosic Materials. Part I. Unmodified Materials. Journal of Macromolecular Science, Part C, vol.20, pp.1-65, 1981.

T. Nguyen, E. Zavarin, and E. M. Barrall, Thermal Analysis of Lignocellulosic Materials. Part II. Modified Materials. Journal of Macromolecular Science, Part C, vol.21, pp.1-60, 1981.

H. Niemi, J. Lahti, H. Hatakka, S. Kärki, S. Rovio et al., Fractionation of organic and inorganic compounds from black liquor by combining membrane separation and crystallization, Chemical Engineering and Technology, vol.34, pp.593-598, 2011.

H. Nimz, Beech Lignin-Proposal of a Constitutional Scheme, Angewandte Chemie International Edition in English, issue.13, pp.313-321, 1974.

I. Norberg, Y. Nordström, R. Drougge, G. Gellerstedt, and E. Sjöholm, A new method for stabilizing softwood kraft lignin fibers for carbon fiber production, Journal of Applied Polymer Science, vol.128, pp.3824-3830, 2013.

Y. Nordström, I. Norberg, E. Sjöholm, and R. Drougge, A new softening agent for melt spinning of softwood kraft lignin, Journal of Applied Polymer Science, issue.129, pp.1274-1279, 2013.

D. J. Nowakowski, A. V. Bridgwater, D. C. Elliott, D. Meier, and P. Wild, Lignin fast pyrolysis: Results from an international collaboration, Journal of Analytical and Applied Pyrolysis, vol.88, pp.53-72, 2010.

F. Öhman, H. Theliander, P. Tomani, P. Axegard, and . Lignoboost-ab, , 2010.

F. Öhman, H. Theliander, P. Tomani, P. Axegard, and A. B. Lignoboost, , vol.794, p.363, 2011.

F. E. Okieimen, Studies in the utilisation of epoxidised vegetable oils as thermal stabiliser for polyvinyl chloride, Industrial Crops and Products, vol.15, pp.71-75, 2002.

D. V. Palaskar, A. Boyer, E. Cloutet, J. F. Le-meins, B. Gadenne et al., Original diols from sunflower and ricin oils: Synthesis, characterization, and use as polyurethane building blocks, Journal of Polymer Science, Part A: Polymer Chemistry, vol.50, pp.1766-1782, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00747662

G. R. Palmese and R. L. Mccullough, Effect of epoxy-amine stoichiometry on cured resin material properties, Journal of Applied Polymer Science, vol.46, pp.1863-1873, 1992.

X. Pan and J. N. Saddler, Effect of replacing polyol by organosolv and kraft lignin on the property and structure of rigid polyurethane foam, Biotechnology for Biofuels, p.12, 2013.

M. P. Pandey and C. S. Kim, Lignin Depolymerization and Conversion: A Review of Thermochemical Methods, Chemical Engineering & Technology, vol.34, pp.29-41, 2010.

C. Pavier and A. Gandini, Oxypropylation of sugar beet pulp. 1. Optimisation of the reaction, Industrial Crops and Products, vol.12, pp.1-8, 2000.

C. Pavier and A. Gandini, Oxypropylation of sugar beet pulp. 2. Separation of the grafted pulp from the propylene oxide homopolymer, Carbohydrate Polymers, vol.42, pp.13-17, 2000.

C. Pavier and A. Gandini, Urethanes and polyurethanes from oxypropylated sugar beet pulp. I. Kinetic study in solution, European Polymer Journal, vol.36, pp.1653-1658, 2000.

L. H. Peebles, Sequence Length Distribution in Segmented Block Copolymers. Macromolecules, vol.7, pp.872-882, 1974.

L. H. Peebles, Hard Block Length Distribution in Segmented Block Copolymers, Macromolecules, issue.9, pp.58-61, 1976.

O. Persenaire, M. Alexandre, P. Degée, and P. Dubois, Mechanisms and Kinetics of Thermal Degradation of Poly(?-caprolactone), Biomacromolecules, issue.2, pp.288-294, 2001.

Z. S. Petrovic, Polyurethanes from vegetable oils, Polymer Reviews, pp.48-109, 2008.

Z. S. Petrovi?, A. Guo, and W. Zhang, Structure and properties of polyurethanes based on halogenated and nonhalogenated soy-polyols, Journal of Polymer Science Part A: Polymer Chemistry, vol.38, pp.4062-4069, 2000.

Z. S. Petrovi?, D. Hong, I. Javni, N. Erina, F. Zhang et al., Phase structure in segmented polyurethanes having fatty acid-based soft segments, Polymer, vol.54, pp.372-380, 2013.

