X? ray crystal structure of the Fe?only hydrogenase (Cpl) from Clostridium pasteurianum to 1.8 angstrom resolution, Science, issue.5395, pp.2821853-1858, 1998. ,
The structure shows unusual coordination to an active site Fe binuclear center, Structure, vol.7, issue.199 11, pp.13-23, 1999. ,
A di?iron dithiolate possessing structural elements of the carbonyl/cyanide sub?site of the H?centre of Fe-only hydrogenase, Chem. Commun, issue.22, pp.2285-2286, 1999. ,
Hydrogenases, Chemical Reviews, vol.114, issue.8, pp.4081-4148, 2014. ,
DOI : 10.1021/cr4005814
URL : https://hal.archives-ouvertes.fr/hal-00869039
The photochemical and oxidative decomposition of carbonylene ,
Iron-only hydrogenase: Synthetic, structural and reactivity studies of model compounds, Coordination Chemistry Reviews, vol.249, issue.15-16, pp.15-161641, 2005. ,
DOI : 10.1016/j.ccr.2005.04.009
Technical and economic feasibility of centralized facilities for solar hydrogen production via photocatalysis and photoelectrochemistry, Energ. Environ. Sci, vol.6, issue.11, pp.1983-2002, 2013. ,
Subsite-specific functionalization of the [4Fe-4S]2+ analog of iron-sulfur protein clusters, Journal of the American Chemical Society, vol.109, issue.8, pp.2546-2547, 1987. ,
DOI : 10.1021/ja00242a067
Synthesis of the H-cluster framework of iron-only hydrogenase, Nature, vol.100, issue.7026, pp.610-613, 2005. ,
DOI : 10.1039/dt9940002181
On the electronic structure of the hydrogenase H-cluster, Chemical Communications, vol.33, issue.239, pp.3696-3698, 2006. ,
DOI : 10.1039/b604994j
A novel {Fe I ?Fe II ?Fe II ?Fe I } iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution ,
Modeling [Fe???Fe] Hydrogenase:?? Evidence for Bridging Carbonyl and Distal Iron Coordination Vacancy in an Electrocatalytically Competent Proton Reduction by an Iron Thiolate Assembly That Operates through Fe(0)???Fe(II) Levels, Journal of the American Chemical Society, vol.129, issue.36 ,
DOI : 10.1021/ja071331f
Photochemical and photophysical studies of tetranuclear copper(I ) halide clusters: An overview, Coord. Chem. Rev, vol.12994, issue.132, pp.11085-11092129, 1994. ,
Photoluminescence Properties of Multinuclear Copper(I) Compounds, Chemical Reviews, vol.99, issue.12, pp.3625-3648, 1999. ,
DOI : 10.1021/cr960109i
Thermochromic Luminescence of Copper Iodide Clusters: The Case of Phosphine Ligands, Inorganic Chemistry, vol.50, issue.21, pp.10682-10692, 2011. ,
DOI : 10.1021/ic201128a
URL : https://hal.archives-ouvertes.fr/hal-00694168
Ab initio studies of the copper(I) tetramers Cu4X4L4 (X = I, Br, Cl). Effects of cluster structure and of halide on photophysical properties, Inorganic Chemistry, vol.33, issue.3, pp.561-566, 1994. ,
DOI : 10.1021/ic00081a026
Thermochromic Luminescence of Sol???Gel Films Based on Copper Iodide Clusters, Chemistry of Materials, vol.20, issue.22, pp.7010-7016, 2008. ,
DOI : 10.1021/cm801780g
Balanced homodyne detection of second-harmonic generation from isolated subwavelength emitters, Applied Physics Letters, vol.89, issue.12, pp.121118-121113, 2006. ,
DOI : 10.1063/1.2356375
URL : https://hal.archives-ouvertes.fr/hal-00022891
Nanocrystal for Nonlinear Microscopy, Small, vol.261, issue.9, pp.1332-1336, 2008. ,
DOI : 10.1002/smll.200701093
