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Elaboration et étude des propriétés mécaniques et thermiques de matériaux constitués de nanotubes de carbone verticalement alignés

Abstract : Vertically aligned carbon nanotube carpets are potential candidates for applications such as interconnections or thermal interface materials (TIMs). This research work deals with the synthesis of aligned carbon nanotube carpets from the aerosol assisted chemical vapour deposition (CVD) technique, with the elaboration of nanocomposites made of different grades of epoxy matrix infiltrated within these carpets, as well as the study of both longitudinal and transverse mechanical and thermal properties of dry carpets themselves and 1D-nanocomposites separately. The synthesis conditions notably enable to vary characteristics of the differents carpets such as their thickness, their density, the mean external diameter of the carbon nanotubes (CNT), the intertube space and the CNT volume fraction, whereas their crystalline structure can be modified with a high temperature thermal treatment. The main goal of this work is to prove and quantify the effect of some of the characteristics of the carbon nanotubes carpets on both mechanical and thermal properties of the different kinds of CNT carpets and resulting composite materials. The two impregnation methods used, liquid way and infusion, lead to dense CNT carpets with a preserved alignment of the CNT and an homogeneous distribution of these latest within the epoxy system. The CNT volume content is evidenced as the key-parameter exacerbating the mechanical and thermal properties mainly in the longitudinal direction compared with the alignment axis of the CNTs. Moreover the mechanical and thermal conduction properties of the CNT carpets and the 1D-nanocomposites are clearly increased when the crystalline structure of the CNT is improved. The significant increasing of the properties brought by the vertically aligned CNT within these anisotropic 1D-nanocomposites compared with the only organic matrixes is promising and opens new pathways aiming to meet the latest specifications related to multifunctionnality in fields such as aeronautics and aerospace.
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Submitted on : Tuesday, April 19, 2016 - 9:12:07 AM
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  • HAL Id : tel-01304046, version 1


Jonathan Bouillonnec. Elaboration et étude des propriétés mécaniques et thermiques de matériaux constitués de nanotubes de carbone verticalement alignés. Matériaux. Université Paul Sabatier - Toulouse III, 2015. Français. ⟨NNT : 2015TOU30228⟩. ⟨tel-01304046⟩



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