101 4.3.1. X-ray spectroscopy analysis ,
Calculation of the order of reaction, p.111 ,
Acido-basic properties study: MBOH conversion, p.127 ,
129 i. X-ray Fluorescence spectroscopy (XRF), 129 ii. X-ray Photoelectron Spectroscopy (XPS), p.129 ,
Infrared and diffuse reflection, Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) ..130 i, p.131 ,
Nuclear Magnetic Resonance (NMR) study, p.135 ,
Bases and Basic Materials in Chemical and Environmental Processes. Liquid versus Solid Basicity, Chemical Reviews, vol.110, issue.4, pp.2217-2249, 2010. ,
DOI : 10.1021/cr9000989
Highly regioselective hydroformylation of internal, functionalized olefins applying Pt/Sn complexes with large bite angle diphosphines, Journal of Organometallic Chemistry, vol.551, issue.1-2, pp.165-170, 1998. ,
DOI : 10.1016/S0022-328X(97)00396-3
Integrated biodiesel production: a comparison of different homogeneous catalysts systems, Bioresource Technology, vol.92, issue.3, pp.297-305, 2004. ,
DOI : 10.1016/j.biortech.2003.08.014
Heterogeneous Catalysts for Biodiesel Production, Energy & Fuels, vol.22, issue.1, pp.207-217, 2008. ,
DOI : 10.1021/ef700250g
On the relationship between the basicity of a surface and its ability to catalyze transesterification in liquid and gas phases: the case of MgO, Physical Chemistry Chemical Physics, vol.100, issue.414, pp.14168-14176, 2015. ,
DOI : 10.1021/jp9518419
URL : https://hal.archives-ouvertes.fr/hal-01153367
Transesterification of soybean oil with zeolite and metal catalysts, Applied Catalysis A: General, vol.257, issue.2, pp.213-223, 2004. ,
DOI : 10.1016/j.apcata.2003.07.010
Production of biodiesel through transesterification of soybean oil using lithium orthosilicate solid catalyst, Fuel Processing Technology, vol.104, pp.167-173, 2012. ,
DOI : 10.1016/j.fuproc.2012.05.009
Study of the Parameters Governing the Reactivity of Weak Inorganic Bases. Towards the Transesterification Reaction, 2012. ,
URL : https://hal.archives-ouvertes.fr/tel-00828477
Activity of solid catalysts for biodiesel production: A review, Fuel Processing Technology, vol.90, issue.6, pp.770-777, 2009. ,
DOI : 10.1016/j.fuproc.2009.03.010
Transesterification, Chemical Reviews, vol.93, issue.4, pp.1449-1470, 1993. ,
DOI : 10.1021/cr00020a004
Biodiesel production using heterogeneous catalysts, Bioresource Technology, vol.102, issue.3, pp.2151-2161, 2011. ,
DOI : 10.1016/j.biortech.2010.10.080
Activity of solid acid catalysts for biodiesel production: A critical review, Applied Catalysis A: General, vol.470, pp.140-161, 2014. ,
DOI : 10.1016/j.apcata.2013.10.052
Heterogeneous basic catalysts for biodiesel production, Catalysis Science & Technology, vol.276, issue.118, pp.2877-2891, 2016. ,
DOI : 10.1016/j.jcat.2010.09.015
Heterogeneous Catalysts for Biodiesel Production, Energy & Fuels, vol.22, issue.1, pp.207-217, 2008. ,
DOI : 10.1021/ef700250g
System and Process for Producing Biodiesel Fuel with Reduced Viscosity and a Cloud Point below Thirty-Two (32) Degrees Fahrenheit, pp.6174501-6174502, 2001. ,
Process for Producing Alkyl Esters from a Vegetable or Animal Oil and an Aliphatic Monoalcohol, pp.6878837-6878839, 2005. ,
Alkaline-earth metal compounds as alcoholysis catalysts for ester oils synthesis, Applied Catalysis A: General, vol.192, issue.1, pp.23-28, 2000. ,
DOI : 10.1016/S0926-860X(99)00337-3
Design of new solid catalysts for the selective conversion of glycerol, European Journal of Lipid Science and Technology, vol.10, issue.9, pp.825-830, 2008. ,
DOI : 10.1051/ocl.2002.0155
Glycerol transesterification with methyl stearate over solid basic catalysts, Applied Catalysis A: General, vol.218, issue.1-2, pp.1-11, 2001. ,
