. Initialement, Si est implantée pour former un plan de NPs d'argent proche de la surface, recuit est effectué post-implantation pour cicatriser la matrice et stabiliser les NPs

. Adichtchev, High-order vibration modes of bimetallic Ag-Au nanoparticles embedded in glass Raman Scattering by Bulk Phonons in Microcrystalline Silver and Copper via Electronic Surface Excitations, Phys. Rev. B Phys. Rev. Lett, vol.79, issue.20251, pp.795050-5053, 1997.

A. , C. Albrecht, M. G. Et-creighton, and J. A. , Anomalously intense Raman spectra of pyridine at a silver electrode Size effects in the elastic deformation behavior of metallic nanoparticles, J. Am. Chem. Soc. J. Nanoparticle Res. IV.D, vol.994, issue.1512, pp.5215-5217, 1977.

. Ashworth, Representation of ion implantation profiles by Pearson frequency distribution curves, II.A.4, II.A.4, pp.870-876, 1990.
DOI : 10.1088/0022-3727/23/7/018

. Babonneau, Telecom Glossaryatis.org/glossary/. I.A.3.a Spontaneous organization of columnar nanoparticles in Fe-BN nanocomposite films, Phys. Rev. B, issue.33, p.71035430, 2005.

M. Bachelier, G. Bachelier, A. 2. Et-mlayah, . Iv, and . Baraldi, Surface plasmon mediated Raman scattering in metal nanoparticles Preventing the Degradation of Ag Nanoparticles Using an Ultrathin a-Al 2 O 3 Layer as Protective Barrier, Phys. Rev. B J. Phys. Chem. C, vol.69, issue.2018, pp.1179431-9439, 2004.

G. T. Baret, Use of a nitride barrier for avoiding silver migration into glass, II.B, vol.3, 1997.

A. Stability and . Nanocrystalsbeversluis, 103524. (document) Continuum generation from single gold nanostructures through near-field mediated intraband transitions, SiO2 matrices, p.68115433, 2003.

. Bonafos, Manipulation of two-dimensional arrays of Si nanocrystals embedded in thin SiO2 layers by low energy ion implantation, Journal of Applied Physics, vol.95, issue.10, p.955696, 2004.
DOI : 10.1063/1.1695594

. Cai, Importance of lattice contraction in surface plasmon resonance shift for free and embedded silver particles, The European Physical Journal D, vol.13, issue.2, pp.245-253, 2001.
DOI : 10.1007/s100530170273

. Cai, Optical measurements of oxidation behavior of silver nanometer particle within pores of silica host Optimization of growth and ordering of Ag nanoparticle arrays on ripple patterned alumina surfaces for strong plasmonic coupling, J. Appl. Phys. Nanotechnology, vol.83, issue.33, p.25035706, 1998.

. Carini, Influence of Packing on Low Energy Vibrations of Densified Glasses, Physical Review Letters, vol.111, issue.24, p.111245502, 2013.
DOI : 10.1103/PhysRevLett.111.245502

. Carles, A new experimental method for the determination of the one phonon density of states in GaAs, Solid State Communications, vol.41, issue.7, pp.557-560, 1982.
DOI : 10.1016/0038-1098(82)90199-5

. Cho, Ultrahigh-density array of silver nanoclusters for SERS substrate with high sensitivity and excellent reproducibility Tight-binding potentials for transition metals and alloys, I.A.2.b [Cleri et Rosato, pp.249-5522, 1993.

C. Et-saviot-]-combe, N. Et-saviot, and L. , Acoustic modes in metallic nanoparticles : Atomistic versus elasticity modeling, Phys. Rev. B IV.D, vol.803, issue.3, p.35411, 2009.

E. A. Coronado, G. C. Et-schatz, A. Derooij, V. P. Drachev, U. K. Chettiar et al., Surface plasmon broadening for arbitrary shape nanoparticles : A geometrical probability approach The oxidation of silver by atomic oxygen The Ag dielectric function in plasmonic metamaterials, On the stress state of silver nanoparticles in ion-implanted silicate glasses. Nucl. Instruments Methods Phys. Res. Sect. B Beam Interact. with Mater. Atoms, pp.363-3821186, 1989.

E. Duval, T. W. Ebbesen, H. J. Lezec, H. F. Ghaemi, T. Thio et al., Far-infrared and Raman vibrational transitions of a solid sphere: Selection rules, I.B.2.e [Ebbesen et al, pp.5795-5797667, 1984.
DOI : 10.1103/PhysRevB.46.5795

. Elechiguerra, Corrosion at the Nanoscale : The Case of Silver Nanowires and Nanoparticles Evidence of a surface plasmon-mediated mechanism in the generation of the SERS background, Chem. Mater. Chem. Commun, vol.17, issue.24131, pp.6042-6052, 2005.

. Farcau, Monolayered Wires of Gold Colloidal Nanoparticles for High-Sensitivity Strain Sensing, IV.E.2, pp.14494-14499, 2011.
DOI : 10.1021/jp202166s

. Ferrari, Raman Spectrum of Graphene and Graphene Layers Design considerations for plasmonic photovoltaics Raman spectra of pyridine adsorbed at a silver electrode, Phys. Rev. Lett. Adv. Mater. Chem. Phys. Lett, vol.97, issue.262, pp.4794-808163, 1974.

