G. M. Whitesides and B. Grzybowski, Self-assembly at all scales, Science, vol.295, issue.5564, pp.2418-2421, 2002.

J. Lehn, Supramolecular chemistry-scope and perspectives molecules, supermolecules, and molecular devices (Nobel Lecture), Angewandte Chemie International Edition in English, vol.27, issue.1, pp.89-112, 1988.

D. B. Varshey, J. R. Sander, T. Fri??i?, and L. R. Macgillivray, Supramolecular Interactions, pp.9-24, 2012.

J. W. Steed and J. L. Atwood, Cation-binding hosts, Supramolecular Chemistry, pp.105-222, 2009.

V. A. Parsegian, Van der Waals forces : a handbook for biologists, chemists, engineers, and physicists, 2005.

E. Isaacs, A. Shukla, P. Platzman, D. Hamann, B. Barbiellini et al., Covalency of the hydrogen bond in ice : A direct X-ray measurement, Physical Review Letters, vol.82, issue.3, p.600, 1999.

M. Nishio, The CH/? hydrogen bond in chemistry. Conformation, supramolecules, optical resolution and interactions involving carbohydrates, Physical Chemistry Chemical Physics, vol.13, issue.31, pp.13873-13900, 2011.

J. A. Howard, F. H. Allen, and G. P. Shields, Implications of molecular and materials structure for new technologies, vol.360, 2012.

J. D. Watson and F. H. Crick, Molecular structure of nucleic acids, Nature, vol.171, issue.4356, pp.737-738, 1953.

P. J. Stang and B. Olenyuk, Self-assembly, symmetry, and molecular architecture : Coordination as the motif in the rational design of supramolecular metallacyclic polygons and polyhedra, Accounts of chemical research, vol.30, issue.12, pp.502-518, 1997.

K. Harris, D. Fujita, and M. Fujita, Giant hollow MnL 2n spherical complexes : structure, functionalisation and applications, Chemical Communications, vol.49, issue.60, pp.6703-6712, 2013.

D. Fujita, Y. Ueda, S. Sato, H. Yokoyama, N. Mizuno et al., Self-assembly of M 30 L 60 icosidodecahedron, Chem, vol.1, issue.1, pp.91-101, 2016.

D. Cao, M. Jurí?ek, Z. J. Brown, A. C. Sue, Z. Liu et al., Three-dimensional architectures incorporating stereoregular donor-acceptor stacks, Chemistry-A European Journal, vol.19, issue.26, pp.8457-8465, 2013.

H. Furukawa, K. E. Cordova, M. O'keeffe, and O. M. Yaghi, The chemistry and applications of metal-organic frameworks, Science, vol.341, issue.6149, p.1230444, 2013.

A. Dhakshinamoorthy, A. M. Asiri, and H. García, Metal-organic framework (MOF) compounds : Photocatalysts for redox reactions and solar fuel production, Angewandte Chemie International Edition, vol.55, issue.18, pp.5414-5445, 2016.

V. Berl, M. Schmutz, M. J. Krische, R. G. Khoury, and J. Lehn, Supramolecular polymers generated from heterocomplementary monomers linked through multiple hydrogen-bonding arrays-formation, characterization, and properties, Chemistry-A European Journal, vol.8, issue.5, pp.1227-1244, 2002.

R. Van-hameren, P. Schön, A. M. Van-buul, J. Hoogboom, S. V. Lazarenko et al., Macroscopic hierarchical surface patterning of porphyrin trimers via self-assembly and dewetting, Science, vol.314, issue.5804, pp.1433-1436, 2006.

R. Marty, R. Szilluweit, A. Sánchez-ferrer, S. Bolisetty, J. Adamcik et al., Hierarchically structured microfibers of "single stack" perylene bisimide and quaterthiophene nanowires, ACS nano, vol.7, issue.10, pp.8498-8508, 2013.

T. Aida, E. W. Meijer, and S. I. Stupp, Functional supramolecular polymers, Science, vol.335, issue.6070, pp.813-817, 2012.

N. Roy, B. Bruchmann, and J. Lehn, Dynamers : dynamic polymers as self-healing materials, Chem. Soc. Rev, vol.44, pp.3786-3807, 2015.

K. Balakrishnan, A. Datar, R. Oitker, H. Chen, J. Zuo et al., Nanobelt self-assembly from an organic n-type semiconductor : Propoxyethyl-PTCDI, Journal of the American Chemical Society, vol.127, issue.30, pp.10496-10497, 2005.

A. Ulman, An Introduction to Ultrathin Organic Films : From Langmuir-Blodgett to Self-Assembly, p.101, 1991.

K. B. Blodgett, Films built by depositing successive monomolecular layers on a solid surface, Journal of the American Chemical Society, vol.57, issue.6, pp.1007-1022, 1935.

K. Ariga, Y. Yamauchi, T. Mori, and J. P. Hill, 25th anniversary article : What can be done with the langmuirblodgett method ? recent developments and its critical role in materials science, Advanced Materials, vol.25, issue.45, pp.6477-6512, 2013.

C. Zhu, J. Shen, Z. Ma, S. Pang, A. Wang et al., Morphology of monolayer LB film by STM, Vacuum, vol.43, issue.11, pp.1111-1113, 1992.

G. Poirier, Coverage-dependent phases and phase stability of decanethiol on Au(111), Langmuir, vol.15, issue.4, pp.1167-1175, 1999.