DOI : 10.1016/S0926-860X(01)00579-8
???One pot??? and selective synthesis of monoglycerides over homogeneous and heterogeneous guanidine catalysts, Green Chem., vol.44, issue.2, pp.72-74, 2004. ,
DOI : 10.1007/BF02666773
Rational Design of Solid Catalysts for the Selective Use of Glycerol as a Natural Organic Building Block, ChemSusChem, vol.245, issue.7, pp.586-613, 2008. ,
DOI : 10.1051/ocl.2003.0074
Mechanistic investigations of antimony-catalyzed polycondensation in the synthesis of poly(ethylene terephthalate), Journal of Polymer Science Part A: Polymer Chemistry, vol.133, issue.3, pp.1049-1059, 2006. ,
DOI : 10.1080/00222339009349570
Catalyst Systems for Polycondensation Reactions, pp.2006-0079395, 2003. ,
Highly regioselective hydroformylation of internal, functionalized olefins applying Pt/Sn complexes with large bite angle diphosphines, Journal of Organometallic Chemistry, vol.551, issue.1-2, pp.165-170, 1998. ,
DOI : 10.1016/S0022-328X(97)00396-3
Synthesis of Alkenoate Esters from Lactones and Alcohols, pp.6835849-6835851, 2004. ,
Synthesis of methyl propyl carbonate via gas-phase transesterification over TiO2/Al2O3, Journal of Molecular Catalysis A: Chemical, vol.331, issue.1-2, pp.125-129, 2010. ,
DOI : 10.1016/j.molcata.2010.08.015
A New Catalytic Transesterification for the Synthesis of Ethyl Methyl Carbonate, Catalysis Letters, vol.91, issue.1/2, pp.63-67, 2003. ,
DOI : 10.1023/B:CATL.0000006318.45345.da
Catalysts for Transesterification of Dimethyl Carbonate with Propyl Alcohol, Energy & Fuels, vol.21, issue.2, pp.633-635, 2007. ,
DOI : 10.1021/ef060492m
Mechanism of the Effect of Thermal Treatment on the Formation of Strong Acid Sites in the Surface Layers of Sulfated Metal Oxides, Kinetics and Catalysis, vol.44, issue.6, pp.834-839, 2003. ,
DOI : 10.1023/B:KICA.0000009062.42282.60
Stability of sulfated zirconia and the nature of the catalytically active species in the transesterification of triglycerides, Journal of Catalysis, vol.255, issue.2, pp.279-286, 2008. ,
DOI : 10.1016/j.jcat.2008.02.014
Solid Acid Catalysts for Biodiesel Production ???-Towards Sustainable Energy, Advanced Synthesis & Catalysis, vol.56, issue.1-2, pp.75-81, 2006. ,
DOI : 10.1002/adsc.200505160
Application of kaolin-based catalysts in biodiesel production via transesterification of vegetable oils in excess methanol, Bioresource Technology, vol.145, pp.175-181, 2013. ,
DOI : 10.1016/j.biortech.2012.12.024
Transesterification of cyclohexyl acrylate with n-butanol and 2-ethylhexanol: acid-treated clay, ion exchange resins and tetrabutyl titanate as catalysts, Reactive and Functional Polymers, vol.40, issue.1, pp.13-27, 1999. ,
DOI : 10.1016/S1381-5148(98)00004-2
Acid Activated Montmorillonite as Catalysts in Methyl Esterification Reactions of Lauric Acid, Journal of Oleo Science, vol.61, issue.9, pp.497-504, 2012. ,
DOI : 10.5650/jos.61.497
Synthesis of Bio-Diesel and Bio-Lubricant by Transesterification of Vegetable Oil with Lower and Higher Alcohols Over Heteropolyacids Supported by Clay (K-10), Process Safety and Environmental Protection, vol.85, issue.5, pp.372-377, 2007. ,
DOI : 10.1205/psep06073
Preparation, characterization and catalytic activity of MMT-clay exchanged sulphonic acid functionalized ionic liquid for transesterification of ??-ketoesters, Catalysis Communications, vol.11, issue.6, pp.503-507, 2010. ,
DOI : 10.1016/j.catcom.2009.11.015
Solid heterogeneous catalysts for transesterification of triglycerides with methanol: A review, Applied Catalysis A: General, vol.363, issue.1-2, pp.1-10, 2009. ,
DOI : 10.1016/j.apcata.2009.05.021
Kinetics of heterogeneously MgO-catalyzed transesterification, Applied Catalysis B: Environmental, vol.62, issue.1-2, pp.35-45, 2006. ,
