). C. Brinker, G. W. Scherrer-stöber, W. Fink, A. Bohn, and E. , Sol-gel science: the physics and chemistry of Sol-Gel Processing, BIBLIOGRAPHIQUES J. Colloid Interface Sci, vol.69, issue.12, pp.62-69, 1968.

G. J. Soler-illia, C. Sanchez, B. Lebeau, and J. Patarin, Chemical Strategies To Design Textured Materials:?? from Microporous and Mesoporous Oxides to Nanonetworks and Hierarchical Structures, Chemical Reviews, vol.102, issue.11, pp.4093-4138, 2000.
DOI : 10.1021/cr0200062

Z. Wen, Q. Wang, Q. Zhang, and J. Li, In Situ Growth of Mesoporous SnO2 on Multiwalled Carbon Nanotubes: A Novel Composite with Porous-Tube Structure as Anode for Lithium Batteries, Advanced Functional Materials, vol.364, issue.15, pp.2772-2778, 2007.
DOI : 10.1002/adfm.200600739

T. Peng, D. Zhao, K. Dai, W. Shi, and K. Hirao, Synthesis of Titanium Dioxide Nanoparticles with Mesoporous Anatase Wall and High Photocatalytic Activity, The Journal of Physical Chemistry B, vol.109, issue.11, pp.4947-4952, 2005.
DOI : 10.1021/jp044771r

A. Galarneau, H. Cambon, F. Di-renzo, R. Ryoo, M. Choi et al., Microporosity and connections between pores in SBA-15 mesostructured silicas as a function of the temperature of synthesis, New Journal of Chemistry, vol.27, issue.1, pp.73-79, 2003.
DOI : 10.1039/b207378c

P. T. Tanev and T. Pinnavaia, A Neutral Templating Route to Mesoporous Molecular Sieves, Science, vol.267, issue.5199, pp.865-867, 1995.
DOI : 10.1126/science.267.5199.865

D. Zhao, P. Yang, N. Melosh, J. Feng, B. F. Chmelka et al., Continuous Mesoporous Silica Films with Highly Ordered Large Pore Structures, Advanced Materials, vol.10, issue.16, pp.1380-1385, 1998.
DOI : 10.1002/(SICI)1521-4095(199811)10:16<1380::AID-ADMA1380>3.0.CO;2-8

P. Yang, D. Zhao, D. I. Margolese, B. F. Chmelka, and G. D. Stucky, Block Copolymer Templating Syntheses of Mesoporous Metal Oxides with Large Ordering Lengths and Semicrystalline Framework, Chemistry of Materials, vol.11, issue.10, pp.2813-2826, 1999.
DOI : 10.1021/cm990185c

M. Faustini, L. Nicole, C. Boissière, P. Innocenzi, C. Sanchez et al., Hydrophobic, Antireflective, Self-Cleaning, and Antifogging Sol???Gel Coatings: An Example of Multifunctional Nanostructured Materials for Photovoltaic Cells, Chemistry of Materials, vol.22, issue.15, pp.4406-4413, 2010.
DOI : 10.1021/cm100937e

D. Zhao, Q. Huo, J. Feng, B. F. Chmelka, and G. D. Stucky, Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures, Journal of the American Chemical Society, vol.120, issue.24, pp.6024-6036, 1998.
DOI : 10.1021/ja974025i

H. Yang, A. Kuperman, N. Coombs, S. Mamiche-afara, and G. A. Ozin, Synthesis of oriented films of mesoporous silica on mica, Nature, vol.379, issue.6567, pp.703-705, 1996.
DOI : 10.1038/379703a0

C. J. Brinker, Y. Lu, A. Sellinger, and H. Fan, Evaporation-Induced Self-Assembly: Nanostructures Made Easy, Advanced Materials, vol.11, issue.7, pp.579-585, 1999.
DOI : 10.1002/(SICI)1521-4095(199905)11:7<579::AID-ADMA579>3.0.CO;2-R

D. Grosso, F. Cagnol, G. J. Soler-illia, A. A. De, E. L. Crepaldi et al., Fundamentals of Mesostructuring Through Evaporation-Induced Self-Assembly, Advanced Functional Materials, vol.14, issue.4, pp.309-322, 2004.
DOI : 10.1002/adfm.200305036

URL : https://hal.archives-ouvertes.fr/hal-00005435

C. Sanchez, L. Rozes, F. Ribot, C. Laberty-robert, D. Grosso et al., ???Chimie douce???: A land of opportunities for the designed construction of functional inorganic and hybrid organic-inorganic nanomaterials, Comptes Rendus Chimie, vol.13, issue.1-2, pp.3-39, 2010.
DOI : 10.1016/j.crci.2009.06.001