R. G. Nuzzo and D. L. Allara, Adsorption of bifunctional organic disulfides on gold surfaces, Journal of the American Chemical Society, vol.105, issue.13, pp.4481-4483, 1983.

C. D. Bain, E. B. Troughton, Y. T. Tao, J. Evall, G. M. Whitesides et al., Formation of monolayer films by the spontaneous assembly of organic thiols from solution onto gold, Journal of the American Chemical Society, vol.111, issue.1, pp.321-335, 1989.

G. Binnig and H. Rohrer, Scanning tunneling microscopy, Surface science, vol.126, issue.1-3, pp.236-244, 1983.

G. Binnig, H. Rohrer, C. Gerber, and E. Weibel, Surface studies by scanning tunneling microscopy, Physical review letters, vol.49, issue.1, p.57, 1982.

T. Marangoni and D. Bonifazi, Nano-and microstructuration of supramolecular materials driven by h-bonded uracil· 2, 6-diamidopyridine complexes, Nanoscale, vol.5, issue.19, pp.8837-8851, 2013.

D. Écija, M. Marschall, J. Reichert, A. Kasperski, D. Nieckarz et al., Dynamics and thermal stability of surface-confined metal-organic chains, Surface Science, vol.643, pp.91-97, 2016.

D. Écija, K. Seufert, D. Heim, W. Auwärter, C. Aurisicchio et al., Hierarchic self-assembly of nanoporous chiral networks with conformationally flexible porphyrins, Acs Nano, vol.4, issue.8, pp.4936-4942, 2010.

Y. Chan, A. E. Schuckman, L. M. Perez, M. Vinodu, C. M. Drain et al., Synthesis and characterization of a thiol-tethered tripyridyl porphyrin on au (111), The Journal of Physical Chemistry C, vol.112, issue.15, pp.6110-6118, 2008.

F. L. Otte, S. Lemke, C. Schütt, N. R. Krekiehn, U. Jung et al., Ordered monolayers of free-standing porphyrins on gold, Journal of the American Chemical Society, vol.136, issue.32, pp.11248-11251, 2014.

M. Jurow, A. E. Schuckman, J. D. Batteas, and C. M. Drain, Porphyrins as molecular electronic components of functional devices, Coordination chemistry reviews, vol.254, issue.19, pp.2297-2310, 2010.

J. Otsuki, STM studies on porphyrins, Coordination Chemistry Reviews, vol.254, issue.19, pp.2311-2341, 2010.

S. Mohnani and D. Bonifazi, Supramolecular architectures of porphyrins on surfaces : The structural evolution from 1d to 2d to 3d to devices, Coordination Chemistry Reviews, vol.254, issue.19, pp.2342-2362, 2010.

J. M. Gottfried, Surface chemistry of porphyrins and phthalocyanines, Surface Science Reports, vol.70, issue.3, pp.259-379, 2015.

W. Auwärter, D. Écija, F. Klappenberger, and J. V. Barth, Porphyrins at interfaces, Nature chemistry, vol.7, issue.2, pp.105-120, 2015.

D. Heim, D. Écija, K. Seufert, W. Auwärter, C. Aurisicchio et al., Self-assembly of flexible one-dimensional coordination polymers on metal surfaces, Journal of the American Chemical Society, vol.132, issue.19, pp.6783-6790, 2010.

A. G. Slater, Y. Hu, L. Yang, S. P. Argent, W. Lewis et al., Thymine functionalised porphyrins, synthesis and heteromolecular surface-based self-assembly, Chemical Science, vol.6, issue.2, pp.1562-1569, 2015.

A. E. Schuckman, B. W. Ewers, L. H. Yu, J. P. Tomé, L. M. Pérez et al., Utilizing nearest-neighbor interactions to alter charge transport mechanisms in molecular assemblies of porphyrins on surfaces, The Journal of Physical Chemistry C, vol.119, issue.24, pp.13569-13579, 2015.

B. Baisch, D. Raffa, U. Jung, O. M. Magnussen, C. Nicolas et al., Mounting freestanding molecular functions onto surfaces : The platform approach, Journal of the American Chemical Society, vol.131, issue.2, pp.442-443, 2008.

P. Du, M. Jaouen, A. Bocheux, C. Bourgogne, Z. Han et al., Surface-confined self-assembled janus tectons : A versatile platform towards the noncovalent functionalization of graphene, Angewandte Chemie, vol.126, issue.38, pp.10224-10230, 2014.
URL : https://hal.archives-ouvertes.fr/hal-01369114

S. Le-liepvre, P. Du, D. Kreher, F. Mathevet, A. Attias et al., Fluorescent self-assembled molecular monolayer on graphene, ACS photonics, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01419546

S. Zhu, Y. Kuang, F. Geng, J. Zhu, C. Wang et al., Self-decoupled porphyrin with a tripodal anchor for molecular-scale electroluminescence, Journal of the American Chemical Society, vol.135, issue.42, pp.15794-15800, 2013.

J. Teyssandier, N. Battaglini, M. Seydou, G. Anquetin, B. Diawara et al., Elaboration of hydrogen-bonded 2d supramolecular assemblies on au (111) from solutions : toward naphthalene tetracarboxylic diimide-melamine nanoporous networks, The Journal of Physical Chemistry C, vol.117, issue.17, pp.8737-8745, 2013.

