W. Pauli, . Dear-radioactive, G. Ladies, E. Phys-fermi, F. Boehm et al., Versuch einer Theorie der ?-Strahlen. I. Z. Physik (3) Lesgourgues (4) Majorana, E. Teoria simmetrica dell'elettrone e del positrone Physics of Massive Neutrinos.; Collaboration, the N.-3. The NEMO-3 Results after Completion of Data Taking GERDA Collaboration, ) Furry, W. H. On Transition Probabilities in Double Beta-Disintegration, pp.27-161, 1930.

I. Barabanov, M. B. Heider, N. Barros, and L. Baudis, Measurement of the Half-Life of the Two-Neutrino Double Beta Decay of Ge-76 with the Gerda Experiment; Collaboration), the N. NEMO-3 and SuperNEMO Double Beta Decay Experiments, 347. (12) Argyriades, p.35110, 2006.

M. Bongrand, G. Broudin-bay, V. Brudanin, and A. J. Caffrey, Measurement of the Two Neutrino Double Beta Decay Half-Life of Zr-96 with the NEMO-3 Detector, 13) Collaboration, R. A. et al N. First Results of the Search of Neutrinoless Double Beta Decay with the NEMO 3 Detector, pp.168-179, 2005.
URL : https://hal.archives-ouvertes.fr/in2p3-00511000

J. B. Albert, M. Auger, D. J. Auty, P. S. Barbeau, E. Beauchamp et al., An Improved Measurement of the 2\nu \beta \beta\ Half-Life of Xe-136 with EXO-200

K. Kishimoto, A. Katsuki, and H. Sakai, Neutrino-Less Double Beta Decay of 48Ca Studied by CaF2(Eu) Scintillators, Physical Review C, issue.5, p.78, 2008.

H. V. Klapdor-kleingrothaus, A. Dietz, L. Baudis, G. Heusser, I. V. Krivosheina et al., Latest Results from the Heidelberg- Moscow Double Beta Decay Experiment. The European Physical Journal A, pp.147-154, 2000.

J. Mott, F. A. Danevich, A. S. Georgadze, V. V. Kobychev, B. N. Kropivyansky et al., Search for $2\ensuremath{\beta}$ Decay of Cadmium and Tungsten Isotopes: Final Results of the Solotvina Experiment.; et al. 130Te Neutrinoless Double-Beta Decay with CUORICINO. Astroparticle Physics, Search for Double Beta Decay of 82Se with the NEMO-3 Detector and Development of Apparatus, pp.35501-822, 2003.

V. I. Tretyak, J. Argyriades, R. Arnold, C. Augier, J. Baker et al., NEMO-3 Collaboration. Results of the Double Beta Decay Experiment NEMO-3 (27) NEMO Collaboration, Measurement of the Background in the NEMO 3 Double Beta Decay Experiment. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, pp.110-113, 2009.

H. Gómez, S. Collaboration, B. Bipo-soulé, S. Collaboration, J. Partington et al., Radon Emanation Chamber: High Sensitivity Measurements for the SuperNEMO Experiment (30) Note de P Discovery of Radon (32) Romer, A. Radiochemistry and the Discovery of Isotopes The Spectrum of the Radium Emanation Radon in the Environment and the Dwellings -A Review of Measerements Carried out in France by Évaluation de L'exposition de La Population Française À La Radioactivité Naturelle Lung Cancer Attributable to Indoor Radon Exposure in France: Impact of the Risk Models and Uncertainty Analysis Attributable Mortality to Radon Exposure in Galicia, Spain. Is It Necessary to Act in the Face of This Health Problem?, Dedicated Radiopurity Detector for the SuperNEMO Experiment AIP Conference Proceedings AIP Conference Proceedings38) VI), C. on H. R. of E. to R. (BEIR; Sciences, C. on L.; Studies, D. on E. and L.; Council, N. R. Health Effects of Exposure to Radon39) Laszlo, P.; Schrobilgen, G. J. One or Several Pioneers? The Discovery of Noble-Gas Compounds, pp.94-97, 1904.

W. Howard, L. Andrews, J. J. Turner, G. C. Pimentel, W. Grochala et al., Krypton Fluoride: Preparation by the Matrix Isolation Technique Physics and Chemistry at Low Temperatures Chemical Methods for Removing Radon and Radon Daughters from Air (45) Stein, L. Removal of Xenon and Radon from Contaminated Atmospheres with Dioxygenyl Hexafluoroantimonate, O2SbF6 Removal of Radon from Air by Oxidation with Bromine Trifluoride Predicted Compounds of Radon with Acetylene and Water Noble-Gas Hydrides: New Chemistry at Low Temperatures (49) Fitzsimmons, A.; Klobukowski, M. Structure and Stability of Organic Molecules Containing Heavy Rare Gas Atoms The Adsorption of Nitrogen by Iron Synthetic Ammonia Catalysts, 52) Brunauer, S.; Deming, L. S.; Deming, W. E.; Teller, E. On a Theory of the van Der Waals Adsorption of Gases, pp.96-7864, 1940.

E. O. Kraemer, H. F. Mark, J. W. Mcbain, A. M. Bakr, . New et al., Advances in Colloid Science (56) Eyraud, C. Forty Years in Instrumental Thermogravimetry and Microcalorimetry. Consequences in the Study of Solid Transformations and for Characterization of the Texture of Porous Materials Adsorption in Slit-like and Cylindrical Micropores in the Henry's Law Region. A Model for the Microporosity of Carbons, 60) Rutherford, E. Absorption of the Radio-Active Emanations by Charcoal61) Rutherford, E. Some Properties of the Radium Emanation. Memoirs of the Manchester Literary and, pp.35-41, 1906.

W. Mohr, A. Becker, K. H. Stehberger, and Y. Kapitanov, Über Die Adsorption Der Radiumemanation, Die Absorption von Radiumemanation Durch Kokosnußkohle, pp.549-576, 1916.