DOI : 10.1016/j.apcatb.2005.04.005
Kinetic Modeling Studies of Heterogeneously Catalyzed Biodiesel Synthesis Reactions, Industrial & Engineering Chemistry Research, vol.50, issue.9, pp.4818-4830, 2011. ,
DOI : 10.1021/ie101403f
Heterogeneous Basic Catalysis, Chemical Reviews, vol.95, issue.3, pp.537-558, 1995. ,
DOI : 10.1021/cr00035a005
Application of the factorial design of experiments and response surface methodology to optimize biodiesel production, Industrial Crops and Products, vol.8, issue.1, pp.29-35, 1998. ,
DOI : 10.1016/S0926-6690(97)10003-6
Biodiesel from sunflower oil by using activated calcium oxide, Applied Catalysis B: Environmental, vol.73, issue.3-4, pp.317-326, 2007. ,
DOI : 10.1016/j.apcatb.2006.12.017
Economic assessment of batch biodiesel production processes using homogeneous and heterogeneous alkali catalysts, Bioresource Technology, vol.100, issue.13, pp.3268-3276, 2009. ,
DOI : 10.1016/j.biortech.2009.02.010
Production of biodiesel through transesterification of soybean oil using lithium orthosilicate solid catalyst, Fuel Processing Technology, vol.104, pp.167-173, 2012. ,
DOI : 10.1016/j.fuproc.2012.05.009
Production of biodiesel and lactic acid from rapeseed oil using sodium silicate as catalyst, Bioresource Technology, vol.102, issue.13, pp.6884-6886, 2011. ,
DOI : 10.1016/j.biortech.2011.04.007
Highly efficient procedure for the synthesis of biodiesel from soybean oil, Fuel Processing Technology, vol.90, issue.5, pp.701-704, 2009. ,
DOI : 10.1016/j.fuproc.2008.12.012
Development of heterogeneous base catalysts for biodiesel production, Bioresource Technology, vol.99, issue.9, pp.3439-3443, 2008. ,
DOI : 10.1016/j.biortech.2007.08.009
Lewis and Br??nsted basic active sites on solid catalysts and their role in the synthesis of monoglycerides, Journal of Catalysis, vol.234, issue.2, pp.340-347, 2005. ,
DOI : 10.1016/j.jcat.2005.06.023
Calcined Mg???Al hydrotalcites as solid base catalysts for methanolysis of soybean oil, Journal of Molecular Catalysis A: Chemical, vol.246, issue.1-2, pp.24-32, 2006. ,
DOI : 10.1016/j.molcata.2005.10.008
Transesterification of sunflower oil over zeolites using different metal loading: A case of leaching and agglomeration studies, Applied Catalysis A: General, vol.346, issue.1-2, pp.79-85, 2008. ,
DOI : 10.1016/j.apcata.2008.05.008
KOH/bentonite catalysts for transesterification of palm oil to biodiesel, Applied Clay Science, vol.53, issue.2, pp.341-346, 2011. ,
DOI : 10.1016/j.clay.2010.12.018
Study of the Parameters Governing the Reactivity of Weak Inorganic Bases. Towards the Transesterification Reaction, 2012. ,
URL : https://hal.archives-ouvertes.fr/tel-00828477
Methylbutynol: a new and simple diagnostic tool for acidic and basic sites of solids, Applied Catalysis, vol.78, issue.2, pp.213-225, 1991. ,
DOI : 10.1016/0166-9834(91)80107-8
Evaluation of Surface Acido???Basic Properties of Inorganic???Based Solids by Model Catalytic Alcohol Reaction Networks, Catalysis Reviews, vol.144, issue.3, pp.315-361, 2006. ,
DOI : 10.1016/j.jcat.2006.04.003
High-pressure reconnaissance investigations in the system Mg2SiO4 - MgO - H2O, Earth and Planetary Science Letters, vol.2, issue.2, pp.130-133, 1967. ,
DOI : 10.1016/0012-821X(67)90114-8
Effects of H2O on the phase behaviour of the forsterite-enstatite system at high pressures and temperatures and implications for the Earth, Physics of the Earth and Planetary Interiors, vol.49, issue.1-2, pp.142-167, 1987. ,
DOI : 10.1016/0031-9201(87)90138-5
Stability of hydrous magnesium silicates in the mantle transition zone, Physics of the Earth and Planetary Interiors, vol.66, issue.3-4, pp.307-312, 1991. ,