R. Madueno, M. T. Räisänen, C. Silien, and M. Buck, Functionalizing hydrogen-bonded surface networks with self-assembled monolayers, Nature, vol.454, issue.7204, pp.618-621, 2008.

S. Wieghold, J. Li, P. Simon, M. Krause, Y. Avlasevich et al., Photoresponse of supramolecular self-assembled networks on graphene-diamond interfaces, Nature Communications, vol.7, pp.2-8, 2016.

J. Teyssandier, Elaboration de réseaux supramoléculaires nanoporeux sur Au(111) par voie de solution : croissance dirigée et propriétés de nano-objets moléculaires et métalliques invités, 2012.

A. Saywell, G. Magnano, C. J. Satterley, L. M. Perdigão, A. J. Britton et al., Self-assembled aggregates formed by single-molecule magnets on a gold surface, Nature communications, vol.1, p.75, 2010.

P. E. Hartnett, A. Timalsina, H. R. Matte, N. Zhou, X. Guo et al., Slip-stacked perylenediimides as an alternative strategy for high efficiency nonfullerene acceptors in organic photovoltaics, Journal of the American Chemical Society, vol.136, issue.46, pp.16345-16356, 2014.

J. A. Theobald, N. S. Oxtoby, M. A. Phillips, N. R. Champness, and P. H. Beton, Controlling molecular deposition and layer structure with supramolecular surface assemblies, Nature, vol.424, issue.6952, pp.1029-1031, 2003.

U. Weber, V. Burlakov, L. Perdigao, R. Fawcett, P. Beton et al., Role of interaction anisotropy in the formation and stability of molecular templates, Physical review letters, vol.100, issue.15, p.156101, 2008.

C. Palma, M. Bonini, A. Llanes-pallas, T. Breiner, M. Prato et al., Pre-programmed bicomponent porous networks at the solid-liquid interface : the low concentration regime, Chemical Communications, issue.42, pp.5289-5291, 2008.

S. D. Feyter, F. C. De, and . Schryver, Two-dimensional supramolecular self-assembly probed by scanning tunneling microscopy, Chemical Society Reviews, vol.32, issue.3, pp.139-150, 2003.

T. Kudernac, S. Lei, J. A. Elemans, and S. D. Feyter, Two-dimensional supramolecular self-assembly : nanoporous networks on surfaces, Chemical Society Reviews, vol.38, issue.2, pp.402-421, 2009.

D. Bonifazi, S. Mohnani, and A. Llanes-pallas, Supramolecular chemistry at interfaces : molecular recognition on nanopatterned porous surfaces, Chemistry-A European Journal, vol.15, issue.29, pp.7004-7025, 2009.

J. W. Colson and W. R. Dichtel, Rationally synthesized two-dimensional polymers, Nature chemistry, vol.5, issue.6, pp.453-465, 2013.

S. Clair, M. Abel, and L. Porte, Growth of boronic acid based two-dimensional covalent networks on a metal surface under ultrahigh vacuum, Chemical Communications, vol.50, issue.68, pp.9627-9635, 2014.
URL : https://hal.archives-ouvertes.fr/hal-01896215

S. Günes, H. Neugebauer, and N. S. Sariciftci, Conjugated polymer-based organic solar cells, Chemical reviews, vol.107, issue.4, pp.1324-1338, 2007.

L. Xu, L. Yang, and S. Lei, Self-assembly of conjugated oligomers and polymers at the interface : structure and properties, Nanoscale, vol.4, issue.15, pp.4399-4415, 2012.

E. Mena-osteritz, A. Meyer, B. M. Langeveld-voss, R. A. Janssen, E. Meijer et al., Two-dimensional crystals of poly (3-alkyl-thiophene) s : Direct visualization of polymer folds in submolecular resolution, Angewandte Chemie, vol.112, issue.15, pp.2791-2796, 2000.

D. Écija, R. Otero, L. Sánchez, J. M. Gallego, Y. Wang et al., Crossover site-selectivity in the adsorption of the fullerene derivative pcbm on Au, vol.46, pp.7874-7877, 2007.

W. Li, Y. Du, H. Zhang, G. Chen, C. Sheng et al., Fullerene-derivative PC 61 BM forms three types of phase-pure monolayer on the surface of Au, vol.654, pp.8-13, 2016.

E. Mena-osteritz and P. Bäuerle, Complexation of C60 on a cyclothiophene monolayer template, Advanced Materials, vol.18, pp.447-451, 2006.

H. Cao, M. Van-den-eede, G. Koeckelberghs, K. S. Mali, and S. D. Feyter, Direct observation of the influence of chirality on the microstructure of regioregular poly(3-alkylthiophene)s at the liquid/solid interface, Chemical Communications, 2016.

B. Grévin, P. Rannou, R. Payerne, A. Pron, and J. Travers, Scanning tunneling microscopy investigations of selforganized poly (3-hexylthiophene) two-dimensional polycrystals, Advanced Materials, vol.15, issue.11, pp.881-884, 2003.

M. Akai-kasaya, K. Shimizu, Y. Watanabe, A. Saito, M. Aono et al., Electronic structure of a polydiacetylene nanowire fabricated on highly ordered pyrolytic graphite, Physical review letters, vol.91, issue.25, p.255501, 2003.

H. Sakaguchi, H. Matsumura, and H. Gong, Electrochemical epitaxial polymerization of single-molecular wires, Nature materials, vol.3, issue.8, pp.551-557, 2004.

