2. L'explosion des nanoparticules d'aluminium (MDM) ,
Ratio massique d'équivalence () ,
,
Continuous crystallization of ultra-fine energetic particles by the FlashEvaporation Process, 2012. ,
URL : https://hal.archives-ouvertes.fr/tel-01749359
Continuous and reactive nanocrystallization: New concepts and processes for dual-use advances, Comptes Rendus Chim, vol.20, issue.4, pp.339-345, 2017. ,
Continuous engineering of nano-cocrystals for medical and energetic applications, Sci. Rep, vol.4, 2014. ,
Continuous formation of submicron energetic particles by the flashevaporation technique, Chem. Eng. J, vol.203, issue.0, pp.158-165, 2012. ,
URL : https://hal.archives-ouvertes.fr/hal-00778462
Tunable continuous production of RDX from microns to nanoscale using polymeric additives, Chem. Eng. J, vol.291, pp.12-19, 2016. ,
A note on the Fragmentation of Conical 'Liners' and its Relation to the Theory of 'Shaped-Charge'-II, Indian Natl. Sci. Acad. J, vol.2, issue.2, 1955. ,
Analysis of Post Detonation Products of Different Explosive Charges, Propellants Explos. Pyrotech, issue.24, pp.182-188, 1999. ,
Equation of state for high explosives detonation products with explicit polar and ionic species, 2006. ,
On the Mechanism of Efficiency of Lead Azide, Propellants Explos. Pyrotech, 2016. ,
Properties of selected high explosives, pp.13-17, 1992. ,
, , 2008.
A review on fulminating gold, Gold Bull, vol.41, issue.4, pp.305-317, 2008. ,
The urban rise and fall of air lead (Pb) and the latent surge and retreat of societal violence, Environ. Int, vol.43, pp.48-55, 2012. ,
Engineering Design Handbookexplosives Series Properties Of Explosives Of Military Interest, 1971. ,
Primary Explosives, 2013. ,
The chemistry of explosives, 2011. ,
, High Energy Materials, 2010.
Analysis of cobalt based explosives by capillary electrophoresis, J. Energ. Mater, vol.15, pp.125-137, 1997. ,
, Explosives, 2012.
Energetic co-ordination compounds: synthesis, characterization and thermolysis studies on bis-(5-nitro-2H-tetrazolatoN2)tetraammine cobalt(III) perchlorate (BNCP) and its new transition metal (Ni/Cu/Zn) perchlorate analogues, J. Hazard. Mater, vol.120, issue.1-3, pp.25-35, 2005. ,
Encyclopedia of explosives and related items volume, vol.6, 1974. ,
Laser ignition of energetic materials, 2015. ,
, Engineering Design Handbook Explosive Trains. United States Army Materiel Command, 1974.
Comparison of Performance of Fast-reacting Nanothermites and Primary Explosives, Propellants Explos. Pyrotech, 2017. ,
Initiation and detonation in lead azide and silver azide at sub-millimeter geometries, 2006. ,
, Explosives Engineering, 1996.
Verfahre zur Darstellung eines Nitrokörpers aus Hexamethylentetramin, 104280. ,
Polymorph of hexahydro-1, 3, 5trinitro-s-triazine. A Fourier transform infrared spectroscopy study of an energetic material, Ind. Eng. Chem. Prod. Res. Dev, vol.22, issue.2, pp.363-365, 1983. ,
, norme française NF T70-500
, norme française NF T70-503
, Deutsches Reichspatent, vol.81, p.1894
, NEW DRUGS, Can. Med. Assoc. J, vol.80, issue.12, p.997, 1959.
A New Method of Preparing the High Explosive RDX, J. Am. Chem. Soc, vol.5, issue.71, pp.1842-1845, 1949. ,
,
Dosage du polymorphisme: spectrométrie IRTF et chimiométrie Application aux formes polymorphes du CL20 (Hexaazahexanitroisowurtzitane/HNIW), 2003. ,
, Energetic materials: particle processing and characterization, 2005.
Notiz uber Triiiitrotoluol, Ann. Chem. Pharm, issue.128, pp.178-179, 1863. ,
Ballistic properties and burning behaviour of an ammonium perchlorate/guanidine nitrate/sodium nitrate airbag solid propellant, Fuel, vol.85, pp.1979-1986, 2006. ,
, Advances in high energy materials, vol.60, p.137, 2010.
Indirect ignition of energetic materials with laser-driven flyer plates, Appl. Opt, vol.56, issue.3, p.134, 2017. ,
, Energetic Materials Encyclopedia, 2018.