D. Grosso, F. Babonneau, P. Albouy, H. Amenitsch, A. R. Balkenende et al., An in Situ Study of Mesostructured CTAB???Silica Film Formation during Dip Coating Using Time-Resolved SAXS and Interferometry Measurements, Chemistry of Materials, vol.14, issue.2, pp.931-939, 2002.
DOI : 10.1021/cm011255u

D. Grosso, .. R. Balkenende, P. Albouy, A. Ayral, H. Amenitsch et al., Two-Dimensional Hexagonal Mesoporous Silica Thin Films Prepared from Block Copolymers:?? Detailed Characterization and Formation Mechanism, Chemistry of Materials, vol.13, issue.5, pp.1848-1856, 2001.
DOI : 10.1021/cm001225b

P. Innocenzi, L. Malfatti, T. Kidchob, S. Costacurta, P. Falcaro et al., Time-Resolved Simultaneous Detection of Structural and Chemical Changes during Self-Assembly of Mesostructured Films, The Journal of Physical Chemistry C, vol.111, issue.14, pp.5345-5350, 2007.
DOI : 10.1021/jp066566c

M. Faustini, B. Louis, P. A. Albouy, M. Kuemmel, and D. Grosso, Preparation of Sol???Gel Films by Dip-Coating in Extreme Conditions, The Journal of Physical Chemistry C, vol.114, issue.17, pp.7637-7645, 2010.
DOI : 10.1021/jp9114755

URL : https://hal.archives-ouvertes.fr/hal-00477806

N. Krins, M. Faustini, B. Louis, and D. Grosso, Films Obtained by Capillary Coating from Aqueous Solutions, Chemistry of Materials, vol.22, issue.23, pp.6218-6220, 2010.
DOI : 10.1021/cm102524u

M. Faustini, Nanopatterning through bottom-up approach; an alternative way for data storage device, pp.38-39, 2011.

M. Faustini, D. R. Ceratti, B. Louis, M. Boudot, P. Albouy et al., Engineering Functionality Gradients by Dip Coating Process in Acceleration Mode, ACS Applied Materials & Interfaces, vol.6, issue.19, pp.17102-17110, 2014.
DOI : 10.1021/am504770x

URL : https://hal.archives-ouvertes.fr/hal-01289937

H. Uchiyama, R. Sasaki, and H. Kozuka, Evaporation-driven self-organization of photoluminescent organic dye-doped silica-poly(vinylpyrrolidone) hybrid films prepared by low-speed dip-coating, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.453, pp.1-6, 2014.
DOI : 10.1016/j.colsurfa.2014.03.066

R. L. Davis, S. Jayaraman, P. M. Chaikin, and R. Register, Creating Controlled Thickness Gradients in Polymer Thin Films via Flowcoating, Langmuir, vol.30, issue.19, pp.5637-5644, 2014.
DOI : 10.1021/la501247x

M. Faustini, L. Nicole, C. Boissière, P. Innocenzi, C. Sanchez et al., Hydrophobic, Antireflective, Self-Cleaning, and Antifogging Sol???Gel Coatings: An Example of Multifunctional Nanostructured Materials for Photovoltaic Cells, Chemistry of Materials, vol.22, issue.15, pp.4406-4413, 2010.
DOI : 10.1021/cm100937e

M. K. Chaudhury and G. M. Whitesides, How to Make Water Run Uphill, Science, vol.256, issue.5063, pp.1539-1541, 1992.
DOI : 10.1126/science.256.5063.1539

H. D. Taylor, The Adjustment and Testing of Telescopes Objectives, 40) Rayleigh, L. Proc. London Math. Soc. 1879, pp.1-11, 1896.

F. Guillemot, Couches poreuses de silice structurées par des latex : structure, propriétés mécaniques et applications optiques, p.10, 2010.

). J. Krepelka, Jemna Mech. A Opt, pp.53-56, 1992.

P. B. Clapham and M. C. Hutley, Reduction of Lens Reflexion by the ???Moth Eye??? Principle, Nature, vol.11, issue.5414, pp.281-282, 1973.
DOI : 10.1038/244281a0

W. Min, B. Jiang, and P. Jiang, Bioinspired Self-Cleaning Antireflection Coatings, Advanced Materials, vol.11, issue.20, pp.3914-3918, 2008.
DOI : 10.1002/adma.200800791

H. Park, D. Shin, G. Kang, S. Baek, K. Kim et al., Broadband Optical Antireflection Enhancement by Integrating Antireflective Nanoislands with Silicon Nanoconical-Frustum Arrays, Advanced Materials, vol.9, issue.48, pp.5796-5800, 2011.
DOI : 10.1002/adma.201103399

Y. Huang, S. Chattopadhyay, Y. Jen, C. Peng, T. Liu et al., Improved broadband and quasi-omnidirectional anti-reflection properties with biomimetic silicon nanostructures, Nature Nanotechnology, vol.15, issue.12, pp.770-774, 2007.
DOI : 10.1038/nnano.2007.389