. Franey, The corrosion of silver by atmospheric sulfurous gases, Corrosion Science, vol.25, issue.2, pp.133-143, 1985.
DOI : 10.1016/0010-938X(85)90104-0

J. C. Garnett, . Garrido, and . Fernandez, Colours in Metal Glasses and in Metallic Films Influence of average size and interface passivation on the spectral emission of Si nanocrystals embedded in SiO2, Philos. Trans. R. Soc. A Math. Phys. Eng. Sci. J. Appl. Phys, vol.203, issue.9123, pp.359-371385, 1904.

. Haik, Novel organic memory devices using Au?Pt?Ag nanoparticles as charge storage elements (document) Optical studies of dynamics in noble metal nanostructures Scattering of light by crystals Surface and interface effects in the optical properties of silver nanoparticles, édition. I.B.2.b, I.B.2.b [Hilger et al, pp.67-723858, 1978.

. Hugall, Disentangling the Peak and Background Signals in Surface-Enhanced Raman Scattering, The Journal of Physical Chemistry C, vol.116, issue.10, pp.6184-6190276, 2005.
DOI : 10.1021/jp3002977

. Hÿtch, Quantitative measurement of displacement and strain fields from HREM micrographs, Ultramicroscopy, vol.74, issue.3, pp.131-146, 1998.
DOI : 10.1016/S0304-3991(98)00035-7

. Johnson, Effects of elastic anisotropy on strain distributions in decahedral gold nanoparticles, Nature Materials, vol.54, issue.2, pp.120-124, 2008.
DOI : 10.1038/nmat2083

J. , C. Johnson, P. Christy, R. Juvé, V. Crut et al., Optical constants of the noble metals I.3, I.A.1.c [Juvé et al. Probing elasticity at the nanoscale : Terahertz acoustic vibration of small metal nanoparticles, Phys. Rev. B Nano Lett, vol.6, issue.105, pp.1853-1861, 1972.

K. Et-brockhouse-]-kamitakahara, W. Et-brockhouse, and B. , Crystal dynamics of silver, Physics Letters A, vol.29, issue.10, pp.639-640, 1969.
DOI : 10.1016/0375-9601(69)91142-6

K. Et-rahman, A. Kara, and T. Et-rahman, Vibrational Properties of Metallic Nanocrystals, Phys. Rev. Lett. IV.D, vol.813, issue.7 1, pp.1453-1456, 1998.

C. Kittel, G. V. Kumar, G. P. Larivière, J. M. Frigerio, J. Rivory et al., Introduction to Solid State Physics Plasmonic nano-architectures for surface enhanced Raman scattering : a review On the Vibrations of an Elastic Sphere):189?212. I.B.1.c [Larivière et al. Estimate of the degree of inhomogeneity of the refractive index of dielectric films from spectroscopic ellipsometry Gold and silver nanoparticles in sensing and imaging : sensitivity of plasmon response to size, shape, and metal composition On the properties of a gaz of charged particles, Proc. London Math. Soc. III.A.1.a [Lee et El-Sayed, pp.1-13, 1882.

. Lynn, Lattice Dynamics of Gold, Physical Review B, vol.8, issue.8, pp.3493-3499, 1973.
DOI : 10.1103/PhysRevB.8.3493

. Nakanishi, Photoconductance and inverse photoconductance in films of functionalized metal nanoparticles Effects of morphology on phonons in nanoscopic silver grains, Nature Phys. Rev. B IV.D, vol.4, issue.725315, pp.460371-460376, 2005.

W. Neugebauer, C. A. Neugebauer, M. B. Webb, Z. H. Ni, H. M. Wang et al., Electrical Conduction Mechanism in Ultrathin, Evaporated Metal Films Graphene thickness determination using reflection and contrast spectroscopy, 74. V.C.3.b [Ni et al.. V.B.2.b [Noda et al, pp.2758-63, 1962.

. Otto, Surface roughness induced electronic Raman scattering, Gold nanoparticle assemblies stabilized by bis(phthalocyaninato)lanthanide(III) complexes through van der Waals interactions . Sci. Rep., 4:3758. V.C.3.b, pp.55-57, 1980.

E. D. Palik, B. Palpant, L. Saviot, J. Lermé, B. Prével et al., Handbook of Optical Constants of Solids Academic Press. I.A.1.c [Palpant et al. Plasmon-phonon coupling and resonant raman scattering of silver clusters, Eur. Phys. J. D, vol.9, issue.1, pp.585-589, 1985.

