A. Murugesan, C. Umarani, R. Subramanian, and N. Nedunchezhian, Renewable and Sustainable Energy Reviews 653. [4] Intergovernmental Panel on Climate Change, Climate Change 2014 Synthesis Report Summary Chapter for Policymakers, 2014. [5] ONU, Protocole de Kyoto à la convention-cadre des nations unies sur les changements climatiques, bibliographiques [1] European Energy Network (EnR), Energy efficiency in Europe: Overview of policies and good practices, pp.46-200832009, 1055.

B. C. Saha, Hemicellulose bioconversion, Journal of Industrial Microbiology and Biotechnology, vol.30, issue.5, p.279, 2003.
DOI : 10.1007/s10295-003-0049-x

C. R. Fischer, D. Klein-marcuschamer, and G. Stephanopoulos, Selection and optimization of microbial hosts for biofuels production, Metabolic Engineering, vol.10, issue.6, p.295, 2008.
DOI : 10.1016/j.ymben.2008.06.009

R. Van-den-broek, A. Faaij, and A. Van-wijk, Biomass combustion for power generation, Biomass and Bioenergy, vol.11, issue.4, p.271, 1996.
DOI : 10.1016/0961-9534(96)00033-5

W. Sebhat, Valorisation de la lignine par catalyse hétérogène en condition sous-critique en milieux aqueux et eau/alcool, 2015.

X. Wang, Biomass Fast Pyrolysis in Fluidized Bed, Product Cleaning by In-Situ Filtration, 2006.

F. Shafizadeh, Advances in Carbohydrate Chemistry, p.419, 1968.

A. Broido, KINETICS OF SOLID-PHASE CELLULOSE PYROLYSIS, 1976.
DOI : 10.1016/B978-0-12-637750-7.50006-6

A. G. Bradbury, Y. Sakai, and F. Shafizadeh, A kinetic model for pyrolysis of cellulose, Journal of Applied Polymer Science, vol.23, issue.11, p.3271, 1979.
DOI : 10.1002/app.1979.070231112

D. Chiaramonti, A. Oasmaa, and Y. Solantausta, Power generation using fast pyrolysis liquids from biomass, Renewable and Sustainable Energy Reviews, vol.11, issue.6, p.1056, 2007.
DOI : 10.1016/j.rser.2005.07.008

A. Gutierrez, M. E. Domine, and Y. Solantausta, Co-processing of upgraded bio-liquids in standard refinery units -fundamentals, 15th Eur. Biomass Conf. Exhib, 2007.

T. Milne, F. Agblevor, M. Davis, S. Deutch, and D. Johnson, A Review of the Chemical Composition of Fast-Pyrolysis Oils from Biomass, p.409, 1997.
DOI : 10.1007/978-94-009-1559-6_32

C. Branca, C. D. Blasi, and A. Galgano, Pyrolysis of Corncobs Catalyzed by Zinc Chloride for Furfural Production, Industrial & Engineering Chemistry Research, vol.49, issue.20, p.9743, 2010.
DOI : 10.1021/ie101067v

O. Terakado, A. Amano, and M. Hirasawa, Explosive degradation of woody biomass under the presence of metal nitrates, Journal of Analytical and Applied Pyrolysis, vol.85, issue.1-2, p.231, 2009.
DOI : 10.1016/j.jaap.2008.12.001

P. R. Patwardhan, J. A. Satrio, R. C. Brown, and B. H. Shanks, Influence of inorganic salts on the primary pyrolysis products of cellulose, Bioresource Technology, vol.101, issue.12, p.4646, 2010.
DOI : 10.1016/j.biortech.2010.01.112

M. V. Twigg and M. S. Spencer, Deactivation of supported copper metal catalysts for hydrogenation reactions, Applied Catalysis A: General, vol.212, issue.1-2, p.161, 2001.
DOI : 10.1016/S0926-860X(00)00854-1

D. Fabbri, C. Torri, and I. Mancini, Pyrolysis of cellulose catalysed by nanopowder metal oxides: production and characterisation of a chiral hydroxylactone and its role as building block, Green Chemistry, vol.46, issue.12, p.1374, 2007.
DOI : 10.1039/b707943e

D. S. Radlein, S. L. Mason, J. Piskorz, and D. S. Scott, Hydrocarbons from the catalytic pyrolysis of biomass, Energy & Fuels, vol.5, issue.5, p.760, 1991.
DOI : 10.1021/ef00029a024

H. Zhang, R. Xiao, H. Huang, and G. Xiao, Comparison of non-catalytic and catalytic fast pyrolysis of corncob in a fluidized bed reactor, Bioresource Technology, vol.100, issue.3, p.1428, 2009.
DOI : 10.1016/j.biortech.2008.08.031

A. Galadima and O. Muraza, Energy Conversion and Management, 2015.

C. A. Mullen and A. A. Boateng, Accumulation of Inorganic Impurities on HZSM-5 Zeolites during Catalytic Fast Pyrolysis of Switchgrass, Industrial & Engineering Chemistry Research, vol.52, issue.48, p.17156, 2013.
DOI : 10.1021/ie4030209

A. Imran, E. A. Bramer, K. Seshan, and G. Brem, High quality bio-oil from catalytic flash pyrolysis of lignocellulosic biomass over alumina-supported sodium carbonate, Fuel Processing Technology, vol.127, p.72, 2014.
DOI : 10.1016/j.fuproc.2014.06.011

M. S. Abu-bakar and J. O. Titiloye, Catalytic pyrolysis of rice husk for bio-oil production, Journal of Analytical and Applied Pyrolysis, vol.103, pp.362-368, 2013.
DOI : 10.1016/j.jaap.2012.09.005

R. H. Venderbosch, A Critical View on Catalytic Pyrolysis of Biomass, ChemSusChem, vol.59, issue.446, p.1306, 2015.
DOI : 10.1002/aic.14038