S. C. Scarpitta, Optimum 222Rn-Adsorbing Activated Charcoals. Health physics, p.62, 1992.
DOI : 10.1097/00004032-199206000-00013

I. Bikit, D. Mrdja, K. Bikit, S. Grujic, D. Knezevic et al., Radon Adsorption by Zeolite Radiation Measurements Dynamic Adsorption of Radon by Activated Carbon The Application of Moment Analysis to the Dynamic Adsorption of Radon by Activated Carbon Active Measurements of Indoor Concentrations of Radon and Thoron Gas Using Charcoal Canisters Quantification of the Dependency of Radon Emanation Power on Soil Temperature, Etude Du Radon et Du Thoron Par Collection Électrostatique et Par Spectrométrie Gamma Dans Le Cadre de L'expérience NEMO de Décroissance Double Bêta73) López, F. O.; Canoba, A. C. 222Rn Gas Diffusion and Determination of Its Adsorption Coefficient on Activated Charcoal, pp.70-74, 1998.

Y. S. Mayya, R. T. Yang, N. J. Adsorbents-hoboken, C. D. Addison, H. Ramebäck et al., Method for Collecting Radon and Testing Therefor. 5106759 Radon Capture with Silver Exchanged Zeolites Integrated Measurement of Radon Using 5A Synthetic Zeolite and Blue Silica Gel Applied Radiation and Isotopes Coordination Polymers All Rights Reserved Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels (81) Férey, G. Hybrid Porous Solids: Past, Present, Future Functional Micropore Chemistry of Crystalline Metal Complex- Assembled Compounds Facile Xenon Capture and Release at Room Temperature Using a Metal-Organic Framework: A Comparison with Activated Charcoal Identification of Metal-Organic Framework Materials for Adsorption Separation of Rare Gases: Applicability of Ideal Adsorbed Solution Theory (IAST) and Effects of Inaccessible Framework Regions, Evaluation of Radon Adsorption Characteristics of a Coconut Shell-Based Activated Charcoal System for Radon and Thoron Removal Applications Preparative Inorg. Reactions 1964, 1 (Copyright (C) 2015 Dubbeldam, D.; Frost, H.; Snurr, R. Q. Heats of Adsorption for Seven Gases in Three Metal?Organic Frameworks: Systematic Comparison of Experiment and Simulation, pp.87-95, 1992.

J. Liu, P. K. Thallapally, D. Strachan, R. C. Goyal, . Meenakshi et al., Activated Carbon Activated Carbon Adsorption Adsorption of Radon and Water Vapor on Commercial Activated Carbons. Separation Science and Technology An Experimental Study on Radon Adsorption Ability and Microstructure of Activated Carbon Radon adsorption on present activated charcoals. Sov. Radiochem. 1978. (96) Cosma, C.; Van Deynse, A.; Poffijn, A. Studies on Radon Adsorption Characteristics of Different Charcoals Used as Amplifiers for the Track Detectors, Metal?Organic Frameworks for Removal of Xe and Kr from Nuclear Fuel Reprocessing Plants Systematic Study of Trace Radioactive Impurities in Candidate Construction Materials for EXO-200. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment99) Wahby, A.; Silvestre-Albero, J.; Sepúlveda-Escribano, A.; Rodríguez-Reinoso, F. CO2 Adsorption on Carbon Molecular Sieves. Microporous and Mesoporous Materials 2012, pp.11584-11589, 1988.

C. Cosma, A. Timar, and V. Benea, Pop, I.; Moldovan, M. Carbon Molecular Sieve for Radon and Thoron Monitoring, Rom. J. Phys, vol.54, pp.3-4, 2009.

S. S. Kistler, Coherent Expanded Aerogels and Jellies., Nature, vol.127, issue.3211, pp.741-741, 1931.
DOI : 10.1038/127741a0

S. S. Kistler, J. T. Method-of-producing-aerogels-stanislas, A. N. Gilbert, L. Koch, R. Jouan et al., Method of Preparing Inorganic Aerogels. US3672833 (A), Silica Aerogels Used as Cherenkov Radiators. Nuclear Instruments and Methods, pp.177-182, 1937.

G. W. Scherer, Structure and Properties of Gels. Cement and Concrete Research, pp.1149-1157, 1999.

J. L. Gurav, I. Jung, H. Park, E. S. Kang, and D. Nadargi, Silica Aerogel: Synthesis and Applications, Journal of Nanomaterials, vol.89, issue.4, p.409310, 2010.
DOI : 10.1021/jp802216p
URL : http://doi.org/10.1155/2010/409310

S. Dorcheh, A. Abbasi, and M. H. , Silica Aerogel; Synthesis, Properties and Characterization, Journal of Materials Processing Technology, vol.199, pp.1-3, 2008.

C. J. Schopfer, R. W. Pekala, C. T. Alviso, X. Lu, J. Gross et al., Radon Adsorption on an Aerogel; ProQuest New Organic Aerogels Based upon a Phenolic-Furfural Reaction, Journal of Non-Crystalline Solids, vol.188, issue.10810912, pp.34-40, 1995.

R. W. Pekala, Organic aerogels from the polycondensation of resorcinol with formaldehyde, Journal of Materials Science, vol.11, issue.11, pp.3221-3227, 1989.
DOI : 10.1007/BF01139044

C. Moreno-castilla and F. J. Maldonado-hódar, Carbon aerogels for catalysis applications: An overview, Carbon, vol.43, issue.3, pp.455-465, 2005.
DOI : 10.1016/j.carbon.2004.10.022

D. Fairen-jimenez, F. Carrasco-marín, D. Djurado, F. Bley, F. Ehrburger-dolle et al., Surface Area and Microporosity of Carbon Aerogels from Gas Adsorption and Smalland Wide-Angle X-Ray Scattering Measurements, The Journal of Physical Chemistry B, issue.17, pp.110-8681, 2006.

