G. Doyon, J. Arch, D. Twede, B. Drasner, A. M. Baylis et al., The Wiley Encyclopedia of Packaging Technology, p.71, 2010.

S. Cros, Techniques de l'ingénieur-Propriétés générales des plastiques, p.152, 2007.

J. L. Keddie, Materials Science and Engineering: R: Reports, vol.21, p.101, 1997.

E. Kientz, Y. Holl, and C. Surf, , p.255, 1993.

N. Agarwal and R. J. Farris, J. Appl. Polym. Sci, vol.72, p.1407, 1999.

J. Feng and M. A. Winnik, Macromolecules, vol.30, p.4324, 1997.

L. N. Butler, C. M. Fellows, and R. G. Gilbert, J. Appl. Polym. Sci, p.1813, 2004.

B. J. Roulstone, M. C. Wilkinson, and J. Hearn, Polym. Int, p.43, 1992.

A. Tzitzinou, J. L. Keddie, J. M. Geurts, A. C. Peters, and R. Satguru, Macromolecules, vol.33, p.2695, 2000.

G. Riess and C. Labbe, Macromol. Rapid Commun, vol.25, p.401, 2004.

J. M. Asua and H. A. Schoonbrood, Acta Polymerica, vol.49, p.671, 1998.

A. Guyot and K. Tauer, Reactive surfactants in emulsion polymerization, Polymer Synthesis, p.43, 1994.

A. Guyot, K. Tauer, J. M. Asua, S. Van-es, C. Gauthier et al., Acta Polymerica, vol.50, p.57, 1999.

M. J. Unzué, H. A. Schoonbrood, J. M. Asua, A. M. Goñi, D. C. Sherrington et al.,

K. Goebel, M. Tauer, K. Sjöberg, and . Holmberg, J. Appl. Polym. Sci, vol.66, p.1803, 1997.

B. Charleux, G. Delaittre, J. Rieger, and F. D'agosto, Macromolecules, vol.45, p.6753, 2012.

P. W. Sherwood, Industrial & Engineering Chemistry, vol.54, p.29, 1962.

R. A. Wessling, D. S. Gibbs, B. E. Obi, D. E. Beyer, P. T. Delassus et al., Poly(vinylidene chloride), Kirk-Othmer Encyclopedia-Chemical Technology, p.1167, 2007.

A. Konishi, Bull. Chem. Soc. Jpn, vol.35, p.193, 1962.

A. Konishi, Bull. Chem. Soc. Jpn, vol.35, 0197.

G. Talamini and E. Peggion, Vinyl polymerization, vol.1, p.331, 1967.

Y. Li, J. Appl. Polym. Sci, p.2397, 1996.

F. M. Lewis, F. R. Mayo, and W. F. Hulse, J. Am. Chem. Soc, vol.67, p.1701, 1945.

F. R. Mayo, F. M. Lewis, and C. Walling, J. Am. Chem. Soc, vol.70, p.1529, 1948.

S. Collins, K. Yoda, N. Anazawa, and C. Birkinshaw, Polym. Degrad. Stab, vol.66, p.87, 1999.

Z. Janovi?, C. S. Marvel, M. J. Diamond, D. J. Kertesz, and G. Fuller, J. Polym. Sci., Part A, vol.9, issue.1, p.2639, 1971.

D. Feldman, J. Polym. Environ, vol.9, p.49, 2001.

J. Bicerano, A. F. Burmester, P. T. Delassus, and R. A. Wessling, Transport of Penetrant Molecules Through Copolymers of Vinylidene Chloride and Vinyl Chloride, Barrier Polymers and Structures, p.126, 1990.

W. M. Lee, Polym. Eng. Sci, vol.20, p.65, 1980.

R. W. Eykamp, A. M. Schneider, and E. W. Merrill, J. Polym. Sci., Part A, issue.2, 1025.

S. W. Lasoski, J. Appl. Polym. Sci, 1960.

Y. Li and Z. Weng, Z. Pan, Chin. J. Polym. Sci, vol.15, p.319, 1997.

G. Doyon, J. Arch, D. Twede, B. Drasner, A. M. Baylis et al., The Wiley Encyclopedia of Packaging Technology, p.71, 2010.

S. Cros, Techniques de l'ingénieur-Propriétés générales des plastiques, p.152, 2007.

C. Fringant, Techniques de l'ingénieur-Fabrication des grands produits industriels en chimie et pétrochimie, p.319, 2004.

J. Qiu, B. Charleux, and K. Matyjaszewski, Progress in Polymer Science, vol.26, p.2083, 2001.

J. Daniel and C. Pichot, Les latex synthétiques-Elaboration, Propriétés, Applications, 2006.

J. L. Keddie, Materials Science and Engineering: R: Reports, vol.21, p.101, 1997.

P. A. Lovell and M. S. El-aasser, Emulsion Polymerization and Emulsion Polymers, 1997.

A. M. Van-herk and R. G. Gilbert, Emulsion Polymerisation, Chemistry and Technology of Emulsion Polymerisation, p.43, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00801589

