tracée à partir de solutions d'acide myristique et de CTAB, en quantités connues, dans l'éthanol absolu permet de quantier les diérentes espèces. La calibration a été réalisée au moins une fois par semaine mais au moins un des mélanges de calibration était injectés chaque jour d'analyse pour vérier l ,
Trois congurations ont été utilisées, avec une distance échantillon-détecteur de 1,255 m et des longueurs d'onde : ? = 4 Å, ? = 7,8 Ået ? = 12 Å. Les diérentes congurations permettent d'avoir accès à une gamme de vecteur de diusion de 0 ,
Transport in Proton Conductors for Fuel-Cell Applications:?? Simulations, Elementary Reactions, and Phenomenology, Chemical Reviews, vol.104, issue.10, pp.4637-4678, 2004. ,
DOI : 10.1021/cr020715f
About the Choice of the Protogenic Group in PEM Separator Materials for Intermediate Temperature, Low Humidity Operation: A Critical Comparison of Sulfonic Acid, Phosphonic Acid and Imidazole Functionalized Model Compounds, Fuel Cells, vol.185, issue.136, pp.355-365, 2005. ,
DOI : 10.1002/fuce.200400059
Lateral proton conduction at a lipid/water interface. Effect of lipid nature and ionic content of the aqueous phase, European Journal of Biochemistry, vol.322, issue.2, pp.379-385, 1987. ,
DOI : 10.1016/0014-5793(84)81157-6
Two-dimensional proton conduction at a membrane surface: Influence of molecular packing and hydrogen bonding, Chemical Physics Letters, vol.150, issue.3-4, pp.311-314, 1988. ,
DOI : 10.1016/0009-2614(88)80048-4
Catanionic surfactants: phase behavior and microemulsions, Langmuir, vol.7, issue.5, pp.889-895, 1991. ,
DOI : 10.1021/la00053a013
Catanionic bilayers as micro-crystals with in-plane ordered alternated charges, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.303, issue.1-2, pp.37-45, 2007. ,
DOI : 10.1016/j.colsurfa.2007.03.028
Ripening of Catanionic Aggregates upon Dialysis, Langmuir, vol.25, issue.2, pp.698-706, 2009. ,
DOI : 10.1021/la8018293
Improvement of data treatment in small-angle neutron scattering, Journal of Applied Crystallography, vol.40, issue.1, pp.165-177, 2007. ,
DOI : 10.1107/S0021889806051442
Improving sensitivity of a small angle x-ray scattering camera with pinhole collimation using separated optical elements, Review of Scientific Instruments, vol.74, issue.4, pp.2456-2462, 2003. ,
DOI : 10.1063/1.1556954
URL : https://hal.archives-ouvertes.fr/cea-00268837
Impedance Spectroscopy: Theory, Experiment, and Applications, 2005. ,
DOI : 10.1002/0471716243
Ion Exchange in Catanionic Mixtures:?? From Ion Pair Amphiphiles to Surfactant Mixtures, Langmuir, vol.23, issue.12, pp.6554-6560, 2007. ,
DOI : 10.1021/la070184w
Solubility of Saturated Fatty Acids in Water at Elevated Temperatures, Bioscience, Biotechnology, and Biochemistry, vol.66, issue.8, pp.1723-1726, 2002. ,
DOI : 10.1271/bbb.66.1723
General patterns of the phase behavior of mixtures of water, nonpolar solvents, amphiphiles, and electrolytes. 1, Langmuir, vol.4, issue.3, pp.499-511, 1988. ,
DOI : 10.1021/la00081a002
Teubner, J. Chem. Phys, vol.87, pp.3195-3200, 1987. ,
Gaussian random fields with two level-cuts???Model for asymmetric microemulsions with nonzero spontaneous curvature?, The Journal of Chemical Physics, vol.115, issue.8, pp.3923-3936, 2001. ,
DOI : 10.1063/1.1388558
Microemulsions with a HIPME (High Internal Phase Microemulsion) Structure, The Journal of Physical Chemistry B, vol.116, issue.7, pp.2131-2137, 2012. ,
DOI : 10.1021/jp207594p
Mesoscopic modelling of frustration in microemulsions, Physical Chemistry Chemical Physics, vol.304, issue.130, pp.7133-7141, 2013. ,
DOI : 10.1039/c3cp43981j
Microemulsion microstructure and interfacial curvature, Colloid & Polymer Science, vol.119, issue.8, pp.1005-1019, 1994. ,