, Cover Picture: (Prop, vol.42, pp.457-571, 2017.
A new kind of detonator-the slapper, 1976. ,
Exploding Foil Initiator (EFI) Modes of Operation Determined Using Down-Barrel Flyer Layer Velocity Measurement, Propellants Explos. Pyrotech, vol.42, issue.3, pp.318-328, 2017. ,
Two-stage optical detonator with shock-detonation transition, vol.6, 2002. ,
Control of the Functioning Time of an all Secondary Laser Ignited Detonator, 2011. ,
Combustion confinée d'explosif condensé pour l'accélaration de projectile, 2014. ,
High Safety and Reliability Electric Detonator, Propellants Explos. Pyrotech, vol.41, issue.5, pp.870-874, 2016. ,
Flying plate detonator, Propellants Explos. Pyrotech, vol.21, issue.3, pp.134-138, 1996. ,
All-Secondary Explosive Flying-Plate Detonators, 1982. ,
Nanothermite/RDX-Based Miniature Device for Impact Ignition of High Explosives, Propellants Explos. Pyrotech, vol.42, issue.3, pp.308-317, 2017. ,
Control of the Functioning Time of an all Secondary Laser, 2011. ,
Electric detonators: EBW and EFI, Propellants Explos. Pyrotech, vol.21, issue.3, pp.150-154, 1996. ,
Conception et développement d'un micro détonateur électrique intégrant des nanothermites pour l'amorçage par impact d'explosifs secondaires, 2017. ,
Development of exploding foil initiators for future IM, 2007 Insensitive Munitions & Energetic Materials Technology Symposium (IMEMTS):" New Programs, New Policies, New Strategies leading to New Joint Solutions, vol.9, pp.15-18, 2007. ,
Critical parameters for detonation propagation and initiation of solid explosives, DTIC Document, 1981. ,
Convective combustion modeling applied to deflagration-to-detonation transition of HMX, Combust. Flame, vol.30, pp.231-241, 1977. ,
814. The burning to detonation of solid explosives, J. Chem. Soc. Resumed, pp.4154-4162, 1960. ,
Deflagration-to-detonation transition in granular HMX, Proc. 1980 JANNAF Propulsion System Hazards Meeting, vol.105, 1980. ,
An Experimental Study of the DeflagrationTo-Detonation Transition in Granular Secondary Explosives, Proc. R. Soc. Math. Phys. Eng. Sci, vol.448, pp.439-448, 1934. ,
Transition from Deflagration to Detonation in Cast Explosives, J. Chem. Phys, vol.31, issue.1, pp.162-167, 1959. ,
On the transition to explosion of the burning of explosives, Combust. Flame, vol.7, pp.175-183, 1963. ,
Transition from combustion to detonation in porous explosives, Combust. Explos. Shock Waves, vol.5, issue.3, pp.216-222, 1969. ,
Minimum propagation diameter and thickness of high explosives, J. Loss Prev. Process Ind, vol.20, issue.4-6, pp.578-583, 2007. ,
Method for the Determination of the Critical Diameter of High Velocity Detonation by conical geometry, Propellants Explos. Pyrotech, vol.17, issue.2, pp.77-81, 1992. ,
Determination of the Critical Diameter of Explosive Materials, ARS J, vol.32, issue.7, pp.1060-1065, 1962. ,
The initiation of solid explosives by shock waves, Symposium (International) on Combustion, vol.8, pp.842-847, 1961. ,
Studies in the transition from deflagration to detonation in granular explosives-III. Proposed mechanisms for transition and comparison with other proposals in the literature, Combust. Flame, vol.22, issue.2, pp.161-170, 1974. ,
High-Temperature Shock Initiation of Explosives, 1978. ,
The Influence of Temperature in the Range from 77 k to 338 k on the Detonation Velocity of RDX/TNT 60/40, Propellants Explos. Pyrotech, vol.5, issue.4, pp.117-118, 1980. ,
Temperature-dependent Shock Initiation of CL-20-based High Explosives, 2017. ,
The effects of confinement and temperature on the shock sensitivity of solid explosives, 1998. ,
HotSpot Ignition Mechanisms for Explosives and Propellants, Philos. Trans. R. Soc. Math. Phys. Eng. Sci, vol.339, issue.1654, pp.269-283, 1992. ,
DOI : 10.1021/ar00023a002
Hot spot ignition mechanisms for explosives, Acc. Chem. Res, vol.25, issue.11, pp.489-496, 1992. ,
DOI : 10.1021/ar00023a002
The Period of Impact, the Time of Initiation and the Rate of Growth of the Explosion of Nitroglycerine, Proc. R. Soc. Math. Phys. Eng. Sci, vol.188, issue.1014, pp.311-329, 1947. ,