DOI : 10.1016/0031-9201(91)90085-V
The role of volatiles in the transition zone, Journal of Geophysical Research: Solid Earth, vol.277, issue.14, pp.4287-4299, 1993. ,
DOI : 10.2475/ajs.277.3.288
A new hydrous silicate, a water reservoir, in the upper part of the lower mantle, Geophysical Research Letters, vol.268, issue.F662, pp.1047-1050, 1997. ,
DOI : 10.1126/science.268.5207.74
The high-pressure behaviour of the 10???? phase: A spectroscopic and diffractometric study up to 42??GPa, Earth and Planetary Science Letters, vol.246, issue.3-4, pp.444-457, 2006. ,
DOI : 10.1016/j.epsl.2006.03.046
The 3.65 A phase in the system MgO-SiO2-H2O: Synthesis, composition, and structure, American Mineralogist, vol.96, issue.8-9, pp.1207-1214, 2011. ,
DOI : 10.2138/am.2011.3782
Crystal structure of the dense hydrous magnesium silicate, phase D, American Mineralogist, vol.82, issue.5-6, pp.651-654, 1997. ,
DOI : 10.2138/am-1997-5-627
Synthesis of Smectite Clay Minerals: A Critical Review, Clays and Clay Minerals, vol.47, issue.5, pp.529-554, 1999. ,
DOI : 10.1346/CCMN.1999.0470501
Textural and structural studies of sol???gel derived CaO- and MgO silica glasses, Journal of Non-Crystalline Solids, vol.354, issue.2-9, pp.749-754, 2008. ,
DOI : 10.1016/j.jnoncrysol.2007.07.076
Synthesis and characterisation of magnesium silicate hydrate gels, Cement and Concrete Research, vol.35, issue.1, pp.85-98, 2005. ,
DOI : 10.1016/j.cemconres.2004.06.022
Effect of Si precursor on structural and catalytic properties of nanosize magnesium silicates, Applied Catalysis A: General, vol.488, pp.208-218, 2014. ,
DOI : 10.1016/j.apcata.2014.09.050
New heterogeneous process for biodiesel production: A way to improve the quality and the value of the crude glycerin produced by biodiesel plants, Catalysis Today, vol.106, issue.1-4, pp.190-192, 2005. ,
DOI : 10.1016/j.cattod.2005.07.181
and MgO Surface: DFT and DRIFT Approaches, The Journal of Physical Chemistry C, vol.116, issue.11, pp.6645-6654, 2012. ,
DOI : 10.1021/jp211171t
URL : https://hal.archives-ouvertes.fr/hal-01054618
Innovation in solid heterogeneous catalysis for the generation of economically viable and ecofriendly biodiesel: A review, Catalysis Reviews, vol.2008, issue.46, pp.157-208, 2016. ,
DOI : 10.1016/j.fuproc.2012.09.053
Kinetics of heterogeneously MgO-catalyzed transesterification, Applied Catalysis B: Environmental, vol.62, issue.1-2, pp.35-45, 2006. ,
DOI : 10.1016/j.apcatb.2005.04.005
Transesterification of rapeseed oil in the presence of basic zeolites and related solid catalysts, Journal of the American Oil Chemists' Society, vol.112, issue.11, pp.1161-1165, 2001. ,
DOI : 10.1016/0021-9517(88)90168-6
Alcoholysis of ester and epoxide catalyzed by solid bases, Surf. Sci. Catal, vol.130, pp.3507-3512, 2000. ,
DOI : 10.1016/S0167-2991(00)80566-2
Surfactant-assisted synthesis of MgO: Characterization and catalytic activity on the transesterification of dimethyl carbonate with glycerol, Applied Catalysis A: General, vol.484, pp.33-38, 2014. ,
DOI : 10.1016/j.apcata.2014.06.028
Bases and Basic Materials in Industrial and Environmental Chemistry: A Review of Commercial Processes, Industrial & Engineering Chemistry Research, vol.48, issue.14, pp.6486-6511, 2009. ,
DOI : 10.1021/ie801878d
Mgo Catalysed Triglyceride Transesterification for Biodiesel Synthesis, Catalysis Letters, vol.145, issue.95, pp.1-7, 2010. ,
DOI : 10.3775/jie.85.135
Challenges of Phosphate and Carbonate Salts as Catalysts for Biodiesel Synthesis, Energy & Fuels, vol.24, issue.7, pp.4095-4096, 2010. ,
DOI : 10.1021/ef100333y
