.. Etudes-d-'un-penta?, 121 5.1. Synthèse du penta(hexyl)[60]fullerène 19, p.122

.. Adler-longo-et-méthode-de-lindsey, Synthèses modernes : méthode d', p.143

.. Synthèse-d-'un-azoture-de-pérylène, 180 2.1. Synthèse en une étape d'un PDI dissymétrique 30, p.181

H. Chromatogrammes, H. W. Kroto, J. R. Heath, S. C. O-'brien, R. F. Curl et al., Références (1) (5) Dusty Objects in the Universe Library, Perspectives of Fullerene Nanotechnology, pp.162-163, 1985.

H. Murayama, S. Tomonoh, J. M. Alford, M. E. Karpuk, and . Fuller, Fullerene Production in Tons and More: From Science to Industry, Fullerenes, Nanotubes and Carbon Nanostructures, vol.12, issue.1-2, pp.1-9, 2005.
DOI : 10.1146/annurev.matsci.29.1.211

T. Tsuzuki, F. Piccinno, F. Gottschalk, S. Seeger, and B. Nowack, Nanotechnology commercialization, J. Nanoparticle Res, vol.2012, issue.139, p.14, 2013.
DOI : 10.1201/b15777

R. D. Johnson, G. Meijer, and D. S. Bethune, C60 has icosahedral symmetry, Journal of the American Chemical Society, vol.112, issue.24, pp.8983-8984, 1990.
DOI : 10.1021/ja00180a055

R. S. Ruoff, R. Malhotra, D. L. Huestis, D. S. Tse, and D. C. Lorents, Anomalous solubility behaviour of C60, Nature, vol.362, issue.6416, pp.140-141, 1993.
DOI : 10.1038/362140a0

D. V. Schur, S. Y. Zaginaichenko, A. D. Zolotarenko, and T. N. Veziroglu, In Carbon Nanomaterials in Clean Energy Hydrogen Systems; NATO Science for Peace and Security Series C: Environmental Security, pp.85-95, 2008.

L. W. Tutt and A. Kost, Optical limiting performance of C60 and C70 solutions, 30) Nalwa, H. S. Adv. Mater, pp.225-226, 1992.
DOI : 10.1038/356225a0

P. M. Allemand, A. Koch, F. Wudl, Y. Rubin, F. Diederich et al., Two different fullerenes have the same cyclic voltammetry, Journal of the American Chemical Society, vol.113, issue.3, pp.1050-1051, 1991.
DOI : 10.1021/ja00003a053

D. Dubois, K. M. Kadish, S. Flanagan, and L. J. Wilson, Electrochemical detection of fulleronium and highly reduced fulleride (C605-) ions in solution, Journal of the American Chemical Society, vol.113, issue.20, pp.7773-7774, 1991.
DOI : 10.1021/ja00020a056

A. D. Haymet, C120 and C60: Archimedean solids constructed from sp2 hybridized carbon atoms, Chemical Physics Letters, vol.122, issue.5, pp.421-424, 1985.
DOI : 10.1016/0009-2614(85)87239-0

Q. Xie, E. Perez-cordero, L. Echegoyen, and A. Hirsch, Electrochemical detection of C606- and C706-: Enhanced stability of fullerides in solution, Fullerenes and Related Structures, pp.3978-3980, 1992.
DOI : 10.1021/ja00036a056

P. D. Hirsch, D. M. Brettreich, F. Fullerenes-wudl, A. Hirsch, K. C. Khemani et al., Chemistry and Reactions, In Fullerenes; ACS Symposium Series, vol.481, issue.43, pp.161-175, 1992.

P. Belik, A. Gügel, J. Spickermann, and K. Müllen, Derivatives, Angewandte Chemie International Edition in English, vol.54, issue.1, pp.78-80, 1993.
DOI : 10.1351/pac198254051015

Y. Rubin, S. Khan, D. I. Freedberg, and C. Yeretzian, Synthesis and x-ray structure of a Diels-Alder adduct of fullerene C60, Journal of the American Chemical Society, vol.115, issue.1, pp.344-345, 1993.
DOI : 10.1021/ja00054a049

M. Maggini, G. Scorrano, and M. Prato, Addition of azomethine ylides to C60: synthesis, characterization, and functionalization of fullerene pyrrolidines, Journal of the American Chemical Society, vol.115, issue.21, pp.9798-9799, 1993.
DOI : 10.1021/ja00074a056