The role of cavities in the initiation and growth of explosion in liquids, Proc. R. Soc. Lond. A, pp.67-86, 1973. ,
Cavity Collapse in Energetic Materials, DTIC Document, 1986. ,
The temperature of a shock-collapsed cavity, Proc. R. Soc. Math. Phys. Eng. Sci, vol.459, pp.1851-1861, 2003. ,
Hot Spots on Rubbing Surfaces and the Detonation of Explosives by Friction, Proc. R. Soc. Math. Phys. Eng. Sci, vol.188, issue.1014, pp.329-349, 1947. ,
The Ignition of Primary Explosives by Electric Discharges, Proc. R. Soc. Math. Phys. Eng. Sci, vol.246, issue.1245, pp.189-196, 1958. ,
High-speed photographic study of the drop-weight impact response of ultrafine and conventional PETN and RDX, Combust. Flame, vol.130, issue.4, pp.298-306, 2002. ,
Initiation And Growth Of Explosion In Liquids And Solids, 1953. ,
Critical shock energy and shock and detonation parameters of an explosive, Def. Sci. J, vol.59, issue.4, p.436, 2009. ,
DOI : 10.14429/dsj.59.1543
, Nano-thermites, 2016.
A survey of combustible metals, thermites, and intermetallics for pyrotechnic applications, p.3018, 1996. ,
Method Of Producing Metals And Alloys, vol.578, p.1897 ,
Thermite reactions: their utilization in the synthesis and processing of materials, J. Mater. Sci, vol.28, issue.14, pp.3693-3708, 1993. ,
Chemical metallurgy: principles and practice, 2003. ,
Des thermites classiques aux composites interstitiels métastables, pp.20-25, 2006. ,
Safer energetic materials by a nanotechnological approach, Nanoscale, vol.3, issue.9, p.3534, 2011. ,
DOI : 10.1039/c1nr10292c
Melt dispersion versus diffusive oxidation mechanism for aluminum nanoparticles: Critical experiments and controlling parameters, Appl. Phys. Lett, vol.92, issue.1, p.11921, 2008. ,
Synthesis of WO3 nanoparticles for superthermites by the template method from silica spheres, Solid State Sci, vol.13, issue.5, pp.908-914, 2011. ,
Combustion velocities and propagation mechanisms of metastable interstitial composites, J. Appl. Phys, vol.98, issue.6, p.64903, 2005. ,
DOI : 10.1063/1.2058175
Combustion Wave Speeds of SolGelSynthesized Tungsten Trioxide and Nano-Aluminum: The Effect of Impurities on Flame Propagation, Energy Fuels, vol.20, issue.6, pp.2370-2376, 2006. ,
Combined Flame and Electrodeposition Synthesis of Energetic Coaxial Tungsten-Oxide/Aluminum Nanowire Arrays, Nano Lett, vol.13, issue.9, pp.4346-4350, 2013. ,
Generation of fast propagating combustion and shock waves with copper oxide/aluminum nanothermite composites, Appl. Phys. Lett, vol.91, issue.24, p.243109, 2007. ,
Synthesis and performance of bismuth trioxide nanoparticles for high energy gas generator use, Nanotechnology, vol.20, issue.40, p.405609, 2009. ,
Synthesis and Reactivity of a SuperReactive Metastable Intermolecular Composite Formulation of Al/KMnO4, Adv. Mater, vol.17, issue.7, pp.900-903, 2005. ,
Encapsulation of Perchlorate Salts within Metal Oxides for Application as Nanoenergetic Oxidizers, Adv. Funct. Mater, vol.22, issue.1, pp.78-85, 2012. ,
Enhanced Propellant Combustion with Nanoparticles, Nano Lett, vol.3, issue.2, pp.253-255, 2003. ,
DOI : 10.1021/nl025905k
Super-reactive Nanoenergetic Gas Generators Based on Periodate Salts, Angew. Chem. Int. Ed, vol.52, issue.37, pp.9743-9746, 2013. ,
DOI : 10.1002/ange.201303545
Sulfates-Based Nanothermites: An Expanding Horizon for Metastable Interstitial Composites, Angew. Chem. Int. Ed, vol.54, issue.15, pp.4458-4462, 2015. ,
DOI : 10.1002/anie.201410634
Persulfate salt as an oxidizer for biocidal energetic nano-thermites, J Mater Chem A, vol.3, issue.22, pp.11838-11846, 2015. ,
DOI : 10.1039/c5ta00756a
, Shimizu-1986-11IPS_A CONCEPT AND THE USE OF NEGATIVE EXPLOSIVES.pdf
Nanothermite foams: From nanopowder to object, Chem. Eng. J, vol.316, pp.807-812, 2017. ,
Boron as Fuel for Ceramic Thermites, Energy Fuels, vol.28, issue.6, pp.4139-4148, 2014. ,