H. Sakaguchi, H. Matsumura, H. Gong, and A. M. Abouelwafa, Direct visualization of the formation of singlemolecule conjugated copolymers, Science, vol.310, issue.5750, pp.1002-1006, 2005.

L. Scifo, M. Dubois, M. Brun, P. Rannou, S. Latil et al., Probing the electronic properties of self-organized poly (3-dodecylthiophene) monolayers by two-dimensional scanning tunneling spectroscopy imaging at the single chain scale, Nano letters, vol.6, issue.8, pp.1711-1718, 2006.

Y. Liu, K. Krug, and Y. Lee, Self-organization of two-dimensional poly (3-hexylthiophene) crystals on Au(111) surfaces, Nanoscale, vol.5, issue.17, pp.7936-7941, 2013.

Y. Terada, K. Miki, M. Fujimori, S. Heike, Y. Suwa et al., Electronic structure of a polymer nanowire on H-terminated Si(100), Journal of applied physics, vol.97, issue.12, p.4302, 2005.

L. Sánchez, R. Otero, J. M. Gallego, R. Miranda, and N. Martín, Ordering fullerenes at the nanometer scale on solid surfaces, Chemical reviews, vol.109, issue.5, pp.2081-2091, 2009.

T. M. Clarke and J. R. Durrant, Charge photogeneration in organic solar cells, Chemical reviews, vol.110, issue.11, pp.6736-6767, 2010.

L. Zhang, X. Zhong, E. Pavlica, S. Li, A. Klekachev et al., A nanomesh scaffold for supramolecular nanowire optoelectronic devices, Nature Nanotechnology, 2016.

E. Varene, L. Bogner, C. Bronner, and P. Tegeder, Ultrafast exciton population, relaxation, and decay dynamics in thin oligothiophene films, Physical review letters, vol.109, issue.20, p.207601, 2012.

R. Abbel, C. Grenier, M. J. Pouderoijen, J. W. Stouwdam, P. E. Leclere et al., White-light emitting hydrogen-bonded supramolecular copolymers based on ?-conjugated oligomers, Journal of the American Chemical Society, vol.131, issue.2, pp.833-843, 2008.

D. A. Bonnell, D. Basov, M. Bode, U. Diebold, S. V. Kalinin et al., Imaging physical phenomena with local probes : From electrons to photons, Reviews of Modern Physics, vol.84, issue.3, p.1343, 2012.
DOI : 10.1103/revmodphys.84.1343

M. C. Chong, L. Sosa-vargas, H. Bulou, A. Boeglin, F. Scheurer et al., Ordinary and hot electroluminescence from single-molecule devices : Controlling the emission color by chemical engineering, Nano Letters, vol.16, issue.10, pp.6480-6484, 2016.
DOI : 10.1021/acs.nanolett.6b02997
URL : https://hal.archives-ouvertes.fr/hal-01719561

Z. Dong, X. Zhang, H. Gao, Y. Luo, C. Zhang et al., Generation of molecular hot electroluminescence by resonant nanocavity plasmons, Nature Photonics, vol.4, issue.1, pp.50-54, 2010.
DOI : 10.1038/nphoton.2009.257

H. Imada, K. Miwa, M. Imai-imada, S. Kawahara, K. Kimura et al., Real-space investigation of energy transfer in heterogeneous molecular dimers, Nature, vol.538, issue.7625, pp.364-367, 2016.

Y. Tsai, K. Tseng, Y. Chen, C. Wu, G. Fan et al., Electroluminescence from spontaneously generated single-vesicle aggregates using solution-processed small organic molecules, ACS nano, vol.10, issue.1, pp.998-1006, 2016.
DOI : 10.1021/acsnano.5b06261
URL : https://hal.archives-ouvertes.fr/hal-01729075

R. Zhang, Y. Zhang, Z. Dong, S. Jiang, C. Zhang et al., Chemical mapping of a single molecule by plasmon-enhanced raman scattering, Nature, vol.498, issue.7452, pp.82-86, 2013.

S. Jiang, Y. Zhang, R. Zhang, C. Hu, M. Liao et al., Distinguishing adjacent molecules on a surface using plasmon-enhanced raman scattering, Nature nanotechnology, 2015.

N. M. Amer, A. Skumanich, and D. Ripple, Photothermal modulation of the gap distance in scanning tunneling microscopy, Applied physics letters, vol.49, issue.3, pp.137-139, 1986.

S. Grafström, Photoassisted scanning tunneling microscopy, Journal of applied physics, vol.91, issue.4, pp.1717-1753, 2002.

O. Probst, S. Dey, J. Fritz, S. Grafström, T. Hagen et al., Laser-assisted scanning tunneling microscopy studies of thin ordered molecular layers, Photons and Local Probes, pp.269-274, 1995.
DOI : 10.1007/978-94-011-0423-4_23

D. Smith and R. Owens, Laser-assisted scanning tunnelling microscope detection of a molecular adsorbate, Applied Physics Letters, vol.76, issue.25, pp.3825-3827, 2000.