R. G. Gilbert, Emulsion polymerization: a mechanistic approach, 1995.

W. D. Harkins, J. Am. Chem. Soc, p.1428, 1947.

W. D. Harkins, J. Polym. Sci, vol.5, p.217, 1950.

Y. Chen and S. Sajjadi, Polymer, vol.50, p.357, 2009.

P. T. Delassus and D. D. Schmidt, J. Chem. Eng. Data, vol.26, p.274, 1981.

W. V. Smith and R. H. Ewart, J. Chem. Phys, p.592, 1948.

W. J. Priest, J. Phys. Chem, vol.56, p.1077, 1952.

R. M. Fitch, British Polymer Journal, vol.5, p.467, 1973.

F. K. Hansen and J. Ugelstad, Particle formation mechanisms, Emulsion Polymerization, I. Piirma, p.51, 1982.

N. Kohut-svelko, R. Pirri, J. M. Asua, and J. R. Leiza, J. Polym. Sci., Part A: Polym. Chem, p.2917, 2009.

W. Bai, L. Zhang, R. Bai, and G. Zhang, Macromol. Rapid Commun, vol.29, 2008.

M. Chainey, M. C. Wilkinson, and J. Hearn, J. Polym. Sci.: Polym. Chem. Ed, vol.23, p.2947, 1985.

B. J. Roulstone, M. C. Wilkinson, and J. Hearn, Polym. Int, p.305, 1992.

P. A. Steward, J. Hearn, and M. C. Wilkinson, Adv. Colloid Interface Sci, vol.86, p.195, 2000.

M. A. Winnik, Curr. Opin. Colloid Interface Sci, 1997.

A. F. Routh and W. B. , Ind. Eng. Chem. Res, p.4302, 2001.

J. M. Geurts, M. Lammers, and A. L. German, Colloids Surf. A: Physicochem. Eng. Asp, vol.108, p.295, 1996.

A. C. Peters, G. C. Overbeek, A. J. Buckmann, J. C. Padget, and T. Annable, Prog. Org. Coat, vol.29, p.183, 1996.

C. He and A. M. Donald, Langmuir, vol.12, p.6250, 1996.

M. Zulauf, P. Lindner, P. Terech, M. Joanicot, K. Wong et al., Ordering of latex particles during film formation, Trends in Colloid and Interface Science IV, p.175, 1990.

J. Y. Charmeau, E. Kientz, and Y. Holl, Prog. Org. Coat, p.87, 1996.

E. Kientz, Y. Holl, and C. Surf, , p.255, 1993.

J. P. Farinha, J. M. Martinho, S. Kawaguchi, A. Yekta, and M. A. Winnik, J. Phys. Chem, p.12552, 1996.

B. J. Roulstone, M. C. Wilkinson, and J. Hearn, Polym. Int, p.43, 1992.

E. Kientz, F. Dobler, and Y. Holl, Polym. Int, vol.34, p.125, 1994.

S. T. Eckersley and A. Rudin, J. Appl. Polym. Sci, vol.48, p.1369, 1993.

B. R. Vijayendran, T. Bone, and L. C. Sawyer, J. Dispersion Sci. Technol, vol.3, p.81, 1982.

L. N. Butler, C. M. Fellows, and R. G. Gilbert, J. Appl. Polym. Sci, p.1813, 2004.

S. Kawaguchi, E. Odrobina, and M. A. Winnik, Macromol. Rapid Commun, vol.16, p.861, 1995.

K. W. Evanson, T. A. Thorstenson, and M. W. Urban, J. Appl. Polym. Sci, vol.42, p.2297, 1991.

E. B. Bradford and J. W. Vanderhoff, Rubber Chem. Technol, p.514, 1968.

Y. Chevalier, C. Pichot, C. Graillat, M. Joanicot, K. Wong et al., Colloid Polym. Sci, vol.270, p.806, 1992.

K. W. Evanson and M. W. Urban, J. Appl. Polym. Sci, vol.42, p.2309, 1991.

M. Torstensson, B. Ranby, and A. Hult, Macromolecules, vol.23, p.126, 1990.

Y. Zhao and M. W. Urban, Macromolecules, vol.33, p.7573, 2000.

M. J. Unzué, H. A. Schoonbrood, J. M. Asua, A. M. Goñi, D. C. Sherrington et al.,

K. Goebel, M. Tauer, K. Sjöberg, and . Holmberg, J. Appl. Polym. Sci, vol.66, p.1803, 1997.

, J. I. Amalvy, Pigm. Resin Technol, 1920.

J. Feng and M. A. Winnik, Macromolecules, vol.30, p.4324, 1997.

N. Agarwal and R. J. Farris, J. Appl. Polym. Sci, vol.72, p.1407, 1999.

A. Tzitzinou, J. L. Keddie, J. M. Geurts, A. C. Peters, and R. Satguru, Macromolecules, vol.33, p.2695, 2000.

Y. Wang, D. Juhue, M. A. Winnik, O. M. Leung, and M. C. Goh, Langmuir, vol.8, p.760, 1992.

Y. Wang, A. Kats, D. Juhue, M. A. Winnik, R. R. Shivers et al., Langmuir, vol.8, p.1435, 1992.

M. Okubo, T. Takeya, Y. Tsutsumi, T. Kadooka, and T. Matsumoto, J. Polym. Sci.: Polym. Chem. Ed, vol.19, p.1, 1981.

D. Juhue and J. Lang, Langmuir, vol.9, p.792, 1993.

D. Juhué and J. Lang, Colloids Surf., A, vol.87, p.177, 1994.

B. Niu and M. W. Urban, J. Appl. Polym. Sci, vol.70, p.1321, 1998.

A. Du-chesne, B. Gerharz, and G. Lieser, Polym. Int, vol.43, p.187, 1997.

S. T. Eckersley and A. Rudin, J. Appl. Polym. Sci, vol.53, p.1139, 1994.

Y. Reyes-mercado, F. Vazquez, F. J. Rodriguez-gomez, and Y. Duda, Colloid Polym. Sci, vol.286, p.603, 2008.

G. Riess and C. Labbe, Macromol. Rapid Commun, vol.25, p.401, 2004.

C. Tondeur, Thèse de doctorat de l'université de Haute-Alsace, 1995.

M. Gerst, H. Schuch, and D. Urban, Amphiphilic Block Copolymers as Surfactants in Emulsion Polymerization, Associative Polymers in Aqueous Media, p.37, 2000.