D. Fairén-jiménez and F. Carrasco-marín, Inter- and Intra-Primary-Particle Structure of Monolithic Carbon Aerogels Obtained with Varying Solvents, Langmuir, vol.24, issue.6, pp.2820-2825, 2008.
DOI : 10.1021/la703386q

D. Bardelang, K. A. Udachin, D. M. Leek, J. C. Margeson, G. Chan et al., = 5???8): A Comprehensive Solid State Study, Crystal Growth & Design, vol.11, issue.12, pp.11-5598, 2011.
DOI : 10.1021/cg201173j

J. W. Lee, S. Samal, N. Selvapalam, H. Kim, and K. Kim, Cucurbituril Homologues and Derivatives: New Opportunities in Supramolecular Chemistry, Accounts of Chemical Research, issue.8, pp.36-621, 2003.
DOI : 10.1002/chin.200346280

S. Lim, H. Kim, N. Selvapalam, K. Kim, S. J. Cho et al., Cucurbit[6]uril: Organic Molecular Porous Material with Permanent Porosity, Exceptional Stability, and Acetylene Sorption Properties, Angewandte Chemie International Edition, issue.18, pp.47-3352, 2008.
DOI : 10.1002/anie.200800772

G. W. Cave, J. Antesberger, L. J. Barbour, R. M. Mckinlay, and J. L. Atwood, Inner Core Structure Responds to Communication between Nanocapsule Walls, Angewandte Chemie International Edition, vol.43, issue.39, pp.43-5263, 2004.
DOI : 10.1002/anie.200460711

J. Tian, P. K. Thallapally, S. J. Dalgarno, P. B. Mcgrail, and J. L. Atwood, Amorphous Molecular Organic Solids for Gas Adsorption, Angewandte Chemie International Edition, issue.30, pp.48-5492, 2009.
DOI : 10.1002/ange.200900479

J. D. Evans, C. J. Sumby, and C. J. Doonan, Synthesis and Applications of Porous Organic Cages, Chemistry Letters, vol.44, issue.5, pp.582-588
DOI : 10.1246/cl.150021

M. Xiong, H. Ding, B. Li, T. Zhou, and C. Wang, Porous Organic Molecular Cages: from Preparation to Applications, Current Organic Chemistry, vol.18, issue.15, pp.18-1965
DOI : 10.2174/1385272819666140514004934

M. Mastalerz, M. W. Schneider, I. M. Oppel, and O. Presly, A Salicylbisimine Cage Compound with High Surface Area and Selective CO2/CH4 Adsorption, Angewandte Chemie International Edition, vol.127, issue.5, pp.1046-1051, 2011.
DOI : 10.1002/anie.201005301

T. Tozawa, J. T. Jones, S. I. Swamy, S. Jiang, D. J. Adams et al., Porous organic cages, Nature Materials, vol.47, issue.12, pp.973-978, 2009.
DOI : 10.1038/nmat2545

L. Chen, P. S. Reiss, S. Y. Chong, D. Holden, K. E. Jelfs et al., Separation of rare gases and chiral molecules by selective binding in porous organic cages, Cooper, A. I. Porous Organic Cages for Gas Chromatography Separations, pp.27-3207, 2014.
DOI : 10.1038/nmat4035
URL : https://hal.archives-ouvertes.fr/in2p3-01071052

I. M. Campbell, Introduction to Synthetic Polymers (126) Modern Size-Exclusion Liquid Chromatography: Practice of Gel Permeation and Gel Filtration Chromatography, 1994.

J. Jiang and A. Cooper, Microporous Organic Polymers: Design, Synthesis, and Function. In Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis, pp.1-33, 2009.
DOI : 10.1007/128_2009_5

C. D. Wood, B. Tan, A. Trewin, H. Niu, D. Bradshaw et al., Hydrogen Storage in Microporous Hypercrosslinked Organic Polymer Networks, Chemistry of Materials, vol.19, issue.8, pp.19-2034, 2007.
DOI : 10.1021/cm070356a

M. P. Tsyurupa and V. A. Davankov, Porous Structure of Hypercrosslinked Polystyrene: State-ofthe-Art Mini-Review. Reactive and Functional Polymers, pp.768-779, 2006.

M. P. Tsyurupa and V. A. Davankov, Hypercrosslinked Polymers: Basic Principle of Preparing the New Class of Polymeric Materials. Reactive and Functional Polymers, pp.2-3, 2002.

N. B. Mckeown and P. M. Budd, Polymers of Intrinsic Microporosity (PIMs): Organic Materials for Membrane Separations, Heterogeneous Catalysis and Hydrogen Storage, Chem. Soc. Rev, issue.8, pp.35-675, 2006.

P. M. Budd, A. Butler, J. Selbie, K. Mahmood, N. B. Mckeown et al., The potential of organic polymer-based hydrogen storage materials, Physical Chemistry Chemical Physics, vol.62, issue.15, pp.9-1802, 2007.
DOI : 10.1039/b618053a

T. Ben and S. Qiu, Porous aromatic frameworks: Synthesis, structure and functions, CrystEngComm, vol.27, issue.1, pp.17-26
DOI : 10.1039/C2CE25409C

T. Ben, H. Ren, S. Ma, D. Cao, J. Lan et al., Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area, Angewandte Chemie International Edition, issue.50, pp.48-9457, 2009.

