P. T. Anastas, J. C. Warner, and G. Chemistry, Theory and Practice Essays on science and society. Toward sustainable chemistry, Science, vol.30, issue.35501, pp.291-339, 1998.

R. G. Bergman, K. P. Kornecki, and J. F. Berry, C???H activation, Nature, vol.45, issue.7134, pp.391-393, 2007.
DOI : 10.1038/446391a

C. Intermolecular, C. Amination-yin, and G. , Understanding the Oxidative Relationships of the Metal Oxo, Hydroxo, and Hydroperoxide Intermediates with Manganese(IV) Complexes Having Bridged Cyclams: Correlation of the Physicochemical Properties with Reactivity Catalytic and Biocatalytic Iron Porphyrin Carbene Formation: Effects of Binding Mode, Carbene Substituent, Porphyrin Substituent, and Protein Axial Ligand, pp.5827-5832, 2011.

R. W. Dugger, J. A. Ragan, and D. H. Ripin, Survey of GMP Bulk Reactions Run in a Research Facility between 1985 and 2002, Organic Process Research & Development, vol.9, issue.3, pp.253-258, 1985.
DOI : 10.1021/op050021j

F. Buda, Mécanismes cinétiques pour l'amélioration de la sécurité des procédés d'oxydation des hydrocarbures Institut national polytechnique de Lorraine, Behr, A.; Neubert, P., Oxidations. In Applied Homogeneous Catalysis, issue.8, 2006.

W. Gmbh and &. Co, KGaA: 2012, pp.437-455

T. Katsuki, K. B. Sharpless, W. Zhang, J. L. Loebach, S. R. Wilson et al., The first practical method for asymmetric epoxidation, Journal of the American Chemical Society, vol.102, issue.18, pp.5974-5976, 1980.
DOI : 10.1021/ja00538a077

E. N. Jacobsen, W. Zhang, A. R. Muci, J. R. Ecker, L. V. Deng et al., Highly enantioselective epoxidation catalysts derived from 1,2-diaminocyclohexane, Chiralité et synthèse asymétrique en chimie thérapeutique. L'actualité chimique 2015 Applied Homogeneous Catalysis, pp.7063-7064, 1991.
DOI : 10.1021/ja00018a068

W. Gmbh, &. Co, D. Kgaa-steinborn, and R. Taube, Zur Komplexkatalyse der Aminomethylierung und Aminierung von Olefinen Catalytic addition of secondary amines to ethylene (Contribution No, Zeitschrift für Chemie Coulson, D. R, vol.14, issue.1720, pp.455-473, 1986.

I. Bertini, H. B. Gray, E. I. Stiefel, and J. S. Valentine, Biological Inorganic Chemistry : Structure and reactivity, pp.278-318, 2007.

R. Hili, A. K. Yudin, and P. B. Danielson, Making carbon-nitrogen bonds in biological and chemical synthesis, Nature Chemical Biology, vol.305, issue.6, pp.284-287, 2002.
DOI : 10.1038/nchembio0606-284

P. Shaik, S. Ferreira, K. N. Iverson, T. M. Maghlaoui, K. Barber et al., Mechanism of Oxidation Reactions Catalyzed by Cytochrome P450 Enzymes Architecture of the Photosynthetic Oxygen-Evolving Center, Chemical Reviews Science, vol.104, issue.95665, pp.3947-3980, 2004.

A. Aukauloo, W. Leibl, A. W. Rutherford, V. L-'krewald, M. Retegan et al., énergie solaire Water photolysis by molecular biomimetics Metal oxidation states in biological water splitting A five-coordinate Mn(iv) intermediate in biological water oxidation: spectroscopic signature and a pivot mechanism for water binding Cooperation of charges in photosynthetic O2 evolution : a linear four step mechanism, Chemical Science Chemical Science Forbush, B Photochemistry and Photobiology, vol.308, issue.116, pp.42-50, 1970.

G. Barbieri, R. Chabaud, T. J. Collins, R. H. Holm, and P. Dauban, Designing Ligands for Oxidizing Complexes Metal-centered oxygen atom transfer reactions Transition Metal-Catalyzed C?H Amination: Scope, Mechanism, and Applications Dequirez, G. Transferts de nitrène catalysés par les métaux de transition, nouveau modèle des centres photochimiques du système II* Ueber die Einwirkung von Benzolsulfonsäurechlorid auf Amidoxime. Berichte der deutschen chemischen Gesellschaft 1891 Nitrene Chemistry in Organic Synthesis: Still in Its Infancy, pp.309-329, 1969.

J. Rissom, G. Kraemer, C. Vorbach, H. Meier, H. Bottler et al., Die Umsetzungen der Sulfonazide Thermal reactions of sulfonyl azides with aliphatic hydrocarbons, Angewandte Chemie International Edition Journal für praktische Chemie Tetrahedron Letters, vol.2012, issue.539, pp.7384-7395, 1930.

A. G. Anastassiou, H. E. Simmons, F. D. Marsh, C. Suarez, A. I. Lyaskovskyy et al., Reaction with Saturated Hydrocarbons Copper-Catalyzed Decomposition of Benzenesulfonyl Azide in Cyclohexene Solution Complexes with Nitrogen-Centered Radical Ligands: Classification, Spectroscopic Features, Reactivity, and Catalytic Applications A new synthesis of sulfonylnitrenes N-Tosyloxycarbamates as Reagents in Rhodium-Catalyzed C-H Amination Reactions Synthesis and reaction of new type I-N ylide, Ntosyliminoiodinane Reaction of methanesulfonyl nitrene with benzene. Attempts to generate sulfonyl nitrenes from sources other than the azides, The I=X (X=O,N,C) Double Bond in Hypervalent Iodine Compounds: Is it Real? Angewandte Chemie International Edition 2014, pp.2296-2297, 1965.

S. Au, J. Huang, C. Che, and W. Yu, Amidation of Unfunctionalized Hydrocarbons Catalyzed by Ruthenium Cyclic Amine or Bipyridine Complexes, The Journal of Organic Chemistry, vol.65, issue.23, pp.65-7858, 2000.
DOI : 10.1021/jo000881s

C. G. Espino, J. Du-bois, O. Verho, E. V. Johnston, B. Åkermark et al., Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation Electrochemical reactivity of manganese(II) porphyrins. Effects of dioxygen, benzoic anhydride, and axial ligands Inorganic Chemistry Electrochemical olefin epoxidation with manganese meso-tetraphenylporphyrin catalyst and hydrogen peroxide generation at polymercoated electrodes Simultaneous Reduction of CO2 and Splitting of H2O by a Single Immobilized Cobalt Phthalocyanine Electrocatalyst Photoinduced oxidation of a watersoluble manganese(III) porphyrin Click chemistry: Diverse chemical function from a few good reactions Efficient water oxidation catalyzed by homogeneous cationic cobalt porphyrins with critical roles for the buffer base, Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones. Angewandte Chemie International Edition Proceedings of the National Academy of Sciences 2013 Ini, S., Remarkable Effects of Metal, Solvent, and Oxidant on Metalloporphyrin-Catalyzed Enantioselective Epoxidation of Olefins, pp.598-600, 1986.

