S. Xpark, respectivement à 3000 et 1260 cm -1 ) mais aussi dans l'intervalle 700-1300 cm -1 , caractéristiques de matériaux de nature polymère, 1990.

. Si-h, 2900 et 2110 cm -1 ) Le fait que l'on soit en présence d'un (Figure 52), ce qui indique qu'il n'y a presque pas de pénétration dans les matériaux préparés à haute température

. En-outre, eau (WCA) des échantillons préparés à 230°C sont plus élevés que ceux des échantillons préparés à température ambiante. Par exemple, WCA = 64° pour MO-Etude1-03 alors que WCA = 84° pour MO-Etude1-07. Cette tendance reflète une plus faible

. Ainsi, analyse ellipsométrique-porosimétrique, complétés de ceux des mesures d'angles de contact de l'eau, confirment clairement que le réseau des films déposés à température ambiante peut accueillir facilement de petites molécules (telles que l'eau ou l'éthanol)

. Haacké, Les résultats présentés dans cette partie ont fait l'objet d'une publication, 2015.

. Afin, analyse des spectres, nous avons décomposé le massif 1300-630 cm -1 . Les positions et les attributions des bandes sont répertoriées dans le Tableau 19 La Figure 62 (a) montre une décomposition typique pour MO-Etude3-03 (6,5 sccm en NH 3 ) dans la gamme de 1300 à 600 cm -1 . L'évolution des aires des bandes d'absorption correspondantes est tracée en fonction du débit d'ammoniac sur la Figure 62 (b)

A. Allouche, Gabedit-A graphical user interface for computational chemistry softwares, Journal of Computational Chemistry, vol.74, issue.1, pp.174-182, 2011.
DOI : 10.1002/jcc.21600

A. Alshebani, Développement de membranes céramiques pour la séparation des gaz. Fibres creuses et composites mésoporeux de nouvelle génération, Thèse en chimie, 2008.

D. Anderson, P. Kottke, and A. Fedorov, Thermodynamic analysis of hydrogen production via sorption-enhanced steam methane reforming in a new class of variable volume batch-membrane reactor, International Journal of Hydrogen Energy, vol.39, issue.31, pp.17985-17997, 2014.
DOI : 10.1016/j.ijhydene.2014.03.127

N. Armaroli and V. Balzani, The Hydrogen Issue, ChemSusChem, vol.324, issue.1, pp.4-21, 2011.
DOI : 10.1002/cssc.201000182

A. Ayral and V. Rouessac, Techniques innovantes pour la caracterisation optique microstructurale de couches minces, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00128558

A. Ayral, V. Hulea, J. Joulin, and A. Julbe, Céramiques pour l'environnement : filtres, membranes, adsorbants et catalyseurs, p.4805, 2014.

M. Babicki and A. Hall, PSA technology hits the fast lane, Consulté le 02 16, 2015, sur Chemical Processing, 2003.

N. Banerji, J. Serra, P. González, S. Chiussi, E. Parada et al., Oxidation processes in hydrogenated amorphous silicon nitride films deposited by ArF laser-induced CVD at low temperatures, Thin Solid Films, vol.317, issue.1-2, pp.317214-218, 1998.
DOI : 10.1016/S0040-6090(97)00621-4

L. Barelli, G. Bidini, F. Gallorini, and &. S. Servili, Hydrogen production through sorption-enhanced steam methane reforming and membrane technology: A review, Energy, vol.33, issue.4, pp.554-570, 2007.
DOI : 10.1016/j.energy.2007.10.018

R. C. Barklie, M. Collins, and S. R. Silva, EPR linewidth variation, spin relaxation times, and exchange in amorphous hydrogenated carbon, Physical Review B, vol.61, issue.5, pp.613546-3554, 2000.
DOI : 10.1103/PhysRevB.61.3546

R. Bell and P. Dean, Properties of Vitreous Silica: Analysis of Random Network Models, Nature, vol.11, issue.5068, pp.1354-1356, 1966.
DOI : 10.1063/1.1749624

J. Bermudez, An overview of novel technologies to valorise coke oven gas surplus, Fuel Processing Technology, vol.110, pp.150-159, 2013.
DOI : 10.1016/j.fuproc.2012.12.007

R. Bhave, Inorganic Membranes Synthesis, Characteristics and Applications, 1991.
DOI : 10.1007/978-94-011-6547-1

I. Blaszczyk-lezak, A. Wrobel, M. Kivitorma, I. Vayrynen, and A. Tracz, Silicon carbonitride by remote microwave plasma CVD from organosilicon precursor: Growth mechanism and structure of resulting Si:C:N films, Applied Surface Science, vol.253, issue.17, pp.7211-7218, 2007.
DOI : 10.1016/j.apsusc.2007.02.193

F. Borgognomi, S. Tosti, M. Vadrucci, and A. Santucci, Pure hydrogen production in a Pd???Ag multi-membranes module by methane steam reforming, International Journal of Hydrogen Energy, vol.36, issue.13, pp.7550-7558, 2011.
DOI : 10.1016/j.ijhydene.2011.03.120

C. Boyer, Hydrogène. Techniques de l'Ingénieur, p.368, 2012.

D. Breck, Zeolite Molecular Sieves, 1974.

P. Britz and &. N. Zartenar, PEM - Fuel Cell System for Residential Applications, Fuel Cells, vol.105, issue.4, pp.269-275, 2004.
DOI : 10.1002/fuce.200400043

