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A. Yoshiasa, H. Arima, M. Okube, H. Fukui, A. Nakatsuka et al., Acknowledgement I am sincerely grateful for the assistance for everybody supported me. I would like to thank for several reasons. First of all, I grateful to my supervisor Prof. Dr. Massimo Nespolo (Lorraine University), who gave me advice on theoretical crystallography. He invited me in France and supported all of the research and life in France. I was influenced by his sincere attitude towards research, Journal of Physics: Conference Series, vol.190, p.12119, 2009.

, I would like to express my appreciation for my other supervisor Prof. Dr. Akira Yoshiasa (Kumamoto University), who gave me advice every time and introduced me to local structural science. He gave me a lot of opportunities for scientific experience such as attendance at international conference and study abroad

H. Isobe, Kumamoto University) for their helpful discussion on my Ph.D. work. I am grateful to Prof. Dr. Kazumasa Sugiyama, Dr. Maki Okube and Dr. Hiroshi Arima (Tohoku University) for writing paper, experiment in KEK

, Dr. Ken-ichi Funakoshi (CROSS) for help at high temperature experiment in SPring-8, critical comment and advice for analysis of XRD experiment. I wish to express my gratitude to Prof

. Masami-kanzaki, . Prof, and . Dr, Xianyu Xue (Okayama University), Dr. Keisuke Hatada (Toyama University) for giving me opportunity to study in their laboratories

, I would like to mention great labmates in Department of Earth Science. Fruitful discussion with members in the department are greatly appericiated. Especially, I wish thank Dr

Y. Eguchi, H. Moribe, G. Yamasaki, U. Ishimaru, and . Nishi, They gave motivation for study. I enjoyed wonderful research life thanks to them. This work was supported by a Research Fellowships of the Japan Society for the Promotion of Science and TOBITATE ryugaku Japan. I am deeply grateful to my family for their kindness