P. J. Krusic, E. Wasserman, P. N. Keizer, J. R. Morton, and K. Preston, Radical Reactions of C60, Science, vol.254, issue.5035, pp.1183-1185, 1991.
DOI : 10.1126/science.254.5035.1183

P. R. Birkett, P. B. Hitchcock, H. W. Kroto, R. Taylor, and D. R. Walton, Preparation and characterization of C60Br6 and C60Br8, Nature, vol.357, issue.6378, pp.479-481, 1992.
DOI : 10.1038/357479a0

S. Miki, M. Kitao, and K. Fukunishi, Introduction of two benzyl groups to C60 by using the collman reagent, Tetrahedron Letters, vol.37, issue.12, pp.2049-2052, 1996.
DOI : 10.1016/0040-4039(96)00215-8

M. Sawamura, H. Iikura, and E. Nakamura, The First Pentahaptofullerene Metal Complexes, Journal of the American Chemical Society, vol.118, issue.50, pp.12850-12851, 1996.
DOI : 10.1021/ja962681x

Y. Matsuo, E. Nakamura, M. Sawamura, N. Nagahama, M. Toganoh et al., Selective Multiaddition of Organocopper Reagents to Fullerenes, Chemical Reviews, vol.108, issue.8, pp.3016-3028, 2000.
DOI : 10.1021/cr0684218

Y. Matsuo, K. Tahara, and E. Nakamura, X-ray Crystallographic Characterization of Potassium Pentaphenyl[60]fullerene, Chemistry Letters, vol.34, issue.8, pp.1078-1079, 2005.
DOI : 10.1246/cl.2005.1078

Y. Matsuo, Y. Kuninobu, A. Muramatsu, M. Sawamura, and E. Nakamura, Synthesis of Metal Fullerene Complexes by the Use of Fullerene Halides, Organometallics, vol.27, issue.14, pp.3403-3409, 2008.
DOI : 10.1021/om8001262

Y. Matsuo, A. Iwashita, and E. Nakamura, Coupling of Alkylarene and Pentamethyl[60]fullerene by Iridium-catalyzed Benzylic C???H Bond Activation, Chemistry Letters, vol.35, issue.8, pp.858-859, 2006.
DOI : 10.1246/cl.2006.858

Y. Itoh, B. Kim, R. I. Gearba, N. J. Tremblay, R. Pindak et al., -Ferrocene Conjugated Monolayers Anchored onto Silicon Oxide with Five Carboxylic Acids and Their Transistor Applications, Chemistry of Materials, vol.23, issue.4, pp.970-975, 2011.
DOI : 10.1021/cm1025975

Y. Matsuo, K. Matsuo, T. Nanao, R. Marczak, S. S. Gayathri et al., A Ruthenium Bridge in Fullerene???Ferrocene Arrays: Synthesis of [Ru(C60Me5)R(CO)2] (R=C6H4Fc, C???CFc) and Their Charge-Transfer Properties, Chemistry ??? An Asian Journal, vol.53, issue.5, pp.841-848, 2008.
DOI : 10.15227/orgsyn.083.0080

Y. Matsuo, A. Muramatsu, J. Lu, and E. Nakamura, Highly Soluble Penta[(alkyl)dimethylsilylmethyl][60]fullerenes and Their Ruthenium and Palladium Complexes, Chemistry Letters, vol.39, issue.4, pp.342-343, 2010.
DOI : 10.1246/cl.2010.342

URL : http://www.journal.csj.jp/doi/pdf/10.1246/cl.2010.342

Y. Matsuo, A. Iwashita, and E. Nakamura, -Pentamethyl[60]fullerene, Organometallics, vol.27, issue.18, pp.4611-4617, 2008.
DOI : 10.1021/om800308n

M. Halim, R. D. Kennedy, S. I. Khan, and Y. Rubin, Gold(I) Triphenylphosphine Complexes Incorporating Pentaarylfulleride Ligands, Inorganic Chemistry, vol.49, issue.9, pp.3974-3976, 2010.
DOI : 10.1021/ic100428f

M. W. Bouwkamp and A. Meetsma, Pentaarylfullerenes as Noncoordinating Cyclopentadienyl Anions, Inorganic Chemistry, vol.48, issue.1, pp.8-9, 2009.
DOI : 10.1021/ic802034m

R. Hamasaki, Y. Matsuo, and E. Nakamura, Synthesis of Functionalized Fullerene by Mono-alkylation of Fullerene Cyclopentadienide, Chemistry Letters, vol.33, issue.3, pp.328-329, 2004.
DOI : 10.1246/cl.2004.328