S. Bulou, L. Brizoual, L. Miska, P. De-poucques, L. Bougdira et al., Wide variations of SiCxNy:H thin films optical constants deposited by H2/N2/Ar/hexamethyldisilazane microwave plasma, Surface and Coatings Technology, vol.208, pp.46-50, 2012.
DOI : 10.1016/j.surfcoat.2012.07.079

E. Bustarret, M. Bensouda, M. Habrard, and J. Bruyere, alloys: A quantitative bonding analysis, Physical Review B, vol.38, issue.12, pp.8171-8184, 1988.
DOI : 10.1103/PhysRevB.38.8171

R. Cargill, Carbon Monoxide, p.43, 1990.

M. Carmo, D. L. Fritz, J. Mergel, and D. Stolten, A comprehensive review on PEM water electrolysis, International Journal of Hydrogen Energy, vol.38, issue.12, pp.4901-4934, 2013.
DOI : 10.1016/j.ijhydene.2013.01.151

A. Carrara, A. Perdichizzi, and G. Barigozzi, Pd???Ag dense membrane application to improve the energetic efficiency of a hydrogen production industrial plant, International Journal of Hydrogen Energy, vol.36, issue.9, pp.36-5311, 2011.
DOI : 10.1016/j.ijhydene.2011.01.169

K. Chang, T. Yoshioka, M. Kanezashi, T. Tsuru, &. K. et al., Molecular simulation of micro-structures and gas diffusion behavior of organic???inorganic hybrid amorphous silica membranes, Journal of Membrane Science, vol.381, issue.1-2, pp.38190-101, 2011.
DOI : 10.1016/j.memsci.2011.07.020

K. Chang, Multi-Focus Image Fusion Using Local Energy Pattern, Applied Mechanics and Materials, vol.145, pp.119-123, 2012.
DOI : 10.4028/www.scientific.net/AMM.145.119

K. Chang, T. Yoshioka, M. Kanezashi, T. Tsuru, and K. Tung, A molecular dynamics simulation of a homogeneous organic???inorganic hybrid silica membrane, Chemical Communications, vol.37, issue.48, pp.9140-9142, 2010.
DOI : 10.1039/c0cc02531c

L. Cheng, Y. Fu, K. Liao, J. Chen, C. Hu et al., A high-permeance supported carbon molecular sieve membrane fabricated by plasma-enhanced chemical vapor deposition followed by carbonization for CO2 capture, Journal of Membrane Science, vol.460, pp.1-8, 2014.
DOI : 10.1016/j.memsci.2014.02.033

L. Christophorou and J. Olthoff, Fundamental Electron Interactions with Plasma Processing Gases, 2004.
DOI : 10.1007/978-1-4419-8971-0

R. Cioraa, B. Fayyaz, P. Liu, V. Suwanmethanond, R. Mallada et al., Preparation and reactive applications of nanoporous silicon carbide membranes, Chemical Engineering Science, vol.59, issue.22-23, pp.4957-4965, 2004.
DOI : 10.1016/j.ces.2004.07.015

G. Connell and A. Lewis, Comments on the evidence for sharp and gradual optical absorption edges in amorphous germanium, Physica Status Solidi (b), vol.5, issue.1, pp.291-298, 1973.
DOI : 10.1002/pssb.2220600132

R. Coustel, M. Haacké, V. Rouessac, J. Durand, M. Drobek et al., An insight into the structure?property relationships of PECVD SiCxNy(O):H materials. Microporous and mesoporous materials, pp.97-102, 2014.
URL : https://hal.archives-ouvertes.fr/hal-01497218

H. Daiguji, Transport and Adsorption Phenomena in Mesopores, 2014.

R. De-lange, K. Keizer, and A. Burggraaf, Analysis and theory of gas transport in microporous sol-gel derived ceramic membranes, Journal of Membrane Science, vol.104, issue.1-2, pp.81-100, 1995.
DOI : 10.1016/0376-7388(95)00014-4

F. Delachat, M. Carrada, G. Ferblantier, J. Grob, and A. Slaoui, Properties of silicon nanoparticles embedded in SiNx deposited by microwave-PECVD, Nanotechnology, vol.20, pp.1-5, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00429238

M. Dicko, F. Darkrim-lamari, and P. Malbrunot, Combustible hydrogène : Production, 2013.

M. Dolan, Non-Pd BCC alloy membranes for industrial hydrogen separation, Journal of Membrane Science, vol.362, issue.1-2, pp.12-28, 2010.
DOI : 10.1016/j.memsci.2010.06.068

N. Du, G. Robertson, I. Pinnau, S. Thomas, and M. Guiver, Copolymers of Intrinsic Microporosity Based on 2, Macromolecular Rapid Communications, vol.331, issue.30, pp.1-584, 2009.

J. Emsley, Nature's building block's: An A-Z Guide to the elements, 2001.

I. Ferreira, E. Fortunato, P. Vilarinho, A. Viana, A. Ramos et al., Hydrogenated silicon carbon nitride films obtained by HWCVD, PA-HWCVD and PECVD techniques, Journal of Non-Crystalline Solids, vol.352, issue.9-20, pp.1361-1366, 2006.
DOI : 10.1016/j.jnoncrysol.2006.02.025

G. De-morveau and L. B. , Méthode de nomenclature chimique, 1787.

F. Gallucci, K. Fernandez, P. Corengia, and M. Van-sint-annaland, Recent advances on membranes and membrane reactors for hydrogen production, Chemical Engineering Science, vol.92, pp.40-66, 2013.
DOI : 10.1016/j.ces.2013.01.008

