L. Qiao, F. Liu, J. Hong, and . Zhang, A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels, Chem. Soc. Rev., vol.47, issue.2, p.631, 2013.
DOI : 10.1039/C3CS60323G

C. Li and . Oloman, Development of a continuous reactor for the electro-reduction of carbon dioxide to formate ??? Part 2: Scale-up, Journal of Applied Electrochemistry, vol.189, issue.3, p.1107, 2007.
DOI : 10.1007/s10800-007-9371-8

F. Koleli and D. Balun, Reduction of CO2 under high pressure and high temperature on Pb-granule electrodes in a fixed-bed reactor in aqueous medium, Applied Catalysis A: General, vol.274, issue.1-2, pp.237-242, 2004.
DOI : 10.1016/j.apcata.2004.07.006

M. Goeppert, J. Czaun, G. K. Jones, G. Prakash, and . Olah, Recycling of carbon dioxide to methanol and derived products ??? closing the loop, Chem. Soc. Rev., vol.102, issue.141, p.7995, 2014.
DOI : 10.1038/ncomms4242

L. Qiao, F. Liu, J. Hong, and . Zhang, A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels, Chem. Soc. Rev., vol.47, issue.2, p.631, 2013.
DOI : 10.1039/C3CS60323G

C. Tsai and K. M. Nicholas, Rhodium-catalyzed hydrogenation of carbon dioxide to formic acid, Journal of the American Chemical Society, vol.114, issue.13, p.5117, 1992.
DOI : 10.1021/ja00039a024

A. D. Munshi, J. C. Main, C. C. Linehan, P. G. Tai, and . Jessop, Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium Trimethylphosphine Complexes:?? The Accelerating Effect of Certain Alcohols and Amines, Journal of the American Chemical Society, vol.124, issue.27, p.7963, 2002.
DOI : 10.1021/ja0167856

A. Federsel, R. Boddien, R. Jackstell, P. Jennerjahn, R. Dyson et al., A Well-Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides, Angewandte Chemie International Edition, vol.36, issue.50, p.9777, 2010.
DOI : 10.1002/anie.201004263

C. Federsel, R. Ziebart, W. Jacstell, M. Baumann, and . Beller, Catalytic Hydrogenation of Carbon Dioxide and Bicarbonates with a Well-Defined Cobalt Dihydrogen Complex, Chemistry - A European Journal, vol.14, issue.1, p.72, 2012.
DOI : 10.1002/chem.201101343

M. T. Jeletic, A. M. Mock, J. C. Appel, and . Linehan, under Ambient Conditions, Journal of the American Chemical Society, vol.135, issue.31, p.11533, 2013.
DOI : 10.1021/ja406601v

A. D. Zhang, J. L. Macintosh, E. A. Wong, P. G. Bielinski, B. Q. Williard et al., hydrogenation to formate enhanced by Lewis acid co-catalysts, Chem. Sci., vol.133, issue.7, p.4291, 2015.
DOI : 10.1021/ic502508p

S. Azua, E. Sanz, and . Peris, Water-Soluble IrIII N-Heterocyclic Carbene Based Catalysts for the Reduction of CO2 to Formate by Transfer Hydrogenation and the Deuteration of Aryl Amines in Water, Chemistry - A European Journal, vol.26, issue.14, p.3963, 2011.
DOI : 10.1002/chem.201002907

K. Göransson, U. Söderling, J. He, W. Zhang, S. Noda et al., Renewable and Sustainable Energy Reviews, 60 H. M. Jhong, S. Ma, P. Kenis, pp.15-482, 1990.

.. Réaction-en-deux-Étapes-par-hydrogénation, 110 2.2. Réaction en une seule étape contrôlée, p.112

). A. Schoenberg, R. F. Heck, T. Kobayashi, M. Tanaka, T. Kobayashi et al., 39 , 3327; b), J. Org. Chem. J. Organomet. Chem. J. Organomet. Chem, vol.231, pp.233-64, 1974.

Y. Sone, Y. J. Tsuji, and . Watanabe, 473, 163; e) A. Yamamoto 170 a) I, J. Organomet. Chem. Bull. Chem. Soc. Jpn, vol.68, p.433, 1994.