Coherent nonlinear emission from a single KTP nanoparticle with broadband femtosecond pulses, Optics Express, vol.17, issue.6, pp.4652-4658, 2009. ,
DOI : 10.1364/OE.17.004652
Concerted Proton???Electron Transfers: Electrochemical and Related Approaches, Accounts of Chemical Research, vol.43, issue.7, pp.1019-1029, 2010. ,
DOI : 10.1021/ar9002812
Update 1 of: Electrochemical Approach to the Mechanistic Study of Proton-Coupled Electron Transfer, Chemical Reviews, vol.110, issue.12, pp.1-40, 2010. ,
DOI : 10.1021/cr100038y
Electrochemical approach to proton-coupled electron transfers: recent advances, Energy & Environmental Science, vol.125, issue.7, pp.7718-7731, 2012. ,
DOI : 10.1039/c2ee03241d
Theory of Coupled Electron and Proton Transfer Reactions, Chemical Reviews, vol.110, issue.12, pp.6939-6960, 2010. ,
DOI : 10.1021/cr1001436
The electrochemical approach to concerted proton--electron transfers in the oxidation of phenols in water, Proceedings of the National Academy of Sciences, vol.106, issue.43, pp.18143-18148, 2009. ,
DOI : 10.1073/pnas.0910065106
Concerted proton-coupled electron transfers in aquo/hydroxo/oxo metal complexes: Electrochemistry of [OsII(bpy)2py(OH2)]2+ in water, Proceedings of the National Academy of Sciences, vol.106, issue.29, pp.11829-11836, 2009. ,
DOI : 10.1073/pnas.0905020106
Electrochemical Approach to Concerted Proton and Electron Transfers. Reduction of the Water???Superoxide Ion Complex, Journal of the American Chemical Society, vol.127, issue.36, pp.12490-12491, 2005. ,
DOI : 10.1021/ja053911n
Breaking Bonds with Electrons and Protons. Models and Examples, Accounts of Chemical Research, vol.47, issue.1, pp.271-280, 2014. ,
DOI : 10.1021/ar4001444
Intramolecular dissociative electron transfer, Chemical Society Reviews, vol.125, issue.5, pp.418-428, 2005. ,
DOI : 10.1039/b300085k
Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage, Chemical Reviews, vol.114, issue.8, pp.4041-4062, 2014. ,
DOI : 10.1021/cr400641x
Proton?coupled electron transfer in azobenzene? hydrazobenzene couples with pending acid?base functions. Hydrogen?bonding and structural effects, J. Am. Chem. Soc, p.34 ,
Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects, Chemical Reviews, vol.108, issue.7 ,
DOI : 10.1021/cr068079z
Identification of active edge sites for electrochemical H 2 evolution from MoS 2 nanocatalysts, Science, issue.5834, pp.317100-102, 2007. ,
Amorphous molybdenum sulfide films as catalysts for electrochemical hydrogen production in water, Chem. Sci., vol.43, issue.7, pp.1262-1267, 2011. ,
DOI : 10.1039/C1SC00117E
Fe, Co, and Ni ions promote the catalytic activity of amorphous molybdenum sulfide films for hydrogen evolution, Chemical Science, vol.50, issue.8 ,
DOI : 10.1039/c2sc20539d
A Molecular MoS2 Edge Site Mimic for Catalytic Hydrogen Generation, Science, vol.335, issue.6069, pp.698-702, 2012. ,
DOI : 10.1126/science.1215868
A Janus cobalt-based catalytic material for electro-splitting of water, Nature Materials, vol.440, issue.9, pp.802-807, 2012. ,
DOI : 10.1038/nmat3385
URL : https://hal.archives-ouvertes.fr/cea-00960632
Anion-exchange synthesis of nanoporous FeP nanosheets as electrocatalysts for hydrogen evolution reaction, Chemical Communications, vol.133, issue.59 ,
DOI : 10.1039/c3cc43107j