I. V. Pechenezhskiy, X. Hong, G. D. Nguyen, J. E. Dahl, R. M. Carlson et al., Infrared spectroscopy of molecular submonolayers on surfaces by infrared scanning tunneling microscopy, Physical review letters, vol.111, issue.111, p.126101, 2013.
DOI : 10.1103/physrevlett.111.126101

S. Grafström, P. Schuller, J. Kowalski, and R. Neumann, Investigation of laser-induced effects in molecular layers by scanning tunneling microscopy, Applied Physics A : Materials Science & Processing, vol.66, pp.1237-1240, 1998.

L. Nienhaus, J. J. Goings, D. Nguyen, S. Wieghold, J. W. Lyding et al., Imaging excited orbitals of quantum dots : Experiment and electronic structure theory, Journal of the American Chemical Society, vol.137, issue.46, pp.14743-14750, 2015.
DOI : 10.1021/jacs.5b09272

J. B. Ballard, E. S. Carmichael, D. Shi, J. W. Lyding, and M. Gruebele, Laser absorption scanning tunneling microscopy of carbon nanotubes, Nano letters, vol.6, issue.1, pp.45-49, 2006.
DOI : 10.1021/nl0519231

G. Scott, S. Ashtekar, J. Lyding, and M. Gruebele, Direct imaging of room temperature optical absorption with subnanometer spatial resolution, Nano letters, vol.10, issue.12, pp.4897-4900, 2010.

D. Fichou, F. Charra, and A. O. Gusev, Nanoscale STM detection of photocurrents in organic semiconductors, Advanced materials, vol.13, issue.8, 2001.

S. Wu, N. Ogawa, and W. Ho, Atomic-scale coupling of photons to single-molecule junctions, Science, vol.312, issue.5778, pp.1362-1365, 2006.
DOI : 10.1126/science.1124881

S. Grafström, J. Kowalski, R. Neumann, O. Probst, and M. Wörtge, Analysis and compensation of thermal effects in laser-assisted scanning tunneling microscopy, Journal of Vacuum Science & Technology B, vol.9, issue.2, pp.568-572, 1991.

S. Grafström, P. Schuller, J. Kowalski, and R. Neumann, Thermal expansion of scanning tunneling microscopy tips under laser illumination, Journal of applied physics, vol.83, issue.7, pp.3453-3460, 1998.

J. Jersch, F. Demming, I. Fedotov, and K. Dickmann, Time-resolved current response of a nanosecond laser pulse illuminated STM tip, Applied Physics A, vol.68, issue.6, pp.637-641, 1999.

S. M. Landi, A. V. Bragas, J. A. Coy, and O. E. Martínez, Avoiding photothermal noise in laser assisted scanning tunneling microscopy, Ultramicroscopy, vol.77, issue.3, pp.207-211, 1999.

A. Bragas, S. Landi, J. Coy, and O. Martínez, Spectroscopic response of photoinduced currents in a laser-assisted scanning tunneling microscope, Journal of applied physics, vol.82, issue.9, pp.4153-4158, 1997.

S. M. Landi and O. E. Mart?nez, Quenching the thermal contribution in laser assisted scanning tunneling microscopy, Journal of Applied Physics, vol.88, issue.8, pp.4840-4844, 2000.

R. Möller, U. Albrecht, J. Boneberg, B. Koslowski, P. Leiderer et al., Detection of surface plasmons by scanning tunneling microscopy, Journal of Vacuum Science & Technology B, vol.9, issue.2, pp.506-509, 1991.

M. Lenner, P. Rácz, P. Dombi, G. Farkas, and N. Kroó, Field enhancement and rectification of surface plasmons detected by scanning tunneling microscopy, Physical Review B, vol.83, issue.20, p.205428, 2011.

T. L. Cocker, V. Jelic, M. Gupta, S. J. Molesky, J. A. Burgess et al., An ultrafast terahertz scanning tunnelling microscope, Nature Photonics, vol.7, issue.8, pp.620-625, 2013.

J. Weaver, L. Walpita, and H. Wickramasinghe, Optical absorption microscopy and spectroscopy with nanometre resolution, Nature, vol.342, issue.6251, pp.783-785, 1989.

C. C. Williams and H. Wickramasinghe, Microscopy of chemical-potential variations on an atomic scale, Nature, vol.344, issue.6264, pp.317-319, 1990.

A. Rettenberger, C. Baur, K. Läuger, D. Hoffmann, J. Grand et al., Variation of the thermovoltage across a vacuum tunneling barrier : Copper islands on Ag, vol.67, pp.1217-1219, 1995.

J. Park, G. He, R. M. Feenstra, and A. Li, Atomic-scale mapping of thermoelectric power on graphene : Role of defects and boundaries, Nano letters, vol.13, issue.7, pp.3269-3273, 2013.

G. Van-de-walle, H. Van-kempen, P. Wyder, and P. Davidsson, Scanning tunneling microscopy on photoconductive semi-insulating GaAs, Applied Physics Letters, vol.50, issue.1, pp.22-24, 1987.

O. Takeuchi, S. Yoshida, and H. Shigekawa, Light-modulated scanning tunneling spectroscopy for nanoscale imaging of surface photovoltage, Applied physics letters, vol.84, issue.18, pp.3645-3647, 2004.

S. Yoshida, Y. Kanitani, R. Oshima, Y. Okada, O. Takeuchi et al., Nanoscale mapping of built-in potential in gaas p-n junction using light-modulated scanning tunneling microscopy, Japanese Journal of Applied Physics, vol.47, issue.7S2, p.6117, 2008.

