A. Vora, J. Gwamuri, N. Pala, A. Kulkarni, J. M. Pearce et al., Exchanging Ohmic Losses in Metamaterial Absorbers with Useful Optical Absorption for Photovoltaics, Scientific Reports, vol.91, issue.1, pp.4901-4914, 2014.
DOI : 10.1016/j.solener.2013.01.030
URL : http://www.nature.com/articles/srep04901.pdf

J. B. Pendry, Negative Refraction Makes a Perfect Lens, Physical Review Letters, vol.83, issue.18, pp.3966-3969, 2000.
DOI : 10.1103/PhysRevLett.83.2845

X. Zhang and Z. Liu, Superlenses to overcome the diffraction limit, Nature Materials, vol.7, issue.6, pp.435-441, 2007.
DOI : 10.1080/09500340308235215

M. Brun, S. Guenneau, A. B. Movchan, S. Cummer, and D. Schurig, Achieving control of in-plane elastic waves One path to acoustic cloaking Sound scattering by anisotropic metafluids based on twodimensional sonic crystals, Appl. Phys. Lett. New J. Phys. Phys. Rev. B, vol.94, issue.79, pp.61903-061906, 2007.

V. G. Veselago, THE ELECTRODYNAMICS OF SUBSTANCES WITH SIMULTANEOUSLY NEGATIVE VALUES OF $\epsilon$ AND ??, Soviet Physics Uspekhi, vol.10, issue.4, pp.509-514, 1968.
DOI : 10.1070/PU1968v010n04ABEH003699

J. B. Pendry, A. J. Holden, D. J. Robbins, and W. J. Stewart, Magnetism from conductors and enhanced nonlinear phenomena, IEEE Transactions on Microwave Theory and Techniques, vol.47, issue.11, pp.2075-2084, 1999.
DOI : 10.1109/22.798002
URL : http://www.cmth.ph.ic.ac.uk/photonics/Newphotonics/pdf/magwires.pdf

K. Chang, Light Fantastic: Flirting With Invisibility, NY.Times, 2007.

R. A. Shelby, D. R. Smith, and S. Schultz, Experimental Verification of a Negative Index of Refraction, Science, vol.292, issue.5514, pp.77-79, 2001.
DOI : 10.1126/science.1058847

S. Linden, C. Enkrich, M. Wegener, J. Zhou, T. Koschny et al., Magnetic Response of Metamaterials at 100 Terahertz, Science, vol.306, issue.5700, pp.1351-1353, 2004.
DOI : 10.1126/science.1105371

A. and L. Beulze, Dissertation from Bordeaux 1 University: Synthesis and characterization of nanoresonators for metamaterials application in the visible range, 2013.

S. Mühlig, A. Cunningham, J. Dintinger, M. Farhat, S. Bin-hasan et al., A self-assembled three-dimensional cloak in the visible, Scientific Reports, vol.81, issue.1, pp.1-7, 2013.
DOI : 10.1007/3-540-44552-8_6

S. N. Sheikholeslami, H. Alaeian, A. L. Koh, and J. A. Dionne, A Metafluid Exhibiting Strong Optical Magnetism, Nano Letters, vol.13, issue.9, pp.4137-4141, 2013.
DOI : 10.1021/nl401642z

A. Alù and N. Engheta, The quest for magnetic plasmons at optical frequencies, Optics Express, vol.17, issue.7, pp.5723-5730, 2009.
DOI : 10.1364/OE.17.005723

A. Vallecchi, M. Albani, and F. Capolino, Collective electric and magnetic plasmonic resonances in spherical nanoclusters, Optics Express, vol.19, issue.3, pp.2754-2772, 2011.
DOI : 10.1364/OE.19.002754

A. S. Urban, X. Shen, Y. Wang, N. Large, H. Wang et al., Three-Dimensional Plasmonic Nanoclusters, Nano Letters, vol.13, issue.9, pp.4399-4403, 2013.
DOI : 10.1021/nl402231z

F. Li, D. P. Josephson, and A. Stein, Colloidal Assembly: The Road from Particles to Colloidal Molecules and Crystals, Angewandte Chemie International Edition, vol.18, issue.2, pp.360-388, 2011.
DOI : 10.1002/adma.200502651

S. J. Barrow, X. Wei, J. S. Baldauf, A. M. Funston, and P. Mulvaney, The surface plasmon modes of self-assembled gold nanocrystals, Nature Communications, vol.6, pp.1-9, 2012.
DOI : 10.1103/PhysRevB.6.4370

X. Shen, A. Asenjo-garcia, Q. Liu, Q. Jiang, F. J. García-de-abajo et al., Three-Dimensional Plasmonic Chiral Tetramers Assembled by DNA Origami, Nano Letters, vol.13, issue.5, pp.2128-2133, 2013.
DOI : 10.1021/nl400538y

S. C. Glotzer and Z. Zhang, Self-Assembly of Patchy Particles, Nano Lett, vol.4, pp.1407-1413, 2004.

G. R. Yi, D. J. Pine, and S. Sacanna, Recent progress on patchy colloids and their self-assembly, Journal of Physics: Condensed Matter, vol.25, issue.19, pp.193101-193113, 2013.
DOI : 10.1088/0953-8984/25/19/193101

G. Van-anders, N. K. Ahmed, R. Smith, S. C. Engel, and . Glotzer, Entropically Patchy Particles: Engineering Valence through Shape Entropy, ACS Nano, vol.8, issue.1, pp.931-940, 2014.
DOI : 10.1021/nn4057353