Z. S. Petrovi?, L. Yang, A. Zlatani?, W. Zhang, and I. Javni, Network structure and properties of polyurethanes from soybean oil, Journal of Applied Polymer Science, vol.105, pp.2717-2727, 2007.

Z. S. Petrovi?, W. Zhang, and I. Javni, Structure and Properties of Polyurethanes Prepared from Triglyceride Polyols by Ozonolysis, Biomacromolecules, issue.6, pp.713-719, 2005.

P. Roger and C. , The Chemistry of Solid Wood, pp.57-126, 1984.

D. P. Pfister, Y. Xia, and R. C. Larock, Recent advances in vegetable oil-based polyurethanes, ChemSusChem, vol.4, pp.703-717, 2011.

M. Phillips, The chemistry of lignin, Chemical Reviews, vol.14, pp.103-170, 1934.

C. Pouteau, S. Baumberger, B. Cathala, and P. Dole, Lignin-polymer blends: Evaluation of compatibility by image analysis, Comptes Rendus-Biologies, vol.327, pp.935-943, 2004.

C. Pouteau, P. Dole, B. Cathala, L. Averous, and N. Boquillon, Antioxidant properties of lignin in polypropylene, Polymer Degradation and Stability, vol.81, pp.9-18, 2003.

C. Prisacariu, Polyurethane Elastomers. From Morphology to Mechanical Aspects, pp.23-60, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00930142

C. Prisacariu and E. Scortanu, Morphology of polyurethanes based on the chain extender ethylene glycol and aromatic flexible diisocyanates, as revealed by scanning electron microscopy, Revue Roumaine de Chimie, vol.53, pp.821-825, 2008.

E. K. Pye, The alcell process a proven alternative to kraft pulping, Tappi Journal, p.74, 1991.

W. Qin and J. F. Kadla, Carbon fibers based on pyrolytic lignin, Journal of Applied Polymer Science, vol.126, pp.203-212, 2012.

Q. Lam, H. Le-bigot, Y. Delmas, M. Avignon, and G. , A new procedure for the destructuring of vegetable matter at atmospheric pressure by a catalyst/solvent system of formic acid/acetic acid. Applied to the pulping of triticale straw, Industrial Crops and Products, vol.14, pp.139-144, 2001.

J. Ralph, K. Lundquist, G. Brunow, F. Lu, H. Kim et al., Lignins: Natural polymers from oxidative coupling of 4-hydroxyphenyl-propanoids, Phytochemistry Reviews, vol.3, pp.29-60, 2004.

N. Ramani, D. Graiver, K. W. Farminer, P. T. Tran, and T. Tran, , pp.603-604, 2010.

E. C. Ramires, J. D. Megiatto, C. Gardrat, A. Castellan, and E. Frollini, Biobased composites from glyoxal-phenolic resins and sisal fibers, Bioresource Technology, vol.101, pp.1998-2006, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00679326

T. G. Rials and W. G. Glasser, Engineering plastics from lignin. XIII: Effect of lignin structure on polyurethane network formation, Holzforschung, vol.40, pp.353-360, 1986.

A. Rybak, P. A. Fokou, and M. A. Meier, Metathesis as a versatile tool in oleochemistry, European Journal of Lipid Science and Technology, vol.110, pp.797-804, 2008.

H. Sadeghifar, C. Cui, and D. S. Argyropoulos, Toward Thermoplastic Lignin Polymers; Part I: Selective Masking of Phenolic Hydroxyl Groups in Kraft Lignins via Methylation & Oxypropylation Chemistries, Industrial & Engineering Chemistry Research, 2012.

R. R. Sailaja and M. V. Deepthi, Mechanical and thermal properties of compatibilized composites of polyethylene and esterified lignin, Materials and Design, pp.4369-4379, 2010.

T. Saito, R. H. Brown, M. A. Hunt, D. L. Pickel, J. M. Pickel et al., Turning renewable resources into value-added polymer: Development of lignin-based thermoplastic, Green Chemistry, vol.14, pp.3295-3303, 2012.
DOI : 10.1039/c2gc35933b

J. Samuelsson, M. Jonsson, T. Brinck, and M. Johansson, Thiol-ene coupling reaction of fatty acid monomers, Journal of Polymer Science Part A: Polymer Chemistry, vol.42, pp.6346-6352, 2004.
DOI : 10.1002/pola.20468

P. Sannigrahi, A. J. Ragauskas, and S. J. Miller, Lignin Structural Modifications Resulting from Ethanol Organosolv Treatment of Loblolly Pine, Energy & Fuels, vol.24, pp.683-689, 2009.

