V. M. Mamaev, A. V. Prisyajnuk, D. N. Laikov, L. S. Logutenko, and Y. Babin, The mechanism of a diad prototropic rearrangement of hydrophosphorylic compounds, Mendeleev Communications, vol.9, issue.6, p.240, 1999.
DOI : 10.1070/MC1999v009n06ABEH001095

D. M. Roundhill, R. F. Sperline, and W. B. Beaulieu, Metal complexes of substituted phosphinites and secondary phosphites, Coordination Chemistry Reviews, vol.26, issue.3, p.263, 1978.
DOI : 10.1016/S0010-8545(00)80349-5

O. Korpiun and K. Mislow, New route to the preparation and configurational correlation of optically active phosphine oxides, Journal of the American Chemical Society, vol.89, issue.18, p.4784, 1967.
DOI : 10.1021/ja00994a037

S. Humbel, C. Bertrand, C. Darcel, C. Bauduin, and S. Jugé, Configurational Stability of Chlorophosphines, Inorganic Chemistry, vol.42, issue.2, p.420, 2003.
DOI : 10.1021/ic026128u
URL : https://hal.archives-ouvertes.fr/hal-01564785

R. R. Holmes, Comparison of Phosphorus and Silicon:?? Hypervalency, Stereochemistry, and Reactivity, Chemical Reviews, vol.96, issue.3, p.927, 1996.
DOI : 10.1021/cr950243n

V. E. Jennings, K. Nikitin, Y. Ortin, and G. D. Gilheany, Degenerate Nucleophilic Substitution in Phosphonium Salts, Journal of the American Chemical Society, vol.136, issue.46, p.16217, 2014.
DOI : 10.1021/ja507433g

M. A. Bochove, M. Van-;-swart, and F. M. Bickelhaupt, Stepwise walden inversion in nucleophilic substitution at phosphorus, Phys. Chem. Chem. Phys., vol.26, issue.2, p.259, 2009.
DOI : 10.1002/cber.18930260146

R. S. Cahn, C. Ingold, and V. Prelog, Specification of Molecular Chirality, Angewandte Chemie International Edition in English, vol.5, issue.4, p.385, 1966.
DOI : 10.1002/anie.196603851

P. Wang, Y. Zhang, R. Glaser, A. E. Reed, P. V. Schleyer et al., The effects of the first- and second-row substituents on the structures and energies of PH4X phosphoranes. An ab initio study, Journal of the American Chemical Society, vol.113, issue.1, p.55, 1991.
DOI : 10.1021/ja00001a011

J. Kobayashi and T. Kawashima, Comptes Rendus Chim, pp.8-9, 2010.

R. R. Holmes, A model for calculating conformational energies in pentacoordinate phosphorus compounds, Journal of the American Chemical Society, vol.100, issue.2, p.433, 1978.
DOI : 10.1021/ja00470a012

R. S. Berry, Correlation of Rates of Intramolecular Tunneling Processes, with Application to Some Group V Compounds, The Journal of Chemical Physics, vol.22, issue.3, p.933, 1960.
DOI : 10.1063/1.1698976

C. Daul, M. Frioud, O. Schafer, and A. Selloni, Non-empirical dynamical DFT calculation of the Berry pseudorotation of PF5, Chemical Physics Letters, vol.262, issue.1-2, p.74, 1996.
DOI : 10.1016/0009-2614(96)01056-1

W. Tang and X. Zhang, New Chiral Phosphorus Ligands for Enantioselective Hydrogenation, Chemical Reviews, vol.103, issue.8, p.3029, 2003.
DOI : 10.1021/cr020049i

D. Gatineau, J. Leclaire, and D. Nuel, Stereogenic Chiral Precursor of Chiral Ligands and Use Thereof, 2014.

E. Schrödinger, An Undulatory Theory of the Mechanics of Atoms and Molecules, Physical Review, vol.38, issue.6, p.1049, 1926.
DOI : 10.1007/BF01399113

W. Koch and M. C. Holthausen, A Chemist's Guide to Density Functional Theory, 2001.
DOI : 10.1002/3527600043

W. Kohn and L. Sham, Self-Consistent Equations Including Exchange and Correlation Effects, Physical Review, vol.119, issue.4A, p.1133, 1965.
DOI : 10.1103/PhysRev.119.1153

Y. Zhao and D. G. Truhlar, The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals, Theoretical Chemistry Accounts, vol.103, issue.1-3, p.215, 2008.
DOI : 10.1002/ijch.199300041

I. N. Levine, Quantum Chemistry: International Edition, 2007.

Y. Zhao, N. E. Schultz, and D. G. Truhlar, Design of Density Functionals by Combining the Method of Constraint Satisfaction with Parametrization for Thermochemistry, Thermochemical Kinetics, and Noncovalent Interactions, Journal of Chemical Theory and Computation, vol.2, issue.2, p.364, 2006.
DOI : 10.1021/ct0502763

J. Tomasi, B. Mennucci, and R. Cammi, Quantum Mechanical Continuum Solvation Models, Chemical Reviews, vol.105, issue.8, p.2999, 2005.
DOI : 10.1021/cr9904009

S. Zhang, J. Baker, and P. Pulay, Values. 1. Methodology, The Journal of Physical Chemistry A, vol.114, issue.1, pp.425-136, 2010.
DOI : 10.1021/jp9067069
URL : https://hal.archives-ouvertes.fr/hal-00000814

D. Lide, CRC Handbook of Chemistry and Physics, CRC, 1997.

I. M. Kolthoff, M. K. Chantooni, and S. Bhowmik, Dissociation constants of uncharged and monovalent cation acids in dimethyl sulfoxide, Journal of the American Chemical Society, vol.90, issue.1, p.23, 1968.
DOI : 10.1021/ja01003a005

L. Chmurzynski and Z. Warnke, Acid-Base Equilibria of Substituted Pyridine N-Oxides in N,N-Dimethylformamide and Dimethyl Sulfoxide, Australian Journal of Chemistry, vol.46, issue.2, p.185, 1993.
DOI : 10.1071/CH9930185

F. G. Bordwell, Equilibrium acidities in dimethyl sulfoxide solution, Accounts of Chemical Research, vol.21, issue.12, p.456, 1988.
DOI : 10.1021/ar00156a004

R. L. Benoit, D. Lefebvre, and M. Fréchette, Basicity of 1,8-bis(dimethylamino)naphthalene and 1,4-diazabicyclo[2.2.2]octane in water and dimethylsulfoxide, Canadian Journal of Chemistry, vol.65, issue.5, p.996, 1987.
DOI : 10.1139/v87-170

J. J. Stewart, Optimization of parameters for semiempirical methods V: Modification of NDDO approximations and application to 70 elements, Journal of Molecular Modeling, vol.73, issue.12, p.1173, 2007.
DOI : 10.1002/jcc.540141106

M. Cossi, N. Rega, G. Scalmani, and V. Barone, Energies, structures, and electronic properties of molecules in solution with the C-PCM solvation model, Journal of Computational Chemistry, vol.24, issue.6, p.669, 2003.
DOI : 10.1002/jcc.10189

A. Leyris, « Nouvelles méthodes en synthèse asymétrique d'oxydes de phosphines secondaires », thesis for a PhD in organic chemistry under the supervision of Buono G, p.151, 2008.