F. Gallucci, L. Paturzo, and A. Basile, A simulation study of the steam reforming of methane in a dense tubular membrane reactor, International Journal of Hydrogen Energy, vol.29, issue.6, pp.611-617, 2004.
DOI : 10.1016/j.ijhydene.2003.08.003

L. Gandia, G. Arzamendi, and P. Dieguez, Renewable Hydrogen Technologies, 2013.

B. S. Ghanem, N. Mckeown, P. Budd, J. Selbie, and D. Fritsch, High-Performance Membranes from Polyimides with Intrinsic Microporosity, Advanced Materials, vol.109, issue.14, pp.2766-2771, 2008.
DOI : 10.1002/adma.200702400

K. Go, S. Sona, S. Kim, K. Kang, and C. Park, Hydrogen production from two-step steam methane reforming in a fluidized bed reactor, International Journal of Hydrogen Energy, vol.34, issue.3, pp.1301-1309, 2009.
DOI : 10.1016/j.ijhydene.2008.11.062

T. Graham, On the absorption and dialytic separation of gases by colloid septa, Philosophical Magazine, vol.156, pp.399-439, 1866.

D. Grainger and M. Hägg, Evaluation of cellulose-derived carbon molecular sieve membranes for hydrogen separation from light hydrocarbons, Journal of Membrane Science, vol.306, issue.1-2, pp.307-317, 2007.
DOI : 10.1016/j.memsci.2007.09.005

M. Grandia, G. Arzamendi, and P. M. Dieguez, Renewable Hydrogen Technologies, 2013.

S. Guruvenket, S. Andrie, M. Simon, K. W. Johnson, and R. A. Sailer, Atmospheric-Pressure Plasma-Enhanced Chemical Vapor Deposition of a-SiCN:H Films: Role of Precursors on the Film Growth and Properties, Applied Materials & Interfaces, pp.5293-5299, 2012.
DOI : 10.1021/am301157p

S. Guruvenket, S. Andrie, M. Simon, K. Johnson, and R. Sailer, Atmospheric Pressure Plasma CVD of Amorphous Hydrogenated Silicon Carbonitride (a-SiCN:H) Films Using Triethylsilane and Nitrogen, Plasma Processes and Polymers, vol.13, issue.70, pp.1126-1136, 2011.
DOI : 10.1002/ppap.201100035

M. Haacké, R. Coustel, V. Rouessac, M. Drobek, S. Roualdès et al., Optimization of the molecular sieving properties of amorphous SiCXNY:H hydrogen selective membranes prepared by PECVD. The european physical journal special topics, 1935.

M. Haacké, R. Coustel, V. Rouessac, S. Roualdès, and A. Julbe, Microwave PECVD Silicon Carbonitride Thin Films: A FTIR and Ellipsoporosimetry Study. Plasma processes and polymers, 2015.

Ø. Hatlevik, S. Gade, M. Keeling, P. Thoen, A. Davidson et al., Palladium and palladium alloy membranes for hydrogen separation and production: History, fabrication strategies, and current performance, Separation and Purification Technology, vol.73, issue.1, pp.59-64, 2010.
DOI : 10.1016/j.seppur.2009.10.020

Y. Hayakawa, N. Terasawa, E. Hayashi, and T. Abe, Plasma polymerization of cyclic perfluoroamines and composite membranes for gas separation, Journal of Applied Polymer Science, vol.62, issue.6, pp.951-954, 1996.
DOI : 10.1002/(SICI)1097-4628(19961107)62:6<951::AID-APP10>3.0.CO;2-W

D. Hegemann, H. Brunner, and C. Oehr, Plasma treatment of polymers for surface and adhesion improvement. Nuclear Instruments and Methods in, Physics Research B, vol.208, pp.281-286, 2003.

G. Holleck, Diffusion and solubility of hydrogen in palladium and palladium--silver alloys, The Journal of Physical Chemistry, vol.74, issue.3, pp.503-511, 1970.
DOI : 10.1021/j100698a005

S. Hosseini, M. Teoh, and T. Chung, Hydrogen separation and purification in membranes of miscible polymer blends with interpenetration networks, Polymer, vol.49, issue.6, pp.491594-1603, 2008.
DOI : 10.1016/j.polymer.2008.01.052

A. Huang and J. Caro, Covalent Post-Functionalization of Zeolitic Imidazolate Framework ZIF-90 Membrane for Enhanced Hydrogen Selectivity, Angewandte Chemie International Edition, vol.350, issue.21, pp.4979-4982, 2011.
DOI : 10.1002/anie.201007861

R. Iler, The chemistry of silica: Solubility, polymerization, colloid and surface properties and biochemistry of silica, 1979.

N. Inagaki, S. Tasaka, and M. Park, Gas separation membrane made by plasma polymerization of 1,3-ditrifluoromethylbenzene/CF4 mixture, Journal of Applied Polymer Science, vol.40, issue.12, pp.143-153, 1990.
DOI : 10.1002/app.1990.070400113

V. I. Ivashchenko, O. K. Porada, L. A. Ivashchenko, I. I. Timofeeva, O. K. Sinel-'nichenko et al., Characteristics of thin plasmachemical silicon carbon nitride films deposited using hexamethyldisilane, Powder Metallurgy and Metal Ceramics, vol.14, issue.507, pp.66-72, 2009.
DOI : 10.1007/s11106-009-9096-9

H. Iwahara, Y. Asakurab, K. Katahirac, and M. Tanakad, Prospect of hydrogen technology using proton-conducting ceramics, Solid State Ionics, vol.168, issue.3-4, pp.299-310, 2004.
DOI : 10.1016/j.ssi.2003.03.001

P. Jedrzejowski, J. Cizek, A. Amassian, J. Klemberg-sapieha, J. Vlcek et al., Mechanical and optical properties of hard SiCN coatings prepared by PECVD, Thin Solid Films, vol.447, issue.448, pp.201-207, 2004.
DOI : 10.1016/S0040-6090(03)01057-5

F. Joensen and J. Rostrup-nielsen, Conversion of hydrocarbons and alcohols for fuel cells, Journal of Power Sources, vol.105, issue.2, pp.195-201, 2002.
DOI : 10.1016/S0378-7753(01)00939-9

Y. Jüttke, H. Richter, I. Voigt, R. Prasad, M. Bazarjani et al., Polymer derived ceramic membranes for gas separation, Chemical engineering transactions, vol.32, pp.1891-1896, 2013.