B. Zhang, Z. Zhong, P. Chen, and R. Ruan, Microwave-assisted catalytic fast pyrolysis of biomass for bio-oil production using chemical vapor deposition modified HZSM-5 catalyst, Bioresource Technology, vol.197, p.79, 2015.
DOI : 10.1016/j.biortech.2015.08.063

M. Barteau, Organic Reactions at Well-Defined Oxide Surfaces, Chemical Reviews, vol.96, issue.4, p.1413, 1996.
DOI : 10.1021/cr950222t

T. N. Pham, D. Shi, and D. E. Resasco, Kinetics and Mechanism of Ketonization of Acetic Acid on Ru/TiO2 Catalyst, Topics in Catalysis, vol.106, issue.6-9, p.706, 2014.
DOI : 10.1021/jp0211988

J. M. Stubenrauch and E. Brosha, Reaction of carboxylic acids on CeO2(111) and CeO2(100), Catalysis Today, vol.28, issue.4, p.431, 1996.
DOI : 10.1016/S0920-5861(96)00251-9

E. Laurent and B. Delmon, Study of the hydrodeoxygenation of carbonyl, car???ylic and guaiacyl groups over sulfided CoMo/??-Al2O3 and NiMo/??-Al2O3 catalysts, Applied Catalysis A: General, vol.109, issue.1, p.77, 1994.
DOI : 10.1016/0926-860X(94)85004-6

I. Graça, J. M. Lopes, M. F. Ribeiro, F. Ramôa-ribeiro, H. S. Cerqueira et al., Catalytic cracking in the presence of guaiacol, Applied Catalysis B: Environmental, vol.101, issue.3-4, p.613, 2011.
DOI : 10.1016/j.apcatb.2010.11.002

R. Prins and M. E. Bussell, Metal Phosphides: Preparation, Characterization and Catalytic Reactivity, Catalysis Letters, vol.47, issue.135, p.1413, 2012.
DOI : 10.1016/j.materresbull.2011.11.019

S. T. Oyama, T. Gott, H. Zhao, and Y. K. Lee, Transition metal phosphide hydroprocessing catalysts: A review, Catalysis Today, vol.143, issue.1-2, p.94, 2009.
DOI : 10.1016/j.cattod.2008.09.019

S. Boonyasuwat, T. Omotoso, D. E. Resasco, and S. P. Crossley, Conversion of Guaiacol over Supported Ru Catalysts, Catalysis Letters, vol.281, issue.53, p.783, 2013.
DOI : 10.1016/j.jcat.2011.03.030

M. Ozagac, Etude mécanistique de l' hydroconversion catalytique de bio-huiles de pyrolyse, 2016.

M. A. Jackson, Energy and Fuels, 2013.

R. W. Snell and B. H. Shanks, Insights into the Ceria-Catalyzed Ketonization Reaction for Biofuels Applications, ACS Catalysis, vol.3, issue.4, p.783, 2013.
DOI : 10.1021/cs400003n

S. Sitthisa and D. E. Resasco, Hydrodeoxygenation of Furfural Over Supported Metal Catalysts: A Comparative Study of Cu, Pd and Ni, Catalysis Letters, vol.550, issue.6, p.784, 2011.
DOI : 10.1016/j.susc.2003.12.014

Y. T. Cheng and G. W. Huber, Chemistry of Furan Conversion into Aromatics and Olefins over HZSM-5: A Model Biomass Conversion Reaction, ACS Catalysis, vol.1, issue.6, p.611, 2011.
DOI : 10.1021/cs200103j

Y. Cheng and G. W. Huber, Production of targeted aromatics by using Diels???Alder classes of reactions with furans and olefins over ZSM-5, Green Chemistry, vol.76, issue.6, p.3114, 2012.
DOI : 10.1016/0021-9517(82)90272-X

A. Gumidyala, T. Sooknoi, and S. Crossley, Selective ketonization of acetic acid over HZSM-5: The importance of acyl species and the influence of water, Journal of Catalysis, vol.340, p.76, 2016.
DOI : 10.1016/j.jcat.2016.04.017

A. T. Nielsen and W. J. Houlihan, The Aldol Condensation, 1968.
DOI : 10.1039/jr9650000833

T. A. Brandvold, Carbohydrate route to para-xylene and terephthalic acid, 2010.

C. L. Williams, C. C. Chang, P. Do, N. Nikbin, S. Caratzoulas et al., -Xylene, ACS Catalysis, vol.2, issue.6, p.935, 2012.
DOI : 10.1021/cs300011a

R. J. Argauer and G. R. Landolt, Crystalline zeolithe ZSM-5 and method of preparing the same, p.702886, 1972.

V. Santos, Caractérisation et modification de l'acidité résiduelle en zéolithes cationiques, 2008.

J. Rabo and G. J. Gajda, Guidelines for mastering the properties of molecular sieves, 1990.

M. Taramasso, G. Perego, and B. Notari, Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides, p.4410501, 1983.

M. Taramasso, G. Manara, V. Fattore, and B. Notari, Silica-based synthetic material containing titanium in the crystal lattice and process for its preparation, 1987.