Combustion of Boron and Boron-Containing Reactive Composites in Laminar and Turbulent Air Flows, Combust. Sci. Technol, vol.189, issue.4, pp.683-697, 2017. ,
Preparation and Properties of BoronBased Nano-B/NiO Thermite, Propellants Explos. Pyrotech, vol.40, issue.6, pp.873-879, 2015. ,
Phosphorus-based nanothermites: A new generation of energetic materials, J. Phys. Chem. Solids, vol.71, issue.2, pp.64-68, 2010. ,
Phosphorus-Based Nanothermites: A New Generation of Pyrotechnics Illustrated by the Example of nCuO/Red P Mixtures, Propellants Explos. Pyrotech, vol.35, issue.3, pp.220-225, 2010. ,
Effect of Fe2O3 as an accelerator on the reaction mechanism of Al-TiO2 nanothermite system, J. Therm. Anal. Calorim, vol.117, issue.2, pp.711-719, 2014. ,
Kinetic analysis of thermite reaction in Al-Ti-Fe2O3 system to produce (Fe,Ti)3Al-Al2O3 nanocomposite, Powder Technol, vol.253, pp.553-560, 2014. ,
An Example Of Negative Explosives Magnesium Sulfatemagnesium Mixture," presented at the 15th International Pyrotechnics Seminar, 1990. ,
The influence of magnesium powder on the thermal behavior of Al-CuO thermite mixture, J. Therm. Anal. Calorim, 2017. ,
Thermite synthesis and characterization of CoZrO2ferromagnetic nanocomposite thin films, J. Alloys Compd, vol.665, pp.197-203, 2016. ,
Nanodiamond for tuning the properties of energetic composites, J. Hazard. Mater, vol.300, pp.194-201, 2015. ,
Lowpower laser ignition of aluminum/metal oxide nanothermites, Int. J. Energ. Mater. Chem. Propuls, vol.13, issue.6, 2014. ,
Energetic nanocomposites for detonation initiation in high explosives without primary explosives, Appl. Phys. Lett, vol.107, issue.24, p.243108, 2015. ,
Burn time of aluminum nanoparticles: Strong effect of the heating rate and melt-dispersion mechanism, Combust. Flame, vol.156, issue.2, pp.543-546, 2009. ,
Mechanochemical mechanism for fast reaction of metastable intermolecular composites based on dispersion of liquid metal, J. Appl. Phys, vol.101, issue.8, p.83524, 2007. ,
Melt-dispersion mechanism for fast reaction of aluminum particles: Extension for micron scale particles and fluorination, Appl. Phys. Lett, vol.92, issue.20, p.201917, 2008. ,
Toward design of the pre-stressed nano-and microscale aluminum particles covered by oxide shell, Combust. Flame, vol.158, issue.7, pp.1413-1417, 2011. ,
Combustion Behavior of Highly Energetic Thermites: Nano versus Micron Composites, Propellants Explos. Pyrotech, vol.30, issue.1, pp.53-62, 2005. ,
Laser ignition of nanocomposite thermites, Combust. Flame, vol.138, issue.4, pp.373-383, 2004. ,
Combustion wave speeds of nanocomposite Al/Fe2O3: the effects of Fe2O3 particle synthesis technique, Combust. Flame, vol.140, issue.4, pp.299-309, 2005. ,
Effects of fuel and oxidizer particle dimensions on the propagation of aluminum containing thermites, Proc. Combust. Inst, vol.33, issue.2, pp.1989-1996, 2011. ,
Solubilities of high explosives: removal of high explosive fillers from munitions by chemical dissolution, 1973. ,
Preparation of explosive nanoparticles in a porous chromium(III) oxide matrix: a first attempt to control the reactivity of explosives, Nanotechnology, vol.19, issue.28, p.285716, 2008. ,
Combustion characteristics of novel hybrid nanoenergetic formulations, Combust. Flame, vol.158, issue.5, pp.964-978, 2011. ,
Fast deflagration to detonation transition of energetic material based on a quasi-core/shell structured nanothermite composite, Compos. Sci. Technol, vol.107, pp.113-119, 2015. ,
Design, fabrication and modeling of solid propellant microrocket-application to micropropulsion, Sens. Actuators Phys, vol.99, issue.1, pp.125-133, 2002. ,
Design, fabrication and modelling of MEMS-based microthrusters for space application, Smart Mater. Struct, vol.10, issue.6, p.1156, 2001. ,
DOI : 10.1088/0964-1726/10/6/304
, REACH: substances préoccupantes (SVHC)
Adsorption of gases in multimolecular layers, Citation Classics), 1977. ,
Adsorption of gases in multimolecular layers, J. Am. Chem. Soc, vol.60, issue.2, pp.309-319, 1938. ,
, Nano-thermites, 2016.