J. Mura and G. Riess, Polym. Adv. Technol, vol.6, p.497, 1995.

A. Jada, G. Hurtrez, B. Siffert, and G. Riess, Macromolecular Chemistry and Physics, vol.197, p.3697, 1996.

G. Riess, Prog. Polym. Sci, vol.28, p.1107, 2003.

C. Burguière, S. Pascual, C. Bui, J. Vairon, B. Charleux et al., Macromolecules, vol.34, p.4439, 2001.

A. Guyot and K. Tauer, Reactive surfactants in emulsion polymerization, Polymer Synthesis, p.43, 1994.

A. Guyot, K. Tauer, J. M. Asua, S. Van-es, C. Gauthier et al., Acta Polymerica, vol.50, p.57, 1999.

J. M. Asua and H. A. Schoonbrood, Acta Polymerica, vol.49, p.671, 1998.

O. Soula, A. Guyot, N. Williams, J. Grade, and T. Blease, J. Polym. Sci., Part A: Polym. Chem, p.4205, 1999.

E. Aramendia, J. Mallégol, C. Jeynes, M. J. Barandiaran, J. L. Keddie et al., Langmuir, vol.19, p.3212, 2003.

J. I. Amalvy, M. J. Unzué, H. A. Schoonbrood, and J. M. Asua, J. Polym. Sci., Part A: Polym. Chem, p.2994, 2002.

H. Huang, D. Lu, L. Shen, and R. Guan, J. Macromol. Sci., Part A: Pure Appl. Chem, p.242, 2008.

S. Lam, A. C. Hellgren, M. Sjöberg, K. Holmberg, H. A. Schoonbrood et al., J. Appl. Polym. Sci, vol.66, p.187, 1997.

C. Gauthier, O. Sindt, G. Vigier, A. Guyot, H. A. Schoonbrood et al., J. Appl. Polym. Sci, vol.84, p.1686, 2002.

E. Aramendia, M. , .. J. Barandiaran, J. Grade, T. Blease et al., Langmuir, 1428.

H. A. Schoonbrood and J. M. Asua, Macromolecules, vol.30, p.6034, 1997.

G. Moad and D. H. Solomon, The Chemistry of Radical Polymerization (Second Edition), p.p. xvi, 2005.

W. A. Braunecker and K. Matyjaszewski, Prog. Polym. Sci, vol.32, p.93, 2007.

J. Nicolas, Y. Guillaneuf, C. Lefay, D. Bertin, D. Gigmes et al., Prog. Polym. Sci, vol.38, p.63, 2013.

K. Matyjaszewski, Macromolecules, vol.45, p.4015, 2012.

G. David, C. Boyer, J. Tonnar, B. Ameduri, P. Lacroix-desmazes et al., Chem. Rev, vol.106, p.3936, 2006.

L. Patrick, V. -h.-alejandro-magno, and R. David, Reverse Iodine Transfer Polymerization (RITP): From Kinetics and Mechanisms to Macromolecular Engineering, Progress in Controlled Radical Polymerization: Mechanisms and Techniques, p.317, 2012.

A. Goto, Y. Kwak, T. Fukuda, S. Yamago, K. Iida et al., J. Am. Chem. Soc, vol.125, p.8720, 2003.

G. Moad, E. Rizzardo, and S. H. Thang, Aust. J. Chem, p.985, 2012.

J. Chiefari, Y. K. Chong, F. Ercole, J. Krstina, J. Jeffery et al.,

C. L. Meijs, G. Moad, E. Moad, S. H. Rizzardo, and . Thang, Macromolecules, p.5559, 1998.

D. Charmot, P. Corpart, H. Adam, S. Z. Zard, T. Biadatti et al., Macromol. Symp, vol.150, p.23, 2000.

D. J. Keddie, G. Moad, E. Rizzardo, and S. H. Thang, Macromolecules, vol.45, p.5321, 2012.

S. Perrier and P. Takolpuckdee, J. Polym. Sci., Part A: Polym. Chem, p.5347, 2005.

D. B. Thomas, A. J. Convertine, R. D. Hester, A. B. Lowe, and C. L. Mccormick, Macromolecules, vol.37, p.1735, 2004.

M. L. Coote and D. J. Henry, Macromolecules, vol.38, p.5774, 2005.

M. L. Coote, E. I. Izgorodina, G. N. Cavigliasso, M. Roth, M. Busch et al., Macromolecules, vol.39, p.4585, 2006.

A. Theis, M. H. Stenzel, T. P. Davis, M. L. Coote, and C. Barner-kowollik, Aust. J. Chem, p.437, 2005.

M. Busch, M. Roth, M. H. Stenzel, T. P. Davis, and C. Barner-kowollik, Aust. J. Chem, p.788, 2007.

D. J. Keddie, Chem. Soc. Rev, vol.43, p.496, 2013.

D. J. Keddie, C. Guerrero-sanchez, and G. Moad, Polym. Chem, 2013.

M. Benaglia, M. Chen, Y. K. Chong, G. Moad, E. Rizzardo et al., Macromolecules, vol.42, p.9384, 2009.

M. Benaglia, J. Chiefari, Y. K. Chong, G. Moad, E. Rizzardo et al., J. Am. Chem. Soc, p.6914, 2009.

D. J. Keddie, C. Guerrero-sanchez, G. Moad, E. Rizzardo, and S. H. Thang, Macromolecules, vol.44, p.6738, 2011.

D. J. Keddie, C. Guerrero-sanchez, G. Moad, R. J. Mulder, E. Rizzardo et al., Macromolecules, vol.45, p.4205, 2012.

M. Save, Y. Guillaneuf, and R. G. Gilbert, Aust. J. Chem, p.693, 2006.

P. B. Zetterlund, Y. Kagawa, and M. Okubo, Chem. Rev, vol.108, p.3747, 2008.

M. F. Cunningham, Prog. Polym. Sci, p.365, 2008.

A. M. Herk, K. Landfester, B. Charleux, F. D'agosto, and G. Delaittre, Preparation of Hybrid Latex Particles and Core-Shell Particles Through the Use of Controlled Radical Polymerization Techniques in Aqueous Media, Hybrid Latex Particles, p.125, 2010.