Sodium phosphate as a solid catalyst for biodiesel preparation, Brazilian Journal of Chemical Engineering, vol.87, issue.1, pp.137-144, 2010. ,
DOI : 10.1016/j.fuel.2008.04.001
Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl esters, Applied Catalysis B: Environmental, vol.144, pp.308-316, 2014. ,
DOI : 10.1016/j.apcatb.2013.07.026
Transesterification of triglycerides with methanol catalyzed by heterogeneous zinc hydroxy nitrate catalyst. Evaluation of variables affecting the activity and stability of catalyst., Energy & Fuels, vol.24, issue.1, pp.634-645, 2009. ,
DOI : 10.1021/ef900780q
Catalytic synthesis of ??-methylene-??-valerolactone: a biomass-derived acrylic monomer, Applied Catalysis A: General, vol.272, issue.1-2, pp.249-256, 2004. ,
DOI : 10.1016/j.apcata.2004.05.048
Synthesis Of Alkenoate Esters From Lactones And Alcohols, 2004. ,
Interactions between rock and organic matter. Esterification and transesterification induced in sediments by methanol and ethanol, Analytical Chemistry, vol.43, issue.12, pp.1656-1657, 1971. ,
DOI : 10.1021/ac60306a006
Transesterification of Edible and Nonedible Vegetable Oils with Alcohols over Heteropolyacids Supported on Acid-Treated Clay, Industrial & Engineering Chemistry Research, vol.48, issue.21, pp.9408-9415, 2009. ,
DOI : 10.1021/ie801543k
Preparation, characterization and catalytic activity of MMT-clay exchanged sulphonic acid functionalized ionic liquid for transesterification of ??-ketoesters, Catalysis Communications, vol.11, issue.6, pp.503-507, 2010. ,
DOI : 10.1016/j.catcom.2009.11.015
Transesterification of cyclohexyl acrylate with n-butanol and 2-ethylhexanol: acid-treated clay, ion exchange resins and tetrabutyl titanate as catalysts, Reactive and Functional Polymers, vol.40, issue.1, pp.13-27, 1999. ,
DOI : 10.1016/S1381-5148(98)00004-2
Role of Water in the Mechanochemical Reactions of MgO???SiO2Systems, Journal of Solid State Chemistry, vol.138, issue.1, pp.169-177, 1998. ,
DOI : 10.1006/jssc.1998.7768
Formation of Layered Magnesium Silicate during the Aging of Magnesium Hydroxide-Silica Mixtures, Journal of the American Ceramic Society, vol.79, issue.3, pp.754-756, 1998. ,
DOI : 10.1111/j.1151-2916.1998.tb02405.x
Effect of Si precursor on structural and catalytic properties of nanosize magnesium silicates, Applied Catalysis A: General, vol.488, pp.208-218, 2014. ,
DOI : 10.1016/j.apcata.2014.09.050
Synthesis and characterisation of magnesium silicate hydrate gels, Cement and Concrete Research, vol.35, issue.1, pp.85-98, 2005. ,
DOI : 10.1016/j.cemconres.2004.06.022
Textural and structural studies of sol???gel derived CaO- and MgO silica glasses, Journal of Non-Crystalline Solids, vol.354, issue.2-9, pp.749-754, 2008. ,
DOI : 10.1016/j.jnoncrysol.2007.07.076
Alcoholysis of ester and epoxide catalyzed by solid bases, Surf. Sci. Catal, vol.130, pp.3507-3512, 2000. ,
DOI : 10.1016/S0167-2991(00)80566-2
Kinetics of heterogeneously MgO-catalyzed transesterification, Applied Catalysis B: Environmental, vol.62, issue.1-2, pp.35-45, 2006. ,
DOI : 10.1016/j.apcatb.2005.04.005
Adsorption and reaction in the transesterification of ethyl acetate with methanol on Lewatit K1221, Journal of Molecular Catalysis A: Chemical, vol.359, pp.57-68, 2012. ,
DOI : 10.1016/j.molcata.2012.03.021
Beyond Oil and Gas: The Methanol Economy, 2011. ,
Catalyse de contact: conception, préparation et mise en oeuvre des catalyseurs industriels, Editions TECHNIP, 1978. ,
Textural and structural studies of sol???gel derived CaO- and MgO silica glasses, Journal of Non-Crystalline Solids, vol.354, issue.2-9, pp.749-754, 2008. ,
DOI : 10.1016/j.jnoncrysol.2007.07.076
Magnesia-Based Cements: A Journey of 150 Years, and Cements for the Future?, Chemical Reviews, vol.116, issue.7, pp.4170-4204, 2016. ,
