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Granulats à base de boues de phosphates : transformations thermiques, propriétés physiques et application

Abstract : Phosphate sludge generated from beneficiation plants of Moroccan phosphate rocks was investigated at the range [900-1200°C] by X-ray diffraction, scanning electron microscopy, thermal analysis dilatometric analysis and impedance spectroscopy. Mixtures of the phosphates ludge and amendments such as a swelling clay (up to 30 wt.% of the clay), a kaolinitic clay (up to 40 wt.% of the sludge) and a fly ash (65.5 wt.% of the ash) were investigated and their properties (shrinkage, density, water absorption and compressive strength) were measured as a function of temperature and clay addition. The results showed that gehlénite neoformed from lime of decomposed carbonates and breakdown products of clay minerals in the first mixture while labradorite/anorthite was the only neoformed phase in the other blends. Also fluoroapatite (original mineral) resisted heating until fusion in almost samples. A new approach based on the methodology of the experimental design was adopted to assess the effect of the processing factors on the studied properties. The measured properties were mainly controlled by temperature, and the effect of clay addition was less regular. Considering the mixtures densities lightweight agglomerates can be produced at specific conditions. On the other hand, the release ability of phosphorus by LWAs in the presence ofalfalfa plants has been performed. It was found that due to the release of phosphorus by soil embedded pellets the growth of alfalfa plants improved. The sintering process of blends of phosphate sludge and a naturally occurring clay material (0-30 wt.%) was investigated in the range 650-1100°C by using impedance spectroscopy. The results showed that the sintering process was effective between 750 and 1000°C and occurred by melt flow.
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Submitted on : Wednesday, December 13, 2017 - 10:55:53 AM
Last modification on : Friday, May 17, 2019 - 9:42:33 AM


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  • HAL Id : tel-01662477, version 1



Mohamed Loutou. Granulats à base de boues de phosphates : transformations thermiques, propriétés physiques et application. Chimie inorganique. Université de Toulon; Université Cadi Ayyad (Marrakech, Maroc). Faculté des sciences Semlalia, 2015. Français. ⟨NNT : 2015TOUL0016⟩. ⟨tel-01662477⟩



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