M. J. Monteiro and M. F. Cunningham, Macromolecules, vol.45, p.4939, 2012.

B. Charleux, G. Delaittre, J. Rieger, and F. D'agosto, Macromolecules, vol.45, p.6753, 2012.

B. Charleux and J. Nicolas, Polymer, vol.48, p.5813, 2007.

R. W. Simms, M. D. Hoidas, and M. F. Cunningham, Macromolecules, p.1076, 2008.

M. E. Thomson, A. Manley, J. S. Ness, S. C. Schmidt, and M. F. Cunningham, Macromolecules, p.7958, 2010.

G. Delaittre, J. Nicolas, C. Lefay, M. Save, and B. Charleux, Chem. Commun, p.614, 2005.

G. Delaittre and B. Charleux, Macromolecules, p.2361, 2008.

G. Delaittre, C. Dire, J. Rieger, J. Putaux, and B. Charleux, Chem. Commun, p.2887, 2009.

B. Charleux, J. Nicolas, and O. Guerret, Macromolecules, vol.38, p.5485, 2005.

J. Nicolas, C. Dire, L. Mueller, J. Belleney, B. Charleux et al., Macromolecules, vol.39, p.8274, 2006.

J. Nicolas, S. Brusseau, and B. Charleux, J. Polym. Sci., Part A: Polym. Chem, p.34, 2009.

C. Dire, S. Magnet, L. Couvreur, and B. Charleux, Macromolecules, vol.42, p.95, 2009.

S. Brusseau, J. Belleney, S. Magnet, L. Couvreur, and B. Charleux, Polym. Chem, p.720, 2010.

B. Grassl, G. Clisson, A. Khoukh, and L. Billon, Eur. Polym. J, vol.44, p.50, 2008.

T. N. Phan and D. Bertin, Macromolecules, p.1886, 2008.

W. Huang, B. Charleux, R. Chiarelli, L. Marx, A. Rassat et al., Macromol. Chem. Phys, p.1715, 2002.

R. Nicolaÿ, L. Marx, P. Hémery, and K. Matyjaszewski, Macromolecules, vol.40, p.6067, 2007.

S. Brusseau, F. D'agosto, S. Magnet, L. Couvreur, C. Chamignon et al., Macromolecules, vol.44, p.5590, 2011.

E. Groison, S. Brusseau, F. D'agosto, S. Magnet, R. Inoubli et al., , vol.1, p.47, 2012.

S. Yamago, K. Iida, J. -i, and . Yoshida, J. Am. Chem. Soc, vol.124, p.2874, 2002.

S. Yamago, K. Iida, J. -i, and . Yoshida, J. Am. Chem. Soc, vol.124, p.13666, 2002.

M. Okubo, Y. Sugihara, Y. Kitayama, Y. Kagawa, and H. Minami, Macromolecules, vol.42, 1979.

Y. Kitayama, A. Chaiyasat, H. Minami, and M. Okubo, Macromolecules, p.7465, 2010.

Y. Kitayama, A. Chaiyasat, and M. Okubo, Macromol. Symp, p.25, 2010.

H. Moribe, Y. Kitayama, T. Suzuki, and M. Okubo, Macromolecules, vol.44, p.263, 2011.

Y. Kitayama, H. Moribe, H. Minami, and M. Okubo, Polymer, 2011.

Y. Kitayama, K. Kishida, H. Minami, and M. Okubo, J. Polym. Sci., Part A: Polym. Chem, p.50, 1991.

Y. Kitayama, H. Moribe, K. Kishida, and M. Okubo, Polym. Chem, vol.3, p.1555, 2012.

Y. Kitayama, K. Kishida, and M. Okubo, J. Polym. Sci., Part A: Polym. Chem, p.716, 2013.

, Fiches Internationales de Sécurité Chimique-Iode, vol.2, p.167

J. Tonnar and P. Lacroix-desmazes, Angew. Chem. Int. Ed, p.1294, 2008.

J. Tonnar and P. Lacroix-desmazes, Soft Matter, 1255.

F. Stoffelbach, L. Tibiletti, J. Rieger, and B. Charleux, Macromolecules, p.7850, 2008.

C. J. Ferguson, R. J. Hughes, B. T. Pham, B. S. Hawkett, R. G. Gilbert et al., Macromolecules, vol.35, p.9243, 2002.

C. J. Ferguson, R. J. Hughes, D. Nguyen, B. T. Pham, R. G. Gilbert et al., Macromolecules, vol.38, p.2191, 2005.

E. Sprong, J. S. Leswin, D. J. Lamb, C. J. Ferguson, B. S. Hawkett et al., Macromol. Symp, p.84, 2005.

J. Bozovic-vukic, H. T. Mañon, J. Meuldijk, C. Koning, and B. Klumperman, Macromolecules, vol.40, p.7132, 2007.

M. Manguian, M. Save, and B. Charleux, Macromol. Rapid Commun, p.399, 2006.

J. Xu, X. Wang, Y. Zhang, W. Zhang, and P. Sun, J. Polym. Sci., Part A: Polym. Chem, p.2484, 2012.

J. Rieger, F. Stoffelbach, C. Bui, D. Alaimo, C. Jérôme et al., Macromolecules, p.4065, 2008.

J. Rieger, G. Osterwinter, C. Bui, F. Stoffelbach, and B. Charleux, Macromolecules, vol.42, p.5518, 2009.

J. Rieger, W. Zhang, F. Stoffelbach, and B. Charleux, Macromolecules, p.6302, 2010.

N. Yeole, D. Hundiwale, and C. Surf, , p.329, 2011.

J. Bernard, M. Save, B. Arathoon, and B. Charleux, J. Polym. Sci., Part A: Polym. Chem, vol.46, p.2845, 2008.

I. Chaduc, W. Zhang, J. Rieger, M. Lansalot, F. D'agosto et al., Macromol. Rapid Commun, vol.32, 1270.

W. Zhang, F. D'agosto, O. Boyron, J. Rieger, and B. Charleux, Macromolecules, vol.44, p.7584, 2011.

I. Chaduc, M. Girod, R. Antoine, B. Charleux, F. D'agosto et al., Macromolecules, vol.45, p.5881, 2012.

I. Chaduc, A. Crepet, O. Boyron, B. Charleux, F. D'agosto et al., Macromolecules, vol.46, p.6013, 2013.

