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, le pourcentage de variance exprimé pour la zone 1 (resp. zone 2) est de 98,7 % (resp. 98,6 %) et l'erreur d'estimation du modèle MCR-ALS est de 1,8 % (resp. 2,3 %)
, XRF) sert à qualifier ou quantifier la composition élémentaire des échantillons solides et liquides de manière non destructrice Le principe physique de la technique est basé sur l'interaction lumière-matière et peut être trouvé facilement dans des ouvrages comme [132]. Le seuil de détection de la XRF est bas et atteint les parties par million (ppm) ce qui permet d'être sous le seuil de détection du MEB-EDS
, Le faisceau de rayons X, de taille 4,2 x 4,1 ?m², est réglé à 4,1 keV (seuil du calcium) Une fois les zones repérées au microscope optique, des balayages rapides avec des pas de 15 x 15 ?m² ont été effectuées pour optimiser les durées d'acquisition sur des zones incluant les zones d'intérêt définies par spectrométrie Raman et MEB-EDS. La taille de pixel a été fixée à 3 x 3 ?m². La profondeur de pénétration dépend de la matrice de l'échantillon analysé
, Figure 168.a) avec 3,6 % de variance exprime en positif l'hématite mélangée au silicium. En négatif, un mélange de trois phases cristalline est visible (lépidocrocite, goethite et magnétite) non corrélé à la présence d'éléments spécifiques. Les zones intenses en hématite sont visibles sur la cartographie associée
, a, montre dans la partie Raman le pic caractéristique de la lépidocrocite (250 cm -1 ) et dans la partie EDS les éléments La carte des concentrations (Figure 170.c) permet de retrouver ici les zones mises en évidence par la MCR-ALS sur les données Raman seules