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Design, synthesis and study of functional organometallic ruthenium complexes for dye-sensitized solar cells and photoelectrochemical cells

Abstract : The first part of the research project will consist in the synthesis and study of new chromophores based on the D-π-[M]-π-A model. At that stage, easy synthesis of symmetrical complexes including two [Ru(dppe)2] metal fragments will be envisaged to afford D-π-A-π-D architectures to be tested in n-type solar cells and p-type solar cells. Later on, as it has been demonstrated that electronic communication may occur through several Ru-based metal centres,the complexes length might be incremented by addition of multiple metal-organic units to create oligomeric structures with strong light-harvesting properties.
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Submitted on : Wednesday, October 17, 2018 - 9:40:09 AM
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Siliu Lyu. Design, synthesis and study of functional organometallic ruthenium complexes for dye-sensitized solar cells and photoelectrochemical cells. Organic chemistry. Université de Bordeaux, 2018. English. ⟨NNT : 2018BORD0095⟩. ⟨tel-01897324⟩

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