W. Zhang, F. D'agosto, P. Dugas, J. Rieger, and B. Charleux, Polymer, vol.54, 2011.

M. Chenal, L. Bouteiller, and J. Rieger, Polym. Chem, 2013.

S. Boissé, J. Rieger, K. Belal, A. Di-cicco, P. Beaunier et al., Chem. Commun, vol.46, 1950.

S. Boissé, J. Rieger, G. Pembouong, P. Beaunier, and B. Charleux, J. Polym. Sci., Part A: Polym. Chem, p.3346, 2011.

X. Zhang, S. Boissé, W. Zhang, P. Beaunier, F. D'agosto et al., Macromolecules, p.4149, 2011.

A. M. Santos, J. Pohn, M. Lansalot, and F. D'agosto, Macromol. Rapid Commun, vol.28, p.1325, 2007.

D. E. Ganeva, E. Sprong, H. De-bruyn, G. G. Warr, C. H. Such et al., Macromolecules, vol.40, p.6181, 2007.

X. Wang, Y. Luo, B. Li, and S. Zhu, Macromolecules, vol.42, p.6414, 2009.

G. Bar-nes, R. Hall, V. Sharma, M. Gaborieau, D. Lucas et al., Eur. Polym. J, vol.45, p.3149, 2009.

R. Wei, Y. Luo, and P. Xu, J. Polym. Sci., Part A: Polym. Chem, 2011.

Y. Luo, X. Wang, Y. Zhu, B. Li, and S. Zhu, Macromolecules, p.7472, 2010.

S. Xu, J. Huang, S. Xu, and Y. Luo, Polymer, vol.54, p.1779, 2013.

J. Zhou, L. Zhang, and J. Ma, Chem. Eng. J

J. Xu, X. Xiao, Y. Zhang, W. Zhang, and P. Sun, J. Polym. Sci., Part A: Polym. Chem, p.1147, 2012.

S. R. Ting, E. H. Min, P. B. Zetterlund, and M. H. Stenzel, Macromolecules, p.5211, 2010.

R. Severac, P. Lacroix-desmazes, and B. Boutevin, Polym. Int, p.1117, 2002.

P. Lacroix-desmazes, R. Severac, and B. Boutevin, Vinylidene Chloride Copolymerization with Methyl Acrylate by Degenerative Chain Transfer, Advances in Controlled/Living Radical Polymerization, p.570, 2003.
URL : https://hal.archives-ouvertes.fr/hal-00801576

G. Moad, E. Rizzardo, and S. H. Thang, Aust. J. Chem, p.379, 2005.

B. Rixens, R. Severac, B. Boutevin, and P. Lacroix-desmazes, Polymer, vol.46, p.3579, 2005.

B. Rixens, R. Severac, B. Boutevin, and P. Lacroix-desmazes, J. Polym. Sci., Part A: Polym. Chem, p.13, 2006.

, WO2008003728, 2008.

P. Lacroix-desmazes, R. Severac, B. Otazaghine, and B. Boutevin, Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.), vol.44, p.683, 2003.

M. Save, Y. Guillaneuf, and R. G. Gilbert, Aust. J. Chem, p.693, 2006.

J. Bozovic-vukic, H. T. Mañon, J. Meuldijk, C. Koning, and B. Klumperman, Macromolecules, vol.40, p.7132, 2007.

F. Stoffelbach, L. Tibiletti, J. Rieger, and B. Charleux, Macromolecules, p.7850, 2008.

J. Rieger, W. Zhang, F. Stoffelbach, and B. Charleux, Macromolecules, p.6302, 2010.

S. Boissé, J. Rieger, K. Belal, A. Di-cicco, P. Beaunier et al., Chem. Commun, vol.46, 1950.

M. Chenal, L. Bouteiller, and J. Rieger, Polym. Chem, 2013.

J. T. Lai, D. Filla, and R. Shea, Macromolecules, vol.35, p.6754, 2002.

Y. Li, J. Appl. Polym. Sci, p.2397, 1996.

J. Brandrup, E. H. Immergut, and E. A. Grulke, Polymer Handbook, 1999.

F. R. Mayo, F. M. Lewis, and C. Walling, J. Am. Chem. Soc, vol.70, p.1529, 1948.

S. Collins, K. Yoda, N. Anazawa, and C. Birkinshaw, Polym. Degrad. Stab, vol.66, p.87, 1999.

J. Brandrup, E. H. Immergut, and E. A. Grulke, Polymer Handbook, p.548, 1999.

S. Beuermann and M. Buback, Prog. Polym. Sci, 2002.

J. D. Burnett and H. W. Melville, Trans. Faraday Soc, vol.46, p.976, 1950.

A. Favier and M. Charreyre, Macromol. Rapid Commun, p.653, 2006.

J. Rieger, G. Osterwinter, C. Bui, F. Stoffelbach, and B. Charleux, Macromolecules, vol.42, p.5518, 2009.

I. Lacik, S. Beuermann, and M. Buback, Macromolecules, vol.34, p.6224, 2001.

Z. Janovi?, C. S. Marvel, M. J. Diamond, D. J. Kertesz, and G. Fuller, J. Polym. Sci., Part A, vol.9, issue.1, p.2639, 1971.

L. Couvreur, C. Lefay, J. Belleney, B. Charleux, O. Guerret et al., Macromolecules, vol.36, p.8260, 2003.

J. Chiefari, Y. K. Chong, F. Ercole, J. Krstina, J. Jeffery et al.,

C. L. Meijs, G. Moad, E. Moad, S. H. Rizzardo, and . Thang, Macromolecules, p.5559, 1998.

C. Ladavière, N. Dörr, and J. P. Claverie, Macromolecules, vol.34, p.5370, 2001.

J. Loiseau, N. Doërr, J. M. Suau, J. B. Egraz, M. F. Llauro et al., Macromolecules, vol.36, p.3066, 2003.

J. Ji, L. Jia, L. Yan, and P. R. Bangal, Journal of Macromolecular Science, Part A, p.445, 2010.

C. Hong, Y. You, R. Bai, C. Pan, and G. Borjihan, J. Polym. Sci., Part A: Polym. Chem, p.3934, 2001.

P. Millard, L. Barner, M. H. Stenzel, T. P. Davis, C. Barner-kowollik et al., Macromol. Rapid Commun, vol.27, p.821, 2006.