F. Galeotti, F. Trespidi, G. Timò, and M. Pasini, Broadband and Crack-Free Antireflection Coatings by Self-Assembled Moth Eye Patterns, ACS Applied Materials & Interfaces, vol.6, issue.8, pp.5827-5834, 2014.
DOI : 10.1021/am500687f

K. Park, H. J. Choi, C. Chang, R. E. Cohen, G. H. Mckinley et al., Nanotextured Silica Surfaces with Robust Superhydrophobicity and Omnidirectional Broadband Supertransmissivity, ACS Nano, vol.6, issue.5, pp.3789-3799, 2012.
DOI : 10.1021/nn301112t

). H. Macleod, Thin-Film Optical Filters, 2010.
DOI : 10.1887/0750306882

H. K. Raut, V. A. Ganesh, .. S. Nair, S. Ramakrishna, W. Glaubitt et al., Anti-reflective coatings: A critical, in-depth review, Energy & Environmental Science, vol.33, issue.21, pp.3779-2012, 2011.
DOI : 10.1039/c1ee01297e

A. Gombert, W. Glaubitt, K. Rose, J. Dreibholz, B. Bläsi et al., Subwavelength-structured antireflective surfaces on glass, Thin Solid Films, vol.351, issue.1-2, pp.73-78, 1999.
DOI : 10.1016/S0040-6090(98)01780-5

X. Li and J. Shen, Thin Solid Films, pp.6236-6240, 2011.

X. Zhang, S. Cai, D. You, L. Yan, H. Lv et al., Template-Free Sol-Gel Preparation of Superhydrophobic ORMOSIL Films for Double-Wavelength Broadband Antireflective Coatings, Advanced Functional Materials, vol.22, issue.35, pp.4361-4365, 2013.
DOI : 10.1002/adfm.201203059

R. B. Pettit, C. J. Brinker, and . Ashley, Sol-gel double-layer antireflection coatings for silicon solar cells, Solar Cells, vol.15, issue.3, pp.267-278, 1985.
DOI : 10.1016/0379-6787(85)90083-3

S. Lien, D. Wuu, W. Yeh, and J. Liu, Tri-layer antireflection coatings (SiO2/SiO2???TiO2/TiO2) for silicon solar cells using a sol???gel technique, Solar Energy Materials and Solar Cells, vol.90, issue.16, pp.2710-2719, 2006.
DOI : 10.1016/j.solmat.2006.04.001

C. J. Brinker and M. S. Harrington, Sol-gel derived antireflective coatings for silicon, Solar Energy Materials, vol.5, issue.2, pp.159-172, 1981.
DOI : 10.1016/0165-1633(81)90027-7

B. Louis, N. Krins, M. Faustini, and D. Grosso, Sol???Gel Optical Thin Films: An in Situ Thermal Ellipsometry Analysis, The Journal of Physical Chemistry C, vol.115, issue.7, pp.3115-3122, 2011.
DOI : 10.1021/jp109653p

T. Murata, H. Ishizawa, A. Tanaka, H. Ishizawa, S. Niisaka et al., Investigation of MgF_2 optical thin films with ultralow refractive indices prepared from autoclaved sols, Applied Optics, vol.47, issue.13, pp.246-66, 2008.
DOI : 10.1364/AO.47.00C246

J. Noack, K. Scheurell, E. Kemnitz, P. Garcia-juan, H. Rau et al., MgF2 antireflective coatings by sol???gel processing: film preparation and thermal densification, Journal of Materials Chemistry, vol.520, issue.35, p.18535, 2012.
DOI : 10.1039/c2jm33324d

D. Grosso, C. Boissière, and C. Sanchez, Ultralow-dielectric-constant optical thin films built from magnesium oxyfluoride vesicle-like hollow nanoparticles, Nature Materials, vol.19, issue.8, pp.572-575, 2007.
DOI : 10.1038/nmat1950

URL : https://hal.archives-ouvertes.fr/hal-00334651

J. D. Bass, C. Boissiere, L. Nicole, D. Grosso, and C. Sanchez, -Based Optical Coatings: An Easy Method to Tune the Refractive Index, Chemistry of Materials, vol.20, issue.17, pp.5550-5556, 2008.
DOI : 10.1021/cm8010106

URL : https://hal.archives-ouvertes.fr/insu-00359427

B. G. Prevo, Y. Hwang, and O. D. Velev, Convective Assembly of Antireflective Silica Coatings with Controlled Thickness and Refractive Index, Chemistry of Materials, vol.17, issue.14, pp.3642-3651, 2005.
DOI : 10.1021/cm050416h