DOI : 10.1021/acs.chemrev.5b00463
Phyllosilicates synthesis: a way of accessing edges contributions in NMR and FTIR spectroscopies. Example of synthetic talc, Physics and Chemistry of Minerals, vol.43, issue.4, pp.361-373, 2013. ,
DOI : 10.1107/S0021889810030499
URL : https://hal.archives-ouvertes.fr/hal-00921010
Effect of Si precursor on structural and catalytic properties of nanosize magnesium silicates, Applied Catalysis A: General, vol.488, pp.208-218, 2014. ,
DOI : 10.1016/j.apcata.2014.09.050
Magnesium and calcium silicate hydrates, Cement and Concrete Research, vol.77, pp.60-68, 2015. ,
DOI : 10.1016/j.cemconres.2015.06.007
O for immobilisation of Magnox sludge, Dalton Transactions, vol.42, issue.37, pp.8126-8137, 2015. ,
DOI : 10.1016/0016-7037(78)90271-5
29Si NMR Observation of an Amorphous Magnesium Silicate Formed during Impregnation of Silica with Mg(II) in Aqueous Solution, The Journal of Physical Chemistry, vol.99, issue.47, pp.17273-17281, 1995. ,
DOI : 10.1021/j100047a036
Solid-state high-resolution silicon-29 chemical shifts in silicates, The Journal of Physical Chemistry, vol.88, issue.8, pp.1518-1522, 1984. ,
DOI : 10.1021/j150652a015
Synthesis and characterisation of magnesium silicate hydrate gels, Cement and Concrete Research, vol.35, issue.1, pp.85-98, 2005. ,
DOI : 10.1016/j.cemconres.2004.06.022
Observation of ???hidden??? magnesium: First-principles calculations and 25Mg solid-state NMR of enstatite, Solid State Nuclear Magnetic Resonance, vol.40, issue.2, pp.91-99, 2011. ,
DOI : 10.1016/j.ssnmr.2011.08.004
MAS NMR spectra of quadrupolar nuclei in disordered solids: The Czjzek model, Journal of Magnetic Resonance, vol.192, issue.2, pp.244-251, 2008. ,
DOI : 10.1016/j.jmr.2008.03.001
URL : https://hal.archives-ouvertes.fr/hal-00269847
Raman Microprobe Spectra and Vibrational Mode Assignments of Talc, Applied Spectroscopy, vol.53, issue.6, pp.140-144, 1980. ,
DOI : 10.1080/0002889708506215
A new molecular precursor for magnesia???silica materials, Journal of Materials Chemistry, vol.11, issue.4, pp.1081-1085, 2001. ,
DOI : 10.1039/b007742i
Infrared Spectra of Methanol and Deuterated Methanols in Gas, Liquid, and Solid Phases, The Journal of Chemical Physics, vol.50, issue.5, pp.1554-1568, 1961. ,
DOI : 10.1039/tf9595501484
and MgO Surface: DFT and DRIFT Approaches, The Journal of Physical Chemistry C, vol.116, issue.11, pp.6645-6654, 2012. ,
DOI : 10.1021/jp211171t
URL : https://hal.archives-ouvertes.fr/hal-01054618
On the relationship between the basicity of a surface and its ability to catalyze transesterification in liquid and gas phases: the case of MgO, Physical Chemistry Chemical Physics, vol.100, issue.414, pp.14168-14176, 2015. ,
DOI : 10.1021/jp9518419
URL : https://hal.archives-ouvertes.fr/hal-01153367
Activity of solid catalysts for biodiesel production: A review, Fuel Processing Technology, vol.90, issue.6, pp.770-777, 2009. ,
DOI : 10.1016/j.fuproc.2009.03.010
-Butoxide MgAl Anionic Clays, The Journal of Physical Chemistry B, vol.107, issue.15, pp.3476-3485, 2003. ,
DOI : 10.1021/jp027663i
The effects of water on biodiesel production and refining technologies: A review, Renewable and Sustainable Energy Reviews, vol.16, issue.5, pp.3456-3470, 2012. ,
DOI : 10.1016/j.rser.2012.03.004
esterification and transesterification, Chem. Soc. Rev., vol.190, issue.428, pp.7887-7916, 2014. ,
DOI : 10.1016/j.cattod.2011.12.024
Transesterification of triacetin, tributyrin, and soybean oil with methanol over hydrotalcites with different water contents, Fuel Processing Technology, vol.91, issue.6, pp.618-624, 2010. ,
DOI : 10.1016/j.fuproc.2010.01.008