S. Muthukrishnan, E. H. Pan, M. H. Stenzel, C. Barner-kowollik, T. P. Davis et al., Macromolecules, vol.40, p.2978, 2007.

I. Chaduc, A. Crepet, O. Boyron, B. Charleux, F. D'agosto et al., Macromolecules, vol.46, p.6013, 2013.

L. Couvreur, Polymérisation et copolymérisation radicalaires de l'acide acrylique contrôlées par le nitroxyde SG1, 2003.

T. Gruendling, T. Junkers, M. Guilhaus, and C. Barner-kowollik, Macromol. Chem. Phys, p.520, 2010.

J. Rieger, F. Stoffelbach, C. Bui, D. Alaimo, C. Jérôme et al., Macromolecules, p.4065, 2008.

P. C. Strazielle, Die Makromolekulare Chemie, vol.119, p.50, 1968.

H. Willcock and R. K. O'reilly, Polym. Chem, p.149, 2010.

G. Moad, E. Rizzardo, and S. H. Thang, Polym. Int, vol.60, p.9, 2011.

A. Goto, K. Ohno, and T. Fukuda, Macromolecules, 1998.

D. J. Keddie, G. Moad, E. Rizzardo, and S. H. Thang, Macromolecules, vol.45, p.5321, 2012.

J. Brandrup, E. H. Immergut, and E. A. Grulke, Polymer Handbook, p.214, 1999.

Y. Li and Z. Weng, Z. Pan, Chin. J. Polym. Sci, vol.15, p.319, 1997.

R. A. Wessling, D. S. Gibbs, B. E. Obi, D. E. Beyer, P. T. Delassus et al., Poly(vinylidene chloride), Kirk-Othmer Encyclopedia-Chemical Technology, p.691, 2007.

J. Rieger, F. Stoffelbach, C. Bui, D. Alaimo, C. Jérôme et al., Macromolecules, p.4065, 2008.

J. Rieger, G. Osterwinter, C. Bui, F. Stoffelbach, and B. Charleux, Macromolecules, vol.42, p.5518, 2009.

, EP2283052, 2011.

R. Severac, P. Lacroix-desmazes, and B. Boutevin, Polym. Int, p.1117, 2002.

J. Brandrup, E. H. Immergut, and E. A. Grulke, Polymer Handbook, p.6, 1999.

J. Rieger, C. Passirani, J. P. Benoit, K. Van-butsele, R. Jérôme et al., Adv. Funct. Mater, vol.16, p.1506, 2006.

W. Bai, L. Zhang, R. Bai, and G. Zhang, Macromol. Rapid Commun, vol.29, 2008.

N. Kohut-svelko, R. Pirri, J. M. Asua, and J. R. Leiza, J. Polym. Sci., Part A: Polym. Chem, p.2917, 2009.

P. Vana, L. Albertin, L. Barner, T. P. Davis, and C. Barner-kowollik, J. Polym. Sci., Part A: Polym. Chem, p.4032, 2002.

S. Nozari, K. Tauer, and A. M. Ali, Macromolecules, vol.38, p.10449, 2005.

Y. Luo, X. Wang, B. Li, and S. Zhu, Macromolecules, 2011.

J. Garnier, P. Dufils, J. Vinas, Y. Vanderveken, A. Van-herk et al., Polym. Degrad. Stab, vol.97, p.170, 2012.

R. W. Eykamp, A. M. Schneider, and E. W. Merrill, J. Polym. Sci., Part A, issue.2, 1025.

S. Boissé, J. Rieger, G. Pembouong, P. Beaunier, and B. Charleux, J. Polym. Sci., Part A: Polym. Chem, p.3346, 2011.

X. Zhang, S. Boissé, W. Zhang, P. Beaunier, F. D'agosto et al., Macromolecules, p.4149, 2011.

X. Qiao, Synthesis of silica-polymer hybrid particles via controlled radical polymerization in aqueous dispersed media, C2P2, UCBL1, Lyon, 2013.
URL : https://hal.archives-ouvertes.fr/tel-01161632

