Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. Hidai, S. Uemura et al., 72 The propargylation of a range of electron rich arenes, heteroarenes and 1,3-dicarbonyl compounds, as well as sulfonamides, III) catalyzed system for the direct allylation and arylation of propargylic alcohols, pp.11846-1495, 1567.

. Mg, 50 mmol) and B(C 6 F 5 ) 3 ?H 2 O (13.3 mg, 25.0 µmol, 5.00 mol%) Isolated (90 mg, 86%) as a colorless oil after column chromatography (0 to 2% EtOAc Petroleum ether)

3. Hz, NMR (100 MHz, CDCl 3 ) ? 142

2. Hz, 40 (s, 3H); 13 C NMR (100 MHz, CDCl 3 ) ? 157, pp.938539-938541

3. Hz, NMR (100 MHz, CDCl 3 ) ? 156, 19836.

. Di-tert, Synthesized according to general procedure after 6 h at 90 °C starting with tert-butanol (120 µL, 1.25 mmol, pp.4-57

. Hz, 12 (s, 1H), 3.06 (s, 2H), 1.44 (s, 6H); 13 C NMR (100 MHz, CDCl 3 ) ? 136, pp.35-42

2. Hzt and J. =. , 5 Hz), 1.94-1.85 (m, 2H), 1.74-1.66 (m, 2H), 1.35 (s, 6H); 13 C NMR (100 MHz, CDCl 3 ) ? 136, pp.34-41

. Adamantyl-azide-56j, 223 Synthesized according to the general procedure (condition A) after 1 h at 23 o C starting with 1-adamantol 31 (76 mg, 0.50 mmol), trimethylsilyl azide (199 µL, 173 mg, 1.50 mmol) and B(C 6 F 5 ) mol%) Isolated (81 mg, 92%) as a colorless amorphous solid after column chromatography (Petroleum ether), p.45

. Mhz, 9. The analytical data are in accordance with those reported in the literature

T. J. Henly, 1-en-1-yl)benzene 56n. Synthesized according to the general procedure (condition A) after 1 h at 0 °C starting with the alcohol 54n (86 mg, 0.50 mmol), trimethylsilyl azide (199 µL, 173 mg, 1.50 mmol) and B(C 6 F 5 ) 3 ?H 2 O (13 mg, 0.025 mmol, J. Org. Chem, vol.27, p.1465, 1983.

1. Hz and J. =. , (s, 6H); 13 C NMR (100 MHz, CDCl 3 ) ? 154, 7.2 Hz, 1H), 7.03-6.97 (m, 2H) 2H), 2.29-2.22 (m, 2H), pp.56-63

A. Odedra, C. Wu, T. B. Pratap, C. Huang, Y. Ran et al., Ruthenium-Catalyzed Aromatization of Enediynes via Highly Regioselective Nucleophilic Additions on a ??-Alkyne Functionality. A Useful Method for the Synthesis of Functionalized Benzene Derivatives, Journal of the American Chemical Society, vol.127, issue.10, p.3406, 2005.
DOI : 10.1021/ja043047j

2. Hz, 76 (s, 6H) 13 C NMR (100 MHz, CDCl 3 ) ? 142, pp.41-43

1. Hz, 19-2.11 (m, 2H), 1.44 (s, 6H); 13 C NMR (100 MHz, CDCl 3 ) ? 159, pp.5032-5034

. Bromophenyl, 4-dimethoxyphenyl)-3-methylbutane 81c. Synthesized according to the general procedure C using 1-(4-bromophenyl)-2-fluoro-2-methylbutane 80c (123 mg, 0.500 mmol)

. Bromophenyl, 4-dimethoxyphenyl)-pentane 81d. Synthesized according to the general procedure C using 1-(4-bromophenyl)-3-ethyl-3-fluoropentane 80d (137 mg, 0.500 mmol)

6. Hz and . Nmr, CDCl 3 ) ? 159, MHz, vol.13

. Dimethoxy-)-adamantane-81e, Synthesized according to the general procedure C using 1-adamantylfluoride 80e (77.1 mg, 0.500 mmol) The nucleophile fraction was distilled off by Kugelrohr distillation and the residue was purified by column chromatography (2% Et 2 O in Petroleum ether) to give a white solid (95 mg, 70%)