T. Homma, K. Harano, H. Isobe, and E. Nakamura, Nanometer-Sized Fluorous Fullerene Vesicles in Water and on Solid Surfaces, Angewandte Chemie International Edition, vol.124, issue.9, pp.1665-1668, 2010.
DOI : 10.1021/ja0259281

M. Sawamura, M. Toganoh, Y. Kuninobu, S. Kato, and E. Nakamura, H and Its Use as Cyclopentadienyl-Type Ligand Precursor, Chemistry Letters, vol.29, issue.3, pp.270-271, 2000.
DOI : 10.1246/cl.2000.270

H. Isobe, H. Mashima, H. Yorimitsu, and E. Nakamura, Synthesis of Fullerene Glycoconjugates through Sulfide Connection in Aqueous Media, Organic Letters, vol.5, issue.23, pp.4461-4463, 2003.
DOI : 10.1021/ol0357705

G. Férey, Building Units Design and Scale Chemistry, Journal of Solid State Chemistry, vol.152, issue.1, pp.37-48, 2000.
DOI : 10.1006/jssc.2000.8667

U. Michelsen and C. A. Hunter, Self-Assembled Porphyrin Polymers, Angewandte Chemie International Edition, vol.39, issue.4, pp.764-767, 2000.
DOI : 10.1002/(SICI)1521-3773(20000218)39:4<764::AID-ANIE764>3.0.CO;2-6

G. Li, L. B. Mcgown, J. P. Hill, W. Jin, A. Kosaka et al., Molecular Nanotube Aggregates of beta- and ggr-Cyclodextrins Linked by Diphenylhexatrienes, Science, vol.264, issue.5156, pp.249-251, 1994.
DOI : 10.1126/science.264.5156.249

F. Giacalone and N. Martín, Fullerene Polymers:?? Synthesis and Properties, Chemical Reviews, vol.106, issue.12, pp.5136-5190, 2006.
DOI : 10.1021/cr068389h

T. Haino, Y. Matsumoto, and Y. Fukazawa, Supramolecular Nano Networks Formed by Molecular-Recognition-Directed Self-Assembly of Ditopic Calix[5]arene and Dumbbell [60]Fullerene, Journal of the American Chemical Society, vol.127, issue.25, pp.8936-8937, 2005.
DOI : 10.1021/ja0524088

?. Hardouin, M. Lerouge, P. Hudhomme, and M. Sallé, Molecular clips and tweezers hosting neutral guests, Chem. Soc. Rev., vol.48, issue.1, pp.30-43, 2010.
DOI : 10.1002/anie.200806175

T. Sugimoto, H. Awaji, I. Sugimoto, Y. Misaki, T. Kawase et al., Ethylene analogs of tetrathiafulvalene and tetraselenafulvalene: new donors for organic metals, Chemistry of Materials, vol.1, issue.5, pp.535-547, 1989.
DOI : 10.1021/cm00005a015

M. J. Cohen, L. B. Coleman, A. F. Garito, and A. Heeger, Electrical conductivity of tetrathiofulvalinium tetracyanoquinodimethan (TTF) (TCNQ), Physical Review B, vol.31, issue.4, pp.1298-1307, 1974.
DOI : 10.1103/PhysRevLett.31.1139

T. J. Kistenmacher, T. E. Phillips, and D. O. Cowan, The crystal structure of the 1:1 radical cation???radical anion salt of 2,2'-bis-l,3-dithiole (TTF) and 7,7,8,8-tetracyanoquinodimethane (TCNQ), Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, vol.30, issue.3, pp.763-768, 1974.
DOI : 10.1107/S0567740874003669/a10935_30293sup1.pdf

D. Jerome, A. Mazaud, M. Ribault, K. J. Bechgaard, . Phys et al., series in solidstate sciences, Organic superconductors, pp.95-98, 1980.