S. Gunathilagan, Evidence for parallel destructive, and competitive epoxidation and dismutation pathways in metalloporphyrin-catalysed alkene oxidation by hydrogen peroxide Metalloporphyrin-based oxidation systems: from biomimetic reactions to application in organic synthesis, Tetrahedron Chemical Communications, vol.5727, issue.31, pp.6847-6853, 2001.

J. T. Groves, K. Shalyaev, J. Lee, K. M. Kadish, K. M. et al., Oxometalloporphyrins in Oxidative Catalysis Hydroxylation and epoxidation catalyzed by ironporphine complexes. Oxygen transfer from iodosylbenzene, The porphyrin Handbook, pp.1032-1033, 1979.

J. Redman, Self-assembly of porphyrins, 2000.

Z. Wang and A. Straumanis, Synthesis of porphyrins: models of natural hemoproteins and impressive catalysts for asymmetric epoxidation of olefins, Polyhedron, vol.19, issue.5, pp.581-586, 2000.

A. B. Sorokin, W. Zhang, J. L. Loebach, S. R. Wilson, E. N. Jacobsen et al., Phthalocyanine Metal Complexes in Catalysis Enantioselective epoxidation of unfunctionalized Olefins Catalized by (Salen)manganese complex Catalytic asymmetric oxidations using optically active (salen)manganese(III) complexes as catalysts, Chemical Reviews Journal of the American Chemical Society Coordination Chemistry Reviews, vol.113, issue.140, pp.8152-8191, 1990.

T. Katsuki, Some Recent Advances in Metallosalen Chemistry, pp.281-0297, 2003.
DOI : 10.1055/s-2003-37101

URL : http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2003-37101.pdf

P. G. Cozzi, V. K. Sivasubramanian, M. Ganesan, S. Rajagopal, and R. Ramaraj, Metal???Salen Schiff base complexes in catalysis: practical aspects, Chem. Soc. Rev., vol.22, issue.7, pp.410-421, 2002.
DOI : 10.1021/om020773r

T. J. Collins, TAML Oxidant Activators: A New Approach to the Activation of Hydrogen Peroxide for Environmentally Significant Problems, Highly enantioselective epoxidation of conjugated cis olefins, pp.50-11827, 1994.

S. Kundu, J. V. Thompson, L. Q. Shen, M. R. Mills, E. L. Bominaar et al., Activation Parameters as Mechanistic Probes in the TAML Iron(V)?Oxo Oxidations of Hydrocarbons Ligand solvation and the macrocyclic effect. Nickel(II)-tetramine complexes Synthesis of macrocyclic tetraamido compounds and new metal insertion process. Google Patents: 2006. 16 A water-stable manganese(V)-oxo complex: definitive assignment of a .nu.Mnv.tplbond.O infrared vibration A Tailor-Made Molecular Ruthenium Catalyst for the Oxidation of Water and Its Deactivation through Poisoning by Carbon Monoxide, Chemistry ? A European Journal Inorganic Chemistry Journal of the American Chemical Society Sun, J. Angewandte Chemie International Edition, vol.2015, issue.201315, pp.1803-1810, 1974.

W. Arafa, T. Laine, A. Shatskiy, M. Kärkäs, B. Åkermark et al., Substituent Effects in Molecular Ruthenium Water Oxidation Catalysts Based on Amide Ligands Activation d'une molécule d'eau coordonnée au manganèse : quatre études de cas Lewis acidic catalysts for olefin epoxidation by iodosylbenzene, Synthesis, Structure and Spectral, and Electrochemical Properties of New Mononuclear Ruthenium(III) Complexes of Tris[(benzimidazol-2- yl)methyl]amine: Role of Steric Hindrance in Tuning the Catalytic Oxidation Activity, pp.1583-1587, 1991.

K. Yoshizawa and S. Fukuzumi, Ruthenium-Catalyzed Selective and Efficient Oxygenation of Hydrocarbons with Water as an Oxygen Source, Angewandte Chemie International Edition, issue.31, pp.47-5772, 2008.

Q. Zeng, F. W. Lewis, L. M. Harwood, F. Hartl, T. Amano et al., Role of ligands in catalytic water oxidation by mononuclear ruthenium complexes Synthesis and Characterization of Mononuclear and Dinuclear Ruthenium Complexes with Tris(2- pyridylmethyl)amine and Tris(5-methyl-2-pyridylmethyl)amine, Further Observations on Water Oxidation Catalyzed by Mononuclear Ru(II) Complexes. Inorganic Chemistry 2012, pp.304-305, 1998.

C. P. Berlinguette, Electronic Modification of the [RuII(tpy)(bpy)(OH2)]2+ Scaffold: Effects on Catalytic Water Oxidation, Journal of the American Chemical Society, vol.132, issue.45, pp.16094-16106, 2010.

J. Godwin, J. B. Ng, S. Yiu, S. Lam, W. W. Wei et al., Catalytic Water Oxidation by Ruthenium(II) Quaterpyridine (qpy) Complexes: Evidence for Ruthenium(III) qpy-N,Ndioxide as the Real Catalysts, Preparation of ruthenium nitrosyl complexes containing 2 C?H Bond Activation by a Ferric Methoxide Complex: A Model for the Rate-Determining Step in the Mechanism of Lipoxygenase)methyl]pyridine L for mononuclear iron(ii) and manganese(ii) compounds; synthesis and crystal structures of [FeL(MeCN)][ClO4]2 and [(MnL(H2O)][ClO4]2, pp.10-471, 1971.

P. Battioni and D. Mansuy, Spectroscopic Characterization of an FeIV Intermediate Generated by Reaction of XO? (X = Cl, Br) with an FeII Complex Bearing a Pentadentate Non-Porphyrinic Ligand ? Hydroxylation and Epoxidation Activity, European Journal of Inorganic Chemistry, issue.2, p.2004, 2004.

A. Thibon, J. Bartoli, S. Bourcier, F. Banse, N. Ségaud et al., Mononuclear iron complexes relevant to nonheme iron oxygenases. Synthesis, characterizations and reactivity of Fe-Oxo and Fe-Peroxo intermediates, Iron Coordination Chemistry with New Ligands Containing Triazole and Pyridine Moieties. Comparison of the Coordination Ability of the N-Donors, pp.9587-9594, 2009.
DOI : 10.1039/b913470k

URL : https://hal.archives-ouvertes.fr/hal-00904652

M. F. Charlot, R. Guillot, B. Andrioletti, A. Aukauloo, . Dipyrrinphenol-mn et al., III) complex: synthesis, electrochemistry, spectroscopic characterisation and reactivity. Dalton transactions Synthesis of imidazole schiff base ligands, their silver(I) complexes and their activities against Candida Albicans. The National University of Ireland, Maynooth A sensitive and selective fluorescent sensor for Zinc(II) and its application to living cell imaging. Sensors and Actuators B: Chemical 2014 Functionalization of Boron Dipyrrin (BODIPY) Dyes through Iridium and Rhodium Catalysis: A Complementary Approach to ?-and ?-Substituted BODIPYs Monoanionic Dipyrrin-Pyridine Ligands: Synthesis, Structure and Photophysical Properties, Electrogenerated Polymers as Efficient and Robust Heterogeneous Catalysts for the Hydrolytic Kinetic Resolution of Terminal Epoxides, pp.9090-9093, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00695893

C. N. Johnson, G. Stemp, N. Anand, S. C. Stephen, T. Gallagher et al., Palladium(0)-Catalysed Arylations using Pyrrole and Indole 2-Boronic Acids Synthesis of new pyrrole?pyridine-based ligands using an in situ Suzuki coupling method, A Scalable Synthesis of Meso-Substituted Dipyrromethanes. Organic Process Research & Development, pp.1025-1027, 1998.