DOI : 10.1007/BF00658900
Effect of Protonation on the Solution and Phase Behavior of Aqueous Sodium Myristate, Journal of Colloid and Interface Science, vol.231, issue.1, pp.42-51, 2000. ,
DOI : 10.1006/jcis.2000.7156
Vibrational dynamics of carboxylic acid dimers in gas and dilute solution, Physical Chemistry Chemical Physics, vol.110, issue.32, pp.4572-4586, 2007. ,
DOI : 10.1039/b704900e
Consistent force field studies of intermolecular forces in hydrogen-bonded crystals. 1. Carboxylic acids, amides, and the C:O.cntdot..cntdot..cntdot.H- hydrogen bonds, Journal of the American Chemical Society, vol.101, issue.18, pp.5111-5121, 1979. ,
DOI : 10.1021/ja00512a001
Metastable and unstable cellular solidification of colloidal suspensions, Nature Materials, vol.35, issue.12, pp.966-972, 2009. ,
DOI : 10.1038/nmat2571
URL : https://hal.archives-ouvertes.fr/hal-00639455
Melt layer solidification of fatty acids in a rectangular cell, The Journal of Chemical Physics, vol.112, issue.3, pp.1554-1559, 2000. ,
DOI : 10.1063/1.480702
On voltaic series and the combination of gases by platinum, Philosophical Magazine Series, vol.3, issue.1486, p.127130, 1839. ,
The High Pressure Hydrogen-Oxygen Fuel Cell, Industrial & Engineering Chemistry, vol.52, issue.4, p.301303, 1960. ,
DOI : 10.1021/ie50604a027
Transport in proton conductors for fuel-cell applications : simulations, elementary reactions, and phenomenology, Chemical Reviews, vol.104, issue.10, p.46374678, 2004. ,
Membranes pour piles ?? combustible : structure et transport. Apport de la diffusion neutronique, ??cole th??matique de la Soci??t?? Fran??aise de la Neutronique, vol.11, p.177197, 2010. ,
DOI : 10.1051/sfn/201011011
(Semi-)Interpenetrating polymer networks as fuel cell membranes, Journal of Membrane Science, vol.368, issue.1-2, p.117, 2011. ,
DOI : 10.1016/j.memsci.2010.11.020
Tetrazolebased , anhydrous proton exchange membranes for fuel cells, Advanced Materials, 2013. ,
DOI : 10.1002/adma.201304121
Vehicle Mechanism, A New Model for the Interpretation of the Conductivity of Fast Proton Conductors, Angewandte Chemie International Edition in English, vol.49, issue.4, p.208209, 1982. ,
DOI : 10.1002/anie.198202082
Studies on anhydrous proton conducting membranes based on imidazole derivatives and sulfonated polyimide, Electrochimica Acta, vol.54, issue.9, p.26032609, 2009. ,
DOI : 10.1016/j.electacta.2008.10.057
About the Choice of the Protogenic Group in PEM Separator Materials for Intermediate Temperature, Low Humidity Operation: A Critical Comparison of Sulfonic Acid, Phosphonic Acid and Imidazole Functionalized Model Compounds, Fuel Cells, vol.185, issue.136, p.355365, 2005. ,
DOI : 10.1002/fuce.200400059
Phase diagrams of water???alkyltrimethylammonium bromide systems, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.315, issue.1-3, pp.1-3205209, 2008. ,
DOI : 10.1016/j.colsurfa.2007.07.031
Transparent Water-in-Oil Dispersions: the Oleopathic Hydro-Micelle, Nature, vol.152, issue.3847, p.102103, 1943. ,
DOI : 10.1038/152102a0
Hydrotropy, solubilisation and related emulsification processes, Transactions of the Faraday Society, vol.44, p.376, 1948. ,
DOI : 10.1039/tf9484400376
Mechanism of Formation and Structure of Micro Emulsions by Electron Microscopy, The Journal of Physical Chemistry, vol.63, issue.10, p.16771680, 1959. ,
DOI : 10.1021/j150580a027
The denition of microemulsion, Colloids and Surfaces, vol.3, issue.4, p.391392, 1981. ,
On the structure of transparent water and oil dispersions (solubilised oils). Transactions of the Faraday Society, p.165, 1946. ,
General patterns of the phase behavior of mixtures of water, nonpolar solvents, amphiphiles, and electrolytes. 1, Langmuir, vol.4, issue.3, p.499511, 1988. ,
