B. D. Ratner, Biomaterials Science: An Interdisciplinary Endeavor, Biomaterials Science: An Introduction to Materials in Medicine, 1997.
DOI : 10.1016/B978-0-08-050014-0.50005-5

D. Gibbons, Introduction to medical implant materials," in ASM Handbook - Materials for medical devices, 2012.

B. D. Ratner, A. S. Hoffman, and F. J. Schoen, Biomaterials science -An introduction to materials in medicine, 1997.

L. Matthew, R. J. Busam, and W. T. Obremskey, Hardware removal: Indications and expectations, Journal of the American, vol.14, pp.113-120, 2006.

M. P. Staiger, A. M. Pietak, and J. Huadmai, Magnesium and its alloys as orthopedic biomaterials: A review, Biomaterials, vol.27, issue.9, pp.1728-1734, 2006.
DOI : 10.1016/j.biomaterials.2005.10.003

A. Denkena and B. Lucas, Biocompatible Magnesium Alloys as Absorbable Implant Materials ??? Adjusted Surface and Subsurface Properties by Machining Processes, CIRP Annals - Manufacturing Technology, vol.56, issue.1, pp.113-116, 2007.
DOI : 10.1016/j.cirp.2007.05.029

J. C. Middleton and A. J. Tipton, Synthetic biodegradable polymers as orthopedic devices, Biomaterials, vol.21, issue.23, pp.2335-2346, 2000.
DOI : 10.1016/S0142-9612(00)00101-0

H. G. Seiler, Handbook on toxicity of inorganic compounds, Analytica Chimica Acta, vol.237, 1987.
DOI : 10.1016/S0003-2670(00)83960-4

F. Witte, The history of biodegradable magnesium implants: A review???, Acta Biomaterialia, vol.6, issue.5, pp.1680-1692, 2010.
DOI : 10.1016/j.actbio.2010.02.028

S. C. Cowin, A. E. Goodship, and J. L. Cunningham, Bone Adaptation, Bone Mechanics Handbook, 2001.
DOI : 10.1201/b14263-31

M. E. Müller, M. Allgöwer, and S. M. Perre, Manual of INTERNAL FIXATION: Techniques Recommended by the Ao-Asif Group, 1991.

M. M. Avedesian and H. Baker, Properties of unalloyed magnesium," in ASM Specialty handbook -Magnesium and Magnesium Alloys, 1999.

Y. H. An, R. A. Draughn, and E. Bonucci, Mechanical testing of bone and the bone-implant interface, 1999.
DOI : 10.1201/9781420073560

X. Gu and Y. Zheng, A review on magnesium alloys as biodegradable materials, Frontiers of Materials Science in China, vol.8, issue.11, pp.111-115, 2010.
DOI : 10.1007/s11706-010-0024-1

L. E. Claes, Mechanical characterization of biodegradable implants, Clinical Materials, vol.10, issue.1-2, pp.41-46, 1992.
DOI : 10.1016/0267-6605(92)90083-6

H. Wang, Y. Estrin, and H. F. Fu, The Effect of Pre-Processing and Grain Structure on the Bio-Corrosion and Fatigue Resistance of Magnesium Alloy AZ31, Advanced Engineering Materials, vol.104, issue.432, pp.967-972, 2007.
DOI : 10.1002/adem.200700200

H. Wang, Y. Estrin, and Z. Zúberová, Bio-corrosion of a magnesium alloy with different processing histories, Materials Letters, vol.62, issue.16, pp.2476-2479, 2008.
DOI : 10.1016/j.matlet.2007.12.052

D. Song, A. B. Ma, and J. Jiang, Corrosion behavior of equal-channel-angular-pressed pure magnesium in NaCl aqueous solution, Corrosion Science, vol.52, issue.2, pp.481-490, 2010.
DOI : 10.1016/j.corsci.2009.10.004

M. Salahshoor and Y. Guo, Biodegradable Orthopedic Magnesium-Calcium (MgCa) Alloys, Processing, and Corrosion Performance, Materials, vol.5, issue.12, pp.135-155, 2012.
DOI : 10.3390/ma5010135

URL : http://doi.org/10.3390/ma5010135

Z. Pu, G. Song, and S. Yang, Grain refined and basal textured surface produced by burnishing for improved corrosion performance of AZ31B Mg alloy, Corrosion Science, vol.57, pp.192-201, 2012.
DOI : 10.1016/j.corsci.2011.12.018

J. L. Clement and P. S. Jarett, Antibacterial Silver, Metal-Based Drugs, vol.1, issue.5-6, pp.467-482, 1994.
DOI : 10.1155/MBD.1994.467

F. Witte, N. Hort, and C. Vogt, Degradable biomaterials based on magnesium corrosion, Current Opinion in Solid State and Materials Science, vol.12, issue.5-6, pp.63-72, 2008.
DOI : 10.1016/j.cossms.2009.04.001

URL : http://www.hzg.de/imperia/md/content/gkss/zentrale_einrichtungen/bibliothek/journals/2009/Witte-curopsolstatematsci.pdf

B. Langelier, X. Wang, and S. Esmaeili, Evolution of precipitation during non-isothermal ageing of an Mg???Ca???Zn alloy with high Ca content, Materials Science and Engineering: A, vol.538, pp.246-251, 2012.
DOI : 10.1016/j.msea.2012.01.038

H. Alemohammad, O. Aminfar, and E. Toyserkani, Morphology and microstructure analysis of nano-silver thin films deposited by laser-assisted maskless microdeposition, Journal of Micromechanics and Microengineering, vol.18, issue.11, 2008.
DOI : 10.1088/0960-1317/18/11/115015

M. O. Pekguleryuz, Current developments in wrought magnesium alloys," in Advances in wrought magnesium alloys -Fundamentals of processing, properties and applications, 2012.