Near-infrared and mid-infrared spectroscopic study of sepiolites and palygorskites, Vibrational Spectroscopy, vol.27, issue.1, pp.1-13, 2001. ,
DOI : 10.1016/S0924-2031(01)00110-2
Modification of fibrous silicates surfaces with organic derivatives: An infrared spectroscopic study, Journal of Colloid and Interface Science, vol.294, issue.1, pp.47-52, 2006. ,
DOI : 10.1016/j.jcis.2005.07.014
Infrared Spectra of Minerals, 1974. ,
Effect of Si precursor on structural and catalytic properties of nanosize magnesium silicates, Applied Catalysis A: General, vol.488, pp.208-218, 2014. ,
DOI : 10.1016/j.apcata.2014.09.050
Infrared study of hydroxyl groups on sepiolite, The Journal of Physical Chemistry, vol.72, issue.3, pp.1072-1074, 1968. ,
DOI : 10.1021/j100849a052
Infrared study of the interactions between the different kinds of water molecules present in sepiolite, Spectrochimica Acta Part A: Molecular Spectroscopy, vol.31, issue.9-10, pp.1497-1499, 1975. ,
DOI : 10.1016/0584-8539(75)80206-6
Single crystal Raman microscopic study of the asbestos mineral chrysotile, Physical Chemistry Chemical Physics, vol.1, issue.10, pp.2559-2564, 1999. ,
DOI : 10.1039/a809238i
Porous Structure and Particle Size of Silica and Hydrotalcite Catalyst Precursors: A Thermoporometric Study, 1993. ,
Raman Microprobe Spectra and Vibrational Mode Assignments of Talc, Applied Spectroscopy, vol.53, issue.6, pp.140-144, 1980. ,
DOI : 10.1080/0002889708506215
Hydroxyl groups as IR active surface probes on MgO crystallites, Surface Science, vol.290, issue.3, pp.388-402, 1993. ,
DOI : 10.1016/0039-6028(93)90721-U
Infrared Characterization of Hydroxyl Groups on MgO:?? A Periodic and Cluster Density Functional Theory Study, Journal of the American Chemical Society, vol.129, issue.20, pp.6442-6452, 2007. ,
DOI : 10.1021/ja068720e
A spectroscopy and catalysis study of the nature of active sites of MgO catalysts: Thermodynamic Br??nsted basicity versus reactivity of basic sites, Journal of Catalysis, vol.235, issue.2, pp.413-422, 2005. ,
DOI : 10.1016/j.jcat.2005.09.004
Hydroxyls on the surface of MgO powders, Spectrochimica Acta Part A: Molecular Spectroscopy, vol.43, issue.12, pp.1573-1576, 1987. ,
DOI : 10.1016/S0584-8539(87)80050-8
Infrared Spectra of Minerals, 1974. ,
DOI : 10.1180/mono-4
The frequency of the H???O???H bending fundamental in solids and liquids, Spectrochimica Acta Part A: Molecular Spectroscopy, vol.40, issue.1, pp.43-48, 1984. ,
DOI : 10.1016/0584-8539(84)80027-6
Behavior of H2O molecules in the channels of natrolite and scolecite: A Raman and IR spectroscopic investigation of hydrous microporous silicates, American Mineralogist, vol.91, issue.7, pp.1039-1048, 2006. ,
DOI : 10.2138/am.2006.2049
On the influence of water traces on the acidity measurement of amorphous aluminosilicates, Catalysis Today, vol.226, pp.89-96, 2014. ,
DOI : 10.1016/j.cattod.2013.10.054
URL : https://hal.archives-ouvertes.fr/hal-01226880
Cations Is a Source of Acidity in Silicoaluminas, The Journal of Physical Chemistry B, vol.110, issue.39, pp.19087-19092, 2006. ,
DOI : 10.1021/jp0624552
Nature, Structure and Strength of the Acidic Sites of Amorphous Silica Alumina:?? An IR and NMR Study, The Journal of Physical Chemistry B, vol.110, issue.31, pp.15172-15185, 2006. ,
DOI : 10.1021/jp062252d
29 Si and 1 H NMR spectroscopy of high-pressure hydrous magnesium silicates, Physics and Chemistry of Minerals, vol.24, issue.3, pp.179-190, 1997. ,
DOI : 10.1007/s002690050031
Characterization of hydrous species in minerals by high-speed proton MAS-NMR, Journal of the American Chemical Society, vol.110, issue.5, pp.1367-1375, 1988. ,
DOI : 10.1021/ja00213a007
