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. Dans-un-monocol-de, 3 mmol) du précurseur hydrazine sont solubilisés dans 10 mL de méthanol anhydre Ensuite 0.3 mL d'acétone anhydre sont ajoutés à la solution. Le produit est filtré et séché sous vide à 50 °C pendant une nuit. 1 H NMR (DMSO-d6, 300 MHz): (ppm) = 1, 10.27 (s, 2H). 19 F NMR (DMSO-d6, 300 MHz): (ppm) = -69

«. De, 04 g (45 mmol) de DABCO sont solubilisés dans 25 mL de dichlorométhane. Purifié par chromatographie flash (CH 2 Cl 2 / Ether du Pétrole 50:50) 8.32 g (11.2 mmol) du 4-4'-Bis(2- Bromotétrafluoroéthoxy)biphenyl sulfoné sont ajoutés. 1.45 g (rdt, La procédure expérimentale suivie est identique à la précédente avec les proportions suivantes2%) de produit pur sont isolés. 1 H NMR (DMSO-d6, 300 MHz): (ppm) = 6.92 (AA'BB', 2H), pp.4-5

«. De, 24 g (37.8 mmol) de diazabicyclooctane (DABCO) sont solubilisés dans 25 mL de dichlorométhane et introduits dans un Partie expérimentale d6, 300 MHz): (ppm) = 7, 4H), 7.25 (AA'BB', 4H). 19 F NMR (DMSO-d6, 300 MHz): (ppm) = -118.8 (dd, 1F), -126.6 (dd, 1F), -134.0 (dd, 1F)

. Mhz, 99 (s, 2H). 19 F NMR (DMSO-d6, 300 MHz): (ppm) = -118, dd, 2F), -126.58 (dd, 2F), -134.22 (dd, 2F)

. Le-produit-pur, 75 g, 56% rdt.) est obtenu après plusieurs recristallisations succesives dans l'hexane/EtOAc du produit brut

6. Et-de-carbonate-de-potassium-dans-la-diméthylacetamide, La solution est chauffée à 140 °C pendant 24 heures puis la solution est refroidie à 80 °C. Les comonomères comportant le bloc phosphoné sont ajoutés avec la quantité stoechiométrique de carbonate de potassium. La solution est rediluée

. Sulphos-12, Premier bloc: 1.0000 g de SDFBP, 0.8436 g de bisphénol-6F et 0, p.77

. Sulphos-12, Premier bloc: 1.0000 g de SDFBP, 0.8436 g de bisphénol-6F et 0

. Résonance-magnétique-nucléaire, RMN) Les spectres RMN 1 H, 19 F et 31 P ont été réalisés à température ambiante. Les analyses en milieu liquide ont été réalisés sur des spectromètres Bruker Avance 300 et 500

. Mhz, Les fréquences d'analyse sont respectivement de 300 et 500 MHz pour le proton, 376 et 470 MHz pour le fluor et de 100 et 125 MHz pour le carbone. Les RMN du solide ont été effectués sur un spectromètre Bruker Avance 500 Solide dont la fréquence d'analyse est de 500 MHz pour le proton, pp.470-200

. Mhz-pour-le-phosphore, Les solvants employés sont le diméthylsulfoxyde deutéré (DMSO-d6) ou le chloroforme deutéré (CDCl 3 ) et la référence interne utilisée est le tétraméthylsilane (TMS)