J. Du and R. K. O-'reilly, Anisotropic particles with patchy, multicompartment and Janus architectures: preparation and application, Chemical Society Reviews, vol.20, issue.5, pp.2402-2416, 2011.
DOI : 10.1002/adma.200702851

E. Bianchi, R. Blaak, and C. N. Likos, Patchy colloids: state of the art and perspectives, Physical Chemistry Chemical Physics, vol.102, issue.14, pp.6397-6410, 2011.
DOI : 10.1080/00268970410001695688

D. Rodríguez-fernández and L. M. Liz-marzán, Metallic Janus and Patchy Particles, Particle & Particle Systems Characterization, vol.116, issue.1, pp.46-60, 2013.
DOI : 10.1021/jp205018u

G. Yi, D. J. Pine, and S. Sacanna, Recent progress on patchy colloids and their self-assembly, Journal of Physics: Condensed Matter, vol.25, issue.19, pp.193101-193113, 2013.
DOI : 10.1088/0953-8984/25/19/193101

S. Sacanna and D. J. Pine, Shape-anisotropic colloids: Building blocks for complex assemblies, Current Opinion in Colloid & Interface Science, vol.16, issue.2, pp.96-105, 2011.
DOI : 10.1016/j.cocis.2011.01.003

A. B. Pawar and I. Kretzschmar, Patchy Particles by Glancing Angle Deposition, Langmuir, vol.24, issue.2, pp.355-358, 2008.
DOI : 10.1021/la703005z

A. B. Pawar and I. Kretzschmar, Multifunctional Patchy Particles by Glancing Angle Deposition, Langmuir, vol.25, issue.16, pp.9057-9063, 2009.
DOI : 10.1021/la900809b

Y. Hou, S. Li, Y. Su, X. Huang, Y. Liu et al., Design and Fabrication of Three-Dimensional Chiral Nanostructures Based on Stepwise Glancing Angle Deposition Technology, Langmuir, vol.29, issue.3, pp.867-872, 2013.
DOI : 10.1021/la304122f

Z. He and I. Kretzschmar, Template-Assisted Fabrication of Patchy Particles with Uniform Patches, Langmuir, vol.28, issue.26, pp.9915-9919, 2012.
DOI : 10.1021/la3017563

Z. He and I. Kretzschmar, Template-Assisted GLAD: Approach to Single and Multipatch Patchy Particles with Controlled Patch Shape, Langmuir, vol.29, issue.51, pp.15755-15761, 2013.
DOI : 10.1021/la404592z

V. N. Manoharan, T. E. Mark, and D. J. Pine, Dense Packing and Symmetry in Small Clusters of Microspheres, Science, vol.301, issue.5632, pp.483-487, 2003.
DOI : 10.1126/science.1086189

Y. Wang, Y. Wang, D. R. Breed, V. N. Manoharan, L. Feng et al., Colloids with valence and specific directional bonding, Nature, vol.109, issue.7422, pp.51-55, 2012.
DOI : 10.1021/jp0549632

Y. Wang, Y. Wang, X. Zheng, G. Yi, S. Sacanna et al., Three-Dimensional Lock and Key Colloids, Journal of the American Chemical Society, vol.136, issue.19, pp.6866-6869, 2014.
DOI : 10.1021/ja502699p

D. Zerrouki, B. Rotenberg, S. Abramson, J. Baudry, C. Goubault et al., Preparation of Doublet, Triangular, and Tetrahedral Colloidal Clusters by Controlled Emulsification, Langmuir, vol.22, issue.1, pp.57-62, 2006.
DOI : 10.1021/la051765t
URL : https://hal.archives-ouvertes.fr/hal-00079315

G. Yi, V. N. Manoharan, E. Michel, M. T. Elsesser, S. Yang et al., Colloidal Clusters of Silica or Polymer Microspheres, Advanced Materials, vol.16, issue.14, pp.1204-1208, 2004.
DOI : 10.1002/adma.200306638

Y. Cho, G. Yi, J. Lim, S. Kim, V. N. Manoharan et al., Self-Organization of Bidisperse Colloids in Water Droplets, Journal of the American Chemical Society, vol.127, issue.45, pp.15968-15975, 2005.
DOI : 10.1021/ja0550632

S. Sacanna, W. T. Irvine, P. M. Chaikin, and D. J. Pine, Lock and key colloids, Nature, vol.20, issue.7288, pp.575-578, 2010.
DOI : 10.1038/nature08906

D. J. Kraft, J. Groenewold, and W. K. , Colloidal molecules with well-controlled bond angles, Soft Matter, vol.36, issue.20, p.3823, 2009.
DOI : 10.1039/b910593j

D. J. Kraft, J. Hilhorst, M. A. Heinen, M. J. Hoogenraad, B. Luigjes et al., Patchy Polymer Colloids with Tunable Anisotropy Dimensions, The Journal of Physical Chemistry B, vol.115, issue.22, pp.7175-7181, 2011.
DOI : 10.1021/jp108760g

A. Désert, C. Hubert, Z. Fu, L. Moulet, J. Majimel et al., Synthesis and Site-Specific Functionalization of Tetravalent, Hexavalent, and Dodecavalent Silica Particles, Angewandte Chemie International Edition, vol.67, issue.42, pp.11068-11072, 2013.
DOI : 10.1021/ac00100a008

S. Reculusa, C. Mingotaud, E. Bourgeat-lami, E. Duguet, and S. Ravaine, Synthesis of Daisy-Shaped and Multipod-like Silica/Polystyrene Nanocomposites, Nano Letters, vol.4, issue.9, pp.1677-1682, 2004.
DOI : 10.1021/nl049161h
URL : https://hal.archives-ouvertes.fr/hal-00150126

