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. Afin-de-mieux-voir-si, (arylthio)octane et 1,8- bis(cycloalkylthio)octane avec CuI générait des réseaux interpénétrés et pour comprendre l'influence de la longueur de l'espaceur dithioéther sur la structure et les propriétés des composés de coordination formés, nous avons réalisé la synthèse d'une série de composés d'iodure de cuivre(I) avec les ligands de type RS(CH 2 ) 8 )SR. Afin de pouvoir comparer avec les autres séries de composés étudiés, nous avons choisi R= Ph, Cy (au vu des résultats photophysiques intéressants avec ce type de substituant cyclohexyle) et Bz (benzyle), pp.8-12

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P. D. Harvey, A. Bonnot, A. Lapprand, C. Strohmann, and M. Knorr, H-1?LUMO (15%) 314 H-3?L+1 (14%) 301.83 0 HOMO?L+9 (13%) 300.61 0 HOMO?L+10 (10%) 300.18 0.0108 H-8?LUMO (12%), H-1?L+5 (10%) 299, 0003 H-2?L+1 (20%), HOMO?L+2 (52%) 317.85 0.0003 H-1?L+1 (24%), HOMO?L+3 (54%) 317.38 0.0026 H-2?L+3 (13%), H-1?L+2 (33%), HOMO?LUMO (23%), HOMO?L+4 (18%) 315.95 0.0507 H-6?L+1 (23%), H-2?LUMO (21%), H-2?L+4 (11%) 315.42 0.0022 H-4?L+1 (15%), H-1?LUMO (12%) 314.47 0.0012 H-23?L+5 (12%), H-19?L+4 (11%), H-15?L+5 (14%) 314.44 0 H-18?LUMO (12%), H-18?L+4 (20%), H-17?L+5 (25%) 314.42 0.0018 H15%) 309.34 0.0077 H-11?L+4 (10%) 308.42 0.0212 H-5?L+1 (16%) 308.11 0.0052 H-26?L+5 (11%), H-25?L+4 (14%) 307.38 0.0606 H-21?LUMO (16%), H-21?L+6 (26%) 307.00 0 H11%) 306.95 0.0199 H-24?L+5 (10%), H-11?L+5 (10%) 306.88 0.0005 H-26?L+4 (11%), H-25?L+5 (18%) 306.78 0.2383 H12%) 306.73 0.0166 H-5?L+2 (35%), H-4?L+3 (25%) 305.91 0.0016 H-12?LUMO (11%) 305.69 0 H-16?L+5 (18%), H-13?LUMO (14%), H-13?L+4 (20%), H-10?L+5 (11%) 304.62 0.0487 H-14?L+5 (11%) 304.42 0.0175 H-6?LUMO (11%) 303.69 0.0001 H-16?LUMO (14%), H-16?L+4 (12%), H-13?L+5 (10%), H-10?LUMO (11%), H- 10?L+6 (22%) 303.55 0.0025 H-14?LUMO (10%), H-14?L+4 (11%), H-6?LUMO (10%), H-3?L+3 (13%) 302.83 0.0025 H-6?L+1 (11%), H-3?L+2 (22%) 302.63 0 H-8?L+2 (30%), H-6?L+3 (29%), H-3?LUMO (14%) 302.41 0.0036 H-8?L+3 (30%), H-6?L+2 (31%)), H-1?L+4 (26%), H-1?L+6 (18%) 296.28 0 H-7?L+1 (44%), H-3?LUMO (22%) 295.99 0 H-7?LUMO (54%), H-3?L+1 (18%), HOMO?L+6 (11%) 294.48 0.0012 H-9?L+1 (14%)20%) 294.15 0.0009 H-8?L+1 (22%), H-6?LUMO (21%), H-5?LUMO (13%), H-4?L+1 (12%) 293.98 0 H-10?L+1 (11%), H-8?L+2 (11%), H-5?L+3 (18%), H-4?L+2 (15%) 293.77 0.0104 H-8?L+3 (13%), H-6?L+2 (11%), H-5?L+2 (23%), H-4?L+3 (20%) 293.70 0.0182 H-8?L+5 (10%), H-6?L+4 (16%), H-2?L+5 (19%) 292.44 0 H-10?L+1 (58%) 292.34 0.0071 H-11?LUMO (10%), H-9?L+1 (28%) 291.84 0.0345 H-8?L+6 (11%), H-6?L+5 (12%), H-2?L+4 (16%) 291.81 0.0022 H-11?L+1 (17%), H-9?LUMO (20%), H-9?L+4 (10%) 291.24 0.0025 H-7?L+3 (31%), H-3?L+2 (18%) 291.22 0.0006 H-7?L+2 (31%)), H-6?L+2 (10%) 289.30 0.0013 H-10?L+2 (19%), H-1?L+12 (12%), HOMO?L+11 (10%) 288.70 0 H-2?L+11 (14%), H-1?L+14 (26%), HOMO?L+13 (24%) -149- 307.91 0 H-30?LUMO (10%), H-21?LUMO (10%) 307.29 0.0052 H-4?L+3 (13%), H-1?L+5 (10%) 306.61 0.0075 H-3?L+3 (21%), H-1?L+3 (17%) 306.12 0 H-6?L+2 (10%), H-2?L+3 (11%) 305.81 0 H-2?L+3 (33%), H-2?L+5 (10%) 305.11 0.0171 H-3?L+5 (13%), H-1?L+5 (11%) 305.05 0.0001 H-3?L+4 (13%), H-3?L+6 (10%), H-1?L+4 (10%) 303.15 0 H-6?L+5 (13%), H-5?L+4 (14%) (14%), H-8?L+5 (10%) 296.65 0.0027 H-7?LUMO (24%), H-7?L+1 (19%) 296.27 0 H-5?LUMO (35%), H-5?L+1 (13%) 296.02 0 HOMO?L+7 (21%) 295.96 0.0039 H-6?LUMO (23%), H-6?L+1 (10%) 295.68 0.0183 H-6?LUMO (13%), HOMO?L+8 (12%) 295.31 0.0297 H-1?L+7 (22%) 295.14 0 H-1?L+8 (21%) 294.62 0 H-6?L+13 (13%), H-5?L+12 (15%), H-4?L+12 (10%) 294.58 0.0065 H-6?L+12 (15%), H-5?L+13 (17%), H-4?L+13 (12%) 294.32 0 H-10?LUMO (24%) 293 (18%), H-9?L+1 (11%), H-5?LUMO (10%), H-2?L+5 (11%) 293.02 0.0079 H-8?LUMO (13%), H-6?LUMO (10%), H-2?L+4 (13%) 292.90 0 H-11?L+2 (22%), H-8?L+2 (24%) 292.72 0 H-3?L+4 (15%) 292.66 0.0175 H-11?LUMO (11%), H-8?L+1 (18%) 292.34 0.0195 H-10?L+5 (11%), H-4?L+5 (12%), H-3?L+5 (11%)11%), H-1?L+6 (14%), pp.0-5, 2015.

