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New recyclable catalysts for the formations of carbon-carbon and carbon-nitrogen bonds

Abstract : Catalysts based on dendrimers and magnetic nanoparticles are becoming increasing utilized in the context of green and sustainable chemistry, because they are easily separated by precipitation or by using asimple magnet respectively, and they are recyclable. In this spirit, the thesis has been devoted to the synthesis, characterization and catalytic applications of iron oxide magnetic nanoparticles-immobilized molecular, nano-and dendritic catalysts involving Ru, Cu and Pd. Magnetically recyclable ruthenium(II) and Cu(I) complexes and Pd nanoparticles have provided excellent catalytic performances in terms of activity, stability and recyclability, using alkyne-azide cycloaddition and carbon-carbon cross coupling reactions. The synthesis of mono-and polymetallic palladium complexes containing the 2-pyridyl-1,2,3-triazole ligand or nonabranch-derived ligands has also been carried out, and their catalytic properties in coupling reactions has been studied
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https://tel.archives-ouvertes.fr/tel-01159007
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Submitted on : Tuesday, June 2, 2015 - 1:12:05 PM
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  • HAL Id : tel-01159007, version 1

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Dong Wang. New recyclable catalysts for the formations of carbon-carbon and carbon-nitrogen bonds. Organic chemistry. Université de Bordeaux, 2014. English. ⟨NNT : 2014BORD0128⟩. ⟨tel-01159007⟩

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