H. Hattori, Anti-Reflection Surface with Particle Coating Deposited by Electrostatic Attraction, Advanced Materials, vol.13, issue.1, pp.51-54, 2001.
DOI : 10.1002/1521-4095(200101)13:1<51::AID-ADMA51>3.0.CO;2-F

G. Wicht, R. Ferrini, S. Schüttel, and L. Zuppiroli, Nanoporous Films with Low Refractive Index for Large-Surface Broad-Band Anti-Reflection Coatings, Macromolecular Materials and Engineering, vol.41, issue.7, pp.628-636, 2010.
DOI : 10.1002/mame.201000045

I. M. Thomas, Method for the preparation of porous silica antireflection coatings varying in refractive index from 122 to 144, Applied Optics, vol.31, issue.28, pp.6145-6149, 1992.
DOI : 10.1364/AO.31.006145

J. Moghal, J. Kobler, J. Sauer, J. Best, M. Gardener et al., High-Performance, Single-Layer Antireflective Optical Coatings Comprising Mesoporous Silica Nanoparticles, ACS Applied Materials & Interfaces, vol.4, issue.2, pp.854-859, 2012.
DOI : 10.1021/am201494m

P. Nostell, A. Roos, and B. Karlsson, Optical and mechanical properties of sol-gel antireflective films for solar energy applications, Thin Solid Films, vol.351, issue.1-2, pp.170-175, 1999.
DOI : 10.1016/S0040-6090(99)00257-6

W. Shimizu and Y. Murakami, Microporous Silica Thin Films with Low Refractive Indices and High Young???s Modulus, ACS Applied Materials & Interfaces, vol.2, issue.11, pp.3128-3133, 2010.
DOI : 10.1021/am100612g

). R. Pettit, C. S. Ashley, S. T. Reed, and C. J. , Sol-Gel Technology For Thin Films, Fibers, Preforms, Electronics and Specialty Shapes, pp.80-109, 1988.

T. Clark, J. D. Ruiz, H. Fan, C. J. Brinker, B. I. Swanson et al., A New Application of UV???Ozone Treatment in the Preparation of Substrate-Supported, Mesoporous Thin Films, Chemistry of Materials, vol.12, issue.12, pp.3879-3884, 2000.
DOI : 10.1021/cm000456f

R. Saxena, O. Rodriguez, W. Cho, W. N. Gill, J. L. Plawsky et al., Internal matrix structure of low-?? mesoporous silica and its relation to mechanical properties, Journal of Non-Crystalline Solids, vol.349, pp.189-199, 2004.
DOI : 10.1016/j.jnoncrysol.2004.08.185

S. Li, Z. Li, and Y. Yan, Ultra-Low-k Pure-Silica Zeolite MFI Films Using Cyclodextrin as Porogen, Advanced Materials, vol.15, issue.18, pp.1528-1531, 2003.
DOI : 10.1002/adma.200305173

C. V. Nguyen, K. R. Carter, C. J. Hawker, J. L. Hedrick, R. L. Jaffe et al., Low-Dielectric, Nanoporous Organosilicate Films Prepared via Inorganic/Organic Polymer Hybrid Templates, Chemistry of Materials, vol.11, issue.11, pp.3080-3085, 1999.
DOI : 10.1021/cm990114d

F. Guillemot, . Brunet-bruneau, E. Bourgeat-lami, T. Gacoin, E. Barthel et al., Latex-Templated Silica Films: Tailoring Porosity to Get a Stable Low-Refractive Index, Chemistry of Materials, vol.22, issue.9, pp.2822-2828, 2010.
DOI : 10.1021/cm903754k

URL : https://hal.archives-ouvertes.fr/hal-00483824

X. S. Zhao and G. Q. Lu, Modification of MCM-41 by Surface Silylation with Trimethylchlorosilane and Adsorption Study, The Journal of Physical Chemistry B, vol.102, issue.9, pp.1556-1561, 1998.
DOI : 10.1021/jp972788m

S. Jung and H. Park, Thin Solid Films, pp.420-421, 2002.
URL : https://hal.archives-ouvertes.fr/in2p3-00015636

A. Carretero-genevrier, C. Boissiere, L. Nicole, and D. Grosso, Revealed by in Situ Ellipsometry, Journal of the American Chemical Society, vol.134, issue.26, pp.10761-10764, 2012.
DOI : 10.1021/ja303170h

URL : https://hal.archives-ouvertes.fr/hal-01468421

S. Guldin, P. Kohn, M. Stefik, J. Song, G. Divitini et al., Self-Cleaning Antireflective Optical Coatings, Nano Letters, vol.13, issue.11, pp.5329-5335, 2013.
DOI : 10.1021/nl402832u

URL : http://discovery.ucl.ac.uk/1446963/1/Guldin_et_al._-_Nano_Letters_-_Self-cleaning_antireflective_optical_coatings._-_2013.pdf

. Polyrise, Modification de la chimie de surface d'espèces macromoléculaires en présence d'une guanidine conjuguée, 2010.