M. Mastalerz, The Next Generation of Shape-Persistant Zeolite Analogues: Covalent Organic Frameworks, Angewandte Chemie International Edition, vol.129, issue.3, pp.445-447, 2008.
DOI : 10.1002/anie.200703871

A. P. Cote, Porous, Crystalline, Covalent Organic Frameworks, Science, vol.310, issue.5751, pp.310-1166, 2005.
DOI : 10.1126/science.1120411

P. Kuhn, M. Antonietti, and A. Thomas, Porous, Covalent Triazine-Based Frameworks Prepared by Ionothermal Synthesis, Angewandte Chemie International Edition, vol.9, issue.18, pp.47-3450, 2008.
DOI : 10.1002/anie.200705710

J. S. Moore, . R. Byg, C. N. Newkome, F. Moorefield, . Vögtle et al., Dendritic molecules: Concepts, syntheses, perspectives. ByG. R. Newkome, C. N. Moorefield, F. V??gtle, VCH, Weinheim 1996, xi, 261 pp., hardcover, DM 198.00 ISBN 3-527-29325-6, Advanced Materials, vol.9, issue.9, pp.761-761, 1996.
DOI : 10.1002/adma.19970090921

D. A. Tomalia, A. M. Naylor, and W. A. Goddard, Starburst Dendrimers: Molecular-Level Control of Size, Shape, Surface Chemistry, Topology, and Flexibility from Atoms to Macroscopic Matter, Angewandte Chemie International Edition in English, vol.29, issue.2, pp.29-138, 1990.
DOI : 10.1002/anie.199001381

P. G. Gennes-;-gennes, H. Hervet, E. Buhleier, W. Wehner, and F. Vögtle, Statistics of « Starburst » Polymers Journal de Physique Lettres Cascade " -and " Nonskid-Chain-like " Syntheses of Molecular Cavity Topologies, Synthesis, vol.44, issue.902, pp.10-146, 1978.

R. G. Denkewalter, J. Kolc, W. J. Lukasavage, R. G. Denkewalter, J. Kolc et al., Macromolecular Highly Branched Homogeneous Compound Based on Lysine Units Preparation of Lysine Based Macromolecular Highly Branched Homogeneous Compound US4360646 (A), Macromolecular Highly Branched Homogeneous Compound. US4410688 (A), pp.2466-2468, 1981.

G. R. Newkome, Z. Yao, G. R. Baker, V. K. Gupta, and . Micelles, Micelles. Part 1. Cascade molecules: a new approach to micelles. A [27]-arborol, The Journal of Organic Chemistry, vol.50, issue.11, pp.50-2003, 1985.
DOI : 10.1021/jo00211a052

C. J. Hawker and J. M. Frechet, Preparation of polymers with controlled molecular architecture. A new convergent approach to dendritic macromolecules, Journal of the American Chemical Society, vol.112, issue.21, pp.112-7638, 1990.
DOI : 10.1021/ja00177a027

D. Brabander-van-den-berg, E. M. Meijer, and E. W. , Poly(propylene imine) Dendrimers: Large-Scale Synthesis by Hetereogeneously Catalyzed Hydrogenations, Angewandte Chemie International Edition in English, vol.26, issue.9, pp.32-1308, 1993.
DOI : 10.1002/anie.199313081

C. Wörner and R. Mülhaupt, Polynitrile- and Polyamine-Functional Poly(trimethylene imine) Dendrimers, Angewandte Chemie International Edition in English, vol.15, issue.9, pp.1306-1308, 1993.
DOI : 10.1002/anie.199313061

K. Rengan and R. Engel, The synthesis of phosphonium cascade molecules, Journal of the Chemical Society, Perkin Transactions 1, vol.1, issue.5, pp.987-990, 1991.
DOI : 10.1039/p19910000987

S. Yokoyama, A. Otomo, T. Nakahama, Y. Okuno, and S. Mashiko, Dendrimers for Optoelectronic Applications, pp.205-226, 2003.
DOI : 10.1007/b11012

R. Kreiter, A. W. Kleij, R. J. Gebbink, G. Koten, and . Van, Dendritic Catalysts, pp.163-199, 2001.
DOI : 10.1007/3-540-45003-3_5

R. Esfand and D. A. Tomalia, Poly(amidoamine) (PAMAM) dendrimers: from biomimicry to drug delivery and biomedical applications, Drug Discovery Today, vol.6, issue.8, pp.427-436, 2001.
DOI : 10.1016/S1359-6446(01)01757-3

C. J. Hawker and J. M. Frechet, Preparation of polymers with controlled molecular architecture. A new convergent approach to dendritic macromolecules, Journal of the American Chemical Society, vol.112, issue.21, pp.112-7638, 1990.
DOI : 10.1021/ja00177a027

C. J. Hawker and J. M. Frechet, Unusual macromolecular architectures: the convergent growth approach to dendritic polyesters and novel block copolymers, Journal of the American Chemical Society, vol.114, issue.22, pp.114-8405, 1992.
DOI : 10.1021/ja00048a009

J. M. Fréchet, H. Ihre, and M. Davey, Preparation of ???Fr??chet-type??? Polyether Dendrons and Aliphatic Polyester Dendrimers by Convergent Growth: An Experimental Primer, Dendrimers and Other Dendritic Polymers, pp.567-586, 2001.
DOI : 10.1002/0470845821.ch24

G. R. Newkome, E. He, and C. N. Moorefield, Suprasupermolecules with Novel Properties:?? Metallodendrimers, Chemical Reviews, vol.99, issue.7, pp.1689-1746, 1999.
DOI : 10.1021/cr9800659

K. Inoue, Functional dendrimers, hyperbranched and star polymers, Progress in Polymer Science, vol.25, issue.4, pp.453-571, 2000.
DOI : 10.1016/S0079-6700(00)00011-3

A. W. Bosman, H. M. Janssen, and E. W. Meijer, About Dendrimers:?? Structure, Physical Properties, and Applications, Chemical Reviews, vol.99, issue.7, pp.1665-1688, 1999.
DOI : 10.1021/cr970069y
URL : http://repository.tue.nl/587824

J. F. Jansen, E. M. Berg, B. De, and E. W. Meijer, Encapsulation of Guest Molecules into a Dendritic Box, Science, vol.266, issue.5188, pp.266-1226, 1994.
DOI : 10.1126/science.266.5188.1226

J. F. Jansen, E. W. Meijer, and E. M. De-brabander-van-den-berg, The Dendritic Box: Shape-Selective Liberation of Encapsulated Guests, Journal of the American Chemical Society, vol.117, issue.15, pp.117-4417, 1995.
DOI : 10.1021/ja00120a032