A. Perro, S. Reculusa, E. Bourgeat-lami, E. Duguet, and S. Ravaine, Synthesis of hybrid colloidal particles: From snowman-like to raspberry-like morphologies, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.284, issue.285, pp.284-285, 2006.
DOI : 10.1016/j.colsurfa.2005.11.073
URL : https://hal.archives-ouvertes.fr/hal-00080647

A. Perro, E. Duguet, O. Lambert, J. Taveau, E. Bourgeat-lami et al., A Chemical Synthetic Route towards ???Colloidal Molecules???, Angewandte Chemie, vol.7, issue.2, pp.367-371, 2009.
DOI : 10.1557/mrs2004.34
URL : https://hal.archives-ouvertes.fr/hal-00350952

A. Désert, I. Chaduc, S. Fouilloux, J. Taveau, O. Lambert et al., High-yield preparation of polystyrene/silica clusters of controlled morphology, Polymer Chemistry, vol.27, issue.5, pp.1130-1132, 2012.
DOI : 10.1021/la2013842

A. Désert, Thèse de l'Université Bordeaux 1: Colloïdes hybrides silice/polystyrène de morphologie contrôlée, 2011.

K. D. Hartlen, A. P. Athanasopoulos, and V. Kitaev, Facile Preparation of Highly Monodisperse Small Silica Spheres (15 to >200 nm) Suitable for Colloidal Templating and Formation of Ordered Arrays, Langmuir, vol.24, issue.5, pp.1714-1720, 2008.
DOI : 10.1021/la7025285

W. Stöber and A. Fink, Controlled growth of monodisperse silica spheres in the micron size range, Journal of Colloid and Interface Science, vol.26, issue.1, pp.62-69, 1968.
DOI : 10.1016/0021-9797(68)90272-5

C. A. Schneider, W. S. Rasband, and K. W. Eliceiri, NIH Image to ImageJ: 25 years of image analysis, Nature Methods, vol.42, issue.7, pp.671-675, 2012.
DOI : 10.2144/000112257

E. Bourgeat-lami, M. Insulaire, S. Reculusa, A. Perro, S. Ravaine et al., Nucleation of Polystyrene Latex Particles in the Presence of <I>??</I>-Methacryloxypropyltrimethoxysilane: Functionalized Silica Particles, Journal of Nanoscience and Nanotechnology, vol.6, issue.2, pp.432-444, 2006.
DOI : 10.1166/jnn.2006.920

A. Désert, C. Hubert, A. Thill, O. Spalla, J. Taveau et al., Regioselective Coating of Tetrapod-like Clusters with Silica, Molecular Crystals and Liquid Crystals, vol.48, issue.1, pp.27-32, 2014.
DOI : 10.1103/PhysRevLett.65.3152

R. M. Metzger, The Physical Chemist's Toolbox, p.667, 2012.
DOI : 10.1002/9781118195598

E. Bourgeat-lami and G. Fevotte, Emulsion copolymerization mechanism of 3- trimethoxysilylpropyl methacrylate and styrene, Acta Polym. Sin, vol.7, pp.912-916, 2006.

A. Perro, D. Nguyen, S. Ravaine, E. Bourgeat-lami, O. Lambert et al., Planar submicronic silica???polystyrene particles obtained by substrate-directed shaping, Journal of Materials Chemistry, vol.42, issue.285, pp.4225-4230, 2009.
DOI : 10.1166/jnn.2006.920
URL : https://hal.archives-ouvertes.fr/hal-00395577

D. Yin, Q. Zhang, H. Zhang, and C. Yin, Fabrication of covalently-bonded polystyrene/SiO2 composites by Pickering emulsion polymerization, Journal of Polymer Research, vol.332, issue.5, pp.689-696, 2009.
DOI : 10.1007/s10965-009-9357-9

A. Guyot and P. Espiard, Poly(ethy acrylate) latexes encapsulating nanoparticles of silica: 2 . grafting process onto silica, Polymer (Guildf), vol.36, pp.4391-4395, 1995.

Z. Zeng, J. Yu, and Z. Guo, Preparation of Functionalized Core-Shell Alumina/Polystyrene Composite Nanoparticles, 1, Macromolecular Chemistry and Physics, vol.151, issue.15, pp.1558-1567, 2005.
DOI : 10.1002/macp.200500060

R. Mueller, H. K. Kammler, K. Wegner, and S. E. Pratsinis, OH Surface Density of SiO2 and TiO2 by Thermogravimetric Analysis, pp.160-165, 2003.

G. D. Jones, Chloromethylation of Polystyrene, Industrial & Engineering Chemistry, vol.44, issue.11, pp.2686-2693, 1952.
DOI : 10.1021/ie50515a054

A. Warshawsky and A. Deshe, Halomethyl octyl ethers: Convenient halomethylation reagents, Journal of Polymer Science: Polymer Chemistry Edition, vol.23, issue.6, pp.1839-1841, 1985.
DOI : 10.1002/pol.1985.170230623

C. Lü, B. Gao, Q. Liu, and C. Qi, Preparation of two kinds of chloromethylated polystyrene particle using 1,4-bis (chloromethoxy) butane as chloromethylation reagent, Colloid and Polymer Science, vol.102, issue.5, pp.553-561, 2007.
DOI : 10.1007/s00396-007-1800-z