. Pizani, High strain effects evidenced by Raman scattering in arsenic clusters in As???implanted GaAs, Applied Physics Letters, vol.66, issue.15, p.661927, 1995.
DOI : 10.1063/1.113279

F. Poinsotte, . Raman, M. N. Polyanskiy, H. Portales, E. Duval et al., Refractive Index Database Raman scattering by electron-hole excitations in silver nanocrystals Probing atomic ordering and multiple twinning in metal nanocrystals through their vibrations Crystallinity dependence of the plasmon resonant Raman scattering by anisotropic gold nanocrystals Effect of conduction electrons on the polarized Raman spectra of copper oxide superconductors Rationale for emittance and reflectivity Size-dependent evolution of the atomic vibrational density of states and thermodynamic properties of isolated Fe nanoparticles Controlling the synthesis and assembly of silver nanostructures for plasmonic applications, Thèse de doctorat, Université Paul Sabatier. III.A.1.a [Polyanskiy, pp.3489-9711725, 1982.

. Sangeetha, Nanoparticle-Based Strain Gauges Fabricated by Convective Self Assembly: Strain Sensitivity and Hysteresis with Respect to Nanoparticle Sizes, The Journal of Physical Chemistry C, vol.117, issue.4, pp.1935-1940, 2013.
DOI : 10.1021/jp310077r

. Saviot, Number of observable features in the acoustic Raman spectra of nanocrystals, Physical Review B, vol.85, issue.7, p.75405, 2012.
DOI : 10.1103/PhysRevB.85.075405

URL : https://hal.archives-ouvertes.fr/hal-00668244

M. Saviot, L. Saviot, D. Murray, R. Shuker, and R. Et-gammon, Acoustic vibrations of anisotropic nanoparticles Raman-Scattering Selection-Rule Breaking and the Density of States in Amorphous Materials, IV.D.2, IV.D, pp.222-225, 1970.

A. H. Sihvola, Electromagnetic Mixing Formulas and Applications, 1999.
DOI : 10.1049/PBEW047E

. Singh, . Hemkar, V. P. Singh, and M. P. Et-hemkar, Dynamical study for the Gruneisen parameters in FCC metals, Journal of Physics F: Metal Physics, vol.7, issue.5, pp.761-768, 1977.
DOI : 10.1088/0305-4608/7/5/008

. Sow, Revisiting Surface-Enhanced Raman Scattering on Realistic Lithographic Gold Nanostripes, The Journal of Physical Chemistry C, vol.117, issue.48, pp.11725650-25658, 2013.
DOI : 10.1021/jp407983h

A. Stepanov, Synthesis of silver nanoparticles in dielectric matrix by ion implantation : a review, Rev Adv Mater Sci II.A, vol.263, issue.2, pp.1-29, 2010.

. Tonndorf, Photoluminescence emission and Raman response of monolayer MoS_2, MoSe_2, and WSe_2, Optics Express, vol.21, issue.4, pp.4908-4924, 2013.
DOI : 10.1364/OE.21.004908

T. , B. Tracy, E. C. Et-benson, and D. K. , Silicon nitride protective coatings for silvered glass mirrors, II.B, vol.3, 1986.

. Tsang, The electron field emission properties of Ag-SiO/sub 2/ nanocomposite layers, 2005 International Vacuum Nanoelectronics Conference, p.958, 2006.
DOI : 10.1109/IVNC.2005.1619558

R. Tubino, Lattice Dynamics and Spectroscopic Properties by a Valence Force Potential of Diamondlike Crystals: C, Si, Ge, and Sn, The Journal of Chemical Physics, vol.56, issue.3, pp.1022-1034, 1972.
DOI : 10.1063/1.1677264

. Vermaak, On surface stress and surface tension, Surface Science, vol.12, issue.2, pp.128-133, 1968.
DOI : 10.1016/0039-6028(68)90118-0

. Waterhouse, The thermal decomposition of silver (I, III) oxide: A combined XRD, FT-IR and Raman spectroscopic study, Physical Chemistry Chemical Physics, vol.3, issue.17, pp.3838-3845, 2001.
DOI : 10.1039/b103226g

. Whitney, Localized Surface Plasmon Resonance Nanosensor:?? A High-Resolution Distance-Dependence Study Using Atomic Layer Deposition, The Journal of Physical Chemistry B, vol.109, issue.43, pp.20522-20530, 2005.
DOI : 10.1021/jp0540656

W. Wolfe, W. L. Zabet-khosousi, A. Et-dhirani, A. Zawadowski, A. Cardona et al., Proclivity for emissivity Charge transport in nanoparticle assemblies Theory of Raman scattering on normal metals with impurities IV.C 1. Three dimensional design of silver nanoparticle assemblies embedded in dielectrics for Raman spectroscopy enhancement and dark-field imaging, Appl. Opt. Chem. Rev. Phys. Rev. B ACS Nano, vol.21, issue.5, pp.4072-124, 1982.

P. Benzo, C. Bonafos, M. Bayle, R. Carles, L. Cattaneo et al., Controlled synthesis of buried delta-layers of Ag nanocrystals for near-field plasmonic effects on free surfaces, Journal of Applied Physics, vol.113, issue.19, p.193505, 2013.
DOI : 10.1063/1.4804171

M. Bayle, P. Benzo, N. Combe, C. Gatel, C. Bonafos et al., Experimental investigation of the vibrational density of states and electronic excitations in metallic nanocrystals, Physical Review B, vol.89, issue.19, p.195402, 2014.
DOI : 10.1103/PhysRevB.89.195402