K. V. Sarkanen, H. L. Hergert, C. H. Sarkanen, and . Ludwig, Lignins: Occurence, formation structure and reactionseds, pp.43-94, 1971.

K. V. Sarkanen and C. H. Ludwig, Lignins: Occurrence, formation, structure and reactions, 1971.

S. Sarkanen, D. C. Teller, E. Abramowski, and J. L. Mccarthy, Lignin. 19. Kraft lignin component conformation and associated complex configuration in aqueous alkaline solution, Macromolecules, vol.15, pp.1098-1104, 1982.

S. Sarkanen, D. C. Teller, J. Hall, and J. L. Mccarthy, Lignin. 18. Associative effects among organosolv lignin components. Macromolecules, vol.14, pp.426-434, 1981.

S. Sarkar and B. Adhikari, Synthesis and characterization of lignin-HTPB copolyurethane, European Polymer Journal, vol.37, pp.1391-1401, 2001.
DOI : 10.1016/s0014-3057(00)00264-0

S. Sarkar and B. Adhikari, Thermal stability of lignin-hydroxy-terminated polybutadiene copolyurethanes, Polymer Degradation and Stability, vol.73, pp.169-175, 2001.
DOI : 10.1016/s0141-3910(01)00084-2

J. H. Saunders, The Reactions of Isocyanates and Isocyanate Derivatives at Elevated Temperatures. Rubber Chemistry and Technology, vol.32, pp.337-345, 1959.

J. H. Saunders and K. C. Frisch, Polyurethanes: chemistry and technology, Part I, High Polymers, 1962.

M. H. Schneider, Furfuryl alcohol lignin adhesive, Industrial Bioprocessing, p.10, 2004.

F. Schulze, Beitrage zur Kenntniss des Lignins, Chem. Zentr, vol.1857, pp.321-325

N. Shukry, S. M. Fadel, F. A. Agblevor, and S. F. El-kalyoubi, Some physical properties of acetosolv lignins from bagasse, Journal of Applied Polymer Science, vol.109, pp.434-444, 2008.

E. A. Silva, M. Zabkova, J. D. Araújo, C. A. Cateto, M. F. Barreiro et al., An integrated process to produce vanillin and lignin-based polyurethanes from Kraft lignin, Chemical Engineering Research and Design, vol.87, pp.1276-1292, 2009.
DOI : 10.1016/j.cherd.2009.05.008

G. Sivasankarapillai and A. G. Mcdonald, Synthesis and properties of lignin-highly branched poly (ester-amine) polymeric systems, Biomass and Bioenergy, vol.35, pp.919-931, 2012.
DOI : 10.1016/j.biombioe.2010.11.002

G. Sivasankarapillai, A. G. Mcdonald, and H. Li, Lignin valorization by forming toughened lignin-co-polymers: Development of hyperbranched prepolymers for cross-linking, Biomass and Bioenergy, vol.47, pp.99-108, 2012.

N. Smolarski, . Frost-&-sullivan, and . Paris, , 2012.

P. Song, Z. Cao, Q. Meng, S. Fu, Z. Fang et al., Effect of lignin incorporation and reactive compatibilization on the morphological, rheological, and mechanical properties of ABS resin, Journal of Macromolecular Science, vol.51, pp.720-735, 2012.

I. Stanzione, J. F. Sadler, J. M. , L. Scala, J. J. Reno et al., Vanillin-based resin for use in composite applications, Green Chemistry, vol.14, pp.2346-2352, 2012.

G. Sun, H. Sun, Y. Liu, B. Zhao, N. Zhu et al., Comparative study on the curing kinetics and mechanism of a lignin-based-epoxy/anhydride resin system, Polymer, vol.48, pp.330-337, 2007.

P. K. Swain, L. M. Das, and S. N. Naik, Biomass to liquid: A prospective challenge to research and development in 21st century, Renewable and Sustainable Energy Reviews, vol.15, pp.4917-4933, 2011.

M. Szycher, Szycher's Handbook of Polyurethanes, 2012.

V. E. Tarabanko, Y. V. Chelbina, A. V. Kudryashev, and N. V. Tarabanko, Separation of Vanillin and Syringaldehyde Produced from Lignins, Separation Science and Technology, vol.48, pp.127-132, 2013.

V. E. Tarabanko, N. V. Koropatchinskaya, A. V. Kudryashev, and B. N. Kuznetsov, Influence of lignin origin on the efficiency of the catalytic oxidation of lignin into vanillin and syringaldehyde, Russian Chemical Bulletin, vol.44, pp.367-371, 1995.