V. G. Teixeira, F. M. Coutinho, F. R. Petrocínioa, and A. S. Gomes, Determination of accessible chloromethyl groups in chloromethylated styrene-divinylbenzene copolymers, Journal of the Brazilian Chemical Society, vol.16, issue.5, pp.951-956, 2005.
DOI : 10.1590/S0103-50532005000600010

R. Rodrigo, C. A. Toro, and J. Cuellar, -divinylbenzene) microparticles with controlled degree of functionalization, Journal of Applied Polymer Science, vol.1, pp.4054-4065, 2013.
DOI : 10.1080/00401706.1959.10489866

F. Galindo, B. Altava, M. I. Burguete, R. Gavara, and S. Luis, A Sensitive Colorimetric Method for the Study of Polystyrene Merrifield Resins and Chloromethylated Macroporous Monolithic Polymers, Journal of Combinatorial Chemistry, vol.6, issue.6, pp.859-61, 2004.
DOI : 10.1021/cc049871l

B. G. Van-ravensteijn, M. Kamp, A. Van-blaaderen, and W. K. , General Route toward Chemically Anisotropic Colloids, Chemistry of Materials, vol.25, issue.21, pp.4348-4353, 2013.
DOI : 10.1021/cm4025606

V. K. Sarin, S. B. Kent, J. P. Tam, and R. B. Merrifield, Quantitative monitoring of solid-phase peptide synthesis by the ninhydrin reaction, Analytical Biochemistry, vol.117, issue.1, pp.147-157, 1981.
DOI : 10.1016/0003-2697(81)90704-1

J. S. Fritz and C. A. , Titration of amines in acetone, Analytical Chemistry, vol.44, issue.9, pp.1673-1674, 1972.
DOI : 10.1021/ac60317a022

M. Whitesides, Thiol-disulfide interchange, Sulphur-Containing Functional Groups, pp.633-658, 1993.

A. Wang, H. P. Ng, Y. Xu, Y. Li, Y. Zheng et al., Gold Nanoparticles: Synthesis, Stability Test, and Application for the Rice Growth, Journal of Nanomaterials, vol.48, issue.6, pp.1-6, 2014.
DOI : 10.1016/S0920-5861(96)00208-8

I. Ojea-jime, F. M. Romero, N. G. Bastus, and V. Puntes, Small Gold Nanoparticles Synthesized with Sodium Citrate and Heavy Water: Insights into the Reaction Mechanism, The Journal of Physical Chemistry C, vol.114, issue.4, pp.1800-1804, 2010.
DOI : 10.1021/jp9091305

M. Roca, N. H. Pandya, S. Nath, and A. J. Haes, Linear Assembly of Gold Nanoparticle Clusters via Centrifugation, Langmuir, vol.26, issue.3, pp.2035-2076, 2010.
DOI : 10.1021/la902572m

N. G. Bastus, J. Comenge, and V. Puntes, Kinetically Controlled Seeded Growth Synthesis of Citrate-Stabilized Gold Nanoparticles of up to 200 nm: Size Focusing versus Ostwald Ripening, Langmuir, vol.27, issue.17, pp.11098-11105, 2011.
DOI : 10.1021/la201938u

J. Kimling, M. Maier, B. Okenve, V. Kotaidis, H. Ballot et al., Turkevich Method for Gold Nanoparticle Synthesis Revisited, The Journal of Physical Chemistry B, vol.110, issue.32, pp.15700-15707, 2006.
DOI : 10.1021/jp061667w

M. Lo-conte, K. S. Carroll, M. Giersig, P. Mulvaney, S. Weisbecker et al., The chemistry of thiol oxidation and detection Preparation of Ordered Colloid Monolayers by Electrophoretic Deposition, Oxidative Stress and Redox Regulation Molecular of Aliphatic Thiols on Gold Golloids, pp.1-42, 1993.

J. Fontana, W. J. Dressick, J. Phelps, J. E. Johnson, R. W. Rendell et al., Virus-Templated Plasmonic Nanoclusters with Icosahedral Symmetry via Directed Self-Assembly Seeded growth of submicron Au colloids with quadrupole plasmon resonance modes Kinetically Controlled Seeded Growth Synthesis of Citrate-Stabilized Gold Nanoparticles of up to 200 nm: Size Focusing versus Ostwald Ripening Seeded Growth Synthesis of Uniform Gold Nanoparticles with Diameters of 15-300 nm, Langmuir Langmuir J. Phys. Chem. C, vol.109, issue.115, pp.3058-3063, 2006.

E. Mahon, D. R. Hristov, and K. Dawson, Stabilising fluorescent silica nanoparticles against dissolution effects for biological studies, Chemical Communications, vol.27, issue.64, pp.7970-7972, 2012.
DOI : 10.1021/la2013842

P. M. Dove, N. Han, A. F. Wallace, and J. J. De-yoreo, Kinetics of amorphous silica dissolution and the paradox of the silica polymorphs, Proceedings of the National Academy of Sciences, vol.44, issue.7, pp.9903-9908, 2008.
DOI : 10.1016/0016-7037(80)90280-X

Y. J. Wong, L. Zhu, W. S. Teo, Y. W. Tan, Y. Yang et al., Revisiting the Sto??ber Method: Inhomogeneity in Silica Shells, Journal of the American Chemical Society, vol.133, issue.30, pp.11422-11425, 2011.
DOI : 10.1021/ja203316q

D. G. Duff, A. Baiker, and P. P. Edwards, A new hydrosol of gold clusters. 1. Formation and particle size variation, Langmuir, vol.9, issue.9, pp.2301-2309, 1993.
DOI : 10.1021/la00033a010