T. Rohand, E. Dolusic, T. H. Ngo, W. Maes, and W. Dehaen, Efficient synthesis of aryldipyrromethanes in water and their application in the synthesis of corroles and dipyrromethenes, Arkivoc, 2007.

V. S. Thoi, J. R. Stork, E. T. Niles, E. C. Depperman, D. L. Tierney et al., Diamidodipyrrins: Versatile Bipyrrolic Ligands with Multiple Metal Binding Modes Manganese(III) Complexes of Bis(hydroxyphenyl)dipyrromethenes Are Potent Orally Active Peroxynitrite Scavengers Nucleophilic Substitution on (Pentafluorophenyl)dipyrromethane: A New Route to Building Blocks for Functionalized BODIPYs and Tetrapyrroles, Ivanov, A.; Skital'tseva, E.; Vasil'tsov, pp.47-10533, 2008.

A. B. Mikhaleva, A. M. Simonov, and B. Y. Simkin, 1H-benzimidazoles from 1- Vinyl-1H-pyrrole-2-carbaldehydes and o-Phenylenediamine Research on the chemistry of 2- hetarylbenzimidazoles. 4. Oxidation of 1-methyl-2-(5?-methyl-2?-hetaryl)benzimidazoles A Versatile Method for the Synthesis of Benzimidazoles from o-Nitroanilines and Aldehydes in One Step via a Reductive Cyclization, Gonsalves, A. M. d. A. R.; Abrantes, pp.3603-3610, 1982.

F. Botelho and H. Furuta, Synthetic porphyrins bearing ?-propionate chains as photosensitizers for photodynamic therapy, Journal of Porphyrins and Phthalocyanines, vol.14, issue.37, pp.438-445, 2010.

F. Gallardo, Synthesis and Antiviral Activity Evaluation of Nitroporphyrins and Nitrocorroles as Potential Agents against Human Cytomegalovirus Infection, ACS Infectious Diseases, vol.2015, issue.18

A. Laguerre, Y. Chang, M. Pirrotta, N. Desbois, C. P. Gros et al., Surface-promoted aggregation of amphiphilic quadruplex ligands drives their selectivity for alternative DNA structures Organic & biomolecular chemistry Photoinitiated Polymerisation: Theory and Applications Kinetics and mechanism of pyrrole chemical polymerization. Synthetic Metals Über die Einwirkung von Halogenphosphor auf Alkyl-formanilide. Eine neue Methode zur Darstellung sekundärer und tertiärer p-Alkylamino-benzaldehyde. Berichte der deutschen chemischen Gesellschaft Zwitterionic N2O2-Type Protonated Dipyrrin Bearing a Phosphate Anionic Moiety as a pH-Responsive Fluorescence Indicator BODIPY Dyes and Their Derivatives: Syntheses and Spectroscopic Properties Invitation à la fluorescence moléculaire, 42. Kadish, K. M., Handbook of Porphyrin Science: With Applications to Chemistry Synthèse et étude d'une nouvelle génération de colorants borondipyrrométhènes (BODIPYs) émettant dans le rouge et le proche infrarouge pour des applications biologiques, pp.7034-7039, 1927.

G. Calzaferri, H. Li, and D. Brühwiler, Dye-Modified Nanochannel Materials for Photoelectronic and Optical Devices, Based Computing Platform in Defending Information Risk, pp.6342-6351, 2008.
DOI : 10.1142/3168

K. Tainaka, K. Tanaka, S. Ikeda, K. I. Nishiza, T. Unzai et al., PRODAN-Conjugated DNA: Synthesis and Photochemical Properties Towards non-blinking colloidal quantum dots, Photoactivatable Push?Pull Fluorophore for Single-Molecule Imaging in Live Cells, pp.9204-9205, 2007.
DOI : 10.1021/ja069156a

X. Qi, E. J. Jun, L. Xu, S. Kim, J. S. Hong et al., New BODIPY Derivatives as OFF?ON Fluorescent Chemosensor and Fluorescent Chemodosimeter for Cu2+: Cooperative Selectivity Enhancement toward Cu2+ Lighting the way ahead with boron dipyrromethene (Bodipy) dyes, Synthèse et étude de systèmes mutlichromophoriques à base de Bodipy. 2011. 51, pp.2881-2884, 1968.

M. Baruah, A. Stefan, M. V. Der-auweraer, W. Dehaen, and N. Boens, Solvent-dependent photophysical properties of borondipyrromethene dyes in solution, Chemical Physics Letters, vol.420, pp.4-6, 2006.

W. Qin, M. Baruah, M. Van-der-auweraer, F. C. De-schryver, N. Boens et al., Photophysical Properties of Borondipyrromethene Analogues in Solution. The Journal of Physical Chemistry A Photophysical Properties of BODIPY-Derived Hydroxyaryl Fluorescent pH Probes in Solution, ChemPhysChem, vol.109, issue.611, pp.7371-7384, 2005.

R. Ziessel, A. Harriman, C. Ikeda, S. Ueda, T. Nabeshima et al., A highly efficient sensor molecule emitting in the near infrared (NIR): 3,5-distyryl-8-(p-dimethylaminophenyl)difluoroboradiaza-s-indacene Aluminium complexes of N2O2-type dipyrrins: the first hetero-multinuclear complexes of metallo-dipyrrins with high fluorescencequantum yields ?-Monoacylated and ?,??-and ?,??-Diacylated Dipyrrins as Highly Sensitive Fluorescence " Turn-on " Zn2+ Probes Selective and sensitive "turn-on" fluorescent Zn2+ sensors based on di-and tripyrrins with readily modulated emission wavelengths properties: Changes effected by coordination, Coordinative Interactions, pp.611-631, 1973.

H. Nishihara, S. K. Das, B. Song, A. Mahler, V. N. Nesterov et al., Electron Transfer Studies of High Potential Zinc Porphyrin?Fullerene Supramolecular Dyads Fluorescence quantum yields of some rhodamine dyes Absolute luminescence yield of cresyl violet. A standard for the red Zinc Biochemistry, Physiology, and Homeostasis: Recent Insights and Current Trends Recent development of zinc-fluorophores Fluorescence enhancement of N2O2-type dipyrrin ligand in two step responding to zinc(II) ion, Bis(dipyrrinato)zinc(II) Complexes: Emission in the Solid State. Inorganic Chemistry 2016 and epoxidation catalyzed by ironporphine complexes. Oxygen transfer from iodosylbenzene Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage, pp.5732-5734, 1979.

J. S. Huang, Metalloporphyrin-based oxidation systems: from biomimetic reactions to application in organic synthesis, Chemical Communications Z, issue.27 2, pp.3996-4015, 2009.