B. Notari and . Stud, Synthesis and Catalytic Properties of Titanium Containing Zeolites, Surf. Sci. Catal, vol.37, p.413, 1988.
DOI : 10.1016/S0167-2991(09)60618-2

F. D. Mercader, Pyrolysis oil upgrading for co-processing in standard refinery units, 2010.

M. Ozagac, Etude mécanistique de l' hydroconversion catalytique de bio-huiles de pyrolyse, 2016.

G. Toussaint, C. Lorentz, M. Vrinat, and C. Geantet, Comprehensive 2D chromatography with mass spectrometry: a powerful tool for following the hydrotreatment of a Straight Run Gas Oil, Analytical Methods, vol.35, issue.12, p.2743, 2011.
DOI : 10.1021/ie960137r
URL : https://hal.archives-ouvertes.fr/hal-00699728

B. Joffres, Synthèse de bio-liquide de seconde génération par hydroliquéfaction catalytique de la lignine, 2013.

C. Marcilly, Catalyse acido-basique, 2003.

A. Auroux, Acidity and Basicity: Determination by Adsorption Microcalorimetry, Molecular Sieves, vol.6, p.45, 2008.
DOI : 10.1007/3829_008

M. Barteau, Organic Reactions at Well-Defined Oxide Surfaces, Chemical Reviews, vol.96, issue.4, p.1413, 1996.
DOI : 10.1021/cr950222t

T. N. Pham, D. Shi, and D. E. Resasco, Kinetics and Mechanism of Ketonization of Acetic Acid on Ru/TiO2 Catalyst, Topics in Catalysis, vol.106, issue.6-9, p.706, 2014.
DOI : 10.1021/jp0211988

J. M. Stubenrauch and E. Brosha, Reaction of carboxylic acids on CeO2(111) and CeO2(100), Catalysis Today, vol.28, issue.4, p.431, 1996.
DOI : 10.1016/S0920-5861(96)00251-9

R. Miller, Ullman's Encyclopedia of Industrial Chemistry, 2001.

M. S. Scurrell, Applied Catalysis, p.41, 1988.

V. N. Bui, Catalyseurs cobalt-molybdène pour l'hydrodésoxygénation du guaicol: effet de support et effet de promotion, 2008.

. Bilans-matières-et-propriétés-des-liquides??????????????, 144 I.4 Analyses des bio-huiles??????????????????????147 I.4.1. La phase aqueuse?????????????????????147 I, p.158

. Mesures-de-la-température-et-des-pressions?????????????, 159 I.6. Régénération de la zéolithe H-MFI-90???????????????...160 I.6.1. Oxydation en température programmée????????????, p.162

I. Etude-de-différents-paramètres-lors-de-la-pyrolyse????, 163 II, p.164

. Dans-la-conversion-des-vapeurs?????????????, 172 III.1. Caractérisation des catalyseurs étudiés??????????????, p.174

M. S. Abu-bakar and J. O. Titiloye, Catalytic pyrolysis of rice husk for bio-oil production, Journal of Analytical and Applied Pyrolysis, vol.103, pp.362-368, 2013.
DOI : 10.1016/j.jaap.2012.09.005

S. Hamieh, Transformation des alcools sur zéolithes protoniques : " rôle paradoxal du coke, 2013.

R. W. Snell and B. H. Shanks, Insights into the Ceria-Catalyzed Ketonization Reaction for Biofuels Applications, ACS Catalysis, vol.3, issue.4, p.783, 2013.
DOI : 10.1021/cs400003n

E. M. Rubin, Genomics of cellulosic biofuels, Nature, vol.23, issue.7206, pp.454-841, 2008.
DOI : 10.1038/nature07190

G. W. Huber and A. Corma, Synergies between Bio- and Oil Refineries for the Production of Fuels from Biomass, Angewandte Chemie International Edition, vol.34, issue.38, pp.7184-7201, 2007.
DOI : 10.1080/08843759108942262

A. V. Bridgwater, Review of fast pyrolysis of biomass and product upgrading, Biomass and Bioenergy, vol.38, pp.68-94, 2012.
DOI : 10.1016/j.biombioe.2011.01.048

A. V. Bridgwater and G. V. Peacocke, Fast pyrolysis processes for biomass, Renewable and Sustainable Energy Reviews, vol.4, issue.1, pp.1-73, 2000.
DOI : 10.1016/S1364-0321(99)00007-6

S. Czernik and A. V. Bridgwater, Overview of Applications of Biomass Fast Pyrolysis Oil, Energy & Fuels, vol.18, issue.2, pp.590-598, 2004.
DOI : 10.1021/ef034067u

R. H. Venderbosch and W. , Prins, Fast pyrolysis technology development, pp.178-208, 2010.
DOI : 10.1002/bbb.205

S. Xiu and A. Shahbazi, Bio-oil production and upgrading research: A review, Renewable and Sustainable Energy Reviews, vol.16, issue.7, pp.4406-4414, 2012.
DOI : 10.1016/j.rser.2012.04.028

W. Nor-roslam-wan-isahak and M. W. Hisham, Mohd Ambar Yarmo, Taufiq-yap Yun Hin, A review on bio-oil production from biomass by using pyrolysis method, Renew. Sustain. Energy Rev, pp.16-5910, 2012.

M. C. Samolada, W. Baldauf, and I. A. Vasalos, Production of a bio-gasoline by upgrading biomass flash pyrolysis liquids via hydrogen processing and catalytic cracking, Fuel, vol.77, issue.14, pp.77-1667, 1998.
DOI : 10.1016/S0016-2361(98)00073-8

A. Gutierrez, M. E. Domine, and Y. Solantaust, Co-processing of upgraded bio-liquids in standard refinery units ? Fundamentals, presented at the 15th European Biomass Conference & Exhibition, 2007.