H. Kobayashi, Organic superconductors/semiconductors/CT salts, Current Opinion in Solid State and Materials Science, vol.2, issue.4, pp.440-445, 1997.
DOI : 10.1016/S1359-0286(97)80086-1

J. Fabre, L. Giral, and M. Viguier, Compte-Rendus Académie Sci, pp.973-976, 1981.

G. Steimecke, H. Sieler, R. Kirmse, and E. Hoyer, 1.3-DITHIOL-2-THION-4.5-DITHIOLAT AUS SCHWEFELKOHLENSTOFF UND ALKALIMETALL, Phosphorous and Sulfur and the Related Elements, vol.16, issue.1, pp.49-55, 1979.
DOI : 10.1107/S0365110X66000203

R. R. Schumaker and E. M. Engler, Thiapen chemistry: synthesis of higher homologs of tetrathiafulvalene, Journal of the American Chemical Society, vol.102, issue.21, pp.6651-6652, 1980.
DOI : 10.1021/ja00541a086

H. Müller, A. Lerf, H. P. Fritz, and K. Andres, Some new applications of thiapendione and synthesis of BIS-(phenylenedithiolo)-tetrathiafulvalene, Synthetic Metals, vol.42, issue.3, pp.2381-2384, 1991.
DOI : 10.1016/0379-6779(91)91386-O

J. Lau, O. Simonsen, J. Becher, P. J. Skabara, and K. Müllen, Synthesis, 42) Skabara, pp.521-526, 1995.
URL : https://hal.archives-ouvertes.fr/pasteur-01420002

M. Sawamura, H. Iikura, and E. Nakamura, The First Pentahaptofullerene Metal Complexes, Journal of the American Chemical Society, vol.118, issue.50, pp.12850-12851, 1996.
DOI : 10.1021/ja962681x

R. Hamasaki, Y. Matsuo, and E. Nakamura, Synthesis of Functionalized Fullerene by Mono-alkylation of Fullerene Cyclopentadienide, Chemistry Letters, vol.33, issue.3, pp.328-329, 2004.
DOI : 10.1246/cl.2004.328

Y. Matsuo and E. Nakamura, Selective Multiaddition of Organocopper Reagents to Fullerenes, Chemical Reviews, vol.108, issue.8, pp.3016-3028, 2008.
DOI : 10.1021/cr0684218

T. Nakae, Y. Matsuo, E. Nakamura, . Org, E. Lett-nakamura et al., -Symmetric Functionalized [60]Fullerenes by Copper-Mediated 5-Fold Addition of Reformatsky Reagents, Organic Letters, vol.10, issue.4, pp.621-623, 2008.
DOI : 10.1021/ol702874w

J. Nierengarten, Copper-catalyzed alkyne-azide cycloaddition for the functionalization of fullerene building blocks, Pure and Applied Chemistry, vol.31, issue.4, pp.1027-1037, 2011.
DOI : 10804393

C. W. Tornøe, C. Christensen, and M. Meldal, Peptidotriazoles on Solid Phase:?? [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides, The Journal of Organic Chemistry, vol.67, issue.9, pp.3057-3064, 2002.
DOI : 10.1021/jo011148j

M. Meldal and C. W. Tornøe, Cu-Catalyzed Azide???Alkyne Cycloaddition, Chemical Reviews, vol.108, issue.8, pp.2952-3015, 2008.
DOI : 10.1021/cr0783479

Q. Xie, E. Perez-cordero, and L. Echegoyen, Electrochemical detection of C606- and C706-: Enhanced stability of fullerides in solution, Journal of the American Chemical Society, vol.114, issue.10, pp.3978-3980, 1992.
DOI : 10.1021/ja00036a056

T. Niinomi, Y. Matsuo, M. Hashiguchi, Y. Sato, and E. Nakamura, Penta(organo)[60]fullerenes as acceptors for organic photovoltaic cells, Journal of Materials Chemistry, vol.130, issue.32, pp.5804-5811, 2009.
DOI : 10.15227/orgsyn.083.0080

Y. Itoh, B. Kim, R. I. Gearba, N. J. Tremblay, R. Pindak et al., -Ferrocene Conjugated Monolayers Anchored onto Silicon Oxide with Five Carboxylic Acids and Their Transistor Applications, Chemistry of Materials, vol.23, issue.4, pp.970-975, 2011.
DOI : 10.1021/cm1025975

K. M. Kadish, K. M. Smith, R. Guilard, N. J. Hackensack, K. L. London-ho et al., Références (1) Handbook of porphyrin science: with applications to chemistry, physics, materials science, engineering, biology and medicine, Chapitre III : Polymères supramoléculaires à base de penta(ZnP)[60]fullerène 6, 2010.

D. M. Guldi, B. Heinrich, B. Donnio, S. Campidelli, R. Willstätter et al., Untersuchungen über Chlorophyll, ) Soret, J.-L. Compte-Rendus Académie Sci (9) Fischer, H.; Halbig, P.; Walach, B. Justus Liebigs Ann. Chem, pp.11374-11381, 1883.