Q. H. Xia, H. Q. Ge, C. P. Ye, Z. M. Liu, and K. X. Su, Advances in Homogeneous and Heterogeneous Catalytic Asymmetric Epoxidation Enantioselective epoxidation of olefins with chiral metalloporphyrin catalysts, Chemical Reviews E.; Andrioletti, B.; Zrig, S Chemical Society Reviews, vol.62, issue.10557, pp.5514-5521, 1997.

D. Wang and J. T. Groves, Efficient water oxidation catalyzed by homogeneous cationic cobalt porphyrins with critical roles for the buffer base, Proceedings of the National Academy of Sciences 2013, pp.110-15579
DOI : 10.1021/cr200177j

I. D. Cunningham, T. N. Danks, J. N. Hay, I. Hamerton, S. Gunathilagan et al., Evidence for parallel destructive, and competitive epoxidation and dismutation pathways in metalloporphyrin-catalysed alkene oxidation by hydrogen peroxide Highly efficient epoxidation of olefins with pyridine noxides catalyzed by ruthenium porphyrins Fast Catalytic Hydroxylation of Hydrocarbons with Ruthenium Porphyrins Ruthenium Oxidation Complexes: Their Uses as Homogenous Organic Catalysts Oxometalloporphyrins in Oxidative Catalysis, Tetrahedron Tetrahedron Letters Inorganic Chemistry J. T, vol.30, issue.4, pp.57-6847, 1989.

Z. Wang and A. Straumanis, Synthesis of porphyrins: models of natural hemoproteins and impressive catalysts for asymmetric epoxidation of olefins, Polyhedron, vol.19, issue.5, pp.581-586, 2000.

A. B. Sorokin, Phthalocyanine Metal Complexes in Catalysis, Chemical Reviews, vol.113, issue.10, pp.8152-8191
DOI : 10.1021/cr4000072

URL : https://hal.archives-ouvertes.fr/hal-00872655

W. Chan, J. L. Zhang, N. J. Eric, M. Palucki, G. J. Mccormick et al., The Journal of Organic Chemistry 10 Enantioselective epoxidation of unfunctionalized Olefins Catalized by (Salen)manganese complex Low temperature asymmetric epoxidation of unfunctionalized olefins catalyzed by (salen)Mn(III) complexes Some Recent Advances in Metallosalen Chemistry Mn-salen catalyst, competitor of enzymes, for asymmetric epoxidation Catalytic asymmetric oxidations using optically active (salen)manganese(III) complexes as catalysts Metal-Salen Schiff base complexes in catalysis: practical aspects Asymmetric olefin epoxidation with sodium hypochlorite catalyzed by easily prepared chiral manganese(III) salen complexes Catalytic epoxidation of olefins and hydroxylation of alkanes with sodium periodate by water-soluble manganese(III)salen, Journal of the American Chemical Society Tetrahedron Letters Journal of Molecular Catalysis A: Chemical Coordination Chemistry Reviews Chemical Society Reviews The Journal of Organic Chemistry Journal of Molecular Catalysis, vol.70, issue.24412, pp.4226-4232, 1990.

G. P. Chiusoli, P. M. Maitlis, R. S. Chemistry, J. M. Workman, R. D. Powell et al., Metal-catalysis in Industrial Organic Processes 13. (a) Vibrational and electrochemical properties of a series of stable manganese(V)-oxo complexes, Inorganic Chemistry, vol.31, issue.9, pp.1548-1550, 1992.

A. D. Ryabov, T. J. Collins, F. T. De-oliveira, A. Chanda, D. Banerjee et al., Activation Parameters as Mechanistic Probes in the TAML Iron(V)?Oxo Oxidations of Hydrocarbons Chemical and Spectroscopic Evidence for an Fe(V)-Oxo Complex, Mechanism of Oxygen Atom Transfer from FeV(O) to Olefins at Room Temperature, pp.1803-1810, 2007.

C. Panda, J. Debgupta, D. Díaz-díaz, K. K. Singh, S. Sen-gupta et al., Iron Complex Catalyzed Selective C?H Bond Oxidation with Broad Substrate Scope Organic Letters A manganese(V)-oxo complex Formation of a Room Temperature Stable FeV(O) Complex: Reactivity Toward Unactivated C?H Bonds Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(v)-oxo complex Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation Designing ligands to achieve robust oxidation catalysts. Iron based systems TAML Oxidant Activators: A New Approach to the Activation of Hydrogen Peroxide for Environmentally Significant Problems, Homogeneous Photochemical Water Oxidation by Biuret-Modified Fe-TAML: Evidence of FeV(O) Intermediate Åkermark, B., A Tailor-Made Molecular Ruthenium Catalyst for the Oxidation of Water and Its Deactivation through Poisoning by Carbon Monoxide, pp.12273-12282, 1989.

W. Harwood, L. M. Hartl, and F. F. , Role of ligands in catalytic water oxidation by mononuclear ruthenium complexes, Coordination Chemistry Reviews, vol.2015, pp.304-305

S. Mandal, B. Stewart, T. Privalov, A. Llobet, L. Sun et al., Electrochemical evidence for catalyticwater oxidation mediated by a high-valent cobalt complex A nickel (II) PY5 complex as an electrocatalyst for water oxidation Alkane functionalization at nonheme iron centers Stoichiometric transfer of metal-bound ligands to alkane Reverse reactivity in hydroxylation of adamantane and epoxidation of cyclohexene catalyzed by the mononuclear ruthenium-oxo complexes with 6-substituted tripodal polypyridine ligands, Synthesis, Structure and Spectral, and Electrochemical Properties of New Mononuclear Ruthenium(III) Complexes of Tris[(benzimidazol-2-yl)methyl]amine: Role of Steric Hindrance in Tuning the Catalytic Oxidation Activity, pp.418-423, 1993.

O. Reinaud and F. Banse, Iron Coordination Chemistry with New Ligands Containing Triazole and Pyridine Moieties Comparison of the Coordination Ability of the N-Donors, Inorganic Chemistry J.-F, vol.2013, issue.522, pp.691-700

P. Battioni, D. Mansuy, C. R. Goldsmith, R. T. Jonas, T. D. Stack et al., Spectroscopic Characterization of an FeIV Intermediate Generated by Reaction of XO? (X = Cl, Br) with an FeII Complex Bearing a Pentadentate Non-Porphyrinic Ligand ? Hydroxylation and Epoxidation Activity C?H Bond Activation by a Ferric Methoxide Complex: Modeling the Rate-Determining Step in the Mechanism of Lipoxygenase, European Journal of Inorganic Chemistry Journal of the American Chemical Society, vol.23, issue.1241, pp.301-308, 2002.

H. L. Kooijman, A. Spek, R. L. Hage, and B. Feringa, A novel pentadentate ligand 2,6-bis[methoxybis(2- pyridyl)methyl]pyridine L for mononuclear iron(ii) and manganese(ii) compounds; synthesis and crystal structures of [FeL(MeCN), MnL(H2O)][ClO4]2 Fukuzumi, S., Ruthenium- Catalyzed Selective and Efficient Oxygenation of Hydrocarbons with Water as an Oxygen Source, pp.1549-1550, 1997.