Oxidation of detonation nanodiamonds in a reactive formulation, Diam. Relat. Mater, vol.47, pp.35-39, 2014. ,
Reactive characterization of nanothermites: Correlation structure/reactivity, J. Therm. Anal. Calorim, vol.111, issue.1, pp.431-436, 2013. ,
Reaction characteristics of Al/Fe2O3 nanocomposites, J. Ind. Eng. Chem, vol.18, issue.5, pp.1768-1773, 2012. ,
A survey of combustible metals, thermites, and intermetallics for pyrotechnic applications, 32nd Joint Propulsion Conference and Exhibit, p.3018, 1996. ,
, STANAG 4487 Explosive, Friction Sensitivity Tests, 2002.
, STANAG 4488 Explosives, Shock Sensitivity Tests, 2002.
, STANAG 4489 Explosives, Impact Sensitivity Tests, 1999.
, North Atlantic Treaty Organization, Electrostatic Discharge Sensitivity Test(S), 2001.
, Recommandations relatives au transport des marchandises dangereuses. Manuel d'épreuves et de critères, Nations Unies, Sixième édition révisée, 2015.
Safer energetic materials by a nanotechnological approach, Nanoscale, vol.3, issue.9, p.3534, 2011. ,
Nanoscale aluminum-metal oxide (thermite) reactions for application in energetic materials, Cent. Eur. J. Energ. Mater, vol.7, issue.2, pp.115-129, 2010. ,
Electrostatically Self-Assembled Nanocomposite Reactive Microspheres, ACS Appl. Mater. Interfaces, vol.1, issue.11, pp.2420-2423, 2009. ,
The effect of nanopowder attributes on reaction mechanism and ignition sensitivity of nanothermites, Materials Research Society Symposium Proceedings, vol.896, p.147, 2006. ,
Combustion of Nanoscale Al/MoO3 Thermite in Microchannels, J. Propuls. Power, vol.23, issue.4, pp.715-721, 2007. ,
Boron as Fuel for Ceramic Thermites, Energy Fuels, vol.28, issue.6, pp.4139-4148, 2014. ,
, explosifs moins sensibles que la pentrite. La principale piste d'étude est l'usage d'explosifs plus puissants, nanostructurés sous différentes formes
Plunkett's Nanotechnology & Mems Industry Almanac, 2006. ,
, CRC Handbook Of Chemistry and Physics, 2016.
Synthèse d'oxyde de tungstène à tailles ultimes en vue de l'élaboration et l'étude de la réactivité de composés nanothermites, 2010. ,
Sulfates-Based Nanothermites: An Expanding Horizon for Metastable Interstitial Composites, Angew. Chem. Int. Ed, vol.54, issue.15, pp.4458-4462, 2015. ,
Continuous formation of submicron energetic particles by the flashevaporation technique, Chem. Eng. J, vol.203, issue.0, pp.158-165, 2012. ,
URL : https://hal.archives-ouvertes.fr/hal-00778462
Continuous and reactive nanocrystallization: New concepts and processes for dual-use advances, Comptes Rendus Chim, vol.20, issue.4, pp.339-345, 2017. ,
, Recommandations relatives au transport des marchandises dangereuses. Manuel d'épreuves et de critères, Nations Unies, Sixième édition révisée, 2015.