G. Taylor, Biofuels and the biorefinery concept, Energy Policy, vol.36, pp.4406-4409, 2008.

Y. Teramoto, S. H. Lee, and T. Endo, Phase structure and mechanical property of blends of Organosolv lignin alkyl esters with poly(?-caprolactone), Polymer Journal, vol.41, pp.219-227, 2009.

T. That, Cardanol-lignin-based polyurethanes, Polymer International, vol.41, pp.13-16, 1996.

S. Thiebaud and M. E. Borredon, Solvent-free wood esterification with fatty acid chlorides, Bioresource Technology, vol.52, pp.169-173, 1995.

S. Thiebaud, M. E. Borredon, G. Baziard, and F. Senocq, Properties of wood esterified by fatty-acid chlorides, Bioresource Technology, vol.59, pp.103-107, 1997.

W. Thielemans and R. P. Wool, Lignin esters for use in unsaturated thermosets: Lignin modification and solubility modeling, Biomacromolecules, issue.6, pp.1895-1905, 2005.

R. W. Thring, P. Ni, and S. M. Aharoni, Molecular weight effects of the soft segment on the ultimate properties of lignin-derived polyurethanes, International Journal of Polymeric Materials, vol.53, pp.507-524, 2004.

R. W. Thring, M. N. Vanderlaan, and S. L. Griffin, Polyurethanes from Alcell® lignin, Biomass and Bioenergy, vol.13, pp.125-132, 1997.

P. Tomani, The lignoboost process, Cellulose Chemistry and Technology, vol.44, pp.53-58, 2010.

P. Tomani, P. Axegård, N. Berglin, A. Lovell, and D. Nordgren, Integration of lignin removal into a kraft pulp mill and use of lignin as a biofuel, Cellulose Chemistry and Technology, pp.45-533, 2011.

P. Tomani, N. Berglin, and P. Axegård, TAPPI Press-TAPPI Engineering, Pulping and Environmental Conference 2009-Innovations in Energy, Fiber and Compliance, pp.2347-2393, 2009.

P. Truter, A. Pizzi, and H. Vermaas, Cold-setting wood adhesives from kraft hardwood lignin, Journal of Applied Polymer Science, vol.51, pp.1319-1322, 1994.

O. Türünç and M. A. Meier, Fatty acid derived monomers and related polymers via thiolene (Click) additions, Macromolecular Rapid Communications, pp.1822-1826, 2010.

A. Van-der-drift and H. Boerrigter, Synthesis gas from biomass for fuels and chemicals, 2006.

M. Van-der-steen and C. V. Stevens, Undecylenic Acid: A Valuable and Physiologically Active Renewable Building Block from Castor Oil, ChemSusChem, issue.2, pp.692-713, 2009.

M. N. Vanderlaan and R. W. Thring, Polyurethanes from Alcell® lignin fractions obtained by sequential solvent extraction, Biomass and Bioenergy, vol.14, pp.525-531, 1998.

G. Vázquez, G. Antorrena, J. González, and S. Freire, The influence of pulping conditions on the structure of acetosolv eucalyptus lignins, Journal of Wood Chemistry and Technology, vol.17, pp.147-162, 1997.

S. Velankar and S. L. Cooper, Microphase separation and rheological properties of polyurethane melts. 1. Effect of block length, Macromolecules, vol.31, pp.9181-9192, 1998.

S. Velankar and S. L. Cooper, Microphase separation and rheological properties of polyurethane melts. 2. Effect of block incompatibility on the microstructure, Macromolecules, vol.33, pp.382-394, 2000.

S. Velankar and S. L. Cooper, Microphase separation and rheological properties of polyurethane melts. 3. Effect of block incompatibility on the viscoelastic properties, Macromolecules, vol.33, pp.395-403, 2000.

M. Vert, Y. Doi, K. H. Hellwich, M. Hess, P. Hodge et al., Terminology for biorelated polymers and applications, Pure and Applied Chemistry, vol.84, pp.377-410, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00720283

J. C. Villar, A. Caperos, and F. García-ochoa, Oxidation of hardwood kraft-lignin to phenolic derivatives with oxygen as oxidant, Wood Science and Technology, vol.35, pp.245-255, 2001.

M. P. Vinardell, V. Ugartondo, and M. Mitjans, Potential applications of antioxidant lignins from different sources, Industrial Crops and Products, vol.27, pp.220-223, 2008.

A. Vishtal and A. Kraslawski, Challenges in industrial applications of technical lignins, BioResources, issue.6, pp.3547-3568, 2011.

J. Wang, K. Yao, A. L. Korich, S. Li, S. Ma et al., Combining renewable gum rosin and lignin: Towards hydrophobic polymer composites by controlled polymerization, Journal of Polymer Science, Part A: Polymer Chemistry, pp.49-3728, 2011.