. Hz, 84 (s, 3H), 3.82 (s, 3H), 2.12-2.07 (m, 9H), 1.80 (s, 6H); 13 C NMR (100 MHz, CDCl 3 ) ? 1593. The analytical data are in accordance with those reported in the literature

. Hz, 36 (s, 6H), 1.32-1.19 (m, 10H), 1.06-0.98 (m, 2H), 0.92 (t, J = 7.0 Hz, 3H); 13 C NMR (100 MHz, CDCl 3 ) ? 159, pp.8384-8385

. Butyl, 4-dimethoxyphenyl)-cyclohexane 81i. Synthesized according to the general procedure C using 1-butyl-fluorocyclohexane 80i (79.2 mg, 0.500 mmol)

M. Couturier, 20-2.04 (m, 2H); 13 C NMR (100 MHz, CDCl 3 ) ? 141 Hz); 19 F NMR 237, NMR (400 MHz 2H), 2.91-2.87 (t, J = 7.4, 2H), pp.47-54, 2010.

. Mhz, CDCl 3 ; CF 3 COOH ? ext. std.) ? -218.8 (tt, J = 48.0 Hz, 23.1 Hz). The analytical data are in accordance with those reported in the literature

. Mhz, CDCl 3 ; CF 3 COOH ? ext. std.) ? -115.9 (dt, J =56.7 Hz, 17.2 Hz). The analytical data are in accordance with those reported in the literature, p.239

D. Condition, 0 mmol) in dry THF (30 mL) at -78 o C, was added (diethylamino)sulfur trifluoride (1.32 mL, 1.61 g, 10.0 mmol, 2.00 equiv) The mixture was slowly warmed to room temperature and stirred for 2 h. The reaction was diluted with Et 2 O, washed with precooled saturated aqueous sodium chloride solution, dried over sodium sulfate, filtered and evaporated on the rotary evaporator (< 20 o C) The residue was purified by silica gel chromatography

E. Condition, R. N. Zuckermann, and W. S. Johnson, 75 mmol) in dry CH 2 Cl 2 (30 mL) at -78 o C, was added (diethylamino)sulfur trifluoride (2.60 mL, 3.14 g, 19.5 mmol, 2.00 equiv). The mixture 238 Daub, J. Org. Chem, issue.910, pp.50-1599, 1985.

F. Beaulieu, L. Beauregard, G. Courchesne, M. Couturier, F. Laflamme et al., 5050. was slowly warmed to room temperature and stirred for 2 h. The reaction was diluted with CH 2 Cl 2 , washed with saturated aqueous sodium chloride solution, dried over sodium sulfate, filtered and evaporated on the rotary evaporator (< 20 o C) The residue was purified by silica gel chromatography, 2009.

. Mhz, CDCl 3 ) ? 97.9, 39, 32.4 (d, J = 23.2 Hz)

. Hz, 1 (d, J = 6.8 Hz)

. Butyl-fluorocyclohexane-80i, Synthesized according to the procedure E starting with 1- butylcyclohexanol 43g (938 mg, 6.00 mmol) Isolated (470 mg, 50%) as a colorless oil after column chromatography (Petroleum ether). R f = 0, p.66

6. Hz, NMR (100 MHz, CDCl 3 ) ? 137.1 (d, J = 4.1 Hz), 130, CDCl, vol.13, issue.3

. Hz, HRMS (EI) for C 11 H 14 ClF: calcd. 200.0768

. Hz, HRMS (EI) for C 11 H 14 BrF: calcd. 244.0263

. Bromophenyl, Synthesized according to the procedure E starting with 1-(4-bromophenyl)-3-ethylpentan-3-ol 43m (1.09 g, 4.00 mmol) Isolated (918 mg, 84%) as a yellow oil after column chromatography (Petroleum ether)

. Fluoroadamantane-80e, Synthesized according to the procedure E starting with 1- adamantanol 31 (761 mg, 5.00 mmol) Isolated (635 mg, 82%) as a white solid after column chromatography (Petroleum ether)