J. Wildschut, J. Arentz, C. B. Rasrendra, R. H. Venderbosch, and H. J. Heeres, Catalytic hydrotreatment of fast pyrolysis oil: Model studies on reaction pathways for the carbohydrate fraction, Environmental Progress & Sustainable Energy, vol.84, issue.3, pp.28-450, 2009.
DOI : 10.1021/ie801387v

R. H. Venderbosch, A. R. Ardiyanti, J. Wildschut, A. Oasmaa, and H. J. Heeres, Stabilization of biomass-derived pyrolysis oils, Journal of Chemical Technology & Biotechnology, vol.77, issue.5, pp.85-674, 2010.
DOI : 10.1007/978-94-009-2737-7_68

D. C. Elliott, Historical Developments in Hydroprocessing Bio-oils, Energy & Fuels, vol.21, issue.3, pp.1792-1815, 2007.
DOI : 10.1021/ef070044u

D. C. Elliott, S. J. Lee, and T. R. Hart, Stabilization of Fast Pyrolysis Oil, 2012.

F. De-miguel-mercader, M. J. Groeneveld, S. R. Kersten, C. Geantet, G. Toussaint et al., Hydrodeoxygenation of pyrolysis oil fractions: process understanding and quality assessment through co-processing in refinery units, Energy & Environmental Science, vol.23, issue.3, p.985, 2011.
DOI : 10.1021/ef800507z

M. Ozagac, C. Bertino-ghera, D. Uzio, M. Rivallan, D. Laurenti et al., Impact of guaiacol on the formation of undesired macromolecules during catalytic hydroconversion of bio-oil: A model compounds study, Biomass and Bioenergy, vol.95, pp.182-193, 2016.
DOI : 10.1016/j.biombioe.2016.09.022
URL : https://hal.archives-ouvertes.fr/hal-01428619

R. French and S. Czernik, Catalytic pyrolysis of biomass for biofuels production, Fuel Processing Technology, vol.91, issue.1, pp.25-32, 2010.
DOI : 10.1016/j.fuproc.2009.08.011

C. Liu, H. Wang, A. M. Karim, J. Suna, and Y. Wang, Catalytic fast pyrolysis of lignocellulosic biomass, Chem. Soc. Rev., vol.37, issue.116, pp.43-7594, 2014.
DOI : 10.1016/j.ijhydene.2012.05.067

G. Yildiz, F. Ronsse, R. Van-duren, and W. Prins, Challenges in the design and operation of processes for catalytic fast pyrolysis of woody biomass, Renewable and Sustainable Energy Reviews, vol.57, pp.1596-1610, 2016.
DOI : 10.1016/j.rser.2015.12.202

D. A. Ruddy, J. A. Schaidle, J. R. Ferrell, I. , J. Wang et al., Recent advances in heterogeneous catalysts for bio-oil upgrading via ???ex situ catalytic fast pyrolysis???: catalyst development through the study of model compounds, Green Chem., vol.28, issue.137, pp.16-454, 2014.
DOI : 10.1021/la2051004

A. A. Lappas, M. C. Samolada, D. K. Iatridis, S. S. Voutetakis, and I. A. Vasalos, Biomass pyrolysis in a circulating fluid bed reactor for the production of fuels and chemicals, Fuel, vol.81, issue.16, pp.2087-2095, 2002.
DOI : 10.1016/S0016-2361(02)00195-3

E. Antonakou, A. A. Lappas, M. H. Nilsen, A. Bouzga, and M. Stocker, Evaluation of various types of Al-MCM-41 materials as catalysts in biomass pyrolysis for the production of bio-fuels and chemicals, Fuel, vol.85, issue.14-15, pp.2202-2212, 2006.
DOI : 10.1016/j.fuel.2006.03.021

A. Aho, N. Kumar, K. Eranen, T. Salmi, M. Hupa et al., Catalytic pyrolysis of woody biomass in a fluidized bed reactor: Influence of the zeolite structure, Fuel, vol.87, issue.12, pp.2493-2501, 2008.
DOI : 10.1016/j.fuel.2008.02.015

F. Gong, Z. Yang, C. Hong, W. Huang, S. Ning et al., Selective conversion of bio-oil to light olefins: Controlling catalytic cracking for maximum olefins, Bioresource Technology, vol.102, issue.19, pp.9247-9254, 2011.
DOI : 10.1016/j.biortech.2011.07.009

G. Dobele, G. Rossinskaja, T. Dizhbite, G. Telysheva, D. Meier et al., Application of catalysts for obtaining 1,6-anhydrosaccharides from cellulose and wood by fast pyrolysis, Journal of Analytical and Applied Pyrolysis, vol.74, issue.1-2, pp.401-405, 2005.
DOI : 10.1016/j.jaap.2004.11.031

K. Bru, J. Blin, A. Julbe, and G. Volle, Pyrolysis of metal impregnated biomass: An innovative catalytic way to produce gas fuel, Journal of Analytical and Applied Pyrolysis, vol.78, issue.2, pp.291-300, 2007.
DOI : 10.1016/j.jaap.2006.08.006
URL : https://hal.archives-ouvertes.fr/hal-00165774

Y. Richardson, J. Blin, G. Volle, J. Motuzas, and A. Julbe, In situ generation of Ni metal nanoparticles as catalyst for H2-rich syngas production from biomass gasification, Applied Catalysis A: General, vol.382, issue.2, pp.220-230, 2010.
DOI : 10.1016/j.apcata.2010.04.047
URL : https://hal.archives-ouvertes.fr/hal-01701151

Q. Lu and C. Dong, Selective fast pyrolysis of biomass impregnated with ZnCl2 to produce furfural: Analytical Py-GC/MS study, Journal of Analytical and Applied Pyrolysis, vol.90, issue.2, pp.90-204, 2011.
DOI : 10.1016/j.jaap.2010.12.007

S. Eibner, F. Broust, J. Blin, and A. Julbe, Catalytic effect of metal nitrate salts during pyrolysis of impregnated biomass, Journal of Analytical and Applied Pyrolysis, vol.113, pp.143-152, 2015.
DOI : 10.1016/j.jaap.2014.11.024
URL : https://hal.archives-ouvertes.fr/hal-01625185

P. A. Horne and P. T. Williams, Upgrading of biomass-derived pyrolytic vapours over zeolite ZSM-5 catalyst: effect of catalyst dilution on product yields, Fuel, vol.75, issue.9, pp.1043-1050, 1996.
DOI : 10.1016/0016-2361(96)00082-8

T. S. Nguyen, M. Zabeti, L. Lefferts, G. Bremb, and K. Seshan, Catalytic upgrading of biomass pyrolysis vapours using faujasite zeolite catalysts, Biomass and Bioenergy, vol.48, pp.48-100, 2013.
DOI : 10.1016/j.biombioe.2012.10.024