General patterns of the phase behavior of mixtures of water, nonpolar solvents, amphiphiles, and electrolytes. 2, Langmuir, vol.5, issue.2, p.305315, 1989. ,
How to study microemulsions, Journal of Colloid and Interface Science, vol.118, issue.2, p.436453, 1987. ,
DOI : 10.1016/0021-9797(87)90480-2
Direct Observation of Phase Separation in Microemulsion Networks, Langmuir, vol.15, issue.17, p.1554485453, 1999. ,
DOI : 10.1021/la990301q
Microemulsion microstructure and interfacial curvature, Colloid & Polymer Science, vol.119, issue.8, p.10051019, 1994. ,
DOI : 10.1007/BF00658900
Bicontinuous microemulsions revisited : a new approach to freeze fracture electron microscopy (FFEM) Colloids and Surfaces A : Physicochemical and Engineering Aspects, pp.1-3159170, 2003. ,
Small-angle x-ray scattering from ternary microemulsions determines microstructure, The Journal of Physical Chemistry, vol.92, issue.8, p.9222862293, 1988. ,
DOI : 10.1021/j100319a038
An attempt to detect bicontinuity from SANS data, Journal of Colloid and Interface Science, vol.312, issue.1, p.5967, 2007. ,
DOI : 10.1016/j.jcis.2006.06.033
Dynamics in an oil-continuous droplet microemulsion as seen by quasielastic scattering techniques, Physical Chemistry Chemical Physics, vol.2, issue.22, p.51685174, 2000. ,
DOI : 10.1039/b005088l
Bicontinuous microemulsions with extremely high temperature stability based on skin friendly oil and sugar surfactant, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.418, p.3946, 2013. ,
DOI : 10.1016/j.colsurfa.2012.10.039
Microemulsion structure in four-component systems for dierent surfactants, Colloids and Surfaces, vol.28, p.2940, 1987. ,
Droplet and bicontinuous structures in microemulsions from multicomponent self-diusion measurements, Langmuir, vol.1, issue.4, p.464468, 1985. ,
Probing the Microstructure of Nonionic Microemulsions with Ethyl Oleate by Viscosity, ROESY, DLS, SANS, and Cyclic Voltammetry, Langmuir, vol.28, issue.29, p.281064010652, 2012. ,
DOI : 10.1021/la300540d
Nonaqueous polar solvents in reverse micelle systems, Chemical Reviews, vol.112, issue.8, p.45694602, 2012. ,
Microemulsions with formamide as polar solvent, The Journal of Physical Chemistry, vol.97, issue.1, p.248254, 1993. ,
DOI : 10.1021/j100103a043
Ionic liquids as amphiphile self-assembly media, Chemical Society Reviews, vol.37, issue.8, p.1709, 2008. ,
Using ionic liquids to formulate microemulsions: Current state of affairs, Current Opinion in Colloid & Interface Science, vol.17, issue.4, p.205211, 2012. ,
DOI : 10.1016/j.cocis.2012.03.002
Optimum phase type and optimum salinity prole in surfactant ooding, Journal of Petroleum Science and Engineering, vol.75, issue.12, p.143153, 2010. ,
Condensation reaction of benzaldehyde and acetone in o/w microemulsions : Eect of microemulsion compositions, Colloids and Surfaces A : Physicochemical and Engineering Aspects, vol.370, pp.1-36471, 2010. ,
Gold nanoparticle synthesis in worm-like catanionic micelles: microstructure conservation and temperature induced recovery, Soft Matter, vol.437, issue.5, p.974, 2009. ,
DOI : 10.1039/B816427D
Arresting amphiphilic self-assembly, Soft Matter, vol.24, issue.4, p.658, 2008. ,
DOI : 10.1039/b717607d
Self-assembly in sugar???oil complex glasses, Nature Materials, vol.33, issue.4, p.287290, 2007. ,
DOI : 10.1038/nmat1864
Frédéric Vidal, and Odile Fichet. Microemulsion as the template for synthesis of interpenetrating polymer networks with predened structure, Polymer, vol.54, issue.17, p.44364445, 2013. ,
Copolymerization of water-soluble monomers in nonionic bicontinuous microemulsions, Journal of Colloid and Interface Science, vol.114, issue.2, p.398408, 1986. ,