. Polyrise, Revêtements Antireflet comprenant des objets dispersé présentant deux domaiens séparés ayantdes indices de réfraction distincts, 2011.

H. Wang, C. Tang, and C. Lee, Enhancement of adhesion between antireflection coating and cellulose triacetate by surface pretreatment using argon-helium plasma, Applied Optics, vol.47, issue.13, pp.79-82, 2008.
DOI : 10.1364/AO.47.000C79

K. Koo, M. Park, Y. Yu, and J. , Atomic force microscopy analysis of cellulose triacetate surface modified in low temperature argon plasma and its adhesion behavior, Journal of Applied Polymer Science, vol.173, issue.4, pp.3963-3971, 2006.
DOI : 10.1002/app.24267

. Nakamura, Anti-glare, anti-reflection film, polarizing plate and liquid crystal display device, 2001.

U. Schulz, P. Munzert, R. Leitel, I. Wendling, and N. Kaiser, Antireflection of transparent polymers by advanced plasma etching procedures, Optics Express, vol.15, issue.20, pp.13108-13113, 2007.
DOI : 10.1364/OE.15.013108

D. Paz-simon, H. Chemtob, A. Croutxé-barghorn, C. Rigolet, S. Michelin et al., Periodic Mesostructured Silica Films Made Simple Using UV Light, The Journal of Physical Chemistry C, vol.118, issue.9, pp.4959-4966, 2014.
DOI : 10.1021/jp410518k

H. Lee, E. K. Lin, H. Wang, W. Wu, and W. Chen, Thin Films Prepared with Varying Process Conditions, Chemistry of Materials, vol.14, issue.4, pp.1845-1852, 2002.
DOI : 10.1021/cm011569h

P. Falcaro, D. Grosso, H. Amenitsch, and P. Innocenzi, Silica Orthorhombic Mesostructured Films with Low Refractive Index and High Thermal Stability, The Journal of Physical Chemistry B, vol.108, issue.30, pp.10942-10948, 2004.
DOI : 10.1021/jp037740p

M. P. Tate, V. N. Urade, J. D. Kowalski, T. Wei, B. D. Hamilton et al., Simulation and Interpretation of 2D Diffraction Patterns from Self-Assembled Nanostructured Films at Arbitrary Angles of Incidence:?? From Grazing Incidence (Above the Critical Angle) to Transmission Perpendicular to the Substrate, The Journal of Physical Chemistry B, vol.110, issue.20, pp.9882-9892, 2006.
DOI : 10.1021/jp0566008

A. Ayouch, X. Dieudonné, G. Vaudel, H. Piombini, K. Vallé et al., Either van der Waals-Bonded or Covalent-Bonded Coating Layers, ACS Nano, vol.6, issue.12, pp.10614-10621, 2012.
DOI : 10.1021/nn303631d

F. Mammeri, E. Bourhis, L. Le-;-rozes, C. Sanchez, R. Saha et al., Mechanical properties of hybrid organic???inorganic materials, Journal of Materials Chemistry, vol.42, issue.2, pp.3787-3810, 2002.
DOI : 10.1016/j.jeurceramsoc.2004.11.013

URL : https://hal.archives-ouvertes.fr/hal-00022637

H. Fan, C. Hartshorn, T. Buchheit, D. Tallant, R. Assink et al., Modulus???density scaling behaviour and framework architecture of nanoporous self-assembled silicas, Nature Materials, vol.64, issue.6, pp.418-423, 2007.
DOI : 10.1038/nmat1913

H. Fan, H. R. Bentley, K. R. Kathan, P. Clem, Y. Lu et al., Self-assembled aerogel-like low dielectric constant films, Journal of Non-Crystalline Solids, vol.285, issue.1-3, pp.79-83, 2001.
DOI : 10.1016/S0022-3093(01)00435-5

M. Boudot, D. R. Ceratti, M. Faustini, C. Boissière, and D. Grosso, Alcohol-Assisted Water Condensation and Stabilization into Hydrophobic Mesoporosity, The Journal of Physical Chemistry C, vol.118, issue.41, pp.23907-23917, 2014.
DOI : 10.1021/jp508372d

URL : https://hal.archives-ouvertes.fr/hal-01289941

X. Li, D. Reinhoudt, and M. Crego-calama, What do we need for a superhydrophobic surface? A review on the recent progress in the preparation of superhydrophobic surfaces, Chemical Society Reviews, vol.23, issue.8, pp.1350-1368, 2007.
DOI : 10.1039/b602486f

T. Sun, G. Wang, L. Feng, B. Liu, Y. Ma et al., Reversible Switching between Superhydrophilicity and Superhydrophobicity, Angewandte Chemie International Edition, vol.43, issue.3, pp.357-360, 2004.
DOI : 10.1002/anie.200352565