A. Pattiya, J. O. Titiloye, and A. V. Bridgwater, Fast pyrolysis of cassava rhizome in the presence of catalysts, Journal of Analytical and Applied Pyrolysis, vol.81, issue.1, pp.72-79, 2008.
DOI : 10.1016/j.jaap.2007.09.002

C. Torri, M. Reinikainen, C. Lindfors, D. Fabbri, A. Oasmaa et al., Investigation on catalytic pyrolysis of pine sawdust: Catalyst screening by Py-GC-MIP-AED, Journal of Analytical and Applied Pyrolysis, vol.88, issue.1, pp.7-13, 2010.
DOI : 10.1016/j.jaap.2010.02.005

G. Yildiz, T. Lathouwers, H. E. Toraman, K. M. Van-geem, G. B. Marin et al., Catalytic Fast Pyrolysis of Pine Wood: Effect of Successive Catalyst Regeneration, Energy & Fuels, vol.28, issue.7, pp.28-4560, 2014.
DOI : 10.1021/ef500636c

S. Vichaphund, D. Aht-ong, V. Sricharoenchaikul, and D. Atong, Production of aromatic compounds from catalytic fast pyrolysis of Jatropha residues using metal/HZSM-5 prepared by ion-exchange and impregnation methods, Renewable Energy, vol.79, pp.79-107, 2015.
DOI : 10.1016/j.renene.2014.10.013

N. Koike, S. Hosokai, A. Takagaki, S. Nishimura, R. Kikuchi et al., Upgrading of pyrolysis bio-oil using nickel phosphide catalysts, Journal of Catalysis, vol.333, pp.333-115, 2016.
DOI : 10.1016/j.jcat.2015.10.022

T. S. Nguyen, L. Lefferts, K. Babu, S. S. Gupta, and K. Seshan, Catalytic Conversion of Biomass Pyrolysis Vapours over Sodium-Based Catalyst: A Study on the State of Sodium on the Catalyst, ChemCatChem, vol.99, issue.12, pp.7-1833, 2015.
DOI : 10.1021/j100043a057

S. D. Stefanidis, S. A. Karakoulia, K. G. Kalogiannis, E. Iliopoulou, A. Delimitis et al., Natural magnesium oxide (MgO) catalysts: A cost-effective sustainable alternative to acid zeolites for the in situ upgrading of biomass fast pyrolysis oil, Applied Catalysis B: Environmental, vol.196, pp.155-173, 2016.
DOI : 10.1016/j.apcatb.2016.05.031

O. D. Mante, J. A. Rodriguez, S. D. Senanayake, and S. P. Babu, Catalytic conversion of biomass pyrolysis vapors into hydrocarbon fuel precursors, Green Chemistry, vol.266, issue.143, pp.2362-2368, 2015.
DOI : 10.1016/j.jcat.2009.06.014

C. Mukarakate, M. J. Watson, J. Ten-dam, X. Baucherel, S. Budhi et al., Upgrading biomass pyrolysis vapors over ??-zeolites: role of silica-to-alumina ratio, Green Chem., vol.24, issue.12, pp.16-4891, 2014.
DOI : 10.1021/ef100896q

Y. Zhao, L. Deng, B. Liao, Y. Fu, and Q. Guo, Aromatics Production via Catalytic Pyrolysis of Pyrolytic Lignins from Bio-Oil, Energy & Fuels, vol.24, issue.10, pp.24-5735, 2010.
DOI : 10.1021/ef100896q

M. S. Abu-bakar and J. O. Titiloye, Catalytic pyrolysis of rice husk for bio-oil production, Journal of Analytical and Applied Pyrolysis, vol.103
DOI : 10.1016/j.jaap.2012.09.005

H. J. Park, H. S. Heo, J. Jeon, J. Kim, R. Ryoo et al., Highly valuable chemicals production from catalytic upgrading of radiata pine sawdust-derived pyrolytic vapors over mesoporous MFI zeolites, Applied Catalysis B: Environmental, vol.95, issue.3-4, pp.95-365, 2010.
DOI : 10.1016/j.apcatb.2010.01.015

Y. Huang, L. Wei, Z. Crandall, J. Julson, and Z. Gu, Combining Mo???Cu/HZSM-5 with a two-stage catalytic pyrolysis system for pine sawdust thermal conversion, Fuel, vol.150, pp.150-656, 2015.
DOI : 10.1016/j.fuel.2015.02.071

P. Li, D. Li, H. Yang, X. Wang, and H. Chen, Effects of Fe-, Zr-, and Co-Modified Zeolites and Pretreatments on Catalytic Upgrading of Biomass Fast Pyrolysis Vapors, Energy & Fuels, vol.30, issue.4, pp.30-3004, 2016.
DOI : 10.1021/acs.energyfuels.5b02894

E. F. Iliopoulou, S. Stefanidis, K. Kalogiannis, A. C. Psarras, A. Delimitis et al., Pilot-scale validation of Co-ZSM-5 catalyst performance in the catalytic upgrading of biomass pyrolysis vapours, Green Chem., vol.5, issue.2, pp.16-662, 2014.
DOI : 10.1002/cctc.201200691

M. M. Yung, A. K. Starace, C. Mukarakate, A. M. Crow, M. A. Leshnov et al., Biomass Catalytic Pyrolysis on Ni/ZSM-5: Effects of Nickel Pretreatment and Loading, Energy & Fuels, vol.30, issue.7, pp.30-5259, 2016.
DOI : 10.1021/acs.energyfuels.6b00239

T. M. Brown, P. Duan, and P. E. Savage, Hydrothermal Liquefaction and Gasification of Nannochloropsis sp., Energy & Fuels, vol.24, issue.6, pp.3639-3646, 2010.
DOI : 10.1021/ef100203u

