Skip to Main content Skip to Navigation

Topological states on surfaces and interfaces of perovskite transition metal oxides

Abstract : The subject of topology in oxides, in particular at the surfaces of perovskite oxides like SrTiO₃, or at the interface of LaA1O₃/SrTiO₃ will be investigated in this thesis. Both compounds, at their (001) oriented surfaces, contain a metallic state confined to a few nanometers at the surface. In addition, we will show that there exist certain three band crossings around which perturbations will cause an inverted and gapped band spectrum to appear. These will lead to topological edge states which can be detected via induced superconductivity as in the case of topological quantum wells or superconductor-semiconductor nanowires. Next, the (111) oriented surface of LaA1O₃/SrTiO₃ will be studied where Hall transport measurements reveal a one to two carrier transition via electrostatic doping. An explanation based on a tight binding modelling including Hubbard U correlations, will be proposed which will give rise to band crossings between sub-bands promoting topological states. Finally, an ab-initio study of CaTiO₃ will be performed to explain the metallic state which exists at its (001) oriented surface and to predict magnetism in the system. CaTiO₃ is different from the other compounds studied previously, due to the large rotation and tilting of the oxygen octahedra surrounding the Ti, which complicates the picture. The structure with and without oxygen vacancies will be studied in-depth to provide details about the conduction band and their orbital characters.
Complete list of metadatas

Cited literature [149 references]  Display  Hide  Download
Contributor : Abes Star :  Contact
Submitted on : Monday, October 8, 2018 - 12:57:06 PM
Last modification on : Wednesday, October 14, 2020 - 4:00:11 AM
Long-term archiving on: : Wednesday, January 9, 2019 - 2:19:17 PM


Version validated by the jury (STAR)


  • HAL Id : tel-01890133, version 1



Manali Vivek. Topological states on surfaces and interfaces of perovskite transition metal oxides. Materials Science [cond-mat.mtrl-sci]. Université Paris Saclay (COmUE), 2018. English. ⟨NNT : 2018SACLS216⟩. ⟨tel-01890133⟩



Record views


Files downloads