F. Liu and M. W. Urban, Prog. Polym. Sci, p.3, 2010.

X. Wang, Y. Luo, B. Li, and S. Zhu, Macromolecules, vol.42, p.6414, 2009.

R. Wei, Y. Luo, and P. Xu, J. Polym. Sci., Part A: Polym. Chem, 2011.

I. Chaduc, A. Crepet, O. Boyron, B. Charleux, F. D'agosto et al., Macromolecules, vol.46, p.6013, 2013.

H. Mori, A. H. Müller, and J. E. Klee, J. Am. Chem. Soc, vol.125, p.3712, 2003.

M. Chenal, L. Bouteiller, and J. Rieger, Polym. Chem, 2013.

D. E. Ganeva, E. Sprong, H. De-bruyn, G. G. Warr, C. H. Such et al., Macromolecules, vol.40, p.6181, 2007.

H. Park and J. Robinson, Pharm. Res, vol.4, p.457, 1987.

R. Dong, M. Lindau, and C. K. Ober, Langmuir, vol.25, p.4774, 2009.

M. , Particules coeur-écorce par polymérisation en émulsion pour des matériaux nanostructurés sans solvants, LCP, 2013.

R. G. Gilbert, Emulsion polymerization: a mechanistic approach, 1995.

I. Chaduc, W. Zhang, J. Rieger, M. Lansalot, F. D'agosto et al., Macromol. Rapid Commun, vol.32, 1270.

W. Zhang, F. D'agosto, O. Boyron, J. Rieger, and B. Charleux, Macromolecules, vol.44, p.7584, 2011.

I. Chaduc, M. Girod, R. Antoine, B. Charleux, F. D'agosto et al., Macromolecules, vol.45, p.5881, 2012.

W. Zhang, F. D'agosto, P. Dugas, J. Rieger, and B. Charleux, Polymer, vol.54, 2011.

I. Chaduc, A. Crepet, O. Boyron, B. Charleux, F. D'agosto et al., Macromolecules, vol.46, p.6013, 2013.

B. Charleux, J. Nicolas, and O. Guerret, Macromolecules, vol.38, p.5485, 2005.

J. Nicolas, C. Dire, L. Mueller, J. Belleney, B. Charleux et al., Macromolecules, vol.39, p.8274, 2006.

Y. Guillaneuf, D. Gigmes, S. R. Marque, P. Astolfi, L. Greci et al., Macromolecules, vol.40, p.3108, 2007.

C. Dire, B. Charleux, S. Magnet, and L. Couvreur, Macromolecules, vol.40, p.1897, 2007.

J. Nicolas, S. Brusseau, and B. Charleux, J. Polym. Sci., Part A: Polym. Chem, p.34, 2009.

S. Brusseau, J. Belleney, S. Magnet, L. Couvreur, and B. Charleux, Polym. Chem, p.720, 2010.

S. Brusseau, F. D'agosto, S. Magnet, L. Couvreur, C. Chamignon et al., Macromolecules, vol.44, p.5590, 2011.

Y. K. Chong, T. P. Le, G. Moad, E. Rizzardo, and S. H. Thang, Macromolecules, vol.32, p.2071, 1999.

C. Yang and Y. Cheng, J. Appl. Polym. Sci, vol.102, p.1191, 2006.

K. Vijayakrishna, S. K. Jewrajka, A. Ruiz, R. Marcilla, J. A. Pomposo et al., Macromolecules, p.6299, 2008.

A. Krieg, C. Pietsch, A. Baumgaertel, M. D. Hager, C. R. Becer et al., Polym. Chem, p.1669, 2010.

C. R. Becer, S. Hahn, M. W. Fijten, H. M. Thijs, R. Hoogenboom et al., J. Polym. Sci., Part A: Polym. Chem, vol.46, p.7138, 2008.

E. Hosseini-nejad, P. Castignolles, R. G. Gilbert, and Y. Guillaneuf, J. Polym. Sci., Part A: Polym. Chem, vol.46, p.2277, 2008.