K. Sell, I. Barke, S. Polei, C. Schumann, V. Von-oeynhausen et al., Surface photovoltage of Ag nanoparticles and au chains on Si(111)," physica status solidi (b), vol.247, pp.1087-1094, 2010.

V. Jacobsen, W. Knoll, M. Kreiter, M. Dürr, A. Yasuda et al., Photoassisted spatially resolved stm measurements of dye-sensitized nanocrystalline tio 2 films, Physical Review B, vol.75, issue.16, p.165325, 2007.

Y. Terada, S. Yoshida, O. Takeuchi, and H. Shigekawa, Real-space imaging of transient carrier dynamics by nanoscale pump-probe microscopy, Nature photonics, vol.4, issue.12, pp.869-874, 2010.

D. R. Lide, CRC handbook of chemistry and physics, vol.85, 2004.

X. Feng and M. O. Senge, An efficient synthesis of highly functionalized asymmetric porphyrins with organolithium reagents, Journal of the Chemical Society, Perkin Transactions, vol.1, issue.9, pp.1030-1038, 2001.

A. Tibaldi, Porphyrin based molecular modules : from synthesis to 2d self-organization, Master's thesis, 2014.

H. Lamrani, Etude des interactions intermoléculaires de type liaison hydrogène pour l'élaboration de réseaux supramoléculaires 2d et nanostructurés, Master's thesis, vol.7, 2015.

A. Lombana, C. Rinfray, F. Volatron, G. Izzet, N. Battaglini et al., Surface organization of polyoxometalate hybrids steered by a 2d supramolecular ptcdi/melamine network, The Journal of Physical Chemistry C, vol.120, issue.5, pp.2837-2845, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01664175

A. Bellec, C. Arrigoni, G. Schull, L. Douillard, C. Fiorini-debuisschert et al., Solution-growth kinetics and thermodynamics of nanoporous self-assembled molecular monolayers, The Journal of chemical physics, vol.134, issue.12, p.124702, 2011.
URL : https://hal.archives-ouvertes.fr/cea-01409138

E. Mattia and S. Otto, Supramolecular systems chemistry, Nature nanotechnology, vol.10, issue.2, pp.111-119, 2015.

S. Conti and M. Cecchini, Predicting molecular self-assembly at surfaces : a statistical thermodynamics and modeling approach, Physical Chemistry Chemical Physics, vol.18, issue.46, pp.31480-31493, 2016.

C. Xu, A. Wan, X. Gong, N. D. Bhupathiraju, J. D. Batteas et al., Reorganization of porphyrin nanoparticle morphology driven by surface energetics, Journal of Porphyrins and Phthalocyanines, pp.1-6, 2016.

A. Otto, Excitation of nonradiative surface plasma waves in silver by the method of frustrated total reflection, Zeitschrift für Physik, vol.216, issue.4, pp.398-410, 1968.

E. Kretschmann and H. Raether, Notizen : radiative decay of non radiative surface plasmons excited by light, Zeitschrift für Naturforschung A, vol.23, issue.12, pp.2135-2136, 1968.

T. Buffeteau, B. Desbat, and J. Turlet, Polarization modulation ft-ir spectroscopy of surfaces and ultra-thin films : experimental procedure and quantitative analysis, Applied Spectroscopy, vol.45, issue.3, pp.380-389, 1991.
URL : https://hal.archives-ouvertes.fr/hal-01549519

C. J. Chen, Introduction to scanning tunneling microscopy, vol.2, 1993.

V. Mironov, Fundamentals of scanning probe microscopy, the textbook for students of the senior courses of higher educational institutions, the russian academy of sciences, Nizhniy Novgorod, 2004.

J. Tersoff and D. Hamann, Theory and application for the scanning tunneling microscope, Physical review letters, vol.50, issue.25, p.1998, 1983.

A. Selloni, P. Carnevali, E. Tosatti, and C. Chen, Voltage-dependent scanning-tunneling microscopy of a crystal surface : Graphite, Scanning Tunneling Microscopy, pp.168-171, 1985.

I. Horcas, R. Fernández, J. Gomez-rodriguez, J. Colchero, J. Gómez-herrero et al., WSxM : a software for scanning probe microscopy and a tool for nanotechnology, Review of Scientific Instruments, vol.78, issue.1, p.13705, 2007.

C. and L. Gouellec, Fabrication de pointes par attaque électrochimique, 2006.

J. Teyssandier, S. D. Feyter, and K. S. Mali, Host-guest chemistry in two-dimensional supramolecular networks, Chemical Communications, vol.52, issue.77, pp.11465-11487, 2016.

L. B. Josefsen and R. W. Boyle, Unique diagnostic and therapeutic roles of porphyrins and phthalocyanines in photodynamic therapy, imaging and theranostics, Theranostics, vol.2, issue.9, p.916, 2012.

M. Gouterman, A theory for the triplet-triplet absorption spectra of porphyrins, The journal of chemical physics, vol.33, issue.5, pp.1523-1529, 1960.

M. Gouterman, Spectra of porphyrins, Journal of Molecular Spectroscopy, vol.6, pp.138-163, 1961.

B. Murphy, S. Krasnikov, A. Cafolla, N. Sergeeva, N. Vinogradov et al., Growth and ordering of Ni(II) diphenylporphyrin monolayers on Ag(111) and Ag/Si(111) studied by STM and LEED, Journal of Physics : Condensed Matter, vol.24, issue.4, p.45005, 2012.