Nanostructured nickel phosphide as an electrocatalyst for the hydrogen evolution reaction, J. Am. Chem. Soc, vol.135, issue.25, pp.9267-9270, 2013. ,
Hydrogen-Evolution Catalysts Based on Non-Noble Metal Nickel-Molybdenum Nitride Nanosheets, Angewandte Chemie International Edition, vol.113, issue.25, pp.6131-6135, 2012. ,
DOI : 10.1002/anie.201200699
Ni???Mo Nanopowders for Efficient Electrochemical Hydrogen Evolution, ACS Catalysis, vol.3, issue.2, pp.166-169, 2012. ,
DOI : 10.1021/cs300691m
Chemistry of Iron Sulfides, Chemical Reviews, vol.107, issue.2, pp.514-562, 2007. ,
DOI : 10.1021/cr0503658
Bioinspired iron sulfide nanoparticles for cheap and long? lived electrocatalytic molecular hydrogen evolution in neutral water, ACS Catal, vol.4, issue.38, pp.681-687, 2014. ,
Iron sulfide based catalyst for electrolytic water reduction into hydrogen gas, p.41, 2013. ,
Protein Design: Toward Functional Metalloenzymes, Chemical Reviews, vol.114, issue.7, pp.3495-3578, 2014. ,
DOI : 10.1021/cr400458x
Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase, Chemical Reviews, vol.114, issue.8 ,
DOI : 10.1021/cr400461p
The Artificial Leaf, Accounts of Chemical Research, vol.45, issue.5 ,
DOI : 10.1021/ar2003013
Iron Pyrite Nanocubes: Size and Shape Considerations for Photovoltaic Application, ACS Nano, vol.6, issue.10, pp.8940-8949, 2012. ,
DOI : 10.1021/nn3029502
Nanocrystal Ink as a Catalytic Electrode for Dye-Sensitized Solar Cells, Angewandte Chemie International Edition, vol.47, issue.26, pp.6694-6698, 2013. ,
DOI : 10.1002/anie.201300401
Chemistry of Iron Sulfides, Chemical Reviews, vol.107, issue.2, pp.514-562, 2007. ,
DOI : 10.1021/cr0503658
Manipulation of Charge Transfer Across Semiconductor Interface. A Criterion That Cannot Be Ignored in Photocatalyst Design, The Journal of Physical Chemistry Letters, vol.3, issue.5, pp.663-672, 2012. ,
DOI : 10.1021/jz201629p
X-ray Crystal Structure of the Fe-Only Hydrogenase (CpI) from Clostridium pasteurianum to 1.8 Angstrom Resolution, Science, vol.282, issue.5395, pp.1853-1858, 1998. ,
DOI : 10.1126/science.282.5395.1853
Desulfovibrio desulfuricans iron hydrogenase: the structure shows unusual coordination to an active site Fe binuclear center, Structure, vol.7, issue.1, pp.13-23, 1999. ,
DOI : 10.1016/S0969-2126(99)80005-7
A novel FeS cluster in Fe-only hydrogenases, Trends in Biochemical Sciences, vol.25, issue.3, pp.138-143, 2000. ,
DOI : 10.1016/S0968-0004(99)01536-4
Hydrogenases: active site puzzles and progress, Current Opinion in Chemical Biology, vol.8, issue.2, pp.133-140, 2004. ,
DOI : 10.1016/j.cbpa.2004.02.004
Chemistry and the hydrogenases, Chemical Society Reviews, vol.32, issue.5, pp.268-275, 2003. ,
DOI : 10.1039/b201317g
Carbon Monoxide and Cyanide Ligands in a Classical Organometallic Complex Model for Fe-Only Hydrogenase, Angewandte Chemie International Edition, vol.38, issue.21, pp.3178-3180, 1999. ,
DOI : 10.1002/(SICI)1521-3773(19991102)38:21<3178::AID-ANIE3178>3.0.CO;2-4
A di-iron dithiolate possessing structural elements of the carbonyl/cyanide sub-site of the H-centre of Fe-only hydrogenase, Chemical Communications, issue.22, pp.2285-2286, 1999. ,
DOI : 10.1039/a906391i