D. G. Duff, A. Baiker, I. Gameson, and P. P. Edwards, A new hydrosol of gold clusters. 2. A comparison of some different measurement techniques, Langmuir, vol.9, issue.9, pp.2310-2317, 1993.
DOI : 10.1021/la00033a011

J. L. Hueso, V. Sebastián, Á. Mayoral, L. Usón, M. Arruebo et al., Beyond gold: rediscovering tetrakis-(hydroxymethyl)-phosphonium chloride (THPC) as an effective agent for the synthesis of ultra-small noble metal nanoparticles and Pt-containing nanoalloys, RSC Advances, vol.133, issue.26, pp.10427-10433, 2013.
DOI : 10.1021/ja2040464

S. Oldenburg, R. Averitt, S. Westcott, and N. Halas, Nanoengineering of optical resonances, Chemical Physics Letters, vol.288, issue.2-4, pp.243-247, 1998.
DOI : 10.1016/S0009-2614(98)00277-2

T. Pham, J. B. Jackson, N. J. Halas, and T. R. Lee, Preparation and Characterization of Gold Nanoshells Coated with Self-Assembled Monolayers, Langmuir, vol.18, issue.12, pp.4915-4920, 2002.
DOI : 10.1021/la015561y

B. J. Jankiewicz, D. Jamiola, J. Choma, and M. Jaroniec, Silica???metal core???shell nanostructures, Advances in Colloid and Interface Science, vol.170, issue.1-2, pp.28-47, 2012.
DOI : 10.1016/j.cis.2011.11.002

J. L. Cardoso, S. G. , and S. Filho, Electrodeposition of gold from formaldehyde-sulfite baths: bath stability and deposits characterization, Qu??mica Nova, vol.34, issue.4, pp.641-645, 2011.
DOI : 10.1590/S0100-40422011000400017

S. Park, M. Park, P. Han, and S. W. Lee, Relative Contributions of Experimental Parameters to NIR-Absorption Spectra of Gold Nanoshells, J. Ind. Eng. Chem, vol.13, pp.65-70, 2007.

M. R. Rasch, K. Sokolov, and B. , Limitations on the Optical Tunability of Small Diameter Gold Nanoshells, Langmuir, vol.25, issue.19, pp.11777-11785, 2009.
DOI : 10.1021/la901249j

S. E. Park, M. Y. Park, P. K. Han, and S. W. Lee, The effect of pH adjusted Gold Colloids on the formation of Gold Clusters over APTMS-Coated Silica Cores, Bull. Korean Chem. Soc, vol.27, pp.1341-1345, 2006.

Z. Liang, Y. Liu, S. S. Ng, X. Li, L. Lai et al., The effect of pH value on the formation of gold nanoshells, Journal of Nanoparticle Research, vol.11, issue.8, pp.3301-3311, 2011.
DOI : 10.1007/s11051-008-9436-6

S. L. Westcott, S. J. Oldenburg, T. R. Lee, and N. J. Halas, Formation and Adsorption of Clusters of Gold Nanoparticles onto Functionalized Silica Nanoparticle Surfaces, Langmuir, vol.14, issue.19, pp.5396-5401, 1998.
DOI : 10.1021/la980380q

H. R. Vutukuri, A. Imhof, and A. Van-blaaderen, Fabrication of Polyhedral Particles from Spherical Colloids and Their Self-Assembly into Rotator Phases, Angewandte Chemie International Edition, vol.130, issue.50, pp.13830-13834, 2014.
DOI : 10.1063/1.3156856

Q. Ruan, L. Shao, Y. Shu, J. Wang, and H. Wu, Growth of Monodisperse Gold Nanospheres with Diameters from 20 nm to 220 nm and Their Core/Satellite Nanostructures, Advanced Optical Materials, vol.6, issue.1, pp.65-73, 2014.
DOI : 10.1103/PhysRevB.6.4370

Y. Min, M. Akbulut, K. Kristiansen, Y. Golan, and J. Israelachvili, The role of interparticle and external forces in nanoparticle assembly, Nat. Mater, vol.73, pp.527-538, 2008.

B. Derjaguin, L. J. Landau-]-e, J. T. Verwey, R. J. Overbeek, and . Hunter, of the adhesion of strongly charged particles in solutions of electrolytes Theory of the stability of lyophobic colloids Intermolecular and surface forces, Academic P. 1991. [6] J. Lyklema, Fundamentals of interface and colloid science Foundations of colloid science Hard Spheres in Vesicles: Curvature- Induced Forces and Particle-Induced Curvature Lock and key model system, Theory of the stability of strongly charged lyophobic sols, pp.633-409, 1941.

R. J. Macfarlane and C. A. Mirkin, Colloidal Assembly via Shape Complementarity, ChemPhysChem, vol.22, issue.15, pp.3215-3217, 2010.
DOI : 10.1002/cphc.201000389

D. J. Ashton, R. L. Jack, and N. B. Wilding, Self-assembly of colloidal polymers via depletion-mediated lock and key binding, Soft Matter, vol.126, issue.40, pp.9661-9666, 2013.
DOI : 10.1063/1.2730797

Y. Li, X. Zhang, and D. Cao, The Role of Shape Complementarity in the Protein-Protein Interactions, Scientific Reports, vol.7, issue.1, pp.3271-3278, 2013.
DOI : 10.1039/c1sm05398a

R. Tuinier, J. Rieger, and C. G. De-kruif, Depletion-induced phase separation in colloid???polymer mixtures, Advances in Colloid and Interface Science, vol.103, issue.1, pp.1-31, 2003.
DOI : 10.1016/S0001-8686(02)00081-7