DOI : 10.1016/0021-9797(86)90425-X
Acrylamide polymerization in concentrated bicontinuous systems, Die Angewandte Makromolekulare Chemie, vol.229, issue.1, p.133143, 1995. ,
Eect of the structures of microemulsions on chemical reactions, Colloid & Polymer Science, vol.278, issue.2, p.150154, 2000. ,
Characterization and polymerization of middle-phase microemulsions in styrene/water systems, Langmuir, vol.7, issue.7, p.13781382, 1991. ,
Formation of porous polymeric structures by the polymerization of single-phase microemulsions formulated with methyl methacrylate and acrylic acid, Langmuir, vol.7, issue.11, p.25862591, 1991. ,
Interpenetrating polymer networks templated on bicontinuous microemulsions containing silicone oil, methacrylic acid, and hydroxyethyl methacrylate, Colloid and Polymer Science, vol.240, issue.3, p.527539, 2012. ,
DOI : 10.1007/s00396-012-2741-8
Bicontinuous-Nanostructured Polymeric Materials from Microemulsion Polymerization, Langmuir, vol.14, issue.21, p.1460686076, 1998. ,
DOI : 10.1021/la970990a
Polymerization in Bicontinuous Microemulsion Glasses, Macromolecules, vol.39, issue.26, p.94679472, 2006. ,
DOI : 10.1021/ma061868y
Gelled Polymerizable Microemulsions. 1. Phase Behavior, Langmuir, vol.23, issue.14, p.77307737, 2007. ,
DOI : 10.1021/la700685g
Construction of Continuous Porous Organogels, Hydrogels, and Bicontinuous Organo/Hydro Hybrid Gels from Bicontinuous Microemulsions, Macromolecules, vol.43, issue.1, p.473479, 2010. ,
DOI : 10.1021/ma901624p
Phase behavior and SANS investigations of edible sugar???limonene microemulsions, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.296, issue.1-3, pp.1-34550, 2007. ,
DOI : 10.1016/j.colsurfa.2006.09.020
Elaboration de matériaux conducteurs protonique à architecture réseaux interpénétrés de polymères à partir de microémulsions, 2013. ,
Ion Exchange in Catanionic Mixtures:?? From Ion Pair Amphiphiles to Surfactant Mixtures, Langmuir, vol.23, issue.12, p.65546560, 2007. ,
DOI : 10.1021/la070184w
Proton transport at the monolayerwater interface, Biochimica et Biophysica ActaBiomembranes, vol.1062, issue.2, p.149156, 1991. ,
Hydrogen-bond control of structure and conductivity of langmuir lms, Physical Review E, vol.57, issue.6, p.68356839, 1998. ,
Phase equilibria of catanionic surfactant-water systems, The Journal of Physical Chemistry, issue.12, p.9132913298, 1987. ,
Ripening of Catanionic Aggregates upon Dialysis, Langmuir, vol.25, issue.2, p.698706, 2009. ,
DOI : 10.1021/la8018293
In-plane distribution in mixtures of cationic and anionic surfactants, Soft Matter, vol.111, issue.24, p.4983, 2009. ,
DOI : 10.1039/b907339f
Solubility of Saturated Fatty Acids in Water at Elevated Temperatures, Bioscience, Biotechnology, and Biochemistry, vol.66, issue.8, p.17231726, 2002. ,
DOI : 10.1271/bbb.66.1723
Refractive Indices and Densities of Normal Saturated Fatty Acids in the Liquid State, Journal of the American Chemical Society, vol.64, issue.12, pp.2739-2741, 1942. ,
DOI : 10.1021/ja01264a004
Origin of the scattering peak in microemulsions, The Journal of Chemical Physics, vol.87, issue.5, p.3195, 1987. ,
DOI : 10.1063/1.453006
Improvement of data treatment in small-angle neutron scattering, Journal of Applied Crystallography, vol.40, issue.1, p.165177, 2007. ,
DOI : 10.1107/S0021889806051442
Gaussian random fields with two level-cuts???Model for asymmetric microemulsions with nonzero spontaneous curvature?, The Journal of Chemical Physics, vol.115, issue.8, p.3923, 2001. ,
DOI : 10.1063/1.1388558
Mesoscopic modelling of frustration in microemulsions, Physical Chemistry Chemical Physics, vol.304, issue.130, p.71337141, 2013. ,