G. Rojas, X. Chen, C. Bravo, J. Kim, J. Kim et al., Self-assembly and properties of nonmetalated tetraphenyl-porphyrin on metal substrates, The Journal of Physical Chemistry C, vol.114, issue.20, pp.9408-9415, 2010.

K. Leung, S. B. Rempe, P. A. Schultz, E. M. Sproviero, V. S. Batista et al., Density functional theory and DFT+U study of transition metal porphines adsorbed on Au(111) surfaces and effects of applied electric fields, Journal of the American Chemical Society, vol.128, issue.11, pp.3659-3668, 2006.

M. Chen, X. Feng, L. Zhang, H. Ju, Q. Xu et al., Direct synthesis of nickel (II) tetraphenylporphyrin and its interaction with a Au(111) surface : a comprehensive study, The Journal of Physical Chemistry C, vol.114, issue.21, pp.9908-9916, 2010.

L. L. Shipman, T. M. Cotton, J. R. Norris, and J. J. Katz, An analysis of the visible absorption spectrum of chlorophyll a monomer, dimer, and oligomers in solution, Journal of the American Chemical Society, vol.98, issue.25, pp.8222-8230, 1976.

C. Chang, Stacked double-macrocyclic ligands iii. spectral properties of cofacial diporphyrins as a function of the inter-chromophore separation, Journal of Heterocyclic Chemistry, vol.14, issue.7, pp.1285-1288, 1977.

A. Mishra, R. K. Behera, P. K. Behera, B. K. Mishra, and G. B. Behera, Cyanines during the 1990s : a review, Chemical Reviews, vol.100, issue.6, pp.1973-2012, 2000.

M. Kasha, H. Rawls, and M. Ashraf-el-bayoumi, The exciton model in molecular spectroscopy, Pure and Applied Chemistry, vol.11, issue.3-4, pp.371-392, 1965.

J. Zimmermann, U. Siggel, J. Fuhrhop, and B. Röder, Excitonic coupling between B and Q transitions in a porphyrin aggregate, The Journal of Physical Chemistry B, vol.107, issue.25, pp.6019-6021, 2003.

J. O. Alben, S. Choi, A. D. Adler, and W. S. Caughey, Infrared spectroscopy of porphyrins, Annals of the New York Academy of Sciences, vol.206, issue.1, pp.278-295, 1973.

D. W. Thomas and A. E. Martell, Metal chelates of tetraphenylporphine and of some p-substituted derivatives1, 2, Journal of the American Chemical Society, vol.81, issue.19, pp.5111-5119, 1959.

J. Carneiro, Elaboration de réseaux nanoporeux sur surfaces métalliques ; propriétés électroactives de surfaces moléculaires organisées, 2013.

W. Xu, M. Dong, H. Gersen, E. Rauls, S. Vázquez-campos et al., Cyanuric acid and melamine on au (111) : Structure and energetics of hydrogenbonded networks, small, vol.3, issue.5, pp.854-858, 2007.

E. Hughes, The crystal structure of melamine, Journal of the American Chemical Society, vol.63, issue.6, pp.1737-1752, 1941.

A. Lombana, N. Battaglini, G. Tsague-kenfac, S. Zrig, and P. Lang, In-solution patterning of standing up porphyrin based nanostructures within hydrogen bonded porous networks-a structural effect of a host matrix on guest entities, Chemical Communications, vol.52, issue.33, pp.5742-5745, 2016.

W. Mizutani, T. Ishida, and H. Tokumoto, Lateral conduction model for intermolecular interaction of self-assembled monolayers, The Japanese Journal of Applied Physics, vol.38, issue.6B, pp.3892-3896, 1999.

C. Rinfray, Greffage de polyoxométallates hybrides, 2014.

M. T. Pope and A. Müller, Polyoxometalate chemistry : an old field with new dimensions in several disciplines, Angewandte Chemie International Edition in English, vol.30, issue.1, pp.34-48, 1991.

R. Thouvenot, M. Fournier, R. Franck, and C. Rocchiccioli-deltcheff, Vibrational investigations of polyoxometalates. 3. isomerism in molybdenum (vi) and tungsten (vi) compounds related to the keggin structure, Inorganic Chemistry, vol.23, issue.5, pp.598-605, 1984.

H. Grönbeck, A. Curioni, and W. Andreoni, Thiols and disulfides on the Au(111) surface : The headgroup-gold interaction, Journal of the American Chemical Society, vol.122, issue.16, pp.3839-3842, 2000.

C. D. Wagner and G. Muilenberg, Handbook of X-ray photoelectron spectroscopy. Perkin-Elmer, 1979.

A. Duwez, Exploiting electron spectroscopies to probe the structure and organization of self-assembled monolayers : a review, Journal of Electron Spectroscopy and Related Phenomena, vol.134, issue.2, pp.97-138, 2004.

A. Ulman, Formation and structure of self-assembled monolayers, Chemical reviews, vol.96, issue.4, pp.1533-1554, 1996.

S. Xu and G. Liu, Nanometer-scale fabrication by simultaneous nanoshaving and molecular self-assembly, Langmuir, vol.13, issue.2, pp.127-129, 1997.

