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, Tableau 5-2 : Comparaison des intermédiaires réactionnels et sous-produits identifiés lors de la décomposition de l'acétaldéhyde par désorption en température et par le procédé plasma-catalyse

, TiO 2 /SiO 2 (spectre b) et Ag/TiO 2 /SiO 2 (spectre c) préalablement saturées en acétaldéhyde. Un zoom des zones 3 000-2 400 cm-1 et 2 000-1 000 cm-1 est également présenté

, Les bandes d'absorption observées après 3 heures d'ozonation de CH 3 CHO sur ces trois surfaces ainsi que leurs attributions sont

, Récapitulatif et comparaison des bandes d'absorption observées après 3 heures d'ozonation des surfaces SiO2, TiO2/SiO2 et Ag/TiO2/SiO2 préalablement saturées en acétaldéhyde Bande

, Formiates et/ou éthoxydes 9

, Cela signifie qu'une partie des intermédiaires réactionnels formés en surface est identique quelle que soit la surface considérée. Il s'agit de l'acide formique, de l'acétone, du crotonaldéhyde et des acétates. La formation de crotonaldéhyde sur SiO 2 en présence d'ozone est remarquable car ce composé 'espèces actives issues de la décomposition de l'ozone sur SiO 2 favorise la, Les spectres d'ozonation de CH 3 CHO présentent un certain nombre de bandes d'absorption communes aux trois surfaces étudiées (Tableau 5-4 bandes n° 1 à 4)

, Chapitre 5-Effet de la température et de l'ozone sur l'oxydation de l'acétaldéhyde adsorbé sur un catalyseur Ag/TiO2/SiO2 nanostructuré

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