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Transitions vers des états électroniques complexes et des structures super périodiques dans les bronzes mono phosphates de tungstènes

Abstract : Conductive materials with low electronic dimensionality can present some transitions toward complex electronic states as superconductivity, Spin Density Waves (SDW) and Charge Density Waves (CDW). The coexistence of several of these instabilities in the same material leads to bustling investigations on new quasi-bidimensional conductors. In this thesis, we chose to study the MonoPhosphate Tungsten Bronzes with pentagonal channels family (MPTBp), of chemical formula (PO2)4(WO3)2m ; one of the main interests of this family is the possibility to directly control the compound’s dimensionality and its carriers density by varying m value (2 ≤ m ≤ 14). In the literature, it’s been shown that some MPTBp members (m=4, 5, 6) present successive CDW states whereas others (m=10) show ferroelectric-type orders. The aim of this thesis is thus to bring into light the effect of the material’s dimensionality on the appearance and the stability of these electronic states in the MPTBp family. In this way, transport measurements, X-Rays diffraction studies of the commensurate and incommensurate modulated structures below and above each transition and inelastic scattering measurements were done on several members with even value of m. In this work we reveal the existence of a CDW state for the m=2, 4, 6, 8 and 10 members, characterized by the formation of tungsten clusters in some areas of the crystal. For the m=8 and 10 members, the CDW is accompanied by a gradual installation of an anti-ferroelectric-like ordering of the tungsten atoms displacements. A CDW depinning phenomenon was observed for the quasi-unidimensional m=2 member, which has never been reported before in the MPTBp family. A strong electron-phonon coupling was evidenced for the high terms of the family (m ≥ 8) by structural analysis, first order resistive transitions observation and by X-Rays inelastic scattering measurements. For these high terms, an order-disorder transition must be considered.
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Submitted on : Thursday, December 6, 2018 - 9:26:10 AM
Last modification on : Thursday, December 12, 2019 - 3:11:20 AM
Long-term archiving on: : Thursday, March 7, 2019 - 1:11:44 PM


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  • HAL Id : tel-01941711, version 2


Elen Duverger-Nédellec. Transitions vers des états électroniques complexes et des structures super périodiques dans les bronzes mono phosphates de tungstènes. Physique [physics]. Normandie Université, 2017. Français. ⟨NNT : 2017NORMC239⟩. ⟨tel-01941711v2⟩



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