Transient FTIR spectroelectrochemical and stopped-flow detection of a mixed valence {Fe(i)???Fe(ii)} bridging carbonyl intermediate with structural elements and spectroscopic characteristics of the di-iron sub-site of all-iron hydrogenase, Chemical Communications, issue.7, pp.700-701, 2002. ,
DOI : 10.1039/b111613b
The Di-Iron Subsite of All-Iron Hydrogenase: Mechanism of Cyanation of a Synthetic {2Fe3S}???Carbonyl Assembly, Chemistry - A European Journal, vol.8, issue.17, pp.4037-4046, 2002. ,
DOI : 10.1002/1521-3765(20020902)8:17<4037::AID-CHEM4037>3.0.CO;2-O
Bimetallic Carbonyl Thiolates as Functional Models for Fe-Only Hydrogenases, Inorganic Chemistry, vol.41, issue.25, pp.6573-6582, 2002. ,
DOI : 10.1021/ic025838x
A Biomimetic Pathway for Hydrogen Evolution from a Model of the Iron Hydrogenase Active Site, Angewandte Chemie International Edition, vol.43, issue.8, pp.1006-1009, 2004. ,
DOI : 10.1002/anie.200353190
Modeling the Active Sites in Metalloenzymes. 3. Density Functional Calculations on Models for [Fe]-Hydrogenase:?? Structures and Vibrational Frequencies of the Observed Redox Forms and the Reaction Mechanism at the Diiron Active Center, Journal of the American Chemical Society, vol.123, issue.16, pp.3734-3742, 2001. ,
DOI : 10.1021/ja000116v
A Density Functional Theory Study on the Active Center of Fe-Only Hydrogenase:?? Characterization and Electronic Structure of the Redox States, Journal of the American Chemical Society, vol.124, issue.18, pp.5175-5182, 2002. ,
DOI : 10.1021/ja0118690
Subcluster, Inorganic Chemistry, vol.43, issue.12, pp.3733-3741, 2004. ,
DOI : 10.1021/ic035326y
??ber den photochemischen und oxydativen Abbau von Carbonylen, Justus Liebig's Annalen der Chemie, vol.54, issue.1, pp.268-287, 1929. ,
DOI : 10.1002/jlac.19294720113
All-iron hydrogenase: synthesis, structure and properties of {2Fe3S}-assemblies related to the di-iron sub-site of the H-cluster, pp.586-595, 2003. ,
Subsite-specific functionalization of the [4Fe-4S]2+ analog of iron-sulfur protein clusters, Journal of the American Chemical Society, vol.109, issue.8, pp.2546-2547, 1987. ,
DOI : 10.1021/ja00242a067
Density-functional approximation for the correlation energy of the inhomogeneous electron gas, Physical Review B, vol.33, issue.12, pp.8822-8824, 1986. ,
DOI : 10.1103/PhysRevB.33.8822
Density-functional exchange-energy approximation with correct asymptotic behavior, Physical Review A, vol.38, issue.6, pp.3098-3100, 1988. ,
DOI : 10.1103/PhysRevA.38.3098
Fully optimized contracted Gaussian basis sets of triple zeta valence quality for atoms Li to Kr, The Journal of Chemical Physics, vol.100, issue.8, pp.5829-5835, 1994. ,
DOI : 10.1063/1.467146
Photodetachment photoelectron spectroscopy of multiply charged anions using electrospray ionization, Review of Scientific Instruments, vol.70, issue.4, pp.1957-1966, 1999. ,
DOI : 10.1063/1.1149694
Probing the Electronic Structure of the Di-Iron Subsite of [Fe]-Hydrogenase:?? A Photoelectron Spectroscopic Study of Fe(I)???Fe(I) Model Complexes, The Journal of Physical Chemistry A, vol.107, issue.23, pp.4612-4618, 2003. ,
DOI : 10.1021/jp034432i
Probing the Intrinsic Electronic Structure of the Cubane [4Fe???4S] Cluster:?? Nature's Favorite Cluster for Electron Transfer and Storage, Journal of the American Chemical Society, vol.125, issue.46, pp.14072-14081, 2003. ,
DOI : 10.1021/ja036831x