C. J. Van-oss, Long-range and short-range mechanisms of hydrophobic attraction and hydrophilic repulsion in specific and aspecific interactions, Journal of Molecular Recognition, vol.14, issue.4, pp.177-190, 2003.
DOI : 10.1017/CBO9781139164665

T. P. Silverstein, The Real Reason Why Oil and Water Don't Mix, Journal of Chemical Education, vol.75, issue.1, pp.116-118, 1998.
DOI : 10.1021/ed075p116

W. B. Rogers and V. N. Manoharan, Programming colloidal phase transitions with DNA strand displacement, Science, vol.4, issue.3, pp.639-642, 2015.
DOI : 10.1038/nchem.1246

U. Gasser, Crystallization in three- and two-dimensional colloidal suspensions, Journal of Physics: Condensed Matter, vol.21, issue.20, pp.203101-203125, 2009.
DOI : 10.1088/0953-8984/21/20/203101

V. J. Anderson and H. N. Lekkerkerker, Insights into phase transition kinetics from colloid science, Nature, vol.48, issue.6883, pp.811-815, 2002.
DOI : 10.1351/pac197648040471

L. Rossi, S. Sacanna, W. T. Irvine, P. M. Chaikin, D. J. Pine et al., Cubic crystals from cubic colloids, Soft Matter, vol.19, issue.9, pp.4139-4142, 2011.
DOI : 10.1021/la0347859

H. Zhang, E. W. Edwards, D. Wang, and H. Möhwald, Directing the self-assembly of nanocrystals beyond colloidal crystallization, Phys. Chem. Chem. Phys., vol.4, issue.28, pp.3288-3299, 2006.
DOI : 10.1021/nl048523i

E. Shevchenko, D. Talapin, C. B. Murray, and S. O-'brien, Structural Characterization of Self-Assembled Multifunctional Binary Nanoparticle Superlattices, Journal of the American Chemical Society, vol.128, issue.11, pp.3620-3637, 2006.
DOI : 10.1021/ja0564261

C. E. Snyder, A. M. Yake, J. D. Feick, and D. Velegol, Nanoscale Functionalization and Site-Specific Assembly of Colloids by Particle Lithography, Langmuir, vol.21, issue.11, pp.4813-4815, 2005.
DOI : 10.1021/la050715l

Y. Wang, Y. Wang, X. Zheng, É. Ducrot, J. S. Yodh et al., Crystallization of DNA-coated colloids, Nature Communications, vol.491, pp.1-8, 2015.
DOI : 10.1038/nature11564

Y. Wang, Y. Wang, X. Zheng, E. Ducrot, M. G. Lee et al., Synthetic Strategies Toward DNA-Coated Colloids that Crystallize, Journal of the American Chemical Society, vol.137, issue.33, pp.10760-10766, 2015.
DOI : 10.1021/jacs.5b06607
URL : http://doi.org/10.1021/jacs.5b06607

Z. Zhang, A. S. Keys, T. Chen, and S. C. Glotzer, Structures through Molecular Mimicry, Langmuir, vol.21, pp.409-413, 2005.

F. Smallenburg and F. Sciortino, Liquids more stable than crystals in particles with limited valence and flexible bonds, Nature Physics, vol.126, issue.9, pp.554-558, 2013.
DOI : 10.1063/1.2434957

J. M. Romo-herrera, R. Alvarez-puebla, and L. M. Liz-marzán, Controlled assembly of plasmonic colloidal nanoparticle clusters, Nanoscale, vol.328, issue.4, pp.1304-1315, 2011.
DOI : 10.1126/science.1187949

L. Hong, A. Cacciuto, E. Luijten, and S. Granick, Clusters of Charged Janus Spheres, Nano Letters, vol.6, issue.11, pp.2510-2514, 2006.
DOI : 10.1021/nl061857i

L. Hong, A. Cacciuto, E. Luijten, and S. Granick, Clusters of Amphiphilic Colloidal Spheres, Langmuir, vol.24, issue.3, pp.621-625, 2008.
DOI : 10.1021/la7030818

A. and L. Beulze, Ph.D dissertation of the university Bordeaux 1: Synthesis and characterization of nanoresonators for metamaterials application in the visible range, 2013.

A. S. Urban, X. Shen, Y. Wang, N. Large, H. Wang et al., Three-Dimensional Plasmonic Nanoclusters, Nano Letters, vol.13, issue.9, pp.4399-4403, 2013.
DOI : 10.1021/nl402231z

J. E. Galván-moya, T. Altantzis, K. Nelissen, F. M. Peeters, M. Grzelczak et al., Self-Organization of Highly Symmetric Nanoassemblies: A Matter of Competition, ACS Nano, vol.8, issue.4, pp.3869-3875, 2014.
DOI : 10.1021/nn500715d

A. Sánchez-iglesias, M. Grzelczak, T. Altantzis, B. Goris, J. Pérez-juste et al., Hydrophobic Interactions Modulate Self-Assembly of Nanoparticles, ACS Nano, vol.6, issue.12, pp.11059-11065, 2012.
DOI : 10.1021/nn3047605

M. Grzelczak, A. Sánchez-iglesias, and L. M. Liz-marzán, Solvent-induced division of plasmonic clusters, Soft Matter, vol.17, issue.38, pp.9094-9098, 2013.
DOI : 10.1021/la0104370