J. R. Platt and M. Gouterman, Radiation biology, J. Chem. Phys, vol.3, issue.5, pp.71-123, 1956.

M. Gouterman, J. B. Kim, J. J. Leonard, and F. R. Longo, The porphyrins 1978, 3. (25), J. Am. Chem. Soc, issue.11, pp.94-3986, 1972.

L. Edwards, D. H. Dolphin, and M. Gouterman, Porphyrins, Journal of Molecular Spectroscopy, vol.35, issue.1, pp.90-109, 1970.
DOI : 10.1016/0022-2852(70)90168-2

D. W. Clack and N. S. Hush, Successive One-Electron Reduction Potentials of Porphins and Metal Prophins in Dimethylformamide, Journal of the American Chemical Society, vol.87, issue.19, pp.4238-4242, 1965.
DOI : 10.1021/ja00947a004

A. Stanienda and G. Biebl, Elektrochemische Untersuchungen an Porphinen, Zeitschrift f??r Physikalische Chemie, vol.52, issue.5_6, pp.254-275, 1967.
DOI : 10.1524/zpch.1967.52.5_6.254

P. Rothemund, A. R. Menotti, S. Neya, H. Yodo, N. Funasaki et al., The Synthesis of ??,??,??,??-Tetraphenylporphine, Journal of the American Chemical Society, vol.63, issue.1, pp.267-270, 1941.
DOI : 10.1021/ja01846a065

A. D. Adler, F. R. Longo, J. D. Finarelli, J. Goldmacher, J. Assour et al., A simplified synthesis for meso-tetraphenylporphine, The Journal of Organic Chemistry, vol.32, issue.2, pp.476-476, 1967.
DOI : 10.1021/jo01288a053

A. D. Adler, L. Sklar, F. R. Longo, J. D. Finarelli, and M. G. Finarelli, -tetraphenylporphin, Journal of Heterocyclic Chemistry, vol.7, issue.5, pp.669-678, 1968.
DOI : 10.1007/978-1-4899-5892-1

J. S. Lindsey, R. G. Little, J. A. Anton, P. A. Loach, J. A. Ibers et al., Metalloporphyrins Catalyzed Oxidations, J. Heterocycl. Chem. J. Heterocycl. Chem, vol.12, issue.181, pp.49-86, 1975.

M. A. Fazio, O. P. Lee, and D. I. Schuster, First Triazole-Linked Porphyrin???Fullerene Dyads, Organic Letters, vol.10, issue.21, pp.4979-4982, 2008.
DOI : 10.1021/ol802053k

URL : http://pubs.acs.org/doi/pdf/10.1021/ol802889d

M. Blanco, J. Chambron, V. Heitz, and J. Sauvage, A Linear Multiporphyrinic [2]-Rotaxane via Amide Bond Formation, Organic Letters, vol.2, issue.20, pp.3051-3054, 2000.
DOI : 10.1021/ol006137b

K. M. Kadish, K. M. Smith, R. Guilard, and A. Einstein, The Porphyrin Handbook: Synthesis and organic chemistry, Ann. Phys, issue.558, pp.322-549, 1905.

C. Villegas, J. L. Delgado, P. Bouit, B. Grimm, W. Seitz et al., Industrial Organic Pigments, Chem. Sci. Angew. Chem. Int. Ed. Chem. Asian J, vol.2, issue.32, pp.1677-59, 2004.

M. W. Holman, R. Liu, and D. M. Adams, Single-Molecule Spectroscopy of Interfacial Electron Transfer, Journal of the American Chemical Society, vol.125, issue.41, pp.12649-12654, 2003.
DOI : 10.1021/ja0343104

L. Spectres-de-masse, SM) MALDI-TOF ont été enregistrés sur spectromètre Bruker Daltonics Biflex III (mode réflectron et linéaire, ionisation positive et négative) en utilisant comme matrice DCTB (trans- 2-[3-(4-tert-butylphényl)-2-méthyl-2-propènylidène]malononitrile), p.ou DIT

U. Vis, Les cuves utilisées sont en quartz avec des épaisseurs de 1 cm ou 1 mm

L. Substrat-recouvert-par-le and P. , PSS est mis en rotation à 5000 tours/min, la solution du composé étudié dans le PMMA est déposée pendant la rotation