Scrambling and Other H/D Exchange Processes by [Fe]-Hydrogenase Model Complexes, Inorganic Chemistry, vol.41, issue.15, pp.3917-3928, 2002. ,
DOI : 10.1021/ic020237r
A novel {Fe I -Fe II -Fe II -Fe I } iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution, Chem. Commun, pp.133-135, 2005. ,
Electronic Structure of the H Cluster in [Fe]-Hydrogenases, Journal of the American Chemical Society, vol.121, issue.34, pp.7877-7884, 1999. ,
DOI : 10.1021/ja991243y
Bioinorganic reaction centers on electrodes ? Modified electrodes possessing amino-acid, peptide and ferredoxin-type groups on a poly(pyrrole) backbone, J. Chem. Soc. Dalton Trans, pp.2181-2189, 1994. ,
Fontecilla-Camps, J. C. Structure, vol.7, pp.13-23, 1999. ,
X-ray Crystal Structure of the Fe-Only Hydrogenase (CpI) from Clostridium pasteurianum to 1.8 Angstrom Resolution, Science, vol.282, issue.5395, pp.1853-1861, 1998. ,
DOI : 10.1126/science.282.5395.1853
Combined Spectroscopic/Computational Study of Binuclear Fe(I)???Fe(I) Complexes:?? Implications for the Fully-Reduced Active-Site Cluster of Fe-Only Hydrogenases, Inorganic Chemistry, vol.44, issue.6, pp.1794-809, 2005. ,
DOI : 10.1021/ic048739n
Subcluster of Fe-Only Hydrogenases, Inorganic Chemistry, vol.41, issue.6, pp.1421-1430, 2002. ,
DOI : 10.1021/ic010770r
Assignment of Molecular Structures to the Electrochemical Reduction Products of Diiron Compounds Related to [Fe???Fe] Hydrogenase:?? A Combined Experimental and Density Functional Theory Study, Inorganic Chemistry, vol.46, issue.2, pp.384-94, 2007. ,
DOI : 10.1021/ic061211t
Modeling the Active Sites in Metalloenzymes. 3. Density Functional Calculations on Models for [Fe]-Hydrogenase:?? Structures and Vibrational Frequencies of the Observed Redox Forms and the Reaction Mechanism at the Diiron Active Center, Journal of the American Chemical Society, vol.123, issue.16, pp.3734-3776, 2001. ,
DOI : 10.1021/ja000116v
Enzymatic Mechanism of Fe-Only Hydrogenase:?? Density Functional Study on H???H Making/Breaking at the Diiron Cluster with Concerted Proton and Electron Transfers, Inorganic Chemistry, vol.43, issue.3, pp.923-953, 2004. ,
DOI : 10.1021/ic0342301
A novel FeS cluster in Fe-only hydrogenases, Trends in Biochemical Sciences, vol.25, issue.3, pp.138-181, 2000. ,
DOI : 10.1016/S0968-0004(99)01536-4
Cluster of [Fe] Hydrogenases. A Density Functional Theory Investigation, Inorganic Chemistry, vol.45, issue.10, pp.4109-4127, 2006. ,
DOI : 10.1021/ic051986m
Electron Transfer at a Dithiolate-Bridged Diiron Assembly:?? Electrocatalytic Hydrogen Evolution, Journal of the American Chemical Society, vol.126, issue.51, pp.16988-99, 2004. ,
DOI : 10.1021/ja045281f
Synthesis of the H-cluster framework of iron-only hydrogenase, Nature, vol.100, issue.7026, pp.610-613, 2005. ,
DOI : 10.1039/dt9940002181
The Di-Iron Subsite of All-Iron Hydrogenase: Mechanism of Cyanation of a Synthetic {2Fe3S}???Carbonyl Assembly, Chemistry - A European Journal, vol.8, issue.17, pp.4037-4083, 2002. ,
DOI : 10.1002/1521-3765(20020902)8:17<4037::AID-CHEM4037>3.0.CO;2-O
Characterization of a Diferrous Terminal Hydride Mechanistically Relevant to the Fe-Only Hydrogenases, Journal of the American Chemical Society, vol.127, issue.46, pp.16012-16015, 2005. ,
DOI : 10.1021/ja055475a