N. Pazos-perez, C. S. Wagner, J. M. Romo-herrera, L. M. Liz-marzán, F. J. García-de-abajo et al., Organized Plasmonic Clusters with High Coordination Number and Extraordinary Enhancement in Surface-Enhanced Raman Scattering (SERS), Angewandte Chemie International Edition, vol.112, issue.51, pp.12688-12693, 2012.
DOI : 10.1021/jp807345h
URL : http://onlinelibrary.wiley.com/doi/10.1002/anie.201207019/pdf

S. Sacanna, W. T. Irvine, P. M. Chaikin, and D. J. Pine, Lock and key colloids, Nature, vol.20, issue.7288, pp.575-578, 2010.
DOI : 10.1038/nature08906

S. Sacanna, W. T. Irvine, L. Rossi, and D. J. Pine, Lock and key colloids through polymerization-induced buckling of monodisperse silicon oil droplets, Soft Matter, vol.70, issue.5, pp.1631-1634, 2011.
DOI : 10.1016/0927-7757(93)80285-M

L. Colón-meléndez, D. J. Beltran-villegas, G. Van-anders, J. Liu, M. Spellings et al., Binding kinetics of lock and key colloids, The Journal of Chemical Physics, vol.142, issue.17, pp.174909-174918, 2015.
DOI : 10.1073/pnas.0610494104

Y. Wang, Y. Wang, X. Zheng, G. Yi, S. Sacanna et al., Three-Dimensional Lock and Key Colloids, Journal of the American Chemical Society, vol.136, issue.19, pp.6866-6869, 2014.
DOI : 10.1021/ja502699p

Y. Wang, Y. Wang, D. R. Breed, V. N. Manoharan, L. Feng et al., Colloids with valence and specific directional bonding, Nature, vol.109, issue.7422, pp.51-55, 2012.
DOI : 10.1021/jp0549632

S. N. Sheikholeslami, H. Alaeian, A. L. Koh, and J. A. Dionne, A Metafluid Exhibiting Strong Optical Magnetism, Nano Letters, vol.13, issue.9, pp.4137-4141, 2013.
DOI : 10.1021/nl401642z

J. Fontana, W. J. Dressick, J. Phelps, J. E. Johnson, R. W. Rendell et al., Virus-Templated Plasmonic Nanoclusters with Icosahedral Symmetry via Directed Self-Assembly, Small, vol.8, issue.15, pp.3058-3063, 2014.
DOI : 10.1038/nnano.2012.249
URL : http://onlinelibrary.wiley.com/doi/10.1002/smll.201400470/pdf

A. S. Blum, C. M. Soto, C. D. Wilson, J. D. Cole, M. Kim et al., Cowpea Mosaic Virus as a Scaffold for 3-D Patterning of Gold Nanoparticles, Nano Letters, vol.4, issue.5, pp.867-870, 2004.
DOI : 10.1021/nl0497474

F. Li, W. C. Yoo, M. B. Beernink, and A. Stein, Site-Specific Functionalization of Anisotropic Nanoparticles: From Colloidal Atoms to Colloidal Molecules, Journal of the American Chemical Society, vol.131, issue.51, pp.18548-18555, 2009.
DOI : 10.1021/ja908364k

W. Yufeng, W. Yu, D. R. Breed, M. Vinothan, and N. , Colloids with valence and specific directional bonding, Nature, vol.491, pp.51-56, 2012.

K. Zhao and T. G. Mason, Directing Colloidal Self-Assembly through Roughness-Controlled Depletion Attractions, Physical Review Letters, vol.22, issue.26, pp.268301-268304, 2007.
DOI : 10.1209/0295-5075/9/3/011

D. J. Kraft, R. Ni, F. Smallenburg, M. Hermes, K. Yoon et al., Surface roughness directed self-assembly of patchy particles into colloidal micelles, Proceedings of the National Academy of Sciences, vol.109, issue.14, pp.10787-10792, 2012.
DOI : 10.1021/jp045576f

E. Valeur and M. Bradley, Amide bond formation: beyond the myth of coupling reagents, Chem. Soc. Rev., vol.61, issue.2, pp.606-631, 2009.
DOI : 10.1016/j.tet.2005.06.003

C. A. Montalbetti and V. Falque, Amide bond formation and peptide coupling, Tetrahedron, vol.61, issue.46, pp.10827-10852, 2005.
DOI : 10.1016/j.tet.2005.08.031

H. S. Rho, H. S. Baek, D. H. Kim, and I. S. Chang, A Convenient Method for the Preparation of Alkanolamides., ChemInform, vol.27, issue.35, pp.584-586, 2006.
DOI : 10.1002/chin.200635052

D. R. Burfield and R. H. Smithers, Desiccant efficiency in solvent drying. 3. Dipolar aprotic solvents, The Journal of Organic Chemistry, vol.43, issue.20, pp.3966-3968, 1978.
DOI : 10.1021/jo00414a038

F. M. Benoiton, N. Leo, and . Chen, Peptide synthesis in partially aqueous solution, FEBS Letters, vol.13, issue.1, pp.104-106, 1981.
DOI : 10.1039/c39780000537

J. A. Howarter, J. P. Youngblood, R. May, I. Final, and F. September, Optimization of Silica Silanization by 3-Aminopropyltriethoxysilane, Langmuir, vol.22, issue.26, pp.11142-11147, 2006.
DOI : 10.1021/la061240g

R. G. Acres, G. G. Ellis, A. V. Alvino, J. Lenahan, C. E. Khodakov et al., Molecular Structure of 3-Aminopropyltriethoxysilane Layers Formed on Silanol-Terminated Silicon Surfaces, The Journal of Physical Chemistry C, vol.116, issue.10, pp.6289-6297, 2012.
DOI : 10.1021/jp212056s

N. Reinhardt, L. Adumeau, O. Lambert, S. Ravaine, and S. Mornet, Quaternary Ammonium Groups Exposed at the Surface of Silica Nanoparticles Suitable for DNA Complexation in the Presence of Cationic Lipids, The Journal of Physical Chemistry B, vol.119, issue.21, pp.6401-6411, 2015.
DOI : 10.1021/acs.jpcb.5b01834
URL : https://hal.archives-ouvertes.fr/hal-01158076

N. M. Reinhardt, Thèse de l'université de Bordeaux 1 : Modification chimique de surface de nanoparticules de silice pour le marquage d'ADN dans des lipoplexes, 2013.