S. K. Sahoo, R. K. Sabat, and S. Panda, Mechanical Property of Pure Magnesium: From Orientation Perspective Pertaining to Deviation from Basal Orientation, Journal of Materials Engineering and Performance, vol.58, issue.514, pp.2346-2353, 2015.
DOI : 10.1007/s11665-015-1522-1

M. R. Bar, Twi " " i " g a " d the ductility " f mag " esium all " ys ?art I? Te " si " " twins, Materials Science and Engineering A, vol.464, pp.1-7, 2007.

S. R. Agnew, J. A. Horton, and T. M. Lillo, Enhanced ductility in strongly textured magnesium produced by equal channel angular processing, Scripta Materialia, vol.50, issue.3, pp.377-381, 2004.
DOI : 10.1016/j.scriptamat.2003.10.006

J. Koike, R. Ohyama, and T. Kobayashi, Grain-Boundary Sliding in AZ31 Magnesium Alloys at Room Temperature to 523 K, MATERIALS TRANSACTIONS, vol.44, issue.4, pp.445-451, 2003.
DOI : 10.2320/matertrans.44.445

URL : http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.460.1411

S. E. Harandi, M. Mirshahi, and S. Koleini, Effect of calcium content on the microstructure, hardness and in-vitro corrosion behavior of biodegradable Mg-Ca binary alloy, Materials Research, vol.16, issue.1, pp.11-18, 2013.
DOI : 10.1590/S1516-14392012005000151

J. W. Seong and W. J. Kim, Development of biodegradable Mg???Ca alloy sheets with enhanced strength and corrosion properties through the refinement and uniform dispersion of the Mg2Ca phase by high-ratio differential speed rolling, Acta Biomaterialia, vol.11, pp.531-542, 2015.
DOI : 10.1016/j.actbio.2014.09.029

W. Kim, J. Kim, and J. Lee, Influence of Ca on the corrosion properties of magnesium for biomaterials, Materials Letters, vol.62, issue.25, pp.4146-4148, 2008.
DOI : 10.1016/j.matlet.2008.06.028

Y. S. Jeong and W. J. Kim, Enhancement of mechanical properties and corrosion resistance of Mg???Ca alloys through microstructural refinement by indirect extrusion, Corrosion Science, vol.82, pp.392-403, 2014.
DOI : 10.1016/j.corsci.2014.01.041

N. Birbilis, K. D. Ralston, and S. Virtanen, Grain character influences on corrosion of ECAPed pure magnesium, Corrosion Engineering, Science and Technology, vol.43, issue.4, pp.224-230, 2010.
DOI : 10.1016/j.intermet.2009.03.009

M. Alvarez-lopez, M. D. Pereda, and J. A. Valle, Corrosion behaviour of AZ31 magnesium alloy with different grain sizes in simulated biological fluids???, Acta Biomaterialia, vol.6, issue.5, pp.1763-1771, 2010.
DOI : 10.1016/j.actbio.2009.04.041

N. N. Aung and W. Zhou, Effect of grain size and twins on corrosion behaviour of AZ31B magnesium alloy, Corrosion Science, vol.52, issue.2, pp.589-594, 2010.
DOI : 10.1016/j.corsci.2009.10.018

K. U. Kainer, Magnesium Alloys and Technologies, 2006.
DOI : 10.1002/3527602046

G. L. Song, R. Mishra, and Z. Q. Xu, Crystallographic orientation and electrochemical activity of AZ31 Mg alloy, Electrochemistry Communications, vol.12, issue.8, pp.1009-1012, 2010.
DOI : 10.1016/j.elecom.2010.05.011

G. Song and Z. Xu, Crystal orientation and electrochemical corrosion of polycrystalline Mg, Corrosion Science, vol.63, pp.100-112, 2012.
DOI : 10.1016/j.corsci.2012.05.019

M. Ben-haroush, G. Ben-hamu, and D. Eliezer, The relation between microstructure and corrosion behavior of AZ80 Mg alloy following different extrusion temperatures, Corrosion Science, vol.50, issue.6, pp.1766-1778, 2008.
DOI : 10.1016/j.corsci.2008.03.003

J. D. Loveless, H. Alemohammad, and J. Li, Laser-assisted maskless microdeposition of silver nano-particles on a magnesium substrate, Materials Letters, vol.63, issue.16, pp.1397-1400, 2009.
DOI : 10.1016/j.matlet.2009.03.015

F. Dullien, Porous Media -Fluid Transport and Pore Structure, 2012.

T. G. Lei, J. N. Calata, and G. Lu, Low-Temperature Sintering of Nanoscale Silver Paste for Attaching Large-Area <formula formulatype="inline"><tex Notation="TeX">$({&#x003E;}100~{\rm mm}^{2})$</tex></formula> Chips, IEEE Transactions on Components and Packaging Technologies, vol.33, issue.1, pp.98-104, 2010.
DOI : 10.1109/TCAPT.2009.2021256

K. Park, D. Seo, and J. Lee, Conductivity of silver paste prepared from nanoparticles, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.313, issue.314, pp.313-314, 2008.
DOI : 10.1016/j.colsurfa.2007.04.147

J. R. Greer and R. A. Street, Thermal cure effects on electrical performance of nanoparticle silver inks, Acta Materialia, vol.55, issue.18, pp.6345-6349, 2007.
DOI : 10.1016/j.actamat.2007.07.040