X. Feng, L. Feng, M. Jin, J. Zhai, L. Jiang et al., Reversible Super-hydrophobicity to Super-hydrophilicity Transition of Aligned ZnO Nanorod Films, Journal of the American Chemical Society, vol.126, issue.1, pp.62-63, 2004.
DOI : 10.1021/ja038636o

J. Yoon and R. L. Garrell, Preventing Biomolecular Adsorption in Electrowetting-Based Biofluidic Chips, Analytical Chemistry, vol.75, issue.19, pp.5097-5102, 2003.
DOI : 10.1021/ac0342673

S. Gregg and K. S. , Adsorption Surface Area and Porosity, Journal of The Electrochemical Society, vol.114, issue.11, p.303, 1991.
DOI : 10.1149/1.2426447

K. Lum, D. Chandler, and J. D. Weeks, Hydrophobicity at Small and Large Length Scales, The Journal of Physical Chemistry B, vol.103, issue.22, pp.4570-4577, 1999.
DOI : 10.1021/jp984327m

K. Lum and A. Luzar, Pathway to surface-induced phase transition of a confined fluid, Physical Review E, vol.56, issue.6, pp.6283-6286, 1997.
DOI : 10.1103/PhysRevE.56.R6283

R. Helmy, Y. Kazakevich, C. Ni, and A. Y. Fadeev, Wetting in Hydrophobic Nanochannels:?? A Challenge of Classical Capillarity, Journal of the American Chemical Society, vol.127, issue.36, pp.12446-12447, 2005.
DOI : 10.1021/ja053267c

S. Smirnov, I. Vlassiouk, P. Takmakov, and F. Rios, Water Confinement in Hydrophobic Nanopores. Pressure-Induced Wetting and Drying, ACS Nano, vol.4, issue.9, pp.5069-5075, 2010.
DOI : 10.1021/nn101080k

M. R. Powell, L. Cleary, M. Davenport, and K. Shea, Electric-field-induced wetting and dewetting in single hydrophobic nanopores, Nature Nanotechnology, vol.123, issue.12, pp.798-802, 2011.
DOI : 10.1038/nnano.2011.189

K. D. O-'hare and P. L. Spedding, Evaporation of a binary liquid mixture, The Chemical Engineering Journal, vol.48, issue.1, pp.1-9, 1992.
DOI : 10.1016/0300-9467(92)85001-P

M. Vayer, T. H. Nguyen, D. Grosso, C. Boissiere, M. A. Hillmyer et al., Characterization of Nanoporous Polystyrene Thin Films by Environmental Ellipsometric Porosimetry, Macromolecules, vol.44, issue.22, pp.8892-8897, 2011.
DOI : 10.1021/ma201497z

G. Niklasson, C. G. Granqvist, and O. Hunderi, Effective medium models for the optical properties of inhomogeneous materials, Applied Optics, vol.20, issue.1, pp.26-30, 1981.
DOI : 10.1364/AO.20.000026

E. De-la-llave, V. Molinero, and D. Scherlis, Role of Confinement and Surface Affinity on Filling Mechanisms and Sorption Hysteresis of Water in Nanopores, The Journal of Physical Chemistry C, vol.116, issue.2, pp.1833-1840, 2012.
DOI : 10.1021/jp206580z

N. A. Natividade, A. G. Ferreira, and I. M. Fonseca, Densities and Excess Molar Volumes of Water + Propyl Acetate + Propan-1-ol and Its Constituent Binaries at 303.15 K, Journal of Chemical & Engineering Data, vol.42, issue.6, pp.1232-1234, 1997.
DOI : 10.1021/je970135t

A. Arce, A. Blanco, A. Soto, and I. Vidal, Densities, refractive indices, and excess molar volumes of the ternary systems water + methanol + 1-octanol and water + ethanol + 1-octanol and their binary mixtures at 298.15 K, Journal of Chemical & Engineering Data, vol.38, issue.2, pp.336-340, 1993.
DOI : 10.1021/je00010a039

G. Vazquez, E. Alvarez, and J. M. Navaza, Surface Tension of Alcohol Water + Water from 20 to 50 .degree.C, Journal of Chemical & Engineering Data, vol.40, issue.3, pp.611-614, 1995.
DOI : 10.1021/je00019a016

D. Spagnolo, Y. Maham, and K. T. Chuang, Calculation of Contact Angle for Hydrophobic Powders Using Heat of Immersion Data, The Journal of Physical Chemistry, vol.100, issue.16, pp.6626-6630, 1996.
DOI : 10.1021/jp951405m