Electrocatalytic Proton Reduction by Phosphido-Bridged Diiron Carbonyl Compounds:?? Distant Relations to the H-Cluster?, Inorganic Chemistry, vol.43, issue.18, pp.5635-5679, 2004. ,
DOI : 10.1021/ic049746e
Steps along the Path to Dihydrogen Activation at [FeFe] Hydrogenase Structural Models:?? Dependence of the Core Geometry on Electrocatalytic Proton Reduction, Inorganic Chemistry, vol.46, issue.5, pp.1741-50, 2007. ,
DOI : 10.1021/ic0623361
Purification of Laboratory Chemicals, 36) Frisch, M. J.; et al. Gaussian 03, pp.4288-92, 1995. ,
Density-functional exchange-energy approximation with correct asymptotic behavior, Physical Review A, vol.38, issue.6, pp.3098-100, 1986. ,
DOI : 10.1103/PhysRevA.38.3098
Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, The Journal of Physical Chemistry A, vol.105, issue.34, pp.8111-8117, 2001. ,
DOI : 10.1021/jp011945l
Fax: (+33) (0)1 69 33 47 99, Phone: (+33), pp.69-102 ,
Sol-Gel Science The Physics and Chemistry of Sol-Gel Processing, J. Phys. Chem. New J. Chem. Chem. Mater. J. Chem. ReV, vol.88, issue.18, pp.5956-1007, 1984. ,
Toward millions of laser pulses with pyrromethene- and perylene-doped xerogels, Applied Optics, vol.36, issue.27, p.6760, 1997. ,
DOI : 10.1364/AO.36.006760
Aqueous routes to lanthanide-doped oxide nanophosphors, J. Mater. Chem., vol.16, issue.23???24, p.529, 2006. ,
DOI : 10.1039/B508656F
SHELXL-97, J. Appl. Crystallogr, vol.32, pp.115-141, 1997. ,
Chance and design???Proton transfer in water, channels and bioenergetic proteins, Biochimica et Biophysica Acta (BBA) - Bioenergetics, vol.1757, issue.8, pp.886-912, 2006. ,
DOI : 10.1016/j.bbabio.2006.06.017
Proton-Coupled Electron Transfer in Biology: Results from Synergistic Studies in Natural and Model Systems, Annual Review of Biochemistry, vol.78, issue.1, pp.673-699, 2008. ,
DOI : 10.1146/annurev.biochem.78.080207.092132
BIOCHEMISTRY: Water Photolysis in Biology, Science, vol.303, issue.5665, pp.1782-1784, 2004. ,
DOI : 10.1126/science.1096767
Radical Initiation in the Class I Ribonucleotide Reductase:?? Long-Range Proton-Coupled Electron Transfer?, Chemical Reviews, vol.103, issue.6, pp.2167-2202, 2003. ,
DOI : 10.1021/cr020421u
Elektronentransfer entlang Peptiden mit Cystein und Methionin als Relais-Aminos??uren, Angewandte Chemie, vol.110, issue.23, pp.4296-4298, 2009. ,
DOI : 10.1002/ange.200900827
Physical chemistry: The peripatetic proton, Nature, vol.103, issue.7133, pp.270-273, 2006. ,
DOI : 10.1038/446270a
Concerted Proton???Electron Transfer: Effect of Hydroxylic Additives on the Reduction of Benzophenone, 4-Cyanobenzophenone, and 4,4???-Dicyanobenzophenone, The Journal of Physical Chemistry C, vol.113, issue.38, pp.16686-16693, 2009. ,
DOI : 10.1021/jp904976v
Electrochemical oxidation of 2,4,6-tri-tert-butylphenol, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol.63, issue.3, pp.311-327, 1975. ,
DOI : 10.1016/S0022-0728(75)80303-2
Electrochemical and Homogeneous Proton-Coupled Electron Transfers:?? Concerted Pathways in the One-Electron Oxidation of a Phenol Coupled with an Intramolecular Amine-Driven Proton Transfer, Journal of the American Chemical Society, vol.128, issue.14, pp.4552-4553, 2006. ,
DOI : 10.1021/ja060527x
Historical Statistics for Mineral and Material Commodities in the United States, 802?807. (34), pp.14-15, 1999. ,