Safer energetic materials by a nanotechnological approach, Nanoscale, vol.3, issue.9, p.3534, 2011. ,
Continuous engineering of nano-cocrystals for medical and energetic applications, Sci. Rep, vol.4, 2014. ,
Tunable continuous production of RDX from microns to nanoscale using polymeric additives, Chem. Eng. J, vol.291, pp.12-19, 2016. ,
Trinitrotoluene Nanostructuring by Spray Flash Evaporation Process, Propellants Explos. Pyrotech, 2017. ,
Dependence of flame propagation on pressure and pressurizing gas for an Al/CuO nanoscale thermite, Proc. Combust. Inst, vol.32, issue.2, pp.1895-1903, 2009. ,
Solubility of Pentaerythritol Tetranitrate, J. Phys. Chem, vol.62, issue.8, pp.1009-1011, 1958. ,
, Studies on the Polymorphs of HMX, vol.2652, 1962.
Solubilities of high explosives: removal of high explosive fillers from munitions by chemical dissolution, 1973. ,
, High Energy Materials, 2010.
Nanodiamond for tuning the properties of energetic composites, J. Hazard. Mater, vol.300, pp.194-201, 2015. ,
Generation of fast propagating combustion and shock waves with copper oxide/aluminum nanothermite composites, Appl. Phys. Lett, vol.91, issue.24, p.243109, 2007. ,
Laser ignition of nanocomposite thermites, Combust. Flame, vol.138, issue.4, pp.373-383, 2004. ,
Deflagration-to-detonation transition in granular HMX, Proc. 1980 JANNAF Propulsion System Hazards Meeting, vol.105, 1980. ,
Gaseous Detonations, 1987. ,
Detonation characteristics of hydrogen-Oxygen mixtures, A.1.Ch.E. Journal, pp.92-96, 1960. ,
An efficient purification method for detonation nanodiamonds, Diam. Relat. Mater, vol.17, issue.1, pp.13-22, 2008. ,
Oxidation of detonation nanodiamonds in a reactive formulation, Diam. Relat. Mater, vol.47, pp.35-39, 2014. ,
Initiation and detonation in lead azide and silver azide at sub-millimeter geometries, 2006. ,
Energetic nanocomposites for detonation initiation in high explosives without primary explosives, Appl. Phys. Lett, vol.107, issue.24, p.243108, 2015. ,
An Analysis of Small Scale Gap Test Sensitivity Data Using Porosity Theory and Nonreactive Shock Hugoniots, 1975. ,
Prediction of shock sensitivity of explosives based on small-scale gap test, J. Hazard. Mater, vol.145, issue.1-2, pp.109-112, 2007. ,
On the Mechanism of Efficiency of Lead Azide, Propellants Explos. Pyrotech, 2016. ,
The Bi-Ti (Bismuth-Titanium) System, Bull. Alloy Phase Diagr, vol.5, issue.6, pp.610-613, 1984. ,
Microstructure and tribological properties of TiAg intermetallic compound coating, Appl. Surf. Sci, vol.257, issue.24, pp.10692-10698, 2011. ,
Strength and microstructure of diffusion bonded titanium using silver and copper interlayers, Mater. Sci. Eng. A, vol.527, issue.20, pp.5189-5193, 2010. ,
Nanoscale aluminum-metal oxide (thermite) reactions for application in energetic materials, Cent. Eur. J. Energ. Mater, vol.7, issue.2, pp.115-129, 2010. ,
Persulfate salt as an oxidizer for biocidal energetic nano-thermites, J Mater Chem A, vol.3, issue.22, pp.11838-11846, 2015. ,
Synthesis and reactivity of nano-Ag2O as an oxidizer for energetic systems yielding antimicrobial products, Combust. Flame, vol.160, issue.2, pp.438-446, 2013. ,
,
,
,
,
, Procédés de préparation des mousses de nanothermite
,
,
,
,
, Analyses thermiques
,
Etude des mélanges métastables d'aluminium nanométrique avec les acides minéraux ,
Réaction de la poudre d'aluminium avec les acides minéraux communs ,
,
,
, Préparation et allumage des pâtes nano-Al/H2SO4
,
,
,
,
, aluminium et le phosphate d'aluminium. Echantillon Chaleur de réaction, p.2635
, Tableau 2 : Chaleur de réaction (J/g) de la mousse de thermite (F-NT), d'une nanothermite (n-Al/n-WO3) et d'un mélange 50
, Illustration schématique du mécanisme de réaction de l'aluminium nanométrique avec de l'acide sulfurique, Figure, vol.12
Combustion Wave Speeds of SolGelSynthesized Tungsten Trioxide and Nano-Aluminum: The Effect of Impurities on Flame Propagation, Energy Fuels, vol.20, issue.6, pp.2370-2376, 2006. ,
Nanostructured energetic materials using sol-gel methodologies, J. Non-Cryst. Solids, vol.285, issue.1, pp.338-345, 2001. ,
DOI : 10.1016/s0022-3093(01)00477-x
URL : https://digital.library.unt.edu/ark:/67531/metadc1413483/m2/1/high_res_d/15004111.pdf
Aerogels and Sol-Gel Composites as Nanostructured Energetic Materials, pp.585-606, 2011. ,
DOI : 10.1007/978-1-4419-7589-8_25
Use of Epoxides in the SolGel Synthesis of Porous Iron(III) Oxide Monoliths from Fe(III) Salts, Chem. Mater, vol.13, issue.3, pp.999-1007, 2001. ,
Electrospun Nanofiber-Based Thermite Textiles and their Reactive Properties, ACS Appl. Mater. Interfaces, vol.4, issue.12, pp.6432-6435, 2012. ,
DOI : 10.1021/am3021125
, Inorganic nanoparticles: synthesis, applications, and perspectives, 2010.