W. Kafrouni, Membranes a-SiCxNy : H déposées par CVD-plasma. Tamis moléculaire pour la perméation de l'hélium, Thèse en Chimie des Matériaux, p.150, 2009.

W. Kafrouni, V. Rouessac, A. Julbe, and J. Durand, Synthesis of PECVD a-SiCXNY:H membranes as molecular sieves for small gas separation, Journal of Membrane Science, vol.329, issue.1-2, pp.130-137, 2009.
DOI : 10.1016/j.memsci.2008.12.028

URL : https://hal.archives-ouvertes.fr/hal-00362053

W. Kafrouni, V. Rouessac, A. Julbe, and J. Durand, Synthesis and characterization of silicon carbonitride films by plasma enhanced chemical vapor deposition (PECVD) using bis(dimethylamino)dimethylsilane (BDMADMS), as membrane for a small molecule gas separation, Applied Surface Science, vol.257, issue.4, pp.1196-1203, 2010.
DOI : 10.1016/j.apsusc.2010.08.013

URL : https://hal.archives-ouvertes.fr/hal-00617020

M. Kanezashi, D. Fuchigami, T. Yoshioka, and T. Tsuru, Control of Pd dispersion in sol???gel-derived amorphous silica membranes for hydrogen separation at high temperatures, Journal of Membrane Science, vol.439, pp.78-86, 2013.
DOI : 10.1016/j.memsci.2013.03.037

S. Kean, Eco-Alchemy in Alberta, Science, vol.326, issue.5956, pp.1052-1055, 2009.
DOI : 10.1126/science.326.5956.1052

S. King, J. Bielefeld, M. French, and W. Landford, Mass and bond density measurements for PECVD a-SiCx:H thin films using Fourier transform-infrared spectroscopy, Journal of Non-Crystalline Solids, vol.357, issue.21, pp.3602-3615, 2011.
DOI : 10.1016/j.jnoncrysol.2011.07.004

K. Das, J. Das, N. Bandyopadhyay, and S. , Highly oriented improved SAPO 34 membrane on low cost support for hydrogen gas separation, Journal of Materials Chemistry A, vol.48, issue.16, pp.4966-4973, 2013.
DOI : 10.1039/c3ta01095c

H. Kita, X. Lin, S. Murata, K. Tanaka, and K. Okamoto, Plasma Polymerization Over Porous Inorganic Membranes and the Permeability of the Membranes. (II)., Journal of Photopolymer Science and Technology, vol.9, issue.2, pp.237-242, 1996.
DOI : 10.2494/photopolymer.9.237

M. Knudsen, The Kinetic Theory of Gases: Some Modern Aspects, 1950.

M. Konuma, Film Deposition by Plasma Techniques, 1992.
DOI : 10.1007/978-3-642-84511-6

W. Koros and M. Hellums, Transport Properties, 1989.
DOI : 10.1002/0471440264.pst376

R. Kothari, D. Buddhi, and R. Sawhney, Comparison of environmental and economic aspects of various hydrogen production methods, Renewable and Sustainable Energy Reviews, vol.12, issue.2, pp.553-563, 2008.
DOI : 10.1016/j.rser.2006.07.012

V. Kulikovsky, R. Ctvrtlik, V. Vorlicek, V. Zelezny, P. Bohac et al., Effect of air annealing on mechanical properties and structure of SiCxNy magnetron sputtered films, Surface and Coatings Technology, vol.240, pp.76-85, 2014.
DOI : 10.1016/j.surfcoat.2013.12.017

L. Landau and E. Lifshitz, Electrodynamics of Continuous Media, 1960.

C. Lasorsa, P. Perillo, and P. Morando, Protective SixOyCz coatings on steel prepared by plasma activated chemical vapour deposition, Surface and Coatings Technology, vol.204, issue.16-17, pp.2813-2816, 2010.
DOI : 10.1016/j.surfcoat.2010.02.054

C. Lau, P. Li, F. Li, T. Chung, and D. Paul, Reverse-selective polymeric membranes for gas separations, Progress in Polymer Science, vol.38, issue.5, pp.740-766, 2013.
DOI : 10.1016/j.progpolymsci.2012.09.006

D. Lee, Q. Li, H. Kim, and K. Lee, Preparation of Ni-MOF-74 membrane for CO2 separation by layer-by-layer seeding technique, Microporous and Mesoporous Materials, vol.163, pp.169-177, 2012.
DOI : 10.1016/j.micromeso.2012.07.008

F. Li, Y. Xiao, Y. Ong, and T. Chung, UV-Rearranged PIM-1 Polymeric Membranes for Advanced Hydrogen Purification and Production, Advanced Energy Materials, vol.38, issue.12, pp.1456-1466, 2012.
DOI : 10.1002/aenm.201200296

. Linde, Hydrogen Recovery by Pressure Swing Adsorption, 2009.