DOI : 10.1039/c3cp43981j
Scattering vector dependence of the small-angle scattering from mixtures of hydrogenated and deuterated organic solvents, Journal of Applied Crystallography, vol.33, issue.3, p.650652, 2000. ,
DOI : 10.1107/S0021889899012789
Structural properties of pure simple alcohols from ethanol, propanol, butanol, pentanol, to hexanol : comparing monte carlo simulations with experimental SAXS data, The Journal of Physical Chemistry B, vol.111, issue.7, p.17381751, 2007. ,
Eect of protonation on the solution and phase behavior of aqueous sodium myristate, Journal of Colloid and Interface Science, vol.231, issue.1, p.4251, 2000. ,
Consistent force eld studies of intermolecular forces in hydrogen-bonded crystals. 1. carboxylic acids, amides, and the c :o.cntdot..cntdot..cntdot.hhydrogen bonds, Journal of the American Chemical Society, vol.101, issue.18, p.51115121, 1979. ,
Metastable and unstable cellular solidication of colloidal suspensions, Nature Materials, vol.8, issue.12, p.966972, 2009. ,
Ice-templating, freeze casting: Beyond materials processing, Journal of Materials Research, vol.87, issue.17, p.22022219, 2013. ,
DOI : 10.1016/j.coldregions.2009.02.001
URL : https://hal.archives-ouvertes.fr/hal-00933994
Melt layer solidification of fatty acids in a rectangular cell, The Journal of Chemical Physics, vol.112, issue.3, p.1554, 2000. ,
DOI : 10.1063/1.480702
Quenched microemulsions : a new route for proton conductors ? Soft Matter, 2014. ,
Supercooled liquids and the glass transition, Nature, vol.410, p.259267, 2001. ,
The Dark Side of Crystal Engineering:?? Creating Glasses from Small Symmetric Molecules that Form Multiple Hydrogen Bonds, Journal of the American Chemical Society, vol.128, issue.32, p.1281037210373, 2006. ,
DOI : 10.1021/ja063353s
Anarchy in the solid state : structural dependence on glassforming ability in triazine-based molecular glasses, Tetrahedron, issue.36, p.6573937402, 2009. ,
and Rheological Properties of Triazine-Based Molecular Glasses: Incriminating Evidence Against Hydrogen Bonds, The Journal of Physical Chemistry B, vol.113, issue.45, p.1488414891, 2009. ,
DOI : 10.1021/jp905268a
Structural study of microemulsions of glycerol stabilised by cetyltrimethylammonium bromide dispersed in heptane + chloroform mixtures, Journal of the Chemical Society, Faraday Transactions, vol.1, issue.9, p.812053, 1985. ,
Anhydrous protonic conductivity of a self-assembled acidbase composite material, The Journal of Physical Chemistry B, vol.108, issue.18, p.55225526, 2004. ,
Recent applications of 2,4,6-trichloro-1,3,5-triazine and its derivatives in organic synthesis, Tetrahedron, issue.41, p.6295079522, 2006. ,
Enthalpy Relaxation upon Glass Transition and Kinetic Fragility of Molecular Liquids, The Journal of Physical Chemistry B, vol.113, issue.15, p.51685171, 2009. ,
DOI : 10.1021/jp8110327
Practical applications of small-angle neutron scattering, Physical Chemistry Chemical Physics, 2013. ,
Introduction à la diusion aux petits angles, p.1742, 2010. ,
Bonnes pratiques de la diusion de neutrons aux petits angles, p.4369, 2010. ,
DOI : 10.1051/sfn/201011004
Scattering Patterns of Self-Assembled Cubic Phases. 2. Analysis of the Experimental Spectra, Langmuir, vol.18, issue.7, p.25292537, 2002. ,
DOI : 10.1021/la011299h
Lyotropic mesophases of a uorinated surfactant with a short nonionic polar head in water, The Journal of Physical Chemistry B, vol.103, issue.17, p.34683475, 1999. ,
From Self-Organizing Polymers to Nanohybrid and Biomaterials, Angewandte Chemie International Edition, vol.41, issue.5, p.688, 2002. ,
DOI : 10.1002/1521-3773(20020301)41:5<688::AID-ANIE688>3.0.CO;2-3