Effect of particle size on thermal decomposition of nitrocellulose, J. Hazard. Mater, vol.168, issue.2-3, pp.1134-1139, 2009. ,
Effect of nitrate content on thermal decomposition of nitrocellulose, J. Hazard. Mater, vol.162, issue.2-3, pp.1141-1144, 2009. ,
Processing and characterization of aluminum-based nanothermites, J. Therm. Anal. Calorim, vol.96, issue.3, pp.677-685, 2009. ,
A survey of combustible metals, thermites, and intermetallics for pyrotechnic applications, p.3018, 1996. ,
Passivation of the surface of aluminum nanopowders by protective coatings of the different chemical origin, Appl. Surf. Sci, vol.253, issue.12, pp.5558-5564, 2007. ,
Thermal stability and reaction properties of passivated Al/CuO nano-thermite, J. Phys. Chem. Solids, vol.72, issue.6, pp.620-625, 2011. ,
Assessment of Stability of Propellants and Safe Lifetimes, Propellants Explos. Pyrotech, vol.40, issue.3, pp.388-393, 2015. ,
, , 2008.
Hierarchical MnO 2 /SnO 2 Heterostructures for a Novel Free-Standing Ternary Thermite Membrane, Inorg. Chem, vol.52, issue.16, pp.9449-9455, 2013. ,
Nanowire Membrane-based Nanothermite: towards Processable and Tunable Interfacial Diffusion for Solid State Reactions, Sci. Rep, vol.3, issue.1, 2013. ,
Synthesis and Reactivity of a Super-Reactive Metastable Intermolecular Composite Formulation of Al/KMnO4, Adv. Mater, vol.17, issue.7, pp.900-903, 2005. ,
Encapsulation of Perchlorate Salts within Metal Oxides for Application as Nanoenergetic Oxidizers, Adv. Funct. Mater, vol.22, issue.1, pp.78-85, 2012. ,
Enhanced Propellant Combustion with Nanoparticles, Nano Lett, vol.3, issue.2, pp.253-255, 2003. ,
Super-reactive Nanoenergetic Gas Generators Based on Periodate Salts, Angew. Chem. Int. Ed, vol.52, issue.37, pp.9743-9746, 2013. ,
Sulfates-Based Nanothermites: An Expanding Horizon for Metastable Interstitial Composites, Angew. Chem. Int. Ed, vol.54, issue.15, pp.4458-4462, 2015. ,
Persulfate salt as an oxidizer for biocidal energetic nano-thermites, J Mater Chem A, vol.3, issue.22, pp.11838-11846, 2015. ,
A Concept And The Use Of Negative Explosives," presented at the 11th International Pyrotechnics Seminar, 1986. ,
Orthophosphates in the Ternary System AI2O3-P2O5-H20, Angew. Chem. Int. Ed. Engl, vol.25, issue.6, pp.525-534, 1986. ,
, Corrosion. Oxford, 1994.