C. Elissalde, O. Bidault, E. Sellier, O. Nguyen, and M. Maglione, Ferroelectric-Based Nanocomposites : Toward Multifunctional Materials, Chem. Mater, vol.19, pp.987-992, 2007.

S. C. Feifel and F. Lisdat, Silica nanoparticles for the layer-by-layer assembly of fully electroactive cytochrome c multilayers, J. Nanobiotechnology, vol.9, pp.1-12, 2011.

Y. An, M. Chen, Q. Xue, and W. Liu, Preparation and self-assembly of carboxylic acid-functionalized silica, Journal of Colloid and Interface Science, vol.311, issue.2, pp.507-513, 2007.
DOI : 10.1016/j.jcis.2007.02.084

M. Cano, G. De-la-cueva-méndez3, ]. K. Kolwas, A. Derkachova, N. J. Halas et al., Self-assembly of a superparamagnetic raspberry-like silica/iron oxide nanocomposite using epoxy-amine coupling chemistry Plasmonic abilities of gold and silver spherical nanoantennas in terms of size dependent multipolar resonance frequencies and plasmon damping rates Seeded growth of submicron Au colloids with quadrupole plasmon resonance modes, Opto- Electronics Rev. Langmuir, vol.125, issue.22, pp.3620-3622, 2006.

F. Shvets, K. Capasso-he, C. Bao, J. Wu, N. B. Bao et al., DNA-enabled self-assembly of plasmonic nanoclusters Three-dimensional plasmonic nanoclusters, Strong Optical Magnetism and Fano Resonances in Asymmetric Plasmonic Metamolecules, pp.1135-1138, 2010.

A. Alù and N. Engheta, The quest for magnetic plasmons at optical frequencies, Optics Express, vol.17, issue.7, pp.5723-5730, 2009.
DOI : 10.1364/OE.17.005723

J. B. Lassiter, H. Sobhani, M. W. Knight, W. S. Mielczarek, P. Nordlander et al., Designing and Deconstructing the Fano Lineshape in Plasmonic Nanoclusters, Nano Letters, vol.12, issue.2, pp.1058-1062, 2012.
DOI : 10.1021/nl204303d

F. Shafiei, F. Monticone, K. Q. Le, X. Liu, T. Hartsfield et al., A subwavelength plasmonic metamolecule exhibiting magnetic-based optical Fano resonance, Nature Nanotechnology, vol.3, issue.2, pp.95-99, 2013.
DOI : 10.1038/ncomms1806

J. Fan, K. Bao, C. Wu, J. Bao, R. Bardhan et al., Fano-like Interference in Self-Assembled Plasmonic Quadrumer Clusters, Nano Letters, vol.10, issue.11, pp.4680-4685, 2010.
DOI : 10.1021/nl1029732

A. Liu, A. Rahmani, G. W. Bryant, L. J. Richter, and S. J. Stranick, Modeling illumination-mode near-field optical microscopy of Au nanoparticles, Journal of the Optical Society of America A, vol.18, issue.3, p.704, 2001.
DOI : 10.1364/JOSAA.18.000704

J. J. Mock, M. Barbic, D. R. Smith, D. A. Schultz, and S. Schultz, Shape effects in plasmon resonance of individual colloidal silver nanoparticles, The Journal of Chemical Physics, vol.22, issue.15, p.6755, 2002.
DOI : 10.1126/science.1066541

J. D. Baena, L. Jelinek, and R. Marqués, Towards a systematic design of isotropic bulk magnetic metamaterials using the cubic point groups of symmetry, Physical Review B, vol.76, issue.24, p.245115, 2007.
DOI : 10.1063/1.1497452

Y. Urzhumov, G. Shvets, J. Fan, F. Capasso, D. Brandl et al., Plasmonic nanoclusters: a path towards negative-index metafluids, Optics Express, vol.15, issue.21, pp.14129-14145, 2007.
DOI : 10.1364/OE.15.014129

A. Vallecchi, M. Albani, and F. Capolino, Effect of irregularities of nanosatellites position and size on collective electric and magnetic plasmonic resonances in spherical nanoclusters, Optics Express, vol.21, issue.6, pp.7667-7685, 2013.
DOI : 10.1364/OE.21.007667

S. J. Barrow, X. Wei, J. S. Baldauf, A. M. Funston, P. Mulvaney1 et al., The surface plasmon modes of self-assembled gold nanocrystals Spheres growing on a sphere: a model to predict the morphology yields of colloidal molecules obtained through a heterogeneous nucleation route Viscosity Gradient as a Novel Mechanism for the Centrifugation-Based Separation of Nanoparticles, Dense packing and Symmetry in Small clusters of microspheres Liquids more stable than crystals in particles with limited valence and flexible bonds, pp.1-9, 2003.