G. R. Newkome, C. N. Moorefield, and F. Vögtle, Dendritic Molecules: Concepts, Synthesis, Perspectives; VCH: Weinheim (169) Tomalia, D. a; Kirchhoff, P. M. Rod-Shaped Dendrimers Architectural Copolymers: Rod-Shaped, Cylindrical Dendrimers, US4694064 (A) Abstract of corresponding document: EP0556871 (A2), pp.120-2678, 1987.
DOI : 10.1002/9783527614875

A. Schlüter, Dendrimers with Polymeric Core: Towards Nanocylinders, pp.165-191, 1998.
DOI : 10.1007/3-540-69779-9_5

A. D. Schluter and J. P. Rabe, Dendronized Polymers: Synthesis, Characterization, Assembly at Interfaces, and Manipulation, Angewandte Chemie International Edition, vol.39, issue.5, pp.864-883, 2000.
DOI : 10.1002/(SICI)1521-3773(20000303)39:5<864::AID-ANIE864>3.0.CO;2-E

V. Percec, J. Heck, D. Tomazos, F. Falkenberg, H. Blackwell et al., Self-assembly of taper-shaped monoesters of oligo(ethylene oxide) with 3,4,5-tris(p-dodecyloxybenzyloxy)benzoic acid and of their polymethacrylates into tubular supramolecular architectures displaying a columnar mesophase, Journal of the Chemical Society, Perkin Transactions 1, issue.22, pp.2799-2811, 1993.
DOI : 10.1039/p19930002799

G. Draheim, H. P. Ritter, and . Dendrimers, Polymerizable dendrimers. Synthesis of a symmetrically branched methacryl derivative bearing eight ester groups, Macromolecular Chemistry and Physics, vol.196, issue.7, pp.2211-2222, 1995.
DOI : 10.1002/macp.1995.021960711

V. Percec, D. Schlueter, J. C. Ronda, G. Johansson, G. Ungar et al., Tubular Architectures from Polymers with Tapered Side Groups. Assembly of Side Groups via a Rigid Helical Chain Conformation and Flexible Helical Chain Conformation Induced via Assembly of Side Groups, Macromolecules, issue.5, pp.29-1464, 1996.

A. L. Rocklin, Substitution Reactions of Hexachlorobenzene, The Journal of Organic Chemistry, vol.21, issue.12, pp.1478-1480, 1956.
DOI : 10.1021/jo01118a040

M. Kulka, Reactions of Hexachlorobenzene with Mercaptides, The Journal of Organic Chemistry, vol.24, issue.2, pp.235-237, 1959.
DOI : 10.1021/jo01084a021

M. E. Peach and A. M. Smith, The thiolate anion as a nucleophile Part III. Reactions with various fluorobenzenes, Journal of Fluorine Chemistry, vol.4, issue.4, pp.399-408, 1974.
DOI : 10.1016/S0022-1139(00)85289-6

R. Adams and A. Ferretti, Thioethers from Halogen Compounds and Cuprous Mercaptides. II, Journal of the American Chemical Society, vol.81, issue.18, pp.81-4927, 1959.
DOI : 10.1021/ja01527a042

J. R. Beck and J. A. Yahner, Nitro Displacement by Methanethiol Anion. Synthesis of Bis-, Tris-, Pentakis-, and Hexakis(methylthio)benzenes, J. Org. Chem, issue.10, pp.43-2048, 1978.
DOI : 10.1021/jo00404a046

M. E. Peach and E. S. Rayner, The thiolate anion as a nucleophile Part IX. Reactions of some fluoroaromatics, Journal of Fluorine Chemistry, vol.13, issue.5, pp.447-454, 1979.
DOI : 10.1016/S0022-1139(00)81580-8

L. Testaferri, M. Tingoli, and M. Tiecco, Reactions of Polychlorobenzenes with Alkanethiol Anions in HMPA. A Simple, High-Yield Synthesis of Poly(alkylthio)benzenes, J. Org. Chem, issue.22, pp.45-4376, 1980.

F. Maiolo, L. Testaferri, M. Tiecco, and M. Tingoli, Fragmentation of Aryl Alkyl Sulfides. A Simple, One-Pot Synthesis of Polymercaptobenzenes from Polychlorobenzenes, J. Org. Chem, issue.15, pp.46-3070, 1981.

D. D. Macnicol, P. R. Mallison, A. Murphy, and G. J. Sym, An Efficient Synthesis of Hexa- Substituted Benzenes and the Discovery of a Novel Host Conformation for Hexakis (?- Naphthylthio) Benzene, Tetrahedron Letters, issue.40, pp.23-4131, 1982.

M. Gingras, J. M. Raimundo, and Y. M. Chabre, Persulfurated Aromatic Compounds, Angewandte Chemie-International Edition, issue.11, pp.45-1686, 2006.
DOI : 10.1002/chin.200623247

M. Gingras, A. Pinchart, and C. Dallaire, Synthesis ofp-Phenylene Sulfide Molecular Asterisks, Angewandte Chemie International Edition, vol.37, issue.22
DOI : 10.1002/(SICI)1521-3773(19981204)37:22<3149::AID-ANIE3149>3.0.CO;2-4

M. Gingras, A. Pinchart, C. Dallaire, T. Mallah, and E. Levillain, Star-Shaped Nanomolecules Based onp-Phenylene Sulfide Asterisks with a Persulfurated Coronene Core, Chemistry - A European Journal, vol.10, issue.12, pp.10-2895, 2004.
DOI : 10.1002/chem.200305605

F. M. Menger and V. A. Azov, Synthesis and Properties of Water-Soluble Asterisk Molecules, Journal of the American Chemical Society, vol.124, issue.37, pp.124-11159, 2002.
DOI : 10.1021/ja0206238