Corrosion behaviour of 6063 aluminium alloy in acidic and in alkaline media, Arab. J. Chem, 2013. ,
Corrosion inhibition of Aluminum in 1 M phosphoric acid solutions using some Chalcones derivatives and synergistic action with halide ions, Afr. J. Pure Appl. Chem, vol.7, issue.12, pp.394-404, 2013. ,
Corrosion Inhibition of Aluminium in 2 M Phosphoric Acid Using the Essential Oil of Mentha Pulegium Leaves:," Port, Electrochimica Acta, vol.34, issue.1, pp.53-62, 2016. ,
Laser ignition of nanocomposite thermites, Combust. Flame, vol.138, issue.4, pp.373-383, 2004. ,
e-EROS Encyclopedia of Reagents for Organic Synthesis, 2001. ,
Polyphosphoric acid, Reag. Org. Synth, 2001. ,
Polyphosphoric acids as a reagent in organic chemistry, Chem. Rev, vol.58, issue.2, pp.321-401, 1958. ,
Phosphorus: an outline of its chemistry, biochemistry, and uses, 1995. ,
Modern Chemical Technology and Emission Control, 1985. ,
Etude de la solubilite du phosphate d'aluminium (AlPO4) dans des solutions hydrothermales d'acide orthophosphorique H3PO4, Mater. Res. Bull, vol.14, issue.5, pp.603-612, 1979. ,
Industrial scale nano-aluminum powder manufacturing, J. Pyrotech, vol.19, pp.19-31, 2004. ,
Structural changes and thermal properties of aluminium micro-and nano-powders, Acta Mater, vol.58, issue.12, pp.4224-4232, 2010. ,
URL : https://hal.archives-ouvertes.fr/hal-00989250
, CRC Handbook of Chemistry and Physics, 2016.
Small particle melting of pure metals, Thin Solid Films, vol.144, issue.2, pp.297-308, 1986. ,
Size-dependent melting properties of small tin particles: nanocalorimetric measurements, Phys. Rev. Lett, vol.77, issue.1, p.99, 1996. ,
The melting behavior of aluminum nanoparticles, Thermochim. Acta, vol.463, issue.1-2, pp.32-40, 2007. ,
Pressure-induced superheating of Al nanoparticles encapsulated in Al2O3 shells without epitaxial interface, Acta Mater, vol.53, issue.4, pp.1059-1066, 2005. ,
The Effect of Added Al2O3 on the Propagation Behavior of an Al/CuO Nanoscale Thermite, Combust. Sci. Technol, vol.180, issue.7, pp.1278-1294, 2008. ,
The thermal decomposition of anhydrous nitric acid vapour, J. Chem. Technol. Biotechnol, vol.3, issue.7, pp.318-322, 1953. ,
Bretherick's handbook of reactive chemical hazards: an indexed guide to published data, 1999. ,
Réactions chimiques dangereuses, INRS, INRS, ED, vol.697, 2003. ,
Aluminum nanopowder: A substance to be handled with care, J Hazard Mater, vol.342, pp.347-352, 2018. ,
Traité de chimie minérale "Aluminium, Masson et Cie, 1932. ,
A summary of hydrogen-air detonation experiments. Division of Systems Research, Office of Nuclear Regulatory Research, US Nuclear Regulatory Commission, 1989. ,
Minimum ignition energy of hydrogen-air mixture: Effects of humidity and spark duration, J. Electrost, vol.65, issue.2, pp.87-93, 2007. ,
Nanothermite foams: From nanopowder to object, Chem. Eng. J, vol.316, pp.807-812, 2017. ,
, En résumé, ce travail de thèse co-financé par la DGA (Direction Générale de l'Armement) et
,
Energetic nanocomposites for detonation initiation in high explosives without primary explosives, Appl. Phys. Lett, vol.107, issue.24, p.243108, 2015. ,
Nanothermite foams: From nanopowder to object, Chem. Eng. J, vol.316, pp.807-812, 2017. ,
Insights into combustion mechanisms of variable aluminum-based iron oxide/-hydroxide nanothermites, J. Vis. Exp. (XX), vol.342, issue.184, pp.347-352, 2017. ,
, « Nanothermites: a toolbox for solving contemporary challenges in pyrotechnics » M. Comet, pp.4-7, 2015.
, Dans différentes présentations d'axes réalisées à l'ISL
,
Réunion d'axe le 11/03/2015: High-performance nanothermites: landscape of possibilities ,
Réunion d'axe le 09/03/2016: Energetic nanocomposites for detonation initiation in high explosives without primary explosives ,
,
Spitzer Figure 4 : Diffractogramme de rayons X de la mousse de thermite, préparée par mélange de 3,45 g de nano-WO3 avec 3,00 g de nano-Al et 4,00 g de H3PO4 (85%) dilué avec 2, p.1150 ,