G. Toussaint, C. Lorentz, M. Vrinat, and C. Geantet, Comprehensive 2D chromatography with mass spectrometry: a powerful tool for following the hydrotreatment of a Straight Run Gas Oil, Analytical Methods, vol.35, issue.12, pp.2743-2748, 2011.
DOI : 10.1021/ie960137r
URL : https://hal.archives-ouvertes.fr/hal-00699728

B. Joffres, M. T. Nguyen, D. Laurenti, C. Lorentz, V. Souchon et al., Lignin hydroconversion on MoS2-based supported catalyst: Comprehensive analysis of products and reaction scheme, Appl. Catal. B: Env, pp.184-153, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01337995

B. Omais, M. Courtiade, N. Charon, D. Thiébaut, A. Quignard et al., Investigating comprehensive two-dimensional gas chromatography conditions to optimize the separation of oxygenated compounds in a direct coal liquefaction middle distillate, Journal of Chromatography A, vol.1218, issue.21, pp.1218-3233, 2011.
DOI : 10.1016/j.chroma.2010.12.049

K. Schofield, The enigmatic mechanism of the flame ionization detector: Its overlooked implications for fossil fuel combustion modeling, Progress in Energy and Combustion Science, vol.34, issue.3, pp.330-350, 2008.
DOI : 10.1016/j.pecs.2007.08.001

G. Yildiz, F. Ronsse, R. Venderbosch, R. Van-duren, S. R. Kersten et al., Effect of biomass ash in catalytic fast pyrolysis of pine wood, Applied Catalysis B: Environmental, vol.168, issue.169, pp.168-169, 2015.
DOI : 10.1016/j.apcatb.2014.12.044

]. D. Mohan, C. U. Pittman, and P. H. Steele, Pyrolysis of Wood/Biomass for Bio-oil:??? A Critical Review, Energy & Fuels, vol.20, issue.3, pp.848-889, 2006.
DOI : 10.1021/ef0502397

P. M. Mortensen, J. D. Grunwaldt, P. A. Jensen, K. G. Knudsen, and A. D. Jensen, A review of catalytic upgrading of bio-oil to engine fuels, Applied Catalysis A: General, vol.407, issue.1-2, pp.1-19, 2011.
DOI : 10.1016/j.apcata.2011.08.046

J. P. Diebold, A Review of the Chemicals and Physical Mechanisms of the Storage Stability of Fast Pyrolysis Bio-oils, 2000.
DOI : 10.2172/753818

A. V. Bridgwater, Upgrading biomass fast pyrolysis liquids, Environmental Progress & Sustainable Energy, vol.79, issue.2, pp.261-268, 2012.
DOI : 10.1016/S0960-8524(00)00180-2

M. S. Abu-bakar and J. O. Titiloye, Catalytic pyrolysis of rice husk for bio-oil production, Journal of Analytical and Applied Pyrolysis, vol.103, pp.362-368, 2013.
DOI : 10.1016/j.jaap.2012.09.005

A. Aho, N. Kumar, K. Eränen, T. Salmi, M. Hupa et al., Catalytic pyrolysis of woody biomass in a fluidized bed reactor: Influence of the zeolite structure, Fuel, vol.87, issue.12, pp.2493-2501, 2008.
DOI : 10.1016/j.fuel.2008.02.015

M. Olazar, R. Aguado, J. Bilbao, and A. Barona, Pyrolysis of sawdust in a conical spouted-bed reactor with a HZSM-5 catalyst, AIChE Journal, vol.206, issue.5, pp.1025-1033, 2000.
DOI : 10.1007/978-94-011-3844-4_2

H. S. Choi and D. Meier, Fast pyrolysis of Kraft lignin???Vapor cracking over various fixed-bed catalysts, Journal of Analytical and Applied Pyrolysis, vol.100, pp.207-212, 2013.
DOI : 10.1016/j.jaap.2012.12.025

R. French and S. Czernik, Catalytic pyrolysis of biomass for biofuels production, Fuel Processing Technology, vol.91, issue.1, pp.25-32, 2010.
DOI : 10.1016/j.fuproc.2009.08.011

T. R. Carlson, J. Jae, Y. Lin, G. A. Tompsett, and G. W. Huber, Catalytic fast pyrolysis of glucose with HZSM-5: The combined homogeneous and heterogeneous reactions, Journal of Catalysis, vol.270, issue.1, pp.110-124, 2010.
DOI : 10.1016/j.jcat.2009.12.013

A. J. Foster, J. Jae, Y. Cheng, G. W. Huber, R. F. Lobo et al., Optimizing the aromatic yield and distribution from catalytic fast pyrolysis of biomass over ZSM-5 Transformation of oxygenate components of biomass pyrolysis oil on a HZSM-5 zeolite. I. Alcohols and phenols, Appl. Catal. Gen. Ind. Eng. Chem. Res, pp.423-424, 2004.

P. A. Horne and P. T. Williams, Reaction of oxygenated biomass pyrolysis model compounds over a ZSM-5 catalyst, Renewable Energy, vol.7, issue.2, pp.131-144, 1996.
DOI : 10.1016/0960-1481(96)85423-1

E. F. Iliopoulou, S. D. Stefanidis, K. G. Kalogiannis, A. Delimitis, A. A. Lappas et al., Catalytic upgrading of biomass pyrolysis vapors using transition metal-modified ZSM-5 zeolite, Applied Catalysis B: Environmental, vol.127, pp.281-290, 2012.
DOI : 10.1016/j.apcatb.2012.08.030

Z. Ma, E. Troussard, and J. A. Van-bokhoven, Controlling the selectivity to chemicals from lignin via catalytic fast pyrolysis, Applied Catalysis A: General, vol.423, issue.424, pp.423-424, 2012.
DOI : 10.1016/j.apcata.2012.02.027

A. Aho, T. Salmi, and D. Y. Murzin, Catalytic pyrolysis of lignocellulosic biomass Role Catal, Sustain. Prod. Bio-Fuels Bio-Chem, pp.137-159

Y. T. Cheng, J. Jae, J. Shi, W. Fan, and G. W. Huber, Production of renewable aromatic compounds by catalytic fast pyrolysis of lignocellulosic biomass with bifunctional Ga/ZSM-5 catalysts, Angew. Chem. Int. Ed. Engl, vol.51, pp.1416-1419, 2012.