E. Kadiri, M. Y. Ghachtouli, S. Guillot, R. Billon, L. Charlot et al., Chemical Activation of a Mononuclear Non-Porphyrinic Manganese Complex using Water as Oxygen Source for the Oxygen Atom Transfer Reaction Efficient Epoxidation of Styrene Derivatives by a Nonheme Iron(IV)-Oxo Complex via Proton-Coupled Electron Transfer with Triflic Acid, Selective steroid oxyfunctionalisation by CYP154C5, a bacterial cytochrome P450. Microbial Cell Factories 2013 Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis, pp.47-5772, 2004.

M. F. Charlot, R. Guillot, B. Andrioletti, A. Aukauloo, A. Abdel-magied et al., Dipyrrinphenol-Mn(III) complex: synthesis, electrochemistry, spectroscopic characterisation and reactivity. Dalton transactions Substituent Effects in Molecular Ruthenium Water Oxidation Catalysts Based on Amide Ligands Recent developments and perspectives in the ruthenium-catalyzed olefin epoxidation, Catalytic Water Oxidation by Ruthenium(II) Quaterpyridine (qpy) Complexes: Evidence for Ruthenium(III) qpy-N,N???dioxide as the Real Catalysts, pp.9090-9093, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00695893

?. Chemistry, S. European-semin, I. Razdolski, J. Xu, J. A. Elemans et al., Extended [small pi]-conjugated ruthenium zinc-porphyrin complexes with enhanced nonlinear-optical properties, Chemical Communications, vol.20, issue.5114, pp.8054-8061, 2014.

M. K. Nazeeruddin, M. Grätzel, C. P. Berlinguette, M. Shatruk, N. Kaveevivitchai et al., Near-IR Photoresponse of Ruthenium Dipyrrinate Terpyridine Sensitizers in the Dye-Sensitized Solar Cells, Further Observations on Water Oxidation Catalyzed by Mononuclear Ru(II) Complexes. Inorganic Chemistry 2012 Ru(II) Complexes of Tetradentate Ligands Related to, pp.5417-5419, 2008.

S. J. Smalley, M. R. Waterland, S. G. Telfer, G. Stochel, V. Bertolasi et al., Heteroleptic Dipyrrin/Bipyridine Complexes of Ruthenium(II) Inorganic Chemistry Photochemistry of transand cis-[RuCl2(dmso)4] in Aqueous and Nonaqueous Solutions Cis-and trans-dihalotetrakis(dimethyl sulfoxide)ruthenium(II) complexes (RuX2(DMSO)4; X = Cl, Br): synthesis, structure, and antitumor activity Dichlorotetrakis(dimethyl sulphoxide)ruthenium(II) and its use as a source material for some new ruthenium(II) complexes The trans-influence: its measurement and significance, Synthèse et caractérisation de complexes métalliques de ruthénium Mutual Influence of Ligands in Complexes cis and trans Effects of Dialkyl Sulfoxides in Complex Compounds of Platinum(II). Chemicke Zvesti, pp.13-15, 1971.

E. O. Lundell, G. E. Hoffman, and J. I. , The Trans Effect in Complex Inorganic Compounds The effect of light on silver chloride in chemical analyses, Chemical Reviews Bureau of Standards Journal of Research, vol.50, issue.4, pp.201-260, 1929.

P. Atkins, J. De-paula, . Atkins-'physical-chemistry, . Oup-oxford-38, S. Tarighi et al., Crystal Structure of cis-Ru(DMSO)4Cl2 in different synthetic methods Synergistic oxygen atom transfer by ruthenium complexes with non-redox metal ions Spectroscopie de résonance paramagnétique électronique10- Phenanthrenesemiquinone radical complexes of ruthenium(iii), osmium(iii) and rhodium(iii) and redox series, Characteristics and reactivity of ruthenium-oxo complexes. Dalton transactions 2016, pp.19-21, 2007.

W. R. Browne, D. A. Hrovat, M. G. Richmond, M. Costas, E. Nordlander et al., Nonheme Fe(IV) Oxo Complexes of Two New Pentadentate Ligands and Their Hydrogen-Atom and Oxygen-Atom Transfer Reactions Ferryl protonation in oxoiron(IV) porphyrins and its role in oxygen transfer, Inorganic Chemistry Journal of the American Chemical Society, vol.54, issue.1378, pp.7152-7164, 2015.

S. Fukuzumi, Enhanced Electron-Transfer Reactivity of Nonheme Manganese(IV)? Oxo Complexes by Binding Scandium Ions, Journal of the American Chemical Society, vol.2013, issue.13524, pp.9186-9194

S. Izquierdo, S. Essafi, I. Del-rosal, P. Vidossich, R. Pleixats et al., Acid Activation in Phenyliodine Dicarboxylates: Direct Observation, Structures, and Implications Development of Ruthenium Catalysts for Water Oxidation High-valent metal-oxo complexes generated in catalytic oxidation reactions using water as an oxygen source Renewable Fuels from Concentrated Solar Power: Towards Practical Artificial Photosynthesis Recent advances and perspectives in the manganese-catalysed epoxidation reactions The Conversion of Triphenylphosphine to the Oxide: A Simple Experiment to Illustrate Catalytic Oxotransfer, Journal of the American Chemical Society Coordination Chemistry Reviews Energy & Environmental Science Tetrahedron Journal of Chemical Education, vol.2016, issue.72110, pp.12747-12750, 1995.

A. Sipe, B. K. Meyer, T. J. Savéant, J. Polyansky, D. E. Muckerman et al., Oxygen transfer in the oxidation of triphenylphosphine by (bpy)2pyRuO2+ Inorganic Chemistry Molecular Catalysis of Electrochemical Reactions Mechanistic Aspects Water Oxidation by a Mononuclear Ruthenium Catalyst: Characterization of the Intermediates, Thummel, R. P., A New Family of Ru Complexes for Water Oxidation, pp.1475-1480, 1981.

R. Staehle, L. Tong, L. Wang, L. Duan, A. Fischer et al., Water Oxidation Catalyzed by Mononuclear Ruthenium Complexes with a 2,2?-Bipyridine-6,6?-dicarboxylate (bda) Ligand: How Ligand Environment Influences the Catalytic Behavior 1307-1319. 1. (a) Dequirez, G. Transferts de nitrène catalysés par les métaux de transition. Développement de nouvelles réactions pour la difonctionnalisation d'alcènes et application en synthèse Mechanistic insights and catalyst design for the development of efficient and selective rhodium-catalyzed C-H amination reactions, Inorganic Chemistry, vol.2014, issue.533, 2009.

P. Dauban, E. Dirhodium, . Ed, P. Müller, C. Fruit et al., Catalyzed C(sp3)-H Amination Using Iodine(III) Oxydants Enantioselective Catalytic Aziridinations and Asymmetric Nitrene Insertions into CH Bonds Iminoiodanes and C-NBond Formation in Organic Synthesis, Advances in Organometallic Chemistry, Inc, pp.77-118, 2003.