K. Liu, S. Song, and V. Subramani, Hydrogen and Syngas Production and Purification Technologies, 2009.
DOI : 10.1002/9780470561256

C. Lo, M. Lin, K. Liao, M. De-guzman, H. Tsai et al., Control of pore structure and characterization of plasma-polymerized SiOCH films deposited from octamethylcyclotetrasiloxane (OMCTS), Journal of Membrane Science, vol.365, issue.1-2, pp.418-425, 2010.
DOI : 10.1016/j.memsci.2010.09.042

G. Lu, J. C. Diniz-da-costa, J. Duke, M. Giessler, S. Socolow et al., Inorganic membranes for hydrogen production and purification: A critical review and perspective, Journal of Colloid and Interface Science, vol.314, issue.2, pp.314589-603, 2007.
DOI : 10.1016/j.jcis.2007.05.067

G. Lucovsky, Chemical effects on the frequencies of Si-H vibrations in amorphous solids, Solid State Communications, vol.29, issue.8, pp.571-576, 1979.
DOI : 10.1016/0038-1098(79)90666-5

M. De-vos, R. Verweij, and H. , Improved performance of silica membranes for gas separation, Journal of Membrane Science, vol.143, issue.1-2, pp.37-51, 1998.
DOI : 10.1016/S0376-7388(97)00334-7

X. Ma, R. Swaidan, B. Teng, O. Salinas, E. Litwiller et al., Carbon molecular sieve gas separation membranes based on an intrinsically microporous polyimide precursor, Carbon, vol.62, pp.6288-96, 2013.
DOI : 10.1016/j.carbon.2013.05.057

H. Matsumoto, T. Shimura, H. Iwahara, T. Higuchi, K. Yashiro et al., Hydrogen separation using proton-conducting perovskites, Journal of Alloys and Compounds, vol.408, issue.412, pp.408-412456, 2006.
DOI : 10.1016/j.jallcom.2004.12.093

M. Meyyappan, L. Delzeit, A. Cassell, and D. Hash, Carbon nanotube growth by PECVD: a review, Plasma Sources Science and Technology, vol.12, issue.2, pp.205-216, 2003.
DOI : 10.1088/0963-0252/12/2/312

A. Morimoto, T. Miura, M. Kumeda, and T. Shimizu, Defects in hydrogenated amorphous silicon???carbon alloy films prepared by glow discharge decomposition and sputtering, Journal of Applied Physics, vol.53, issue.11, pp.7299-7305, 1982.
DOI : 10.1063/1.329879

N. Mousseau and G. Barkema, Binary continuous random networks, Journal of Physics: Condensed Matter, vol.16, issue.44, pp.5183-5190, 2004.
DOI : 10.1088/0953-8984/16/44/015

H. Nagasawa, H. Shigemoto, M. Kanezashi, T. Yoshioka, and T. Tsuru, Characterization and gas permeation properties of amorphous silica membranes prepared via plasma enhanced chemical vapor deposition, Journal of Membrane Science, vol.441, pp.45-53, 2013.
DOI : 10.1016/j.memsci.2013.03.056

S. Nehlsen, T. Hunte, and J. Müller, Gas permeation properties of plasma polymerized thin film siloxane-type membranes for temperatures up to 350??C, Journal of Membrane Science, vol.106, issue.1-2, pp.1-7, 1995.
DOI : 10.1016/0376-7388(95)00071-J

M. Nomura, K. Ono, S. Gopalakrishnan, T. Sugawara, and S. Nakao, Preparation of a stable silica membrane by a counter diffusion chemical vapor deposition method, Journal of Membrane Science, vol.251, issue.1-2, pp.151-158, 2005.
DOI : 10.1016/j.memsci.2004.11.008

T. Norby and R. Haugsrud, Nonporous Inorganic Membranes: For Chemical Processing : Dense Ceramic Membranes for Hydrogen Separation, 2006.

N. Ockwig and T. Nenoff, Membranes for Hydrogen Separation, Chemical Reviews, vol.107, issue.10, pp.4078-4110, 2007.
DOI : 10.1021/cr0501792

T. Ohta, Energy Carriers and Conversion Systems with Emphasis on Hydrogen, 2009.

S. Oyama, Review on Mechanisms of Gas Permeation through Inorganic Membranes, Journal of the Japan Petroleum Institute, vol.54, issue.5, pp.298-309, 2011.
DOI : 10.1627/jpi.54.298

P. Tanaka, D. , L. Tanco, M. Nagase, T. Okazaki et al., Fabrication of Hydrogen-Permeable Composite Membranes Packed with Palladium Nanoparticles, Advanced Materials, vol.247, issue.332, pp.630-632, 2006.
DOI : 10.1002/adma.200501900

P. Tanaka, D. , L. Tanco, M. Okazaki, J. Wakui et al., Preparation of ???pore-fill??? type Pd???YSZ?????-Al2O3 composite membrane supported on ??-Al2O3 tube for hydrogen separation, Journal of Membrane Science, vol.320, issue.1-2, pp.436-441, 2008.
DOI : 10.1016/j.memsci.2008.04.044

X. Pagès, Décharge luminescente transportée pour la synthèse de membranes a-SiCx : H à l'intérieur d'un support céramique tubulaire, Thèse en chimie des Matériaux, p.210, 2001.