Solid-state nuclear magnetic resonance investigations of the nature, property, and activity of acid sites on solid catalysts, Solid State Nuclear Magnetic Resonance, vol.39, issue.3-4, pp.116-141, 2011. ,
DOI : 10.1016/j.ssnmr.2011.03.007
Study, The Journal of Physical Chemistry C, vol.113, issue.28, pp.12293-12300, 2009. ,
DOI : 10.1021/jp811383y
URL : https://hal.archives-ouvertes.fr/inria-00071448
Effect of silane coupling agents on properties of precipitated sodium???aluminium silicates, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.182, issue.1-3, pp.65-81, 2001. ,
DOI : 10.1016/S0927-7757(00)00815-3
Fehlordnung bei Smectiten in Abh??ngigkeit vom Zwischenschichtkation, Zeitschrift f??r anorganische und allgemeine Chemie, vol.54, issue.3, pp.503-515, 2003. ,
DOI : 10.1107/S010827019701439X
Synchrotron powder X-ray diffraction study of the structure and dehydration behavior of sepiolite, American Mineralogist, vol.92, issue.1, pp.91-97, 2007. ,
DOI : 10.2138/am.2007.2134
A Structural Study of Talc and Talc-Tremolite Relations, Journal of the American Ceramic Society, vol.72, issue.203, pp.34-42, 1960. ,
DOI : 10.1107/S0365110X49000801
The Scherrer Formula for X-Ray Particle Size Determination, Physical Review, vol.74, issue.10, pp.978-982, 1939. ,
DOI : 10.1098/rspa.1938.0079
Changes of the main physical and technological properties of talc due to mechanical strain, Applied Clay Science, vol.42, issue.3-4, pp.398-404, 2009. ,
DOI : 10.1016/j.clay.2008.04.002
Preparation, characterization and catalytic activity of MMT-clay exchanged sulphonic acid functionalized ionic liquid for transesterification of ??-ketoesters, Catalysis Communications, vol.11, issue.6, pp.503-507, 2010. ,
DOI : 10.1016/j.catcom.2009.11.015
Kinetics of heterogeneously MgO-catalyzed transesterification, Applied Catalysis B: Environmental, vol.62, issue.1-2, pp.35-45, 2006. ,
DOI : 10.1016/j.apcatb.2005.04.005
Transesterification of triacetin, tributyrin, and soybean oil with methanol over hydrotalcites with different water contents, Fuel Processing Technology, vol.91, issue.6, pp.618-624, 2010. ,
DOI : 10.1016/j.fuproc.2010.01.008
On the relationship between the basicity of a surface and its ability to catalyze transesterification in liquid and gas phases: the case of MgO, Physical Chemistry Chemical Physics, vol.100, issue.414, pp.14168-14176, 2015. ,
DOI : 10.1021/jp9518419
URL : https://hal.archives-ouvertes.fr/hal-01153367
Laponite and hybrid surfactant/laponite particles processed as spheres by spray-drying, New Journal of Chemistry, vol.16, issue.4, p.1116, 2009. ,
DOI : 10.1590/S1516-14392007000100009
Physicochemical studies on precipitated magnesium silicates, Journal of Materials Science, vol.38, issue.11, pp.3831-3840, 2007. ,
DOI : 10.1007/s10853-006-0464-2
Amorphous magnesium silicate ??? synthesis, physicochemical properties and surface morphology, Advanced Powder Technology, vol.15, issue.5, pp.549-565, 2004. ,
DOI : 10.1163/1568552042000183
Influence of Tetrahedral Layer Charge on the Organization of Interlayer Water and Ions in Synthetic Na-Saturated Smectites, The Journal of Physical Chemistry C, vol.119, issue.8, pp.4158-4172, 2015. ,
DOI : 10.1021/jp5123322
URL : https://hal.archives-ouvertes.fr/hal-01122276
Monte Carlo Molecular Modeling Studies of Hydrated Li-, Na-, and K-Smectites: Understanding the Role of Potassium as a Clay Swelling Inhibitor, Journal of the American Chemical Society, vol.117, issue.50, pp.12608-12617, 1995. ,
DOI : 10.1021/ja00155a025
The recent work on X-rays and crystals and its bearing on chemistry, Journal of the Chemical Society, Transactions, vol.109, pp.252-269, 1916. ,
DOI : 10.1039/ct9160900252