M. Orlinkov and . Commun, 17, 279; b )I, 2007.

D. L. Coetzee, J. Dodds, S. Klankermayer, W. Brosinski, A. M. Leitner et al., Homogeneous Catalytic Hydrogenation of Amides to Amines, Chemistry - A European Journal, vol.3, issue.33, p.11039, 2013.
DOI : 10.1002/chem.201204270

V. Stein, M. Meuresch, D. Limper, M. Schmitz, M. Hölscher et al., Highly Versatile Catalytic Hydrogenation of Carboxylic and Carbonic Acid Derivatives using a Ru-Triphos Complex: Molecular Control over Selectivity and Substrate Scope, Journal of the American Chemical Society, vol.136, issue.38, p.13217, 2014.
DOI : 10.1021/ja506023f

. En-boîte-À-gants and . Parr-Équippé-d-'un-barreau-aimanté-et-chargé-avec-le-catalyseur, 2-méthylallyl) 2 ] (12 mg, 37 µmol), triphos (25 mg, 40 µmol), l'amine (3.7 mmol) et 10 mL de tétrahydrofurane. Après dissolution, l'acide formique (1 mL, Ru(COD), issue.1, p.25

2. Hz, 26 (d, J = 8.7 Hz, 2H); 13 C RMN (50 MHz, CDCl 3 ): ? = 13, p.16961

T. Wesselbaum, J. Vom-stein, W. Klankermayer, and . Leitner, Hydrogenation of Carbon Dioxide to Methanol by Using a Homogeneous Ruthenium-Phosphine Catalyst, Angewandte Chemie International Edition, vol.127, issue.30, p.7499, 2012.
DOI : 10.1002/anie.201202320

M. Dulière, J. Devillers, and . Marchand-brynaert, Novel Phosphinite???Ruthenium(II) Complexes Covalently Bound on Silica: Synthesis, Characterization, and Catalytic Behavior versus Oxidation Reactions of Alcohols into Aldehydes, Organometallics, vol.22, issue.4, p.804, 2003.
DOI : 10.1021/om020876+

W. Leung, Q. W. Ip, S. Wong, and T. C. Mak, Syntheses and Structures of Group 14 1,3-Dimetallacyclobutanes, Organometallics, vol.22, issue.22, p.4604, 2003.
DOI : 10.1021/om0340793

J. Farrugia, -III with a Graphical User Interface (GUI), Journal of Applied Crystallography, vol.30, issue.5, p.565, 1997.
DOI : 10.1107/S0021889897003117

URL : https://hal.archives-ouvertes.fr/tel-00800330

E. Alberico, P. Sponholz, C. Cordes, M. Nielsen, H. Drexler et al., Selective Hydrogen Production from Methanol with a Defined Iron Pincer Catalyst under Mild Conditions, Angewandte Chemie International Edition, vol.495, issue.697, p.14162, 2013.
DOI : 10.1002/anie.201307224

L. Huang, X. Zhang, Y. R. Zhang, W. Parr, and . Yang, 22-Schmidt, Andreas 23-Ishikura, Minoru; Heterocycles Density-Functional Theory of Atoms and Molecules, Gaussian 09, Revision B.01, M. J. Frisch, G. W. Trucks, H. B, 1989.

L. Huang and J. Zhao, C60-Bodipy dyad triplet photosensitizers as organic photocatalysts for photocatalytic tandem oxidation/[3+2] cycloaddition reactions to prepare pyrrolo[2,1-a]isoquinoline, Chemical Communications, vol.107, issue.36, p.3751, 2013.
DOI : 10.1039/c3cs35531d

J. Zheng, ;. C. Darcel, and J. Sortais, Methylation of secondary amines with dialkyl carbonates and hydrosilanes catalysed by iron complexes, Chem. Commun., vol.5, issue.91, p.14229, 2014.
DOI : 10.1039/C4CC05517A

URL : https://hal.archives-ouvertes.fr/hal-01114594

D. Hou, M. Wang, M. Chung, Y. Hsieh, G. Tsai et al., Formation of 4,5,6,7-Tetrahydroisoindoles by Palladium-Catalyzed Hydride Reduction, The Journal of Organic Chemistry, vol.72, issue.24, p.9231, 2007.
DOI : 10.1021/jo7016845

J. Jazwinski, Interaction of amines with rhodium(II) tetracarboxylates in solution: formation of nitrogenous stereogenic center, Tetrahedron: Asymmetry, vol.17, issue.16, p.2358, 2006.
DOI : 10.1016/j.tetasy.2006.09.001

J. Alcazar, Reproducibility Across Microwave Instruments:?? Preparation of a Set of 24 Compounds on a Multiwell Plate under Temperature-Controlled Conditions, Journal of Combinatorial Chemistry, vol.7, issue.3, p.353, 2005.
DOI : 10.1021/cc049815k