X. Pagès, V. Rouessac, D. Cot, G. Nabias, and J. Durand, Gas permeation of PECVD membranes inside alumina substrate tubes, Separation and Purification Technology, vol.25, issue.1-3, pp.399-406, 2001.
DOI : 10.1016/S1383-5866(01)00068-5

P. Pandey and R. Chauhan, Membranes for gas separation, Progress in Polymer Science, vol.26, issue.6, pp.853-893, 2001.
DOI : 10.1016/S0079-6700(01)00009-0

S. Park, N. Kim, U. Kim, S. Hong, and H. Sasabe, Plasma Polymerization of Hexamethyldisilazane, Polymer Journal, vol.38, issue.3, pp.242-249, 1990.
DOI : 10.1002/pola.1986.080240402

S. Peter, S. Bernütz, S. Berg, and F. Richter, FTIR analysis of a-SiCN:H films deposited by PECVD, Vacuum, vol.98, pp.9881-87, 2013.
DOI : 10.1016/j.vacuum.2013.04.014

T. Peters, M. Stange, and R. Bredesen, On the high pressure performance of thin supported Pd???23%Ag membranes???Evidence of ultrahigh hydrogen flux after air treatment, Journal of Membrane Science, vol.378, issue.1-2, pp.28-34, 2011.
DOI : 10.1016/j.memsci.2010.11.022

J. Phair and S. Badwal, Review of proton conductors for hydrogen separation, Ionics, vol.349, issue.137, pp.103-115, 2006.
DOI : 10.1007/s11581-006-0016-4

J. Phair and R. Donelson, Developments and Design of Novel (Non-Palladium-Based) Metal Membranes for Hydrogen Separation, Industrial & Engineering Chemistry Research, vol.45, issue.16, pp.5657-5674, 2006.
DOI : 10.1021/ie051333d

S. Qiu, M. Xue, and G. Zhu, Metal???organic framework membranes: from synthesis to separation application, Chem. Soc. Rev., vol.4, issue.391, pp.6116-6140, 2014.
DOI : 10.1039/C4CS00159A

M. Rahimpour, The enhancement of hydrogen recovery in PSA unit of domestic petrochemical plant, Chemical Engineering Journal, vol.226, pp.44-459, 2013.
DOI : 10.1016/j.cej.2013.04.029

H. Raut, V. Ganesh, S. Nair, A. Ramakrishna, and S. , Anti-reflective coatings: A critical, in-depth review, Energy & Environmental Science, vol.33, issue.21, pp.3779-3804, 2011.
DOI : 10.1039/c1ee01297e

S. Reinecke and B. Sleep, Knudsen diffusion, gas permeability, and water content. Water ressources research, pp.1280-1295, 2002.

J. Ristein, R. T. Stief, L. Ley, and W. Beyer, A comparative analysis of a-C:H by infrared spectroscopy and mass selected thermal effusion, Journal of Applied Physics, vol.84, issue.7, pp.3836-3847, 1998.
DOI : 10.1063/1.368563

L. Robeson, The upper bound revisited, Journal of Membrane Science, vol.320, issue.1-2, pp.390-400, 2008.
DOI : 10.1016/j.memsci.2008.04.030

S. Rodrigues, R. Whitley, and A. Mendes, Preparation and characterization of carbon molecular sieve membranes based on resorcinol???formaldehyde resin, Journal of Membrane Science, vol.459, pp.207-216, 2014.
DOI : 10.1016/j.memsci.2014.02.013

R. Roldan, Technical and economic feasibility of adapting an industrial steam reforming unit for production of hydrogen from renewable ethanol, International Journal of Hydrogen Energy, vol.40, issue.4, pp.40-42035, 2015.
DOI : 10.1016/j.ijhydene.2014.12.003

C. Romero, J. Noyola, U. Santiago, R. Valladares, A. Valladares et al., A New Approach to the Computer Modeling of Amorphous Nanoporous Structures of Semiconducting and Metallic Materials: A Review, Materials, vol.3, issue.1, pp.467-502, 2010.
DOI : 10.3390/ma3010467

J. Rostrup-nielsen, J. , S. Norskov, and J. , Hydrogen and synthesis gas by steam-and C02 reforming Advances in Catalysis, pp.65-139, 2002.

S. Roualdès, Elaboration par PECVD et caractérisation de membranes polysiloxanes plasma pour la perméation gazeuse, Thèse en Chimie des Matériaux, p.260, 2000.

S. Roualdès, A. Van-der-lee, R. Berjoan, J. Sanchez, and J. Durand, Gas separation properties of organosilicon plasma polymerized membranes, AIChE Journal, vol.14, issue.158, pp.1566-1575, 1999.
DOI : 10.1002/aic.690450718

V. Rouessac, Contribution à l'étude microstructurale des couches minces supportées a-SiO et autres membranes poreuses, 2007.

J. Sakata, M. Yamamoto, and M. Hirai, Plasma polymerized membranes and gas permeability. II, Journal of Applied Polymer Science, vol.31, issue.7, 1986.
DOI : 10.1002/app.1986.070310704

P. Scharlin, Carbon Dioxide in Water and Aqueous Electrolyte Solutions, IUPAC Solubility Data Series, p.62, 1996.

H. Schlemm, A. Mai, S. Roth, D. Roth, K. Baumgartner et al., Industrial large scale silicon nitride deposition on photovoltaic cells with linear microwave plasma sources, Surface and Coatings Technology, vol.174, issue.175, pp.174-175208, 2003.
DOI : 10.1016/S0257-8972(03)00611-X

J. Schmidt and M. Kerr, Highest-quality surface passivation of low-resistivity p-type silicon using stoichiometric PECVD silicon nitride, Solar Energy Materials and Solar Cells, vol.65, issue.1-4, pp.585-591, 2001.
DOI : 10.1016/S0927-0248(00)00145-8