D. J. Mihalcik, C. A. Mullen, and A. A. Boateng, Screening acidic zeolites for catalytic fast pyrolysis of biomass and its components, Journal of Analytical and Applied Pyrolysis, vol.92, issue.1, pp.224-232, 2011.
DOI : 10.1016/j.jaap.2011.06.001

C. A. Mullen, A. A. Boateng, D. J. Mihalcik, and N. M. Goldberg, Catalytic Fast Pyrolysis of White Oak Wood in a Bubbling Fluidized Bed, Energy & Fuels, vol.25, issue.11, pp.5444-5451, 2011.
DOI : 10.1021/ef201286z

T. S. Nguyen, M. Zabeti, L. Lefferts, G. Brem, and K. Seshan, Catalytic upgrading of biomass pyrolysis vapours using faujasite zeolite catalysts, Biomass and Bioenergy, vol.48, pp.100-110, 2013.
DOI : 10.1016/j.biombioe.2012.10.024

A. Aho, N. Kumar, A. V. Lashkul, K. Eränen, M. Ziolek et al., Catalytic upgrading of woody biomass derived pyrolysis vapours over iron modified zeolites in a dual-fluidized bed reactor, Fuel, vol.89, issue.8, 1992.
DOI : 10.1016/j.fuel.2010.02.009

E. Antonakou, A. Lappas, M. H. Nilsen, A. Bouzga, and M. Stöcker, Evaluation of various types of Al-MCM-41 materials as catalysts in biomass pyrolysis for the production of bio-fuels and chemicals, Fuel, vol.85, issue.14-15, pp.2202-2212, 2006.
DOI : 10.1016/j.fuel.2006.03.021

M. H. Nilsen, E. Antonakou, A. Bouzga, A. Lappas, K. Mathisen et al., Investigation of the effect of metal sites in Me???Al-MCM-41 (Me=Fe, Cu or Zn) on the catalytic behavior during the pyrolysis of wooden based biomass, Microporous and Mesoporous Materials, vol.105, issue.1-2, pp.189-203, 2007.
DOI : 10.1016/j.micromeso.2007.05.059

M. C. Samolada, A. Papafotica, and I. A. Vasalos, Catalyst Evaluation for Catalytic Biomass Pyrolysis, Energy & Fuels, vol.14, issue.6, pp.1161-1167, 2000.
DOI : 10.1021/ef000026b

S. Wan, T. Pham, S. Zhang, L. Lobban, D. Resasco et al., catalyst, AIChE Journal, vol.96, issue.7, pp.2275-2285, 2013.
DOI : 10.1016/j.apcatb.2010.01.033

S. D. Stefanidis, K. G. Kalogiannis, E. F. Iliopoulou, A. A. Lappas, and P. A. Pilavachi, In-situ upgrading of biomass pyrolysis vapors: Catalyst screening on a fixed bed reactor, Bioresource Technology, vol.102, issue.17, pp.8261-8267, 2011.
DOI : 10.1016/j.biortech.2011.06.032

M. A. Patel, M. A. Baldanza, V. Teixeira-da-silva, and A. V. Bridgwater, In situ catalytic upgrading of bio-oil using supported molybdenum carbide, Applied Catalysis A: General, vol.458, pp.48-54, 2013.
DOI : 10.1016/j.apcata.2013.03.029

C. H. Bartholomew, Mechanisms of catalyst deactivation, Applied Catalysis A: General, vol.212, issue.1-2, pp.17-60, 2001.
DOI : 10.1016/S0926-860X(00)00843-7

G. T. Neumann and J. C. Hicks, Novel Hierarchical Cerium-Incorporated MFI Zeolite Catalysts for the Catalytic Fast Pyrolysis of Lignocellulosic Biomass, ACS Catalysis, vol.2, issue.4, pp.642-646, 2012.
DOI : 10.1021/cs200648q

A. Gonç-alves, J. Silvestre-albero, E. V. Ramos-fernández, J. C. Serrano-ruiz, J. J. Órfão et al., Highly dispersed ceria on activated carbon for the catalyzed ozonation of organic pollutants, Appl. Catal

M. Ishikawa, M. Tamura, Y. Nakagawa, and K. Tomishige, Demethoxylation of guaiacol and methoxybenzenes over carbon-supported Ru???Mn catalyst, Applied Catalysis B: Environmental, vol.182, pp.193-203, 2016.
DOI : 10.1016/j.apcatb.2015.09.021

A. M. Azeez, D. Meier, J. Odermatt, and T. Willner, Fast Pyrolysis of African and European Lignocellulosic Biomasses Using Py-GC/MS and Fluidized Bed Reactor, Energy & Fuels, vol.24, issue.3, pp.2078-2085, 2010.
DOI : 10.1021/ef9012856

A. Oasmaa, D. C. Elliott, and J. Korhonen, Acidity of Biomass Fast Pyrolysis Bio-oils, Energy & Fuels, vol.24, issue.12, pp.6548-6554, 2010.
DOI : 10.1021/ef100935r

C. A. Gaertner, J. C. Serrano-ruiz, D. J. Braden, and J. A. Dumesic, Ketonization Reactions of Carboxylic Acids and Esters over Ceria???Zirconia as Biomass-Upgrading Processes, Industrial & Engineering Chemistry Research, vol.49, issue.13, pp.6027-6033, 2010.
DOI : 10.1021/ie1004338