Z. Z. Fang and H. Wang, Densification and grain growth during sintering of nanosized particles, International Materials Reviews, vol.89, issue.72, pp.326-352, 2008.
DOI : 10.1016/S0965-9773(97)00195-5

E. Foroozmehr, H. Alemohammad, and X. Wan, Laser-assisted surface patterning of magnesium with silver nanoparticles: synthesis, characterization and modelling, Journal of Physics D: Applied Physics, vol.44, issue.49, 2011.
DOI : 10.1088/0022-3727/44/49/495305

E. Jabari, S. Tong, and A. Azhari, Non-planar interconnects in double-sided flexible Cu-PET substrates using a laser-assisted maskless microdeposition process: 3D finite element modeling and experimental analysis, Optics and Lasers in Engineering, vol.54, pp.117-127, 2014.
DOI : 10.1016/j.optlaseng.2013.10.002

. Roskill, Magnesium Metal: Global Industry Markets and Outlook 2012, 2012.

Z. Yang, J. P. Li, and J. X. Zhang, Review on Research and Development of Magnesium Alloys, Acta Metallurgica Sinica (English Letters), vol.21, issue.5, pp.313-328, 2008.
DOI : 10.1016/S1006-7191(08)60054-X

I. Polmear, The light metals," in Light Alloys (Fourth Edition) -From Traditional Alloys to Nanocrystals, 2005.

A. Azushima, R. Kopp, and A. Korhonen, Severe plastic deformation (SPD) processes for metals, CIRP Annals - Manufacturing Technology, vol.57, issue.2, pp.716-735, 2008.
DOI : 10.1016/j.cirp.2008.09.005

R. Abbaschian, L. Abbaschian, and R. , Reed-Hill, Physical metallurgy principles, Fourth edition, 2008.

R. Kaibyshev, M. Barnett, and C. Bettles, Advances in wrought magnesium alloys - Fundamentals of processing, properties and applications, 2012.

M. Mabuchi, H. Iwasaki, and K. Higashi, Low Temperature Superplasticity of Magnesium Alloys Processed by ECAE, Materials Science Forum, vol.243, issue.245, pp.243-245, 1997.
DOI : 10.4028/www.scientific.net/MSF.243-245.547

E. O. Hall, The Deformation and Ageing of Mild Steel: III Discussion of Results, Proceedings of the Physical Society, pp.747-752, 1951.
DOI : 10.1088/0370-1301/64/9/303

R. M. Aikin, The mechanical properties of in-situ composites, JOM, vol.162, issue.8, pp.35-39, 1997.
DOI : 10.1007/BF02914400

D. Orlov, K. D. Ralston, and N. Birbilis, Enhanced corrosion resistance of Mg alloy ZK60 after processing by integrated extrusion and equal channel angular pressing, Acta Materialia, vol.59, issue.15
DOI : 10.1016/j.actamat.2011.06.033

J. F. Nie, Effects of precipitate shape and orientation on dispersion strengthening in magnesium alloys, Scripta Materialia, vol.48, issue.8, pp.1009-1015, 2003.
DOI : 10.1016/S1359-6462(02)00497-9

I. Polmear, Grades and alloys," in ASM Specialty handbook -Magnesium and Magnesium Alloys, 1999.

J. Crolet and G. Béranger, Corrosion en milieu aqueux des métaux et alliages," in Corrosion et vieillissement: phénomènes et mécanismes.? Tech " iques de l'I " ge " ieur, 1998.

E. E. Stansbury and R. A. Buchanan, Fundamentals of Electrochemical Corrosion, 2000.

G. L. Song and A. Atrens, Corrosion Mechanisms of Magnesium Alloys, Advanced Engineering Materials, vol.1, issue.1, pp.11-33, 1999.
DOI : 10.1002/(SICI)1527-2648(199909)1:1<11::AID-ADEM11>3.0.CO;2-N

G. Song and A. Atrens, Understanding Magnesium Corrosion???A Framework for Improved Alloy Performance, Advanced Engineering Materials, vol.5, issue.12, pp.837-858, 2003.
DOI : 10.1002/adem.200310405

E. Gali, Part 1 -Electrochemical fundamentals and active-passive corrosion behaviors," in Corrosion Resistance of Aluminum and Magnesium Alloys: Understanding, Performance, and Testing, 2010.

I. Polmear, Magnesium alloys and applications, Materials Science and Technology, vol.24, issue.9, pp.1-16, 1994.
DOI : 10.1179/imr.1993.38.3.138

G. L. Song, Corrosion behavior and prevention strategies for magnesium (Mg) alloys," in Corrosion Prevention of Magnesium Alloys, 2013.

P. Kurze, Corrosion and Corrosion Protection of Magnesium, Magnesium -Alloys and Technologies, p.13, 2004.
DOI : 10.1002/3527602046.ch13

R. Zeng, J. Zhang, and W. Huang, Review of studies on corrosion of magnesium alloys, Transactions of Nonferrous Metals Society of China, vol.16, pp.763-771, 2006.
DOI : 10.1016/S1003-6326(06)60297-5

E. Gali, Part 3 -Properties, use, and performance of magnesium and its alloys," in Corrosion Resistance of Aluminum and Magnesium Alloys Understanding, Performance, 2010.