M. Schmidt, K. Baldridge, J. Boatz, S. Elbert, M. Gordon et al., General atomic and molecular electronic structure system, Journal of Computational Chemistry, vol.115, issue.11, pp.1347-1363, 1993.
DOI : 10.1002/jcc.540141112

V. R. Shayapov, Y. Rumyantsev, N. Fainer, and B. Ayupov, Optical and mechanical properties of films obtained by plasma decomposition of hexamethyldisilazane, Russian Journal of Physical Chemistry A, vol.86, issue.11, pp.1716-1720, 2012.
DOI : 10.1134/S0036024412110258

L. Shi, A. Goldbach, and H. Xu, High-flux H2 separation membranes from (Pd/Au)n nanolayers, International Journal of Hydrogen Energy, vol.36, issue.3, pp.2281-2284, 2011.
DOI : 10.1016/j.ijhydene.2010.11.056

Y. Shirasaki, T. Tsuneki, Y. Ota, I. Yasuda, S. Tachibana et al., Development of membrane reformer system for highly efficient hydrogen production from natural gas, International Journal of Hydrogen Energy, vol.34, issue.10, pp.4482-4487, 2009.
DOI : 10.1016/j.ijhydene.2008.08.056

B. Song and J. Forsyth, CACHET 2: Carbon Capture and Hydrogen Production with Membranes, Energy Procedia, pp.1050-1059, 2013.
DOI : 10.1016/j.egypro.2013.05.201

W. Soppe, A. Biebericher, C. Devilee, H. Donker, and H. Schlemm, High rate growth of micro-crystalline silicon by microwave-PECVD, 3rd World Conference on Photovoltaic Energy Conversion, 2003.

T. Sperle, D. Chen, R. Lodeng, and A. Holmen, Pre-reforming of natural gas on a Ni catalyst, Applied Catalysis A: General, vol.282, issue.1-2, pp.195-204, 2005.
DOI : 10.1016/j.apcata.2004.12.011

H. Suda, H. Yamauchi, Y. Uchimaru, I. Fujiwara, and K. Haraya, Preparation and gas permeation properties of silicon carbide-based inorganic membranes for hydrogen separation, Desalination, vol.193, issue.1-3, pp.252-255, 2006.
DOI : 10.1016/j.desal.2005.04.143

L. Sun and J. Thonnelier, Perméation gazeuse, 2004.

A. Szekeres, K. Kirov, and S. Alexandrova, Plasma photoresist stripping in a planar reactor, Physica Status Solidi (a), vol.126, issue.1, pp.371-374, 1981.
DOI : 10.1002/pssa.2210630148

H. Takaba, E. Matsuda, and S. Nakao, Correlation of Temperature Dependence of Gas Permeability with Pore Size in Molecular Sieving Membranes:?? A Grand Canonical Ensemble Molecular Dynamics Study, The Journal of Physical Chemistry B, vol.108, issue.37, pp.14142-14147, 2004.
DOI : 10.1021/jp049068h

A. Taylor, F. Fendrych, L. Fekete, J. Vl?ek, V. ?ezá?ová et al., Novel high frequency pulsed MW-linear antenna plasma-chemistry: Routes towards large area, low pressure nanodiamond growth, Diamond and Related Materials, vol.20, issue.4, pp.613-615, 2011.
DOI : 10.1016/j.diamond.2011.01.003

C. Tixier, P. Tristant, J. Desmaison, and D. Merle, Remote Microwave Plasma Enhanced Chemical Vapour Deposition of Amorphous Carbon : Optical Emission Spectroscopy Characterisation of the Afterglow and Growth Rates, Le Journal de Physique IV, vol.05, issue.C5, pp.593-600, 1995.
DOI : 10.1051/jphyscol:1995570

URL : https://hal.archives-ouvertes.fr/jpa-00253932

K. Tsugawa, M. Ishihara, J. Kim, M. Hasegawa, and Y. Koga, Large Area and Low Temperature Nanodiamond Coating by Microwave Plasma Chemical Vapor Deposition. New Diamond and Frontier Carbon Technology, pp.337-346, 2006.

R. Uhlhorn, K. Keiser, and A. Burggraaf, Gas and surface diffusion in modified ??-alumina systems, Journal of Membrane Science, vol.46, issue.2-3, pp.225-241, 1989.
DOI : 10.1016/S0376-7388(00)80337-3

R. Uhlhorn, K. Keizer, and A. Burggraaf, Gas transport and separation with ceramic membranes. Part I. Multilayer diffusion and capillary condensation, Journal of Membrane Science, vol.66, issue.2-3, pp.259-269, 1992.
DOI : 10.1016/0376-7388(92)87016-Q

R. Uhlhorn, K. Keizer, and A. Burggraaf, Gas transport and separation with ceramic membranes. Part II. Synthesis and separation properties of microporous membranes, Journal of Membrane Science, vol.66, issue.2-3, pp.271-287, 1992.
DOI : 10.1016/0376-7388(92)87017-R

A. Valladares, J. Díaz-celaya, J. Galván-colín, L. Mejía-mendoza, F. Alvarez-ramirez et al., New Approaches to the Computer Simulation of Amorphous Alloys: A Review, Materials, vol.4, issue.12, pp.716-781, 2011.
DOI : 10.3390/ma4040716

R. Van-ginhoven, H. Jónsson, and L. Corrales, Silica glass structure generation for ab initio calculations using small samples of amorphous silica, Physical Review B, p.71, 2005.

