94 (C Ar -CH 2 -C Ar ), 126.95 (C Ar -CH 2 -C Ar ), Ar -CH 2 -C Ar ), 128.08 (C Ar -CH 2 -C Ar ), p.599770 ,
CDCl 3 ): 0.97 (s, 9? ,
Ar-CH 2 -Ar), Ar-CH 2 -Ar), p.61 ,
33 (C Ar -CH 2 -C Ar ), 130.47 (C Ar -CH 2 -C Ar, 130.88 (C Ar -CH 2 -C Ar ), 131.88 (C Ar -CH 2 -C Ar ), p.633150 ,
CDCl 3 ): 0.82 (s, 9H, t-Bu), 0.99 (s, 9H, p.3797 ,
18 (m, 6H, POCH 2 CH 3 ) 1.35 (s, 9H, 2H, OCH 2 CH 2 CH 3 ), 1.83 (d, 3H, 2 J HH = 7.0 Hz, CHCH 3 ), 3.27 (d, 1H (d, 1H, 2 J HH = 13.2 Hz, ArCH 2 Ar), 3.37 (d, 1H, 2 J HH = 13.8 Hz, ArCH 2 Ar), 3.75 (m, 2H, OCH 2 CH 2 CH 3 ), 4.00 (m, 4H, POCH 2 CH 3 Hz, ArCH 2 Ar), 4.32 (d, 1H, 2 J HH = 12.7 Hz, ArCH 2 Ar), 4.40 (d, 1H, 2 J HH = 13.1 Hz, ArCH 2 Ar), 4.43 (d, 1H, 2 J HH = 13.3 Hz, ArCH 2 Ar), p.75977935034148 ,
131.5 (d, J = 3.2 Hz, Ar C-CH 2 -C Ar ), 132.2 (d, J = 3.2 Hz, Ar C-CH 2 -C Ar ), Ar C-CH 2 -C Ar ) Ar C-CH 2 -C Ar ) ,
CD 3 OD): 0 ,
97 (s, 9H, t-Bu), 1.33 (s, 9H, t-Bu), 1.35 (s, 9H, p.5027 ,
131.5 (d, J = 3.2 Hz, Ar C-CH 2 -C Ar ), 132.2 (d, J = 3.2 Hz, Ar C-CH 2 -C Ar ), Ar C-CH 2 -C Ar ) Ar C-CH 2 -C Ar ) ,
143.0 (d, J = 8.9 Hz, Ar C-O-PO) ,
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La conversion est complète et un bon rendement est observé au bout de 24 heures, mais l'excès énantiomérique du 2-méthyl-1,1'-binaphtalène était très faible (moins de 5%) Contrairement aux attentes, les groupes hydroxyle libres sur le bord inférieur des ligands macrocycliques n ,