G. L. Makar and J. Kruger, Corrosion of magnesium, International Materials Reviews, vol.41, issue.4, pp.138-153, 1993.
DOI : 10.1016/0025-5416(85)90328-3

S. Abela, Protective Coatings for Magnesium Alloys," in Magnesium Alloys - Corrosion and Surface Treatments, p.10, 2011.

I. Polmear, Magnesium alloys in Light Alloys (Fourth Edition) -From Traditional Alloys to Nanocrystals, 2005.

H. Hornberger, S. Virtanen, and A. R. Boccaccini, Biomedical coatings on magnesium alloys ??? A review, Acta Biomaterialia, vol.8, issue.7, pp.2442-2455, 2012.
DOI : 10.1016/j.actbio.2012.04.012

K. Y. Chiu, M. H. Wong, and F. T. Cheng, Characterization and corrosion studies of fluoride conversion coating on degradable Mg implants, Surface and Coatings Technology, vol.202, issue.3, pp.590-598, 2007.
DOI : 10.1016/j.surfcoat.2007.06.035

M. Carboneras, M. C. Garcia-alonso, and M. L. Escudero, Biodegradation kinetics of modified magnesium-based materials in cell culture medium, Corrosion Science, vol.53, issue.4, pp.1433-1439, 2011.
DOI : 10.1016/j.corsci.2011.01.014

H. M. Wong, K. W. Yeung, and K. O. Lam, A biodegradable polymer-based coating to control the performance of magnesium alloy orthopaedic implants, Biomaterials, vol.31, issue.8, pp.2084-2096, 2010.
DOI : 10.1016/j.biomaterials.2009.11.111

R. A. Draughn and Y. H. An, Mechanical properties of bone," in Mechanical testing of bone and the bone-implant interface, 1999.

W. Jee and S. Cowin, Integrated Bone Tissue Physiology, Bone mechanics handbook, 2001.
DOI : 10.1201/b14263-3

J. B. Park and R. S. Lakes, An introduction to biomaterials -Second edition, 1992.

B. Cummings, Bone fracture healing process, 2004.

W. R. Fordham, S. Redmond, and A. Westerland, Silver as a Bactericidal Coating for Biomedical Implants, Surface and Coatings Technology, vol.253, pp.52-57, 2014.
DOI : 10.1016/j.surfcoat.2014.05.013

R. Marsell and T. A. Einhorn, The biology of fracture healing, Injury, vol.42, issue.6, pp.551-555, 2011.
DOI : 10.1016/j.injury.2011.03.031

M. P. Sealy and Y. Guo, Fabrication and Characterization of Surface Texture for Bone Ingrowth by Sequential Laser Peening Biodegradable Orthopedic Magnesium-Calcium Implants, Journal of Medical Devices, vol.5, issue.1, 2011.
DOI : 10.1115/1.4003117

Y. Yun, Z. Dong, and D. Yang, Biodegradable Mg corrosion and osteoblast cell culture studies, Materials Science and Engineering: C, vol.29, issue.6, pp.1814-1821, 2009.
DOI : 10.1016/j.msec.2009.02.008

N. T. Kirkland and N. Birbilis, Developments in Mg-based Alloys for Biomaterials, Magnesium Biomaterials -Design, Testing, and Best Practice, 2013.
DOI : 10.1007/978-3-319-02123-2_4

M. Moravej and D. Mantovani, Biodegradable Metals for Cardiovascular Stent Application: Interests and New Opportunities, International Journal of Molecular Sciences, vol.12, issue.12, pp.4250-4270, 2011.
DOI : 10.3390/ijms12074250

URL : http://doi.org/10.3390/ijms12074250

G. O. Hofmann, Biodegradable implants in traumatology: a review on the state-of-the-art, Archives of Orthopaedic and Trauma Surgery, vol.18, issue.Suppl 237, pp.123-132, 1995.
DOI : 10.1007/BF00443385

C. K. Seal, K. Vince, and M. A. Hodgson, Biodegradable surgical implants based on magnesium alloys ??? A review of current research, IOP Conf. Series: Materials Science and Engineering, 2009.
DOI : 10.1088/1757-899X/4/1/012011

H. S. Brar, J. Wong, and M. V. Manuel, Investigation of the mechanical and degradation properties of Mg???Sr and Mg???Zn???Sr alloys for use as potential biodegradable implant materials, Journal of the Mechanical Behavior of Biomedical Materials, vol.7, pp.87-95, 2012.
DOI : 10.1016/j.jmbbm.2011.07.018

J. Kubásek, D. V-"-jt?ch, and J. , Structure, mechanical properties, corrosion behavior and cytotoxicity of biodegradable Mg???X (X=Sn, Ga, In) alloys, Materials Science and Engineering: C, vol.33, issue.4, pp.2421-2432, 2013.
DOI : 10.1016/j.msec.2013.02.005

A. L. Boskey, Bone Mineralization, Bone Mechanics Handbook -Second Edition, 2001.
DOI : 10.1201/b14263-7

Z. Li, X. Gu, and S. Lou, The development of binary Mg???Ca alloys for use as biodegradable materials within bone, Biomaterials, vol.29, issue.10, pp.1329-1344, 2008.
DOI : 10.1016/j.biomaterials.2007.12.021

B. L. Mordike and P. Lukac, Physical Metallurgy, Magnesium Technology - Metallurgy, 2006.
DOI : 10.1007/3-540-30812-1_3

D. J. Zuliani and B. Cloasset, Magnesium-calcium alloys for debismuthizing lead, 1991.

P. Vilars and K. Cenzual, Pearson's Crystal Data: Crystal Structure Database for Inorganic Compounds, p.9, 2008.

J. F. Nie and B. C. Muddle, Precipitation hardening of Mg-Ca(-Zn) alloys, Scripta Materialia, vol.37, issue.10, pp.1475-1481, 1997.
DOI : 10.1016/S1359-6462(97)00294-7