J. M. Pelet and D. Putnam, Macromolecules, vol.42, p.1494, 2009.

I. Chaduc, M. Lansalot, F. D'agosto, and B. Charleux, Macromolecules, vol.45, p.1241, 2012.

L. Ruiz-perez, A. Pryke, M. Sommer, G. Battaglia, I. Soutar et al., Macromolecules, p.2203, 2008.

A. Katchalsky, P. Spitnik, J. Polym, and . Sci, , vol.2, p.432, 1947.

S. Fisher and R. Kunin, The Journal of Physical Chemistry, vol.60, p.1030, 1956.

R. Saito, K. Yamaguchi, T. Hara, and C. Saegusa, Macromolecules, vol.40, p.4621, 2007.

H. Dong, H. Du, and X. Qian, The Journal of Physical Chemistry B, p.12857, 2009.

R. Dong, M. Lindau, and C. K. Ober, Langmuir, vol.25, p.4774, 2009.

Y. Wi, K. Lee, B. H. Lee, and S. Choe, Polymer, vol.5626, p.49, 2008.

J. Chiefari, Y. K. Chong, F. Ercole, J. Krstina, J. Jeffery et al.,

C. L. Meijs, G. Moad, E. Moad, S. H. Rizzardo, and . Thang, Macromolecules, p.5559, 1998.

Y. Mitsukami, M. S. Donovan, A. B. Lowe, and C. L. Mccormick, Macromolecules, vol.34, p.2248, 2001.

M. Barsbay, O. Güven, T. P. Davis, C. Barner-kowollik, and L. Barner, Polymer, vol.50, p.973, 2009.

N. Yeole, D. Hundiwale, and C. Surf, , p.329, 2011.

N. Yeole, D. Hundiwale, and T. Jana, J. Colloid Interface Sci, vol.354, p.506, 2011.

M. Mertoglu, S. Garnier, A. Laschewsky, K. Skrabania, and J. Storsberg, Polymer, vol.46, p.7726, 2005.

H. Thielking and W. Kulicke, Anal. Chem, p.1169, 1996.

M. Llauro, J. Loiseau, F. Boisson, F. Delolme, C. Ladavière et al., J. Polym. Sci., Part A: Polym. Chem, p.5439, 2004.

C. Ladavière, P. Lacroix-desmazes, and F. Delolme, Macromolecules, vol.42, p.70, 2008.

C. Barner-kowollik, T. Gruendling, J. Falkenhagen, and S. Weidner, Mass Spectrometry in Polymer Chemistry, 2012.

A. Favier and M. Charreyre, Macromol. Rapid Commun, p.653, 2006.

R. D. Bohme and R. A. Wessling, J. Appl. Polym. Sci, vol.16, p.1761, 1972.

S. Collins, K. Yoda, N. Anazawa, and C. Birkinshaw, Polym. Degrad. Stab, vol.66, p.87, 1999.

Y. Li, J. Appl. Polym. Sci, p.2397, 1996.

P. Pendleton, B. Vincent, and M. L. Hair, J. Colloid Interface Sci, vol.80, p.512, 1981.

T. Yoshioka, T. Kameda, S. Imai, M. Noritsune, and A. Okuwaki, Polym. Degrad. Stab, vol.93, 1979.

D. H. Davies and P. M. Henheffer, Transactions of the Faraday Society, vol.66, p.2329, 1970.

A. Eisenberg, T. Yokoyama, and E. Sambalido, J. Polym. Sci., Part A-1: Polym. Chem, 1717.

A. Odajima, A. E. Woodward, and J. A. Sauer, J. Polym. Sci, vol.55, p.181, 1961.

C. Castro, L. Gargallo, D. Radic, G. Kortaberria, and I. Mondragon, Carbohydr. Polym, vol.83, p.81, 2011.

R. A. Wessling, F. L. Dicken, S. R. Kurowsky, and D. S. Gibbs, Applied Polymer Symposium, vol.25, p.83, 1974.

K. H. Illers, Kolloid-Z. u. Z. Polymere, vol.250, p.426, 1972.

E. Penzel, H. Haberkorn, and J. Heilig, Die Angewandte Makromolekulare Chemie, vol.273, p.15, 1999.

D. M. Heymans and M. F. Daniel, Polym. Adv. Technol, 1995.

D. P. Jensen and L. W. Morgan, J. Appl. Polym. Sci, vol.42, p.2845, 1991.

S. T. Eckersley and A. Rudin, J. Appl. Polym. Sci, vol.48, p.1369, 1993.

P. R. Sperry, B. S. Snyder, M. L. O'dowd, and P. M. Lesko, Langmuir, vol.10, p.2619, 1994.

W. Lee and A. Routh, , vol.3, p.301, 2006.

Y. Li and Z. Weng, Z. Pan, Chin. J. Polym. Sci, vol.15, p.319, 1997.

M. , Particules coeur-écorce par polymérisation en émulsion pour des matériaux nanostructurés sans solvants, 2013.

M. Chenal, J. Rieger, C. Véchambre, J. Chenal, L. Chazeau et al., Macromol. Rapid Commun, vol.34, p.1524, 2013.

F. Santos, P. Fabre, X. Drujon, G. Meunier, and L. Leibler, J. Polym. Sci., Part B: Polym. Phys, vol.38, p.2989, 2000.

A. C. Hellgren, Prog. Org. Coat, vol.34, p.91, 1997.

Y. Chevalier, C. Pichot, C. Graillat, M. Joanicot, K. Wong et al., Colloid Polym. Sci, vol.270, p.806, 1992.

A. Zosel, W. Heckmann, G. Ley, and W. Mächtle, Colloid Polym. Sci, vol.265, p.113, 1987.

J. Feng and M. A. Winnik, Macromolecules, vol.30, p.4324, 1997.

N. Agarwal and R. J. Farris, J. Appl. Polym. Sci, vol.72, p.1407, 1999.

.. .. Réactifs,

.. .. Modes,

. .. Synthèse-des-macroraft,

. .. Techniques-de-caractérisation,

. .. Gravimétrie,

. .. Résonance-magnétique-nucléaire-;-rmn),

C. ). ,

. .. Spectrométrie-de-masse-maldi-tof,

D. ). ,

A. ). ,

. , Microscopie électronique en transmission (MET)

. .. Ultramicrotomie,

. , Microscopie électronique à balayage (MEB)

U. .. Spectroscopie,

. .. Analyse-thermogravimétrique-;-atg),

D. ). , 223 6.3.15 Mesure de la température minimum de formation du film (TMFF), Calorimétrie différentielle à balayage

. , Mesures de perméabilité à l'O 2 (PO 2 ) et à la vapeur d'eau (PVE)

. .. Références-bibliographiques,

, Chapitre 6-Matériels & Méthodes

J. T. Lai, D. Filla, and R. Shea, Macromolecules, vol.35, p.6754, 2002.

T. Boursier, I. Chaduc, J. Rieger, F. D'agosto, M. Lansalot et al., Polym. Chem, 2011.

J. Rieger, F. Stoffelbach, C. Bui, D. Alaimo, C. Jérôme et al., Macromolecules, p.4065, 2008.

J. Rieger, G. Osterwinter, C. Bui, F. Stoffelbach, and B. Charleux, Macromolecules, vol.42, p.5518, 2009.

K. Paek, S. Chung, C. Cho, and B. J. Kim, Chemical Communications, 2011.

I. Chaduc, M. Lansalot, F. D'agosto, and B. Charleux, Macromolecules, vol.45, p.1241, 2012.

L. Couvreur, C. Lefay, J. Belleney, B. Charleux, O. Guerret et al., Macromolecules, vol.36, p.8260, 2003.

H. E. Gottlieb, V. Kotlyar, and A. Nudelman, The Journal of Organic Chemistry, vol.62, p.7512, 1997.

, Annexe B-Publications Sommaire B, vol.1

. Poly,

, Study of the solution and aqueous emulsion copolymerization of vinylidene chloride with methyl acrylate in the presence a poly(ethylene oxide) macromolecular RAFT agent, p.241

, Brevet : Process for the preparation of a vinilydene chloride copolymer WO, 2013.

, Poly(vinylidene chloride)-Based Amphiphilic Block Copolymers

E. Velasquez, G. Pembouong, J. Rieger, F. Stoffelbach, O. Boyron et al., The controlled/living free-radical copolymerization of vinylidene chloride (VDC) with methyl acrylate (MeA) or acrylic acid (AA) was studied by the reversible addition?fragmentation chain transfer (RAFT) technique using a trithiocarbonate RAFT agent. The reactions were performed in 1,4-dioxane solution at 30 °C and led to good control and high chain-end functionality. P(VDC-co-MeA)-b-PAA, PAA-b-P(VDC-co-MeA), and PAA-b-P(VDC-co-AA) amphiphilic block copolymers were then prepared in the same conditions, starting either from a hydrophobic P(VDCco-MeA) macromolecular RAFT (macro-RAFT) agent or from a hydrophilic PAA one. The advantage of the first synthesis pathway relies on the very good transfer efficiency to trithiocarbonate-ended P(VDC-co-MeA) and on the rapid consumption of the latter even when low percentages (10 mol %) of MeA comonomer are incorporated in the macro-RAFT agent. In contrast, for the second approach a rapid consumption of the macroRAFT agent is only reached with 30 mol % of MeA in the comonomer feed, Macromolecules, vol.46, 2013.

P. , AA) diblock copolymers might also be obtained with controlled features in a one-pot process. Keywords: vinylidene chloride, controlled/living free-radical polymerization, reversible additionfragmentation chain transfer (RAFT), amphiphilic block copolymers