C. D. Warren, Low-cost carbon fiber-Will the market develop? Composites Technology, vol.12, pp.7-9, 2006.

E. Windeisen, G. ;. Wegener, and M. L. Martin, Polymer Science: A Comprehensive Reference, pp.255-265, 2012.

D. W. Wong, Structure and action mechanism of ligninolytic enzymes, Applied Biochemistry and Biotechnology, vol.157, pp.174-209, 2009.

K. Wörmeyer, T. Ingram, B. Saake, G. Brunner, and I. Smirnova, Comparison of different pretreatment methods for lignocellulosic materials. Part II: Influence of pretreatment on the properties of rye straw lignin, Bioresource Technology, vol.102, pp.4157-4164, 2011.

L. C. Wu and W. G. Glasser, Engineering plastics from lignin. I. Synthesis of hydroxypropyl lignin, Journal of Applied Polymer Science, vol.29, pp.1111-1123, 1984.

L. C. Wu and W. G. Glasser, Engineering Plastics From Lignin. I. Synthesis of hydroxypropyl lignin, Journal of Applied Polymer Science, vol.29, pp.1111-1123, 1984.

B. Xiao, X. F. Sun, and R. Sun, Chemical modification of lignins with succinic anhydride in aqueous systems, Polymer Degradation and Stability, vol.71, pp.223-231, 2001.
DOI : 10.1016/s0141-3910(00)00133-6

Y. Xu, Z. Petrovic, S. Das, and G. L. Wilkes, Morphology and properties of thermoplastic polyurethanes with dangling chains in ricinoleate-based soft segments, Polymer, vol.49, pp.4248-4258, 2008.

W. P. Yang, C. W. Macosko, and S. T. Wellinghoff, Thermal degradation of urethanes based on 4,4'-diphenylmethane diisocyanate and 1,4-butanediol (MDI/BDO), Polymer, vol.27, pp.1235-1240, 1986.
DOI : 10.1016/0032-3861(86)90012-1

Q. Yin, W. Yang, C. Sun, and M. Di, Preparation and properties of lignin-epoxy resin composite, BioResources, vol.7, pp.5737-5748, 2012.
DOI : 10.15376/biores.7.4.5737-5748

URL : http://ojs.cnr.ncsu.edu/index.php/BioRes/article/download/BioRes_07_4_5737_Yin_Lignin_Epoxy_Resin_Composite/1823

H. Yoshida, R. Mörck, P. Kringstad-knut, and H. Hatakeyama, Fractionation of Kraft Lignin by Successive Extraction with Organic Solvents. II. Thermal Properties of Kraft Lignin Fractions, Holzforschung, p.171, 1987.

L. Yu, K. Dean, and L. Li, Polymer blends and composites from renewable resources, Progress in Polymer Science, pp.31-576, 2006.

X. Yue, F. Chen, and X. Zhou, Improved interfacial bonding of PVC/Wood-flour composites by lignin amine modification, BioResources, issue.6, pp.2022-2034, 2011.

J. Zakzeski, P. C. Bruijnincx, A. L. Jongerius, and B. M. Weckhuysen, The catalytic valorization of lignin for the production of renewable chemicals, Chem. Rev, vol.110, pp.3552-3599, 2010.

J. Zakzeski and B. Weckhuysen, Lignin solubilization and aqueous phase reforming for the production of aromatic chemicals and hydrogen, ChemSusChem, vol.4, pp.369-378, 2011.

H. Zhang, H. Pang, J. Shi, T. Fu, and B. Liao, Investigation of liquefied wood residues based on cellulose, hemicellulose, and lignin, Journal of Applied Polymer Science, vol.123, pp.850-856, 2011.
DOI : 10.1002/app.34521

L. Zhang and J. Huang, Effects of hard-segment compositions on properties of polyurethanenitrolignin films, Journal of Applied Polymer Science, vol.81, pp.3251-3259, 2001.

L. Zhang and J. Huang, Effects of nitrolignin on mechanical properties of polyurethanenitrolignin films, Journal of Applied Polymer Science, vol.80, pp.1213-1219, 2001.

W. Zhang, Y. Ma, C. Wang, S. Li, M. Zhang et al., Preparation and properties of lignin-phenol-formaldehyde resins based on different biorefinery residues of agricultural biomass, Industrial Crops and Products, issue.43, pp.326-333, 2013.

A. Zlatani?, Z. S. Petrovi?, and K. Du?ek, Structure and Properties of Triolein-Based Polyurethane Networks, Biomacromolecules, vol.3, pp.1048-1056, 2002.