C. Sanchez, P. Belleville, M. Popall, and L. Nicole, Applications of advanced hybrid organic???inorganic nanomaterials: from laboratory to market, Chemical Society Reviews, vol.39, issue.2, pp.696-753, 2011.
DOI : 10.1039/c0cs00025f

R. Ciriminna, A. Fidalgo, V. Pandarus, F. Béland, L. M. Ilharco et al., The Sol???Gel Route to Advanced Silica-Based Materials and Recent Applications, Chemical Reviews, vol.113, issue.8, pp.6592-6620, 2013.
DOI : 10.1021/cr300399c

X. Guo, J. E. Jakes, S. Banna, Y. Nishi, L. Shohet et al., organosilicate glass, Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, vol.32, issue.3, p.31512, 2014.
DOI : 10.1116/1.4871680

M. N. Golubovic, H. D. Hettiarachchi, and W. M. Worek, Sorption properties for different types of molecular sieve and their influence on optimum dehumidification performance of desiccant wheels, International Journal of Heat and Mass Transfer, vol.49, issue.17-18, pp.2802-2809, 2006.
DOI : 10.1016/j.ijheatmasstransfer.2006.03.012

J. Hue, M. Dupoy, T. Bordy, R. Rousier, S. Vignoud et al., Benzene and xylene detection by absorbance in the range of 10???100ppb application: Quality of indoor air, Sensors and Actuators B: Chemical, vol.189, issue.159, pp.194-198, 2013.
DOI : 10.1016/j.snb.2013.03.047

URL : https://hal.archives-ouvertes.fr/hal-00955764

S. C. Reyes, J. H. Sinfelt, G. J. Demartin, R. H. Ernst, and E. Iglesia, Frequency Modulation Methods for Diffusion and Adsorption Measurements in Porous Solids, The Journal of Physical Chemistry B, vol.101, issue.4, pp.614-622, 1997.
DOI : 10.1021/jp961036+

N. Katsanos and N. Bakaoukas, Diffusion and Adsorption Measurements in Porous Solids by Inverse Gas Chromatography, The Journal of Physical Chemistry B, vol.109, issue.22, pp.11240-11246, 2005.
DOI : 10.1021/jp040741c

D. Lee, Y. Jin, N. Jung, J. Lee, and J. Lee, on Amine-Functionalized Mesoporous Silica Mounted on a Microcantilever Array, Environmental Science & Technology, vol.45, issue.13, pp.5704-5709, 2011.
DOI : 10.1021/es200680v

J. Xiao and J. Wei, Diffusion mechanism of hydrocarbons in zeolites???I. Theory, Chemical Engineering Science, vol.47, issue.5, pp.1123-1141, 1992.
DOI : 10.1016/0009-2509(92)80236-6

L. Zhuravlev, The surface chemistry of amorphous silica. Zhuravlev model, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.173, issue.1-3, pp.1-38, 2000.
DOI : 10.1016/S0927-7757(00)00556-2

Y. Tomita, R. Takahashi, S. Sato, T. Sodesawa, and M. J. Otsuda, Humidity Control Ability of Silica with Bimodal Pore Structures Prepared from Water Glass, Journal of the Ceramic Society of Japan, vol.112, issue.1309, pp.491-495, 2004.
DOI : 10.2109/jcersj.112.491

P. Fratzl and F. G. Barth, Biomaterial systems for mechanosensing and actuation, Nature, vol.2, issue.7272, pp.442-448, 2009.
DOI : 10.1038/nature08603

E. Reyssat and L. Mahadevan, Hygromorphs: from pine cones to biomimetic bilayers, Journal of The Royal Society Interface, vol.17, issue.7024, pp.951-957, 2009.
DOI : 10.1038/nature03185

M. Ma, L. Guo, D. G. Anderson, and R. Langer, Bio-Inspired Polymer Composite Actuator and Generator Driven by Water Gradients, Science, vol.339, issue.6116, pp.186-189, 2013.
DOI : 10.1126/science.1230262

URL : http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3635810

Y. Osada and A. Matsuda, Shape memory in hydrogels, Nature, vol.376, issue.6537, p.219, 1995.
DOI : 10.1038/376219a0

Y. Osada, H. Okuzaki, and H. Hori, A polymer gel with electrically driven motility, Nature, vol.355, issue.6357, pp.242-244, 1992.
DOI : 10.1038/355242a0

R. P. Clark, The thermal decomposition of poly-4,4'-oxydiphenylene pyromellitimide, Thermochimica Acta, vol.6, issue.5, pp.473-480, 1973.
DOI : 10.1016/0040-6031(73)85079-8

X. Dieudonné, Etude d'empilements multicouches colloïdaux préparés par voie sol gel: Propriétés optiques et mécaniques, p.80, 2011.

