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D. Intrinsèquement and . Le, cas où liquide est de l'eau, la surface est dite hydrophile lorsque l'angle de contact est quasi-nul, alors qu'elle est hydrophobe lorsque l

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C. Annexe and P. Evonik, Spectres ToF-SIMS en mode négatif (m/z = 0-700) des nanoparticules de TiO 2, p.268

C. Annexe, Clichés SEM à faible agrandissement d'un revêtement composite de référence déposé sur un substrat de silicium témoignant de l'homogéneité du dépôt sur le substrat, p.270

C. Annexe, Représentation des environnements chimiques (%) obtenus par déconvolution des pics XPS C1s, O1s, et Si2p (XPS) du revêtement composite déposé sur substrat de silicium, p.271

C. Annexe, 10 Spectres ToF-SIMS en mode positif (m/z = 0-700) du revêtement composite déposé sur substrat de silicium après test photocatalytique en présence d'un polluant modèle (l'acide formique), p.274

C. Annexe, 11 Spectres ToF-SIMS en mode négatif (m/z = 0-700) du revêtement composite déposé sur substrat de silicium après test photocatalytique en présence d'un polluant modèle (l'acide formique), p.274

C. Annexe and U. , Représentation des environnements chimiques (%) obtenus par déconvolution des pics XPS C1s, O1s, et Si2p (XPS) du revêtement composite déposé sur substrat de silicium après traitement, p.277

C. Annexe and .. Tof-sims-en-mode-positif, -700) d'un substrat textile PET/PVC revêtu d'un revêtement composite Signatures caractéristiques du substrat textile PET/PVC seul (*) et signatures caractéristiques du revêtement composite (?), p.285

C. Annexe and .. Tof-sims-en-mode-positif, 0-700) du substrat textile PET/PVC revêtu d'un revêtement composite pré-traité sous UV pendant 27h en présence d'eau. Signatures caractéristiques du substrat textile PET/PVC seul (*) et signatures caractéristiques du revêtement composite (?), p.286

C. Annexe, Représentation des environnements chimiques (%) obtenus par déconvolution des pics XPS C1s, O1s, p.287

C. Annexe and .. Tof-sims-en-mode-positif, -700) d'un substrat textile PET/PVC revêtu d'un revêtement composite après un photo-vieillissement de 1000h. Signatures caractéristiques du substrat textile PET/PVC seul (*) et signatures caractéristiques du revêtement composite (?), p.288

C. Annexe, EDS du substrat substrat non-tissé Tyvek® revêtu du revêtement composite, Image SEM, p.292

C. Annexe and .. Tof-sims-en-mode-positif, du substrat non-tissé Tyvek® revêtu d'un revêtement composite pré-traité sous UV pendant 27h en présence d'eau. Signatures caractéristiques du revêtement composite (?) détectés à m/z = 326,967 ; 388,896 ; 446,877 ; 460,901; 504,877; 520,782 ; 580,863, p.295

C. Annexe and .. Tof-sims-en-mode-positif, 700) du substrat non-tissé Tyvek® revêtu d'un revêtement composite après un photo-vieillissement accéléré, p.297

C. Annexe, Spectres et images supplémentaires au Chapitre III Annexe C-1 Spectres ToF-SIMS en mode positif (m

C. Annexe, Spectres ToF-SIMS en mode négatif (m/z = 0-700) des nanoparticules de TiO Energie de liaison (eV) Intensité

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. Si-oh, Elongation 3400-3200 O-H (polymérique) Elongation 2935-2915 C-H (CH 2 ) Elongation symétrique et asymétrique 2865-2845 C-H (CH 3 ) Elongation symétrique et asymétrique 1750-1725 C=O Elongation 1610-1500 COO Elongation asymétrique 1485-1445 C-H (CH 2 ) Déformation symétrique 1470-1430 C-H (CH 3 ) Déformation symétrique

D. Annexe, Spectre ToF-SIMS en mode positif d'un dépôt de nanoparticules de TiO 2 déposé à partir de la solution commerciale "Nanostructured & Amorphous Materials" par dip-coating sur substrat de silicium, p.302

D. Annexe, Spectre ToF-SIMS en mode négatif d'un dépôt de nanoparticules de TiO 2 déposé à partir de la solution commerciale "Nanostructured & Amorphous Materials" par dip-coating sur substrat de silicium, p.302

D. Annexe, Représentation des environnements chimique (%) obtenus par déconvolution des pics XPS C1s, O1s, et Si2p des microparticules SiO 2 /TiO 2 avec le Brij-56 comme agent porogène produites à l'échelle R&D 305

D. Annexe, Spectre ToF-SIMS en mode positif des microparticules SiO 2 /TiO 2 produites par Pylote à l'échelle "R&D" (agent porogène: CTAB) n'ayant pas subit de traitement thermique, p.309

D. Annexe, Spectre ToF-SIMS en mode négatif de microparticules SiO 2 /TiO 2 produites par Pylote à l'échelle "R&D" (agent porogène: CTAB) n'ayant pas subit de traitement thermique, p.310

D. Annexe, Représentation des environnements chimique (%) obtenus par déconvolution des pics XPS C1s, O1s, et Si2p des microparticules SiO 2 /TiO 2 produites par Pylote à l'échelle semi-industrielle (campagne 1), p.314

F. -echantillon, TiO 2 sur non tissé Tyvek -Echantillon D (taux de dispersant: 4,9% massique -dispersant : acétique) -Echantillon E (taux de dispersant: 9% massique dispersant : acide acétique), Annexe D-20 Spectres généraux XPS des dépôts de microparticules SiO 2, pp.318-320