A. Drynda, T. Hassel, and R. Hoehn, Development and biocompatibility of a novel corrodible fluoride-coated magnesium-calcium alloy with improved degradation kinetics and adequate mechanical properties for cardiovascular applications, Journal of Biomedical Materials Research Part A, vol.8, issue.17, pp.763-775, 2010.
DOI : 10.1002/jbm.a.32582

Y. Murakoshi, K. Kikuchi, and M. Katoh, Fabrication and Property of Degradable Magnesium-Calcium Alloy Composites with Hydroxyapatite, IFMBE Proceedings, pp.1226-1229, 2010.
DOI : 10.1007/978-3-642-14515-5_311

H. Han, Y. Minghui, and H. Seok, The modification of microstructure to improve the biodegradation and mechanical properties of a biodegradable Mg alloy, Journal of the Mechanical Behavior of Biomedical Materials, vol.20, pp.54-60, 2013.
DOI : 10.1016/j.jmbbm.2012.12.007

M. Furukawa, Z. Horita, and M. Nemoto, Review -Processing of metals by equalchannel angular pressing, Journal of Materials Science, pp.2835-2843, 2001.

Y. Iwahashia, Z. Horita, and M. Nemoto, The process of grain refinement in equal-channel angular pressing, Acta Materialia, vol.46, issue.9, pp.3317-3331, 1998.
DOI : 10.1016/S1359-6454(97)00494-1

S. Biswas, S. S. Dhinwal, and S. Suwas, Room-temperature equal channel angular extrusion of pure magnesium, Acta Materialia, vol.58, issue.9, pp.3247-3261, 2010.
DOI : 10.1016/j.actamat.2010.01.051

K. Matsubara, Y. Miyahara, and Z. Horita, Developing superplasticity in a magnesium alloy through a combination of extrusion and ECAP, Acta Materialia, vol.51, issue.11, pp.3073-3084, 2003.
DOI : 10.1016/S1359-6454(03)00118-6

R. Lapovok, Y. Estrin, and M. V. Popov, Enhanced Superplasticity in a Magnesium Alloy Processed by Equal-Channel Angular Pressing with a Back-Pressure, Advanced Engineering Materials, vol.13, issue.1, pp.429-433, 2008.
DOI : 10.1002/adem.200700363

A. Mussi, J. J. Blandin, and L. Salvo, Resistance to strain-induced damage of an ultrafine-grained magnesium alloy deformed in superplastic conditions, Acta Materialia, vol.54, issue.14, pp.3801-3809, 2006.
DOI : 10.1016/j.actamat.2006.04.011

URL : https://hal.archives-ouvertes.fr/hal-00141849

M. Furukawa, Y. Iwahashi, and Z. Horita, The shearing characteristics associated with equal-channel angular pressing, Materials Science and Engineering: A, vol.257, issue.2, pp.328-332, 1998.
DOI : 10.1016/S0921-5093(98)00750-3

M. Nemoto, Z. Horita, and M. Furukawa, Microstructural Evolution for Superplasticity Using Equal-Channel Angular Pressing, Materials Science Forum, vol.304, issue.306, pp.304-306, 1999.
DOI : 10.4028/www.scientific.net/MSF.304-306.59

R. B. Figueiredo and T. G. Langdon, Principles of grain refinement in magnesium alloys processed by equal-channel angular pressing, Journal of Materials Science, vol.434, issue.422, pp.4758-4762, 2009.
DOI : 10.1007/s10853-009-3725-z

Y. T. Zhu and T. C. Lowe, Observations and issues on mechanisms of grain refinement during ECAP process, Materials Science and Engineering: A, vol.291, issue.1-2, pp.46-53, 2000.
DOI : 10.1016/S0921-5093(00)00978-3

Z. Horita, K. Matsubara, and K. Makii, A two-step processing route for achieving a superplastic forming capability in dilute magnesium alloys, Scripta Materialia, vol.47, issue.4, pp.255-260, 2002.
DOI : 10.1016/S1359-6462(02)00135-5

K. Matsubara, Y. Miyahara, and Z. Horita, Achieving enhanced ductility in a dilute magnesium alloy through severe plastic deformation, Metallurgical and materials transactions A, pp.1735-1744, 2004.
DOI : 10.1007/s11661-004-0082-z

B. Beausir, S. Suwas, and L. S. Toth, Analysis of texture evolution in magnesium during equal channel angular extrusion, Acta Materialia, vol.56, issue.2, pp.200-214, 2008.
DOI : 10.1016/j.actamat.2007.09.032

W. J. Kim, S. I. Hong, and Y. S. Kim, Texture development and its effect on mechanical properties of an AZ61 Mg alloy fabricated by equal channel angular pressing, Acta Materialia, vol.51, issue.11, pp.3293-3307, 2003.
DOI : 10.1016/S1359-6454(03)00161-7

Y. Yoshida, L. Cisar, and S. Kamado, Effect of Microstructural Factors on Tensile Properties of an ECAE-Processed AZ31 Magnesium Alloy, MATERIALS TRANSACTIONS, vol.44, issue.4, pp.468-475, 2003.
DOI : 10.2320/matertrans.44.468

E. Zhang and L. Yang, Microstructure, mechanical properties and bio-corrosion properties of Mg???Zn???Mn???Ca alloy for biomedical application, Materials Science and Engineering: A, vol.497, issue.1-2, pp.111-118, 2008.
DOI : 10.1016/j.msea.2008.06.019