E. Vassallo, A. Cremona, F. Ghezzi, F. Dellera, L. Laguardia et al., Structural and optical properties of amorphous hydrogenated silicon carbonitride films produced by PECVD, Applied Surface Science, vol.252, issue.22, pp.7993-8000, 2006.
DOI : 10.1016/j.apsusc.2005.10.017

M. Vetter, I. Martin, A. Orpella, J. Puigdollers, C. Voz et al., IR-study of a-SiCx:H and a-SiCxNy:H films for c-Si surface passivation, Thin Solid Films, vol.451, issue.452, pp.451-452340, 2004.
DOI : 10.1016/j.tsf.2003.10.125

C. Wang and G. Hsiue, Oxidation of polyethylene surface by glow disharge and subsequent graft copolymerization of acrylic acid, Journal of Polymer Science Part A: Polymer Chemistry, pp.311307-1314, 1993.

H. Wang, X. Dong, and Y. Lin, Highly stable bilayer MFI zeolite membranes for high temperature hydrogen separation, Journal of Membrane Science, vol.450, pp.425-432, 2014.
DOI : 10.1016/j.memsci.2013.08.030

L. Wang and F. Hong, Carbon-based molecular sieve membranes for gas separation by inductively-coupled-plasma chemical vapor deposition, Microporous and Mesoporous Materials, vol.77, issue.2-3, pp.167-174, 2005.
DOI : 10.1016/j.micromeso.2004.09.001

M. Wang, Z. Wang, X. Gong, and Z. Guo, The intensification technologies to water electrolysis for hydrogen production ??? A review, Renewable and Sustainable Energy Reviews, vol.29, pp.573-588, 2014.
DOI : 10.1016/j.rser.2013.08.090

J. Weichart and J. Müller, Plasma polymerization of silicon organic membranes for gas separation, Surface and Coatings Technology, vol.59, issue.1-3, pp.342-344, 1993.
DOI : 10.1016/0257-8972(93)90109-2

J. Weichart and J. Müller, Investigation of the concentration driven permeation of diluted SO2, NO2 and CO in silicon organic membranes prepared by plasma polymerization, Journal of Membrane Science, vol.86, issue.1-2, pp.87-93, 1994.
DOI : 10.1016/0376-7388(93)E0125-4

M. Wertheimer and M. Moisau, Processing of electronic materials by microwave plasma, Pure and Applied Chemistry, vol.66, issue.6, pp.1343-1352, 1994.
DOI : 10.1351/pac199466061343

P. Westermann, B. Jorgensen, L. Lange, B. K. Ahring, and C. H. Christensen, Maximizing renewable hydrogen production from biomass in a bio/catalytic refinery, International Journal of Hydrogen Energy, vol.32, issue.17, pp.4135-4141, 2007.
DOI : 10.1016/j.ijhydene.2007.06.018

F. Wooten, K. Winer, and D. Weaire, Computer Generation of Structural Models of Amorphous Si and Ge, Physical Review Letters, vol.54, issue.13, pp.1392-1395, 1985.
DOI : 10.1103/PhysRevLett.54.1392

A. Wrobel, I. Blaszczyk-lezak, P. Uznanski, and B. Glebocki, Remote Hydrogen Microwave Plasma Chemical Vapor Deposition of Amorphous Silicon Carbonitride (a-SiCN) Coatings Derived From Tris(dimethylamino)Silane, Plasma Processes and Polymers, vol.151, issue.448, pp.542-556, 2011.
DOI : 10.1002/ppap.201000203

M. Yamamoto, J. Sakata, and M. Hirai, Plasma polymerized membranes and gas permeability. I, Journal of Applied Polymer Science, vol.29, issue.10, pp.2981-2987, 1984.
DOI : 10.1002/app.1984.070291004

S. Yan, H. Maeda, K. Kusakabe, and S. Morooka, Hydrogen-Permselective SiO2 Membrane Formed in Pores of Alumina Support Tube by Chemical Vapor Deposition with Tetraethylorthosilicate, Industrial & Engineering Chemistry Research, vol.33, issue.9, pp.2096-2101, 1994.
DOI : 10.1021/ie00033a011

H. Yasuda, Glow discharge polymerization, Journal of Polymer Science: Macromolecular Reviews, vol.16, issue.1, pp.199-293, 1981.
DOI : 10.1002/pol.1981.230160104

H. Yasuda and T. Hsu, Some aspects of plasma polymerization investigated by pulsed R.F. discharge, Journal of Polymer Science: Polymer Chemistry Edition, vol.15, issue.1, pp.1403-1408, 1975.
DOI : 10.1002/pol.1977.170150109

W. Yave, A. Szymczyk, N. Yave, and Z. Roslaniec, Design, synthesis, characterization and optimization of PTT-b-PEO copolymers: A new membrane material for CO2 separation, Journal of Membrane Science, vol.362, issue.1-2, pp.407-416, 2010.
DOI : 10.1016/j.memsci.2010.06.060

S. Yokoyama, M. Hirose, and Y. Osaka, Electron Spin Resonance in Discharge-Produced Silicon Nitride, Japanese Journal of Applied Physics, vol.20, issue.1, p.20, 1981.
DOI : 10.1143/JJAP.20.L35

S. Yun and S. Oyama, Correlations in palladium membranes for hydrogen separation: A review, Journal of Membrane Science, vol.375, issue.1-2, pp.28-45, 2011.
DOI : 10.1016/j.memsci.2011.03.057

W. Zachariasen, THE ATOMIC ARRANGEMENT IN GLASS, Journal of the American Chemical Society, vol.54, issue.10, pp.3841-3851, 1932.
DOI : 10.1021/ja01349a006