N. Battaglini, Z. Qin, P. Campiglio, V. Repain, C. Chacon et al., Directed growth of mixed self-assembled monolayers on a nanostructured template : a step toward the patterning of functional molecular domains, Langmuir, vol.28, issue.42, pp.15095-15105, 2012.
URL : https://hal.archives-ouvertes.fr/hal-01987562

Y. Liang, Z. Xu, J. Xia, S. Tsai, Y. Wu et al., For the bright future?bulk heterojunction polymer solar cells with power conversion efficiency of 7.4%, Advanced Materials, vol.22, issue.20, pp.135-138, 2010.

W. Chen, T. Xu, F. He, W. Wang, C. Wang et al., Hierarchical nanomorphologies promote exciton dissociation in polymer/fullerene bulk heterojunction solar cells, Nano letters, vol.11, issue.9, pp.3707-3713, 2011.

X. Yang and J. Loos, Toward high-performance polymer solar cells : the importance of morphology control, Macromolecules, vol.40, issue.5, pp.1353-1362, 2007.

M. Williams, N. R. Tummala, S. G. Aziz, C. Risko, and J. Brédas, Influence of molecular shape on solid-state packing in disordered PC61BM and PC71BM fullerenes, The journal of physical chemistry letters, vol.5, issue.19, pp.3427-3433, 2014.

W. Liang, Excitons, Physics Education, vol.5, issue.4, p.226, 1970.

P. E. Shaw, A. Ruseckas, and I. D. Samuel, Exciton diffusion measurements in poly (3-hexylthiophene), Advanced Materials, vol.20, issue.18, pp.3516-3520, 2008.

Z. He, C. Zhong, S. Su, M. Xu, H. Wu et al., Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure, Nature Photonics, vol.6, issue.9, pp.591-595, 2012.

P. Avouris and B. N. Persson, Excited states at metal surfaces and their non-radiative relaxation, The Journal of Physical Chemistry, vol.88, issue.5, pp.837-848, 1984.

J. Jersch, F. Demming, L. Hildenhagen, and K. Dickmann, Field enhancement of optical radiation in the nearfield of scanning probe microscope tips, Applied Physics A : Materials Science & Processing, vol.66, issue.1, pp.29-34, 1998.

A. Bragas, S. Landi, and O. Martínez, Laser field enhancement at the scanning tunneling microscope junction measured by optical rectification, Applied physics letters, vol.72, issue.17, pp.2075-2077, 1998.

O. J. Martin and C. Girard, Controlling and tuning strong optical field gradients at a local probe microscope tip apex, Applied Physics Letters, vol.70, issue.6, pp.705-707, 1997.

, What is a lock-in amplifier ?, 2000.

O. Probst, S. Grafström, J. Fritz, S. Dey, J. Kowalski et al., Contrast mechanisms in photothermal scanning tunneling microscopy, Applied Physics A, vol.59, issue.2, pp.109-113, 1994.

J. Jia, K. Inoue, Y. Hasegawa, W. Yang, and T. Sakurai, Variation of the local work function at steps on metal surfaces studied with STM, Physical Review B, vol.58, issue.3, p.1193, 1998.

P. Han, A. R. Kurland, A. N. Giordano, S. U. Nanayakkara, M. M. Blake et al., Heads and tails : simultaneous exposed and buried interface imaging of monolayers, ACS nano, vol.3, issue.10, pp.3115-3121, 2009.

J. D. Monnell, J. J. Stapleton, S. M. Dirk, W. A. Reinerth, J. M. Tour et al., Relative conductances of alkaneselenolate and alkanethiolate monolayers on au {111}, The Journal of Physical Chemistry B, vol.109, issue.43, pp.20343-20349, 2005.

J. C. Thomas, D. P. Goronzy, K. Dragomiretskiy, D. Zosso, J. Gilles et al., Mapping buried hydrogen-bonding networks, ACS nano, vol.10, issue.5, pp.5446-5451, 2016.

A. D. Raki?, A. B. Djuri?i?, J. M. Elazar, and M. L. Majewski, Optical properties of metallic films for verticalcavity optoelectronic devices, des logiciels de calcul des propriétés ont été créés, vol.37, issue.22, pp.5271-5283, 1998.

J. P. Tavener, Gold/platinum thermocouple and the DC measurement requirements, Isothermal Technology Limited, 2000.

A. Thon, M. Merschdorf, W. Pfeiffer, T. Klamroth, P. Saalfrank et al., Photon-assisted tunneling versus tunneling of excited electrons in metal-insulator-metal junctions, Applied Physics A, vol.78, issue.2, pp.189-199, 2004.

C. Marchiori and M. Koehler, Density functional theory study of the dipole across the p3ht : Pcbm complex : the role of polarization and charge transfer, Journal of Physics D : Applied Physics, vol.47, issue.21, p.215104, 2014.

S. Braun, W. R. Salaneck, and M. Fahlman, Energy-level alignment at organic/metal and organic/organic interfaces, Advanced Materials, vol.21, pp.1450-1472, 2009.

R. Sharma, H. Lee, V. Gupta, H. Kim, M. Kumar et al., Photo-physics of PTB7, PCBM and ICBA based ternary solar cells, Organic Electronics, vol.34, pp.111-117, 2016.

O. O. Adegoke, I. H. Jung, M. Orr, L. Yu, T. Goodson et al., Effect of acceptor strength on optical and electronic properties in conjugated polymers for solar applications, Journal of the American Chemical Society, vol.137, issue.17, pp.5759-5769, 2015.