H. Kwart and A. A. Khan, Copper-Catalyzed Decomposition of Benzenesulfonyl Azide in Cyclohexene Solution, Journal of the American Chemical Society, vol.89, issue.8, pp.1951-1953, 1967.
DOI : 10.1021/ja00984a035

D. S. Breslow, M. F. Sloan, J. T. Groves, T. E. Nemo, R. S. Myers et al., A new synthesis of sulfonylnitrenes Hydroxylation and epoxidation catalyzed by ironporphine complexes. Oxygen transfer from iodosylbenzene Tosylamidation of cyclohexane by a cytochrome P-450 model, Tetrahedron Letters Journal of the American Chemical Society Chemical Communications, vol.9, issue.101424, pp.5349-5352, 1968.

J. P. Mahy, G. Bedi, P. Battioni, and D. Mansuy, ChemInform Abstract: Amination of Alkanes Catalyzed by Iron and Manganese Porphyrins: Particular Selectivity for ?? and ??-1 Oxidations of Linear Alkanes., ChemInform, vol.13, issue.15, pp.10-11, 1989.
DOI : 10.1002/chin.199015082

S. Au, J. Huang, W. Yu, and W. Y. Yu, Aziridination of Alkenes and Amidation of Alkanes by Bis(tosylimido)ruthenium(VI) Porphyrins. A Mechanistic Study, Catalytic C-H amination: the stereoselectivity issue, pp.9120-9132, 1999.
DOI : 10.1021/ja9913481

E. R. King, E. T. Hennessy, T. A. Betley, T. Katsuki, T. Uchida et al., 10 Asymmetric Nitrene Transfer Reactions: Sulfimidation, Aziridination and C?H Amination Using Azide Compounds as Nitrene Precursors Some Recent Advances in Metallosalen Chemistry Asymmetric Nitrene Transfer Reactions: Sulfimidation, Aziridination and C?H Amination Using Azide Compounds as Nitrene Precursors General route to highly functionalized cyclopentane derivatives by intramolecular C-H insertion Intramolecular nitrene carbon-hydrogen insertions mediated by transition-metal complexes as nitrogen analogs of cytochrome P-450 reactions An Enabling Method for Chemical Synthesis, Catalytic C?H Bond Amination from High-Spin Iron Imido Complexes Organic Process Research & Development Catalytic Intermolecular Amination of C?H Bonds: Method Development and Mechanistic Insights, pp.4917-4923, 1982.

C. G. Espino and J. Du-bois, A Rh-Catalyzed C???H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones, Angewandte Chemie International Edition, vol.11, issue.195, pp.598-600, 2001.
DOI : 10.1016/S0957-4166(99)00565-0

S. Au, J. Huang, C. Che, W. Yu, C. G. Espino et al., Amidation of Unfunctionalized Hydrocarbons Catalyzed by Ruthenium Cyclic Amine or Bipyridine Complexes Expanding the Scope of C?H Amination through Catalyst Design Metal-Metal Bond-Containing Complexes as Catalysts for C-H Functionalization Intermolecular C-H amination of complex molecules: insights into the factors governing the selectivity, Analyzing Site Selectivity in Rh2(esp)2-Catalyzed Intermolecular C?H Amination Reactions Nitrene Chemistry in Organic Synthesis: Still in Its Infancy, pp.7858-7864, 2000.

J. B. Mack, J. Du-bois, J. F. Berry, D. G. Musaev, K. P. Kornecki et al., Rh2(II,III) Catalysts with Chelating Carboxylate and Carboxamidate Supports: Electronic Structure and Nitrene Transfer Reactivity Evidence for a One-Electron Mechanistic Regime in Dirhodium-Catalyzed Intermolecular C-H Amination Understanding the differential performance of Rh2(esp)2 as a catalyst for C-H amination, Journal of the American Chemical Society Chemistry ? A European Journal Journal of the American Chemical Society Z, vol.2016, issue.22, pp.2327-2341, 2009.

R. H. Perry, T. J. Cahill, J. L. Roizen, J. Du-bois, R. N. Zare et al., Capturing fleeting intermediates in a catalytic C?H amination reaction cycle Axial Ligand Coordination to the C?H Amination Catalyst Rh2(esp)2: A Structural and Spectroscopic Study The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates. Dalton transactions Ligand dependence of the electronic configuration of the rhodium-rhodium bond in Rh25+ complexes as studied by electon spin resonance and electrochemistry Handbook of Bond Dissociation Energies in Organic Compounds Toward a Synthetically Useful Stereoselective C?H Amination of Hydrocarbons Single Electron Transfer at an Electrode Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation, Catalyzed Intramolecular Amidation of Carbamates. Chemistry ? An Asian Journal Homogeneous Photochemical Water Oxidation by Biuret-Modified Fe-TAML: Evidence of FeV(O) Intermediate. 32. Creutz, C.; Sutin, N., Reaction of tris(bipyridine)ruthenium(III) with hydroxide and its application in a solar energy storage system. Proceedings of the National Academy of Sciences of the United States of America, pp.1101-1108, 1975.

T. Collins, ESSAYS ON SCIENCE AND SOCIETY: Toward Sustainable Chemistry, Science, vol.291, issue.5501, pp.48-49, 2001.
DOI : 10.1126/science.291.5501.48

K. P. Kornecki and J. F. Berry, Evidence for a One-Electron Mechanistic Regime
DOI : 10.1002/chem.201100708

C. Intermolecular, C. Skubi, K. L. Blum, T. R. Yoon, and T. P. , Dual Catalysis Strategies in Photochemical Synthesis, Chemistry ? A European Journal, vol.17, issue.3, pp.5827-5832, 2011.

C. K. Prier, D. A. Rankic, and D. W. Macmillan, Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis, Chemical Reviews, vol.113, issue.7, pp.10035-10074, 2013.
DOI : 10.1021/cr300503r

W. Adam, A. Griesbeck, and E. Staab, A convenient " one-pot " synthesis of epoxy alcohols via photooxygenation of olefins in the presence of titanium(IV) catalyst, Tetrahedron Letters, issue.25, pp.27-2839, 1986.

H. Cano-yelo and A. Deronzier, Photo-oxidation of some carbinols by the Ru(II) polypyridyl complex-aryl diazonium salt system, Tetrahedron Letters, vol.25, issue.48, pp.25-5517, 1984.
DOI : 10.1016/S0040-4039(01)81614-2

S. Ohzu, T. Ishizuka, Y. Hirai, S. Fukuzumi, and T. Kojima, Photocatalytic Oxidation of Organic Compounds in Water by Using Ruthenium(II)-Pyridylamine Complexes as Catalysts with High Efficiency and Selectivity, Chemistry - A European Journal, vol.7, issue.5, pp.1563-1567
DOI : 10.1021/ol052025e

D. A. Dirocco and T. Rovis, Catalytic Asymmetric ?-Acylation of Tertiary Amines Mediated by a Dual Catalysis Mode: N-Heterocyclic Carbene and Photoredox Catalysis, Journal of the American Chemical Society, vol.2012, issue.19, pp.134-8094

M. D. Kärkäs, O. Verho, E. V. Johnston, B. Åkermark, H. Li et al., Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation Visible Light-Driven Water Oxidation Promoted by Host?Guest Interaction between Photosensitizer and Catalyst with A High Quantum Efficiency Development of Ruthenium Catalysts for Water Oxidation Water oxidation catalyzed by a charge-neutral mononuclear ruthenium(iii) complex. Dalton transactions Highly efficient photocatalytic oxygenation reactions using water as an oxygen source High-valent metal-oxo complexes generated in catalytic oxidation reactions using water as an oxygen source, 1304-1310. 10. (a), pp.11863-12001, 2011.