R. D. Johnson, A. Pinchart, I. H. Badr, M. Gingras, and L. G. Bachas, Polymeric Membrane Ion-Selective Electrodes Based on Molecular Asterisk Ionophores, Electroanalysis, vol.14, issue.19-20, pp.19-20, 2002.
DOI : 10.1002/1521-4109(200211)14:19/20<1419::AID-ELAN1419>3.0.CO;2-R

Y. Suenaga, T. Kuroda-sowa, M. Munakata, M. Maekawa, and H. Morimoto, Syntheses and structures of copper(I) and silver(I) coordination polymers with hexakis(methylthio)benzene, Polyhedron, vol.18, issue.3-4, pp.3-4, 1998.
DOI : 10.1016/S0277-5387(98)00314-3

Y. Suenaga, T. Kuroda-sowa, M. Munakata, M. Maekawa, and H. Morimoto, A Linear-Chain Copper(I) Coordination Polymer with Hexakis(methylthio)benzene, Acta Crystallographica Section C Crystal Structure Communications, vol.54, issue.11, pp.54-1566, 1998.
DOI : 10.1107/S010827019800643X/cf1226sup1.cif

D. P. Warren, T. Thioacrylate, V. I. Monomers-gostevskaya, G. M. Gavrilova, A. V. Afonin et al., Synthesis of Hexakis(vinylthio)benzene, Russian Journal of Organic Chemistry, vol.4606864, issue.373, pp.388-389, 1986.

T. M. Leslie and H. Samson, Low Loss High Refractive Index Vinyl Sulfide Compounds and Method of Making Same, US2004044251 (A1), 2004.

A. Fermi, G. Bergamini, R. Peresutti, E. Marchi, M. Roy et al., Molecular asterisks with a persulfurated benzene core are among the strongest organic phosphorescent emitters in the solid state, Dyes and Pigments, vol.110, pp.113-122, 2014.
DOI : 10.1016/j.dyepig.2014.04.036
URL : https://hal.archives-ouvertes.fr/hal-01067966

T. M. Miller and T. Neenan, Convergent synthesis of monodisperse dendrimers based upon 1,3,5-trisubstituted benzenes, Chemistry of Materials, vol.2, issue.4, pp.346-349, 1990.
DOI : 10.1021/cm00010a006

T. M. Miller, T. X. Neenan, R. Zayas, and H. Bair, Synthesis and characterization of a series of monodisperse, 1,3,5-phenylene-based hydrocarbon dendrimers including C276H186 and their fluorinated analogs, Journal of the American Chemical Society, vol.114, issue.3, pp.1018-1025, 1992.
DOI : 10.1021/ja00029a034

U. Wiesler and K. Müllen, Polyphenylene dendrimers via Diels???Alder reactions: the convergent approach, Chemical Communications, issue.22, pp.2293-2294, 1999.
DOI : 10.1039/a907339f
URL : http://hdl.handle.net/11858/00-001M-0000-000F-53C7-2

J. C. Bart, The crystal structure of a modification of hexaphenylbenzene, Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, vol.24, issue.10, pp.1277-1287, 1968.
DOI : 10.1107/S0567740868004176

M. Mayor, M. Buschel, K. M. Fromm, J. M. Lehn, and J. Daub, Electron Transfer Through Molecular Bridges Between Reducible Pentakis(thiophenyl)benzene Subunits, Chemistry, vol.28, issue.6, pp.1266-1272, 2001.
DOI : 10.1002/1521-3765(20010316)7:6<1266::AID-CHEM1266>3.0.CO;2-S

G. N. Vyas, N. M. Shah, . Quinacetophenone, and . Ether, Organic Syntheses Depsidone Synthesis. Part 14. The Total Synthesis of Psoromic Acid: Isopropyl Ethers as Useful Phenolic Protective Groups, J. Chem. Soc., Perkin Trans, vol.31, issue.1 0, pp.90-2593, 1951.

S. Chanthamath, S. Takaki, K. Shibatomi, and S. Iwasa, Highly Stereoselective Cyclopropanation of ?,?-Unsaturated Carbonyl Compounds with Methyl (Diazoacetoxy)acetate Catalyzed by a Chiral Ruthenium(II) Complex, Angew. Chem. Int. Ed, vol.2013, issue.22, pp.52-5818

M. Ingratta and J. Duhamel, Correlating Pyrene Excimer Formation with Polymer Chain Dynamics in Solution. Possibilities and Limitations, Macromolecules, vol.40, issue.18, pp.40-6647, 2007.
DOI : 10.1021/ma070368h

K. F. Bernady, M. B. Floyd, J. F. Poletto, and M. J. Weiss, Prostaglandins and Congeners. 20. Synthesis of Prostaglandins via Conjugate Addition of Lithium Trans-1-Alkenyltrialkylalanate Reagents. A Novel Reagent for Conjugate 1,4-Additions, J. Org. Chem, issue.9, pp.44-1438, 1979.

F. Beuerle, N. Chronakis, and A. Hirsch, Regioselective synthesis and zone selective deprotection of [60]fullerene tris-adducts with an e,e,e addition pattern, Chemical Communications, vol.43, issue.29, pp.3676-3678, 2005.
DOI : 10.1039/b504748j

M. Miyashita, A. Yoshikoshi, P. A. Grieco, and P. Pyridinium, A Mild and Efficient Catalyst for the Tetrahydropyranylation of Alcohols, J. Org. Chem, issue.23, pp.42-3772, 1977.

C. Kubel, S. L. Chen, and K. Mullen, Poly(4???-vinylhexaphenylbenzene)s:?? New Carbon-Rich Polymers, Macromolecules, vol.31, issue.18, pp.31-6014, 1998.
DOI : 10.1021/ma971707h

K. Matyjaszewski, T. P. Davis, A. L. Duréault, and U. Bordeaux, Handbook of Radical Polymerization A Model for Living Radical Polymerization, Makromol. Chem., Rapid Commun, vol.3, issue.2102112, pp.133-140, 1982.