E. F. Iliopoulou, Review of C-C Coupling Reactions in Biomass Exploitation Processes, Current Organic Synthesis, vol.7, issue.6, pp.587-598, 2010.
DOI : 10.2174/157017910794328592

M. Renz, Ketonization of carboxylic acids by decarboxylation: mechanism and scope, Eur. J. Org. Chem, pp.979-988, 2005.

M. Glinski, J. Kijenski, and A. Jakubowski, Ketones from monocarboxylic acids: Catalytic ketonization over oxide systems, Applied Catalysis A: General, vol.128, issue.2, pp.209-217, 1995.
DOI : 10.1016/0926-860X(95)00082-8

L. Vivier and D. Duprez, Ceria-Based Solid Catalysts for Organic Chemistry, ChemSusChem, vol.47, issue.108, pp.654-778, 2010.
DOI : 10.5012/bkcs.2007.28.8.1265
URL : https://hal.archives-ouvertes.fr/hal-00751894

K. M. Dooley, A. K. Bhat, C. P. Plaisance, and A. D. Roy, Ketones from acid condensation using supported CeO2 catalysts: Effect of additives, Applied Catalysis A: General, vol.320
DOI : 10.1016/j.apcata.2007.01.021

R. W. Snell and B. H. Shanks, Ceria calcination temperature influence on acetic acid ketonization: Mechanistic insights, Applied Catalysis A: General, vol.451, pp.86-93, 2013.
DOI : 10.1016/j.apcata.2012.08.043

R. W. Snell, S. H. Hakim, J. A. Dumesic, and B. H. Shanks, Catalysis with ceria nanocrystals: Bio-oil model compound ketonization, Applied Catalysis A: General, vol.464, issue.465, pp.464-465
DOI : 10.1016/j.apcata.2013.06.003

T. N. Pham, T. Sooknoi, S. P. Crossley, and D. E. Resasco, Ketonization of Carboxylic Acids: Mechanisms, Catalysts, and Implications for Biomass Conversion, ACS Catalysis, vol.3, issue.11, pp.2456-2473, 2013.
DOI : 10.1021/cs400501h

J. C. Kuriacose and S. S. Jewur, Studies on the surface interaction of acetic acid on iron oxide, Journal of Catalysis, vol.50, issue.2, pp.330-3410021, 1977.
DOI : 10.1016/0021-9517(77)90042-2

F. C. Calaza, T. Chen, D. R. Mullins, Y. Xu, and S. H. Overbury, Reactivity and reaction intermediates for acetic acid adsorbed on CeO2, Catal. Ceria, pp.65-76, 2015.

C. Amen-chen, H. Pakdel, and C. Roy, Production of monomeric phenols by thermochemical conversion of biomass: a review, Bioresource Technology, vol.79, issue.3, pp.277-299, 2001.
DOI : 10.1016/S0960-8524(00)00180-2

K. Bourikas, C. Kordulis, and A. Lycourghiotis, The Role of the Liquid???Solid Interface in the Preparation of Supported Catalysts, Catalysis Reviews, vol.211, issue.4, pp.363-444, 2006.
DOI : 10.1006/jcis.1995.1452

M. M. Dubinin, E. D. Zaverina, and L. V. Radushkevich, Sorption and structure of active carbons. I. Adsorption of organic vapors, Zhurnal Fiz. Khimii, vol.21, pp.151-162, 1947.

W. A. Dietz, Response Factors for Gas Chromatographic Analyses, Journal of Chromatographic Science, vol.5, issue.2, pp.68-71, 1967.
DOI : 10.1093/chromsci/5.2.68

B. Joffres, C. Lorentz, M. Vidalie, D. Laurenti, A. A. Quoineaud et al., Catalytic hydroconversion of a wheat straw soda lignin: Characterization of the products and the lignin residue, Applied Catalysis B: Environmental, vol.145, pp.167-176, 2014.
DOI : 10.1016/j.apcatb.2013.01.039
URL : https://hal.archives-ouvertes.fr/hal-00924184

P. G. Blake and G. E. Jackson, The thermal decomposition of acetic acid, Journal of the Chemical Society B: Physical Organic, pp.1153-1155, 1968.
DOI : 10.1039/j29680001153

P. G. Blake and G. E. Jackson, High- and low-temperature mechanisms in the thermal decomposition of acetic acid, Journal of the Chemical Society B: Physical Organic, pp.94-96, 1969.
DOI : 10.1039/j29690000094

O. Nagashima, S. Sato, R. Takahashi, and T. Sodesawa, Ketonization of carboxylic acids over CeO2-based composite oxides, Journal of Molecular Catalysis A: Chemical, vol.227, issue.1-2, pp.231-239, 2005.
DOI : 10.1016/j.molcata.2004.10.042

A. J. Crisci, H. Dou, T. Prasomsri, and Y. , Cascade Reactions for the Continuous and Selective Production of Isobutene from Bioderived Acetic Acid Over Zinc-Zirconia Catalysts, ACS Catalysis, vol.4, issue.11, pp.4196-4200, 2014.
DOI : 10.1021/cs501018k

V. N. Bui, D. Laurenti, P. Afanasiev, and C. Geantet, Hydrodeoxygenation of guaiacol with CoMo catalysts. Part I: Promoting effect of cobalt on HDO selectivity and activity, Applied Catalysis B: Environmental, vol.101, issue.3-4, pp.239-245, 2011.
DOI : 10.1016/j.apcatb.2010.10.025

M. T. Klein, Lignin Thermolysis Pathways, Massachussetts Institute of Technology, 1981.

V. N. Bui, D. Laurenti, P. Delichère, and C. Geantet, Hydrodeoxygenation of guaiacol, Applied Catalysis B: Environmental, vol.101, issue.3-4, pp.246-255, 2011.
DOI : 10.1016/j.apcatb.2010.10.031
URL : https://hal.archives-ouvertes.fr/hal-00484193