F. Quaranta, A. Ricoux, R. Trehoux, A. Mahammed, A. Gross et al., Oxidation catalysis via visible-light water activation of a [Ru(bpy)3](2+) chromophore BSAmetallocorrole couple Albumin-Conjugated Corrole Metal Complexes: Extremely Simple Yet Very Efficient Biomimetic Oxidation Systems Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage Photochemically induced olefin oxidation by titanyl and vanadyl porphyrins Mechanistic considerations in the photodisproportionation of .mu.-oxo-bis((tetraphenylporphinato)iron(III)) Oxidation of alkanes by dioxygen catalysed by photoactivated iron porphyrins, Dalton Trans Journal of the American Chemical Society Chemical Reviews Journal of Molecular Catalysis Journal of the American Chemical Society Chemical Communications, vol.620, issue.10710, pp.2323-2327, 1985.

I. Saito, M. Takayama, T. Matsuura, P. N. Singh, S. M. Mandel et al., Selective Formation of Triplet Alkyl Nitrenes from Photolysis of ?-Azido-Propiophenone and Their Reactivity The photochemical reaction of cerium(IV) ammonium nitrate with alkenes. Rate and mechanism for the addition of the nitrate radical to alkenes Visible-Light Sensitization of Vinyl Azides by Transition-Metal Photocatalysis Sensitized photolysis of organic azides. Possible case of nonclassical energy transfer Nitrogen-centered radical-mediated C-H imidation of arenes and heteroarenes via visible light induced photocatalysis Site-selective arene C-H amination via photoredox catalysis, Catalytic Intermolecular Amination of C?H Bonds: Method Development and Mechanistic Insights, pp.2237-2240, 1968.

C. G. Espino, K. W. Fiori, M. Kim, J. Du-bois, F. Bolletta et al., Rate Constants for the Quenching of Excited States of Metal Complexes in fluid solution Estimation of excited-state redox potentials by electron-transfer quenching Application of electron-transfer theory to excited-state redox processes Electron-transfer reactions of quinones, hydroquinones and methyl viologen, photosensitized by tris(2,2[prime or minute]-bipyridine)-ruthenium(II) Faraday Transactions 2: Molecular and Chemical Physics Kinetic relaxation measurement of rapid electron transfer reactions by flash photolysis. Conversion of light energy into chemical energy using the tris(2,2'-bipyridine)ruthenium(3+)-tris(2,2'-bipyridine)ruthenium(2+*) couple Toward a Synthetically Useful Stereoselective C?H Amination of Hydrocarbons Electron transfer between methyl viologen radicals and graphene oxide: Reduction, electron storage and discharge Isolation and oxidation-reduction of methylviologen cation radicals. Novel disproportionation in charge-transfer salts by x-ray crystallography, Expanding the Scope of C?H Amination through Catalyst Design Axial Ligand Coordination to the C?H Amination Catalyst Rh2(esp)2: A Structural and Spectroscopic Study, pp.15378-15379, 1975.

T. W. Hudnall, V. M. Lynch, and J. L. Sessler, Ion-Mediated Electron Transfer in a Supramolecular

A. Ensembleb, J. Savéant, and A. Macchioni, Effect of Ion Pairing on the Mechanism and Rate of Electron Transfer Ion Pairing in Transition-Metal Organometallic Chemistry, Science Electrochemical Aspects. The Journal of Physical Chemistry B Chemical Reviews, vol.329, issue.1056, pp.1324-1327, 2001.

C. P. Anderson, D. J. Salmon, T. J. Meyer, R. C. Young, S. Karlsson et al., Photochemical Generation of Ru(bpy)3+ and 02 Accumulative electron transfer: Multiple charge separation in artificial photosynthesis Insights into Decomposition Pathways and Fate of Ru(bpy)32+ during Photocatalytic Water Oxidation with S2O82-as Sacrificial Electron Acceptor Sulfate Radical Anion as a New Reagent for Fast Photochemical Oxidation of Proteins Potential for activated persulfate degradation of BTEX contamination, Journal of the American Chemical Society Faraday Discussions ACS Catalysis Analytical Chemistry Water Research, vol.99, issue.821815, pp.233-252, 1977.

P. Polczynski, R. Jurczakowski, and W. Grochala, Stabilization and strong oxidizing properties of Ag(ii) in a fluorine-free solvent, Quantum yield of formation of the lowest excited state of Ru(bpy)2+3 and Ru(phen)2+3. Inorganica Chimica Acta, pp.7480-7482, 1980.

P. Allongue, M. Delamar, B. Desbat, O. Fagebaume, R. Hitmi et al., Covalent Modification of Carbon Surfaces by Aryl Radicals Generated from the Electrochemical Reduction of Diazonium Salts The Electronic Spectra of Phenyl Radicals Solvent-induced and polyether-ligand-induced redox isomerization within an asymmetrically coordinated mixed-valence ion: trans-(py)(NH3)4Ru(4-NCpy)Ru(2,2'-bpy)2Cl4+-The action of diazo-salts on aromatic sulphonamides. Part I Chauvin, B. Physico-chimie de méso-tétraphénylporphyrines glycoconjuguées pour la photothérapie dynamique : vers une meilleure compréhension de la distribution plasmatique et de la localisation subcellulaire ? 2011. 43 Research on the chemistry of 2- hetarylbenzimidazoles. 4. Oxidation of 1-methyl-2-(5?-methyl-2?-hetaryl)benzimidazoles Design and development of photoanodes for water-splitting dye-sensitized photoelectrochemical cells, Journal of the American Chemical Society Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences Inorganic Chemistry Journal of the Chemical Society Transactions Chem Heterocycl Compd Chemical Society Reviews, vol.119, issue.20136, pp.201-207, 1921.

J. J. Concepcion and T. J. Meyer, Accumulation of multiple oxidative equivalents at a single site by crosssurface electron transfer on TiO2, Journal of the American Chemical Society, vol.2013, issue.13531, pp.11587-94

Z. Yu, F. Li, and L. Sun, Recent advances in dye-sensitized photoelectrochemical cells for solar hydrogen production based on molecular components, Energy & Environmental Science, vol.16, issue.3, pp.760-775, 2015.
DOI : 10.1039/C4CP04489D

D. Meoh and . Etoh, Samples were prepared by diluting 1 mg of product in 1 mL of solvent Then these solutions were diluted 10 times in CH3CN. For intermediate species, the sample were frozen in liquid nitrogen after the dilution then allowed to melt at room temperature just a few seconds before injection it in the device. 3. Electronic Paramagnetic Resonance spectroscopy For X-band (9.47 GHz) EPR measurements, we used a Bruker Elexsys E 500 spectrometer with an Oxford ESR9 liquid helium (5 K) flow cryostat using a gold-chromel thermocouple directly below the sample position. The complexes were dissolved either in DCM, acetone or DCM + 0.1 M TBAPF6 then transferred to an EPR tube and frozen to 77 K. Sample concentrations were typically 1 mM. For chemical oxidation in Chapter IV, the samples for EPR were prepared in an acetone/liquid nitrogen bath at -40 °C, and then 200 µL were transferred into an EPR tube that was pre-degassed and cooled in an acetone, ElectroSpray Ionisation Mass Spectrometry Mass spectra were realized on MicrOTOFq (Bruker. 2009) with the ESI + or ESI -method in high resolution mode