G. G. Stoney, . R. Proc, . Soc, and . Math, The Tension of Metallic Films Deposited by Electrolysis, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, vol.82, issue.553, pp.172-175, 1909.
DOI : 10.1098/rspa.1909.0021

G. C. Janssen, M. M. Abdalla, and F. Van-keulen, Celebrating the 100th anniversary of the Stoney equation for film stress: Developments from polycrystalline steel strips to single crystal silicon wafers, Thin Solid Films, vol.517, issue.6, pp.1858-1867, 2009.
DOI : 10.1016/j.tsf.2008.07.014

J. Brinker and G. W. Scherer, Sol Gel Science: The Physics and Chemistry of Sol-Gel Processing, pp.447-448, 1990.

H. Kozuka, Stress evolution on gel-to-ceramic thin film conversion, Journal of Sol-Gel Science and Technology, vol.64, issue.41, pp.287-297, 2006.
DOI : 10.1007/s10971-006-9213-x

R. R. Syms, Deposition of thick silica-titania sol-gel films on Si substrates, Journal of Non-Crystalline Solids, vol.170, issue.3, pp.223-233, 1994.
DOI : 10.1016/0022-3093(94)90051-5

T. Parrill, Heat treatment of spun-on acid-catalyzed sol-gel silica films, Journal of Materials Research, vol.104, issue.03, pp.723-730, 2011.
DOI : 10.1557/JMR.1994.0723

M. A. Fardad, E. M. Yeatman, E. J. Dawnay, M. Green, and F. Horowitz, Effects of H2O on structure of acid-catalysed SiO2 sol-gel films, Journal of Non-Crystalline Solids, vol.183, issue.3, pp.260-267, 1995.
DOI : 10.1016/0022-3093(94)00661-X

L. Blanc, A. Tetelin, C. Boissiere, G. Tortissier, C. Dejous et al., Love Wave Characterization of the Shear Modulus Variations of Mesoporous Sensitive Films During Vapor Sorption, IEEE Sensors Journal, vol.12, issue.5, pp.1442-1449, 2012.
DOI : 10.1109/JSEN.2011.2173189

URL : https://hal.archives-ouvertes.fr/hal-00696611

G. H. Haertling, Ferroelectric Ceramics: History and Technology, Journal of the American Ceramic Society, vol.17, issue.207, pp.797-818, 1999.
DOI : 10.1111/j.1151-2916.1999.tb01840.x

N. Setter, D. Damjanovic, L. Eng, G. Fox, S. Gevorgian et al., Ferroelectric thin films: Review of materials, properties, and applications, Journal of Applied Physics, vol.100, issue.5, p.51606, 2006.
DOI : 10.1063/1.2336999

N. Suzuki, X. Jiang, R. R. Salunkhe, M. Osada, and Y. Yamauchi, Chemical Preparation of Ferroelectric Mesoporous Barium Titanate Thin Films: Drastic Enhancement of Curie Temperature Induced by Mesopore-Derived Strain, Chemistry - A European Journal, vol.57, issue.36, pp.11283-11286, 2014.
DOI : 10.1002/chem.201403308

K. Kajiyoshi, N. Ishizawa, and M. Yoshimura, Preparation of Tetragonal Barium Titanate Thin Film on Titanium Metal Substrate by Hydrothermal Method, Journal of the American Ceramic Society, vol.58, issue.4, pp.369-374, 1991.
DOI : 10.1111/j.1151-2916.1991.tb06889.x

M. Kuemmel, J. Allouche, L. Nicole, C. Boissière, C. Laberty et al., A Chemical Solution Deposition Route To Nanopatterned Inorganic Material Surfaces, Chemistry of Materials, vol.19, issue.15, pp.3717-3725, 2007.
DOI : 10.1021/cm0706245

I. J. Clark, T. Takeuchi, N. Ohtori, and D. C. Sinclair, Hydrothermal synthesis and characterisation of BaTiO3 fine powders: precursors, polymorphism and properties, Journal of Materials Chemistry, vol.9, issue.1, pp.83-91, 1999.
DOI : 10.1039/a805756g

W. Hertl, Kinetics of Barium Titanate Synthesis, Journal of the American Ceramic Society, vol.71, issue.4, pp.879-883, 1988.
DOI : 10.1063/1.1731812

J. O. Eckert, C. C. Hung-houston, B. L. Gersten, M. M. Lencka, and R. E. Riman, Kinetics and Mechanisms of Hydrothermal Synthesis of Barium Titanate, Journal of the American Ceramic Society, vol.21, issue.2, pp.2929-2939, 1996.
DOI : 10.1063/1.1750380

R. Ryoo, S. H. Joo, and S. Jun, Synthesis of Highly Ordered Carbon Molecular Sieves via Template-Mediated Structural Transformation, The Journal of Physical Chemistry B, vol.103, issue.37, pp.7743-7746, 1999.
DOI : 10.1021/jp991673a