Y. Wan, G. Xiong, and H. Luo, Preparation and characterization of a new biomedical magnesium???calcium alloy, Materials & Design, vol.29, issue.10, pp.2034-2037, 2008.
DOI : 10.1016/j.matdes.2008.04.017

N. T. Kirkland, N. Birbilis, and J. Walker, In-vitro dissolution of magnesium-calcium binary alloys: Clarifying the unique role of calcium additions in bioresorbable magnesium implant alloys, Journal of Biomedical Materials Research Part B: Applied Biomaterials, vol.40, issue.1, pp.91-100, 2010.
DOI : 10.1002/jbm.b.31687

N. T. Kirkland, J. Lespagnol, and N. Birbilis, A survey of bio-corrosion rates of magnesium alloys, Corrosion Science, vol.52, issue.2, pp.287-291, 2010.
DOI : 10.1016/j.corsci.2009.09.033

H. R. Bakhsheshi-rad, M. H. Idris, and M. R. Kadir, Microstructure analysis and corrosion behavior of biodegradable Mg?Ca, Materials and Design, vol.33, pp.88-97, 2012.

K. V. Kutniy, I. I. Papirov, and M. A. Tikhonovsky, Influence of grain size on mechanical and corrosion properties of magnesium alloy for medical implants, Materialwissenschaft und Werkstofftechnik, vol.40, issue.4, pp.242-246, 2009.
DOI : 10.1002/mawe.200900434

M. H. Idris, H. Jafari, and S. E. Harandi, Characteristics of As-Cast and Forged Biodegradable Mg-Ca Binary Alloy Immersed in Kokubo Simulated Body Fluid, Advanced Materials Research, pp.301-306, 2012.

N. T. Kirkland, N. Birbilis, and M. P. Staiger, Assessing the corrosion of biodegradable magnesium implants: A critical review of current methodologies and their limitations, Acta Biomaterialia, vol.8, issue.3, pp.925-936, 2012.
DOI : 10.1016/j.actbio.2011.11.014

B. M. Kannan and R. K. Singh-raman, In vitro degradation and mechanical integrity of calcium-containing magnesium alloys in modified-simulated body fluid, Biomaterials, vol.29, issue.15, pp.2306-2314, 2008.
DOI : 10.1016/j.biomaterials.2008.02.003

W. A. Badawy, N. H. Hilala, and M. El-rabiee, Electrochemical behavior of Mg and some Mg alloys in aqueous solutions of different pH, Electrochimica Acta, vol.55, issue.6, pp.1880-1887, 2010.
DOI : 10.1016/j.electacta.2009.10.083

A. S. Bondarenko, G. A. Ragoisha, . Progress-in-chemometrics-research, A. L. Pomerantsev, and . Ed, The program is available online at http, 2005.

L. Dupuy, Comportement mécanique d'un alliage d'aluminium hyper-déformé, 2000.

A. Mussi, Affinage de la microstructure et amélioration des propriétés mécaniques d'u " alliage de mag " ésium par hyper-déformations, 2003.

S. E. Harandi, M. Mirshahi, and S. Koleini, Effect of calcium content on the microstructure, hardness and in-vitro corrosion behavior of biodegradable Mg-Ca binary alloy, Materials Research, vol.16, issue.1, pp.11-18, 2013.
DOI : 10.1590/S1516-14392012005000151

Y. N. Wang and J. C. Huang, The role of twinning and untwinning in yielding behavior in hot-extruded Mg???Al???Zn alloy, Acta Materialia, vol.55, issue.3, pp.897-905, 2007.
DOI : 10.1016/j.actamat.2006.09.010

N. T. Kirkland, M. P. Staiger, and D. Nisbet, Performance-driven design of Biocompatible Mg alloys, JOM, vol.52, issue.9, pp.28-34, 2011.
DOI : 10.1007/s11837-011-0089-z

Y. Zong, G. Yuan, and X. Zhang, Comparison of biodegradable behaviors of AZ31 and Mg?Nd?Zn?Zr all " ys i " Ha " k's, Materials Science and Engineering B, pp.395-401, 2012.

M. Anik and G. Celikten, Analysis of the electrochemical reaction behavior of alloy AZ91 by EIS technique in H3PO4/KOH buffered K2SO4 solutions, Corrosion Science, vol.49, issue.4, pp.1878-1894, 2007.
DOI : 10.1016/j.corsci.2006.10.016

G. Baril, G. Galicia, and C. Deslouis, An Impedance Investigation of the Mechanism of Pure Magnesium Corrosion in Sodium Sulfate Solutions, Journal of The Electrochemical Society, vol.154, issue.2, pp.108-113, 2007.
DOI : 10.1149/1.2401056

URL : https://hal.archives-ouvertes.fr/hal-00806016

Z. Wen, C. Wu, and C. Dai, Corrosion behaviors of Mg and its alloys with different Al contents in a modified simulated body fluid, Journal of Alloys and Compounds, vol.488, issue.1, pp.392-399, 2009.
DOI : 10.1016/j.jallcom.2009.08.147

R. Pinto, M. G. Ferreira, and M. J. Carmezim, The corrosion behaviour of rare-earth containing magnesium alloys in borate buffer solution, Electrochimica Acta, vol.56, issue.3, pp.1535-1545, 2011.
DOI : 10.1016/j.electacta.2010.09.081

X. N. Gu, N. Li, and W. R. Zhou, Corrosion resistance and surface biocompatibility of a microarc oxidation coating on a Mg???Ca alloy, Acta Biomaterialia, vol.7, issue.4, pp.1880-1889, 2011.
DOI : 10.1016/j.actbio.2010.11.034