. Characterisations, 250 MHz) ?: ?140, pp.156-61

U. Dmso and R. , 313 nm ; 23 found : ?max = 360 nm, 314 nm Ru-F5DPPy (15) Protocol: 5 (40 mg, 86 µmol,1.00 eq) was dissolved in THF (20 mL) then triethylamine 0.2 M in THF (3.3 mL, 660 µmol, 7.70 eq) was added. This mixture was added dropwise in a yellow suspension of(Cl)2] (41 mg, 85 µmol, 1.00 eq) in toluene (20 mL) then heated at 110 °C under argon in the dark during 2 days. After concentration, the crude product was dissolved in DCM (30 mL) then washed with water (3 x 50 mL) The organic phase was evaporated and the solid was washed with diethyl ether, reference values : ?max = 365 nm, p.74

. Ru-f5dpbi, Protocol 37 µmol,1.00 eq) was dissolved in THF (10 mL) then trimethylamine (26 µL, 184 µmol, 5.00 eq) was added. This mixture was added dropwise in a yellow suspension of [Ru(DMSO)4(Cl)2] (18 mg, 37 µmol, 1.00 eq) in toluene (10 mL) then heated at 66 °C under argon in the dark during 4 days. After concentration, the crude product was dissolved in DCM (20 mL) then washed with aq, NaCl, vol.32, issue.86, p.10

. Ml, After the addition of an aqueous solution of (nBu4N, OH) 1.5 M (44 µL, 66 µmol, 1.00 eq), the solution was stirred during 2 hours. Then the solution was extracted with DCM (3 x 10 mL) After evaporation of organic phase, the product was obtained as a colorless sticky oil (25 mg, p.81

. Mg, 00 eq) in water (1 mL), the solution was mixed at room temperature for 10 min. A white precipitate was formed. After filtration, the product was obtained as white solid

. Mg, 00 eq) in water (1 mL), the solution was mixed at room temperature for 10 min. A white precipitate was formed. After filtration, the product was obtained as white solid (3 mg

B. 1. Gottlieb, H. E. Kotlyar, V. Nudelman, and A. , NMR Chemical Shifts of Common Laboratory Solvents as Trace Impurities, The Journal of Organic Chemistry, vol.62, issue.21, pp.62-7512, 1997.
DOI : 10.1021/jo971176v

F. Neese, W. Yang, R. G. Parr, and A. D. Becke, The ORCA program system Wiley Interdisciplinary Reviews: Computational Molecular Science Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density Density?functional thermochemistry. III. The role of exact exchange, Physical Review B The Journal of Chemical Physics, vol.2, issue.3727, pp.73-78, 1988.

A. Schäfer, C. Huber, and R. Ahlrichs, Fully optimized contracted Gaussian basis sets of triple zeta valence quality for atoms Li to Kr, The Journal of Chemical Physics, vol.100, issue.8, pp.5829-5835, 1994.
DOI : 10.1016/0009-2614(90)85472-O

F. Neese, An improvement of the resolution of the identity approximation for the formation of the Coulomb matrix, Journal of Computational Chemistry, vol.102, issue.14, pp.1740-1747, 2003.
DOI : 10.1063/1.469408

F. Weigend, Accurate Coulomb-fitting basis sets for H to Rn, Physical Chemistry Chemical Physics, vol.33, issue.9, pp.1057-1065, 2006.
DOI : 10.1007/s002140050244

A. Klamt and G. Schuurmann, COSMO: a new approach to dielectric screening in solvents with explicit expressions for the screening energy and its gradient, 799- 805. 8. (a) Casida, M. E., In Recent Advances in Density Functional Methods, 1993.
DOI : 10.1039/P29930000799

S. Stratmann, R. E. Scuseria, G. E. Frisch, M. J. Bauernschmitt, R. Ahlrichs et al., An efficient implementation of timedependent density-functional theory for the calculation of excitation energies of large molecules Treatment of electronic excitations within the adiabatic approximation of time dependent density functional theory Time-dependent density functional theory within the Tamm? Dancoff approximation Time-dependent density functional theory for radicals: An improved description of excited states with substantial double excitation character, Neese, F., Prediction of electron paramagnetic resonance g values using coupled perturbed, pp.8218-8224, 1995.

?. Hartree, . Fock, ?. Kohn, T. Sham-theory-petrenko, S. Kossmann et al., Enantioselective Catalytic Aziridinations and Asymmetric Nitrene Insertions into CH Bonds Efficient time-dependent density functional theory approximations for hybrid density functionals: Analytical gradients and parallelization. The Journal of Chemical Physics, Chemical Reviews, vol.115, issue.1345, pp.11080-11096, 2001.

D. J. Cioslowski, . Fox-gaussian01, I. Gaussian, C. Wallingford, D. G. Truhlar et al., A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions Revised Basis Sets for the LANL Effective Core Potentials Electrogenerated Polymers as Efficient and Robust Heterogeneous Catalysts for the Hydrolytic Kinetic Resolution of Terminal Epoxides Synthesis of new pyrrole?pyridine-based ligands using an in situ Suzuki coupling method A Versatile Method for the Synthesis of Benzimidazoles from o-Nitroanilines and Aldehydes in One Step via a Reductive Cyclization, The Journal of Chemical Physics Journal of Chemical Theory and Computation ChemCatChem Böttger, M.; Wiegmann, B.; Schaumburg, S Beilstein Journal of Organic Chemistry Synthesis A. M. Simonov; Oleinikova, L. Y. Chem Heterocycl Compd M, vol.09, issue.8018, pp.1029-1031, 1982.

A. R. Abrantes, M. Laranjo, M. Botelho, F. Furuta, and H. , Synthetic porphyrins bearing ?-propionate chains as photosensitizers for photodynamic therapy, Journal of Porphyrins and Phthalocyanines, vol.14, issue.20, pp.438-445, 2010.

M. J. Saif, K. R. Flower, I. P. Evans, A. Spencer, G. Wilkinson et al., A general method for the preparation of N-heterocyclic carbene? silver(I) complexes in water Dichlorotetrakis(dimethyl sulphoxide)ruthenium(II) and its use as a source material for some new ruthenium(II) complexes Photochemistry of trans-and cis-[RuCl2(dmso)4] in Aqueous and Nonaqueous Solutions Reaction of tris(bipyridine)ruthenium(III) with hydroxide and its application in a solar energy storage system(ii) quaterpyridine complex as a visible light-driven catalyst for both water oxidation and reduction short history of SHELX WinGX suite for small-molecule single-crystal crystallography, 7903-7907. 26. Sheldrick, G. M. SHELXS-97Rh2(esp)2(NHTces), pp.493-500, 1973.