T. Otsu and M. Yoshida, Role of Initiator-Transfer Agent-Terminator (iniferter) in Radical Polymerizations: Polymer Design by Organic Disulfides as Iniferters, Die Makromolekulare Chemie, Rapid Communications, vol.3, issue.2, pp.127-132, 1982.
DOI : 10.1002/marc.1982.030030208

A. B?edzki and D. Braun, Polymerisationsausl??sung mit substituierten Ethanen, 1. Polymerisation von Methylmethacrylat mit 1,1,2,2-Tetraphenyl-1,2-diphenoxyethan, Die Makromolekulare Chemie, vol.182, issue.4, pp.1047-1056, 1981.
DOI : 10.1002/macp.1981.021820405

A. B?edzki, D. Braun, and K. Titzschkau, Polymerisationsausl??sung mit substituierten ethanen, 6. Polymerisation von methylmethacrylat mit verschiedenen tetraphenylethanen, Die Makromolekulare Chemie, vol.184, issue.4, pp.745-754, 1983.
DOI : 10.1002/macp.1983.021840409

K. Matyjaszewski and J. Spanswick, ?Living? and controlled radical polymerization, Journal of Physical Organic Chemistry, vol.21, issue.4, pp.26-33, 2005.
DOI : 10.1002/poc.610080414
URL : http://doi.org/10.1016/s1369-7021(05)00745-5

M. K. Georges, R. P. Veregin, P. M. Kazmaier, and G. K. Hamer, Narrow molecular weight resins by a free-radical polymerization process, Macromolecules, vol.26, issue.11, pp.26-2987, 1993.
DOI : 10.1021/ma00063a054

C. J. Hawker, A. W. Bosman, and E. Harth, New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations, Chemical Reviews, vol.101, issue.12, pp.3661-3688, 2001.
DOI : 10.1021/cr990119u
URL : http://repository.tue.nl/689596

M. Kato, M. Kamigaito, M. Sawamoto, and T. Higashimura, Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris(triphenylphosphine )ruthenium(II)

J. Wang, K. Matyjaszewski, and . Controlled, Controlled/"living" radical polymerization. atom transfer radical polymerization in the presence of transition-metal complexes, Journal of the American Chemical Society, vol.117, issue.20, pp.117-5614, 1995.
DOI : 10.1021/ja00125a035

F. Ercole, J. Krstina, J. Jeffery, T. P. Le, R. T. Mayadunne et al., Living Free-Radical Polymerization by Reversible Addition?Fragmentation Chain Transfer: The RAFT Process, Macromolecules, issue.16, pp.31-5559, 1998.

M. Destarac, D. Charmot, X. Franck, and S. Zard, Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents, Macromolecular Rapid Communications, vol.21, issue.15, pp.1035-1039, 2000.
DOI : 10.1002/1521-3927(20001001)21:15<1035::AID-MARC1035>3.0.CO;2-5
URL : https://hal.archives-ouvertes.fr/hal-00954901

G. Moad, E. Rizzardo, and D. H. Solomon, Selectivity of the reaction of free radicals with styrene, Macromolecules, vol.15, issue.3, pp.909-914, 1982.
DOI : 10.1021/ma00231a042

A. A. Gridnev and S. D. Ittel, Catalytic Chain Transfer in Free-Radical Polymerizations, Chemical Reviews, vol.101, issue.12, pp.3611-3660, 2001.
DOI : 10.1021/cr9901236

J. Hérisson, P. Chauvin, and Y. , Catalyse de Transformation Des Oléfines Par Les Complexes Du Tungstène. II. Télomérisation Des Oléfines Cycliques En Présence D'oléfines Acycliques, Die Makromolekulare Chemie, vol.141, issue.1, pp.161-176, 1971.
DOI : 10.1002/macp.1971.021410112

S. W. Benson, F. R. Cruickshank, D. M. Golden, G. R. Haugen, H. E. Neal et al., Additivity rules for the estimation of thermochemical properties, Chemical Reviews, vol.69, issue.3, pp.69-279, 1969.
DOI : 10.1021/cr60259a002

T. J. Katz, S. J. Lee, and N. Acton, Stereospecific polymerizations of cycloalkenes induced by a metal-carbene, Tetrahedron Letters, vol.17, issue.47, pp.4247-4250, 1976.
DOI : 10.1016/0040-4039(76)80086-X

C. W. Bielawski and R. H. Grubbs, Living Ring-Opening Metathesis Polymerization. Progress in Polymer Science, pp.1-29, 2007.
DOI : 10.1002/9783527629091.ch6

S. Danishefsky, M. Hirama, K. Gombatz, T. Harayama, E. Berman et al., Stereospecific total synthesis of dl-pentalenolactone, Journal of the American Chemical Society, vol.100, issue.20, pp.100-6536, 1978.
DOI : 10.1021/ja00488a063

E. J. Corey, I. Székely, and C. S. Shiner, Synthesis of 6,9??-oxido-11??, 15??-dihydroxyprosta-()5, ()13-dienoic acid, an isomer of PGI2 (vane's PGX), C42H36OS5): 2,3, pp.3529-35326, 1977.
DOI : 10.1016/S0040-4039(01)83284-6

H. Nmrs, 1. , and C. , 250 MHz, CDCl3) ?= 9, pp.5-6

H. Nmr, CDCl3) ? 7, 20H, CHarom), 4.80 (h, J = 6.1 Hz, 1H, CH-(CH3)2), pp.3-6

C. Nmr, HRMS (ESI-MS): 746.1839 Da +/-1ppm IR (?, cm -1 , neat), 1887 (w) 1596 (w) (m) H NMR (250 MHz, CDCl3) ?= 7.58 (s, 1H, OH), pp.3018-2974