C. W. Chung, R. G. Ding, and Y. L. Chiu, Effect of ECAP on microstructure and mechanical properties of cast AZ91 magnesium alloy, Journal of Physics: Conference Series, vol.241, pp.1-4, 2010.
DOI : 10.1088/1742-6596/241/1/012101

M. Y. Zheng, X. G. Qiao, and S. W. Xu, In-situ quasicrystal-reinforced magnesium matrix composite processed by equal channel angular extrusion (ECAE), Journal of Materials Science, vol.3, issue.422, pp.2587-2590, 2005.
DOI : 10.1007/s10853-005-2081-x

Y. Watanabe, P. D. Sequeira, and O. Sitdikov, Effect of Processing Route on Microstructure and Texture Development in ECAP of Al-Ti Alloy, Materials Science Forum, vol.561, issue.565, pp.561-565, 2007.
DOI : 10.4028/www.scientific.net/MSF.561-565.251

K. Oh-ishi, Y. Hashi, and A. Sadakata, Microstructural control of an Al-Mg-Si alloy using Equal-Channel Angular Pression, Materials Science Forum, pp.333-338, 2002.

M. Zha, Y. Li, and R. H. Mathiesen, Dispersion of soft Bi particles and grain refinement of matrix in an Al???Bi alloy by equal channel angular pressing, Journal of Alloys and Compounds, vol.605, pp.131-136, 2014.
DOI : 10.1016/j.jallcom.2014.03.126

G. Min, H. Cui, and Q. Lu, Grain Refinement and Dispersion Precipitation of I-Phase in Mg-Zn-Y Alloy Processed by ECAP, Materials Science Forum, vol.667, issue.669, pp.667-669, 2010.
DOI : 10.4028/www.scientific.net/MSF.667-669.593

M. Barnett, M. R. Barnett, and C. Betles, Twinning and its role in wrought magnesium alloys," in Advances in wrought magnesium alloys -Fundamentals of processing, properties and applications, 2012.

R. G. Sambasiva and Y. V. Prasad, Grain boundary strengthening in strongly textured magnesium produced by hot rolling, Metallurgical Transactions A, vol.13, pp.19822219-2226

P. Haden, I. L. Dillamore, and D. J. Stratford, Texture control and the yield anisotropy of plane strain magnesium extrusion, Texture, vol.1, pp.17-29, 1972.

Y. Uematsu, K. Tokaji, and M. Kamakura, Effect of extrusion conditions on grain refinement and fatigue behaviour in magnesium alloys, Materials Science and Engineering: A, vol.434, issue.1-2, pp.131-140, 2006.
DOI : 10.1016/j.msea.2006.06.117

S. R. Agnew, M. H. Yo, and C. N. Tome, Application of texture simulation to understanding mechanical behavior of Mg and solid solution alloys containng Li or Y

T. Al-samman and G. Gottstein, Dynamic recrystallization during high temperature deformation of magnesium, Materials Science and Engineering: A, vol.490, issue.1-2, pp.411-420, 2008.
DOI : 10.1016/j.msea.2008.02.004

W. M. Gan, M. Y. Zheng, and H. Chang, Microstructure and tensile property of the ECAPed pure magnesium, Journal of Alloys and Compounds, vol.470, issue.1-2, pp.256-262, 2009.
DOI : 10.1016/j.jallcom.2008.02.030

A. Trampuz and A. F. Widmer, Infections associated with orthopedic implants, Current Opinion in Infectious Diseases, vol.19, issue.4, pp.349-356, 2006.
DOI : 10.1097/01.qco.0000235161.85925.e8

P. Zhang, Z. Zhang, and W. Li, Antibacterial TiO2 Coating Incorporating Silver Nanoparticles by Microarc Oxidation and Ion Implantation, Journal of Nanomaterials, 2013.
DOI : 10.1155/2013/542878

URL : http://doi.org/10.1155/2013/542878

L. Zhao, P. K. Chu, and Y. Zhang, Antibacterial coatings on titanium implants, Journal of Biomedical Materials Research Part B: Applied Biomaterials, vol.437, issue.104, pp.470-480, 2009.
DOI : 10.1002/jbm.b.31463

E. M. Schoenfisch and M. H. Hetrick, Reducing implant-related infections: active release strategies, Chemical Society Reviews, vol.35, pp.780-789, 2006.

J. S. Kim, E. Kuk, and K. N. Yu, Antimicrobial effects of silver nanoparticles, Nanomedicine: Nanotechnology, Biology and Medicine, vol.3, issue.1, pp.95-101, 2007.
DOI : 10.1016/j.nano.2006.12.001

D. Lee, R. E. Cohen, and M. F. Rubner, Antibacterial Properties of Ag Nanoparticle Loaded Multilayers and Formation of Magnetically Directed Antibacterial Microparticles, Langmuir, vol.21, issue.21, pp.9651-9659, 2005.
DOI : 10.1021/la0513306

M. Bosetti, A. Masse, and E. Tobin, Silver coated materials for external fixation devices: in vitro biocompatibility and genotoxicity, Biomaterials, vol.23, issue.3, pp.887-892, 2002.
DOI : 10.1016/S0142-9612(01)00198-3

M. Lihe, W. Yulin, and W. Yizao, Corrosion Resistance of Ag-ion Implanted Mg-Ca-Zn Alloys in SBF, Rare Metal Materials and Engineering, vol.39, issue.12, pp.2075-2078, 2010.
DOI : 10.1016/S1875-5372(11)60002-7

H. Zhao and J. Cui, Electroless plating of silver on AZ31 magnesium alloy substrate, Surface and Coatings Technology, vol.201, issue.8, pp.4512-4517, 2007.
DOI : 10.1016/j.surfcoat.2006.09.044

A. Ewald, S. K. Glückermann, and R. Thull, Antimicrobial titanium/silver PVD coatings on titanium, BioMedical Engineering OnLine, vol.5, 2006.