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. Qui-rapportait, H. D. En-hardt, and H. Gechnizdjani, (mptrz) (soit un atome S-donneur et deux atomes N-donneurs par ligand) et de CuI Le polymère [Cu 12 (? 4 -mptrz) 4 (? 4 -I) 3 (? 3 -I) 4 (? 2 -I)] n est construit à partir d'un SBU Cu 6 I 5 de type rugby-shaped, d'un SBU plan Cu 4 I 3, pp.4-7, 1974.

S. Filippo, J. Zyontz, L. E. Potenza, and J. , Synthesis and characterization of some halocopper(I)-alkyl sulfide complexes including the crystal structure of .mu.-(diethyl sulfide)-bis(diethyl sulfide)tetra-.mu.-iodo-tetracopper(I), [(C2H5)2S]3[CuI]4, Inorganic Chemistry, vol.14, issue.7, pp.1667-1671, 1975.
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V. Schéma, Synthèse du précurseur chiral de platine(II)

. Dans-la-procédure-classique, la réaction doit être réalisée en l'absence d'oxygène et d'eau sous atmosphère inerte afin d'empêcher l'homocouplage de Glaser 21 En effet, ce dernier peut conduire à de faibles rendements. CuI est introduit en quantité catalytique car il est régénéré. On utilise le THF comme solvant à la température ambiante (25 °C)

. C?car, L = phosphine) a déjà été établi par le passé à la fois expérimentalement et par calculs DFT comme étant principalement ??? * mixte avec un transfert de charge métal-ligand (MLCT) mélangé avec un transfert de charge ligand-métal (LMCT), p.26

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6. M. Yield, 4. , 6. , 2. , and C. , Bright yellow solid R f = 0 1 H NMR (CDCl 3 , 300 MHz): ? 7 1.18 (br.s, 62H, CH 3 and C 17 H 35 ), 0.81 (t, 6H, J = 6.0 Hz, CH 3 , C 17 H 35 ) 13 C NMR (CDCl 3 , 75 MHz): ? 133 (s, CH arom, 2.15 (m, 4H, CH 2 ), 1.72 (m, 4H, CH 2 ), 1.39 (m, 6H, CH 2 ) 31.9 (s, CH 2 ), 31.4 (t, J = 7.5 Hz MHz): ? 20.0 (s, J Pt-P = 2502 Hz). ESI-MS: m/z (%) = 1068.6 (100) [M + Na] +, pp.213-215

. Mhz, CDCl 3 ): ? 1.85 (m, 12H), 1.57 (m, 12H), 12H), 0.93 (t, J = 7.2 Hz, pp.44-62

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@. Poly, (heptadecyl)(phenyl)(i-propyl))phosphine)platinum(II, p.12

. Hz, 10 (J P-Pt = 2446 Hz) IR: ? (C?C) = 2112 cm -1 . Mass spec, MALDI TOF): > 10 000. GPC (polystyrene standards): M n = 15700

@. Poly, ,3-benzothiadiazole)bis((S)-(heptadecyl)(phenyl)(i-propyl))phosphine )platinum(II), p.13

. Hz, 29 (J P-Pt = 2336 Hz) IR : ? (C?C) = 2090 cm -1 . Anal. Calcd. for PtC