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SM) MALDI-TOF ont été enregistrés sur spectromètre Bruker Daltonics Biflex III (mode réflectron et linéaire, ionisation positive et négative) en utilisant comme matrice DCTB (trans- 2-[3-(4-tert-butylphényl)-2-méthyl-2-propènylidène]malononitrile), p.ou DIT ,
Les cuves utilisées sont en quartz avec des épaisseurs de 1 cm ou 1 mm ,
PSS est mis en rotation à 5000 tours/min, la solution du composé étudié dans le PMMA est déposée pendant la rotation ,