J. M. Schakenraad, Biology, biochemestry, and medecine -Some background concepts," in Biomaterials science -An introduction to materials in medecine, 1996.

D. Eglin, K. Rohde, and P. Roach, Modern biomaterials: a review -Bulk properties and implications of surface modifications, Journal of Materials Science: Materials in Medicine, vol.18, pp.1263-1277, 2007.

A. I. Teixeira, G. A. Mckie, and J. D. Foley, The effect of environmental factors on the response of human corneal epithelial cells to nanoscale substrate topography, Biomaterials, vol.27, issue.21, pp.3945-3954, 2006.
DOI : 10.1016/j.biomaterials.2006.01.044

A. B. Novaes, S. L. De-souza, and R. R. De-barros, Influence of implant surfaces on osseointegration, Brazilian Dental Journal, vol.21, issue.6, pp.471-481, 2010.
DOI : 10.1590/S0103-64402010000600001

A. Cunha, Multiscale Femtosecond Laser Surface Texturing of Titanium and Titanium Alloys for Dental and Orthopaedic Implants
URL : https://hal.archives-ouvertes.fr/tel-01215468

S. Puckett, R. Pareta, and T. J. Webster, Nano rough micron patterned titanium for directing osteoblast morphology and adhesion, Internation Journal of Nanomedecine, vol.3, pp.229-241, 2008.

X. Li, J. Huang, and M. J. Edirisinghe, Novel patterning of nano-bioceramics: template-assisted electrohydrodynamic atomization spraying, Journal of The Royal Society Interface, vol.28, issue.12, pp.253-257, 2008.
DOI : 10.1002/jbm.820281213

G. Munir, G. Koller, and L. D. Silvio, The pathway to intelligent implants: osteoblast response to nano silicon-doped hydroxyapatite patterning, Journal of The Royal Society Interface, vol.94, issue.10, pp.678-688, 2011.
DOI : 10.1529/biophysj.107.125278

M. Zenou, O. Ermak, and A. Saar, Laser sintering of copper nanoparticles, Journal of Physics D: Applied Physics, vol.47, issue.2, 2014.
DOI : 10.1088/0022-3727/47/2/025501

E. F. Rauch and M. Véron, Automated crystal orientation and phase mapping in TEM, Materials Characterization, vol.98, pp.1-9, 2014.
DOI : 10.1016/j.matchar.2014.08.010

URL : https://hal.archives-ouvertes.fr/hal-01121290

K. Lu, W. Li, and B. Chen, Sintering of Porous Materials," in Sintering -Mechanisms of Convention, Nanodensification and Field, Assisted Processes, 2013.

H. Pan, F. Pan, and R. Yang, Thermal and electrical conductivity of binary magnesium alloys, Journal of Materials Science, vol.11, issue.3, pp.2107-3124, 2014.
DOI : 10.1007/s10853-013-8012-3

E. D. Palik, Handbook of Optical Constants of Solids II, 1991.

W. E. Forsythe, Smithsonian physical tables. 9th rev, 1964.

X. Cao, M. Jahazi, and J. P. Immrigeon, A review of laser welding techniques for magnesium alloys, Journal of Materials Processing Technology, vol.171, issue.2, pp.188-204, 2006.
DOI : 10.1016/j.jmatprotec.2005.06.068

F. Cernuschi, S. Ahmaniemi, and P. Vuoristo, Modelling of thermal conductivity of porous materials: application to thick thermal barrier coatings, Journal of the European Ceramic Society, vol.24, issue.9, pp.2657-2667, 2004.
DOI : 10.1016/j.jeurceramsoc.2003.09.012

M. S. Brown and C. B. Arnold, Fundamentals of Laser-Material Interaction and Application to Multiscale Surface Modification, Laser Precision Microfabrication.: Springer Series in Materials Science, 2010.
DOI : 10.1007/978-3-642-10523-4_4

H. E. Bennett, J. M. Bennett, and E. J. Ashley, Verification of the Anomalous-Skin-Effect Theory for Silver in the Infrared, Physical Review, vol.165, issue.3, pp.755-764, 1968.
DOI : 10.1103/PhysRev.165.755

K. Kim, Y. Kim, and S. Jung, Microstructure and adhesion characteristics of a silver nanopaste screen-printed on Si substrate, Nanoscale Research Letters, vol.7, issue.1, pp.1-6, 2012.
DOI : 10.1186/1556-276X-7-49

O. Sitdikov and R. Kaibyshev, Dynamic Recrystallization in Pure Magnesium, MATERIALS TRANSACTIONS, vol.42, issue.9, pp.1928-1937, 2001.
DOI : 10.2320/matertrans.42.1928

P. Minarik, R. Kral, and M. Janecek, Effect of ECAP processing on corrosion resistance of AE21 and AE42 magnesium alloys, Applied Surface Science, vol.281, pp.44-48, 2013.
DOI : 10.1016/j.apsusc.2012.12.096

B. A. Shaw and R. C. Wolfe, Corrosion of Magnesium and Magnesium-Base Alloys, ASM Handbook -Corrosion: Materials.: ASM International, 2005.