H. Nmr, CDCl3) ? 7, MHz, vol.664, issue.58, pp.37-44

H. Nmr, CDCl3) ? = 706 (s, 2H), 3, MHz, vol.5, issue.2, pp.6-6

R. Mhz, HRMS (ESI-MS): 762.1788 Da +-1 ppm IR (?, cm -1 , neat ) : 3317 (w,br), (m) H NMR (400 MHz, pp.2918-2862

R. Mhz, HRMS (ESI-MS): 762.1788 Da +/-1 ppm IR (?, cm -1 , neat ) : 3317 (w,br)(m), 701 cm -1 (m) Synthesispentakis(p-tolylthio)phenoxy)ethyl acrylate Alcohol 33 (1500 mg, 1.96 mmol), was dissolved in dry DCM (10 mL), Et3N (400 µL, 3.93 mmol) was added. The mixture was cooled to 0°C and acryloyl chloride (214 µL, 2.36 mmol) was added. The solution was warmed to room temperature and, The organic layer was dried over MgSO4 and filtered. After removal the solvent, the crude was purified by column chromatography over silica gel using cyclohexane/dichloromethane as eluent. Acrylate 31 was obtained as a yellow solid, pp.2918-2862

C. Nmr, HRMS (ESI-MS): 802.1737 Da +/-1 ppm IR (?, cm -1 , neat ) (m) cm -1 Synthesis of 38 (C35H32OS4): (2,3,5,6-tetrakis(p-tolylthio)phenyl)methanol Tetrafluorobenzyl alcohol (200 mg, 1.10 mmol), was dissolved in dry DMF (5 mL), K2CO3 (976 mg, 5.90 mmol) was added. The mixture was purged with Argon. The 4-methylbenzenethiol (823 mg, 5.60 mmol) was added. The reaction mixture was heated to 80 °C and stirred overnight, After reaction, the mixture was treated with NaOH 2M (50 mL) and extracted with CH2Cl2, pp.3018-2918

H. Nmr, CDCl3) ? 7, 1H), 5.08 (d, J = 7.2 Hz, 2H), 2.33 (s, 12H), pp.12-18

C. Nmr, HRMS (ESI-MS): 596.1336 Da+/-1ppm IR (?, cm -1 , neat ) : 3447 (w,br) (s) cm -1 Synthesis of 29 (C38H34O2S4): 2,3,5,6-tetrakis(p-tolylthio)benzyl acrylate Tetrasulfurated phenol (500 mg, 0.84 mmol), was dissolved in dry DCM (2 mL), Et3N (234 µL, 1.68 mmol) was added. The mixture was cooled to 0 °C and acryloyl chloride (81 µL, 1.01 mmol) was added. The solution was warmed to room temperature and stirred under Argon overnight. The organic phase was washed with H2O, MHz, vol.3020, issue.845, pp.2918-2855, 1920.

H. Nmr, 25 (s, 1H), 6.05 (dd, J = 17.2, 1.6 Hz, 1H) (s, 1H), MHz, vol.657, issue.2, pp.3-7

H. Nmr, CDCl3) ? 7, 12H), 6.75 (s, 2H), 4.98 (d, J = 6.6 Hz, 2H), 2.35 (s, 9H), 2.02 (t, J = 6.8 Hz, 1H), pp.23-29

H. Nmr, 72 (s, 2H), 6.35 (dd, J = 17.3, 1.5 Hz, 1H), 6.03 (dd, J = 17.3, 10.4 Hz, 1H), 5.77 (dd, J = 10.4, 1.5 Hz, 1H), 5.55 (s, 2H), pp.3-7

. Bromoiodobenzene, and phenylacetylene (450 mg, 4.40 mmol) were stirred for 6 h with CuI (76.0 mg, 0.40 mmol) of and Pd(PPh3)4 as catalysts (231 mg, 0.40 mmol) in 5 mL of piperidine at 0 °C. The reaction mixture was acidified with HCl 2M, and 30 mL of CH2Cl2 was added. The organic phase was washed twice with HCl 2 M and H2O. After removal the solvent, the crude was purified by column chromatography over silica gel using cyclohexane/dichloromethane as eluent

H. Nmr, CDCl3) ? 7, MHz, vol.7, pp.72-79

C. Kubel, S. L. Chen, and K. Mullen, Poly(4 '-Vinylhexaphenylbenzene)s: New Carbon-Rich Polymers Synthesis of 46 (C42H29Br): (4-Bromophenyl)pentaphenylbenzene Compound 44 (700 mg, 2.74 mmol) of and tetracyclone 45 (1.20 g, 3.15 mmol) were heated to 250 °C in 3 mL of diphenyl ether during 94 h. The raw product was washed with 20 mL of cold n-hexane and recrystallized from toluene, Macromolecules, issue.18, pp.31-6014, 1998.

H. Nmr, CDCl3) ? 7.20 (d, J = 8.5 Hz, MHz, vol.7, issue.6, pp.15-21

C. Kubel, S. L. Chen, K. Mullen, and . Poly, Vinylhexaphenylbenzene)s: New Carbon-Rich Polymers Synthesis of 47 (C44H32): 4-Vinylhexaphenylbenzene Compound 46 (1410 mg, 2.00 mmol) and tributylvinylstannane (698 mg, 2.20 mmol) were reacted in dry toluene 40 mL with Pd(PPh3)4 (46 mg, 0.04 mmol) and 2,6-di-tert-butyl-4-methylphenol 5 mg to prevent polymerization. The solution was heated to reflux for 6 h. After reaction, Macromolecules, issue.18, pp.31-6014, 1998.

C. Kubel, S. L. Chen, K. Mullen, and . Poly, -Vinylhexaphenylbenzene)s: New Carbon-Rich Polymers Synthesis of 51 (C16H14O4S2): 4,4'-Dithiobisbenzoic acid dimethyl ester 4, Dithiobisbenzoic acid was heated at reflux in MeOH (100 mL) with H2SO4 conc, pp.31-6014, 1998.
URL : https://hal.archives-ouvertes.fr/hal-01058624

C. Nmr, 101 MHz, CDCl3) ? 167

H. Nmr, DMSO-d6) ? 7, MHz, vol.74, issue.709