A. Développements and .. , 223 B. Effets lors de l'ablation et conséquences sur les mesures, p.224

V. Figure, Exemple d'une droite d'étalonnage avec ses intervalles de confiance en orange, de prédiction à 95% de confiance en bleu et la prédiction de la concentration et sa précision relative en vert

V. Figure, Exemples de distributions de résidus en fonction de la concentration : a/ distribution normale. b/ corrélation curviligne c/ hétéroscédascité, 1998.

. Actuellement, information la plus importante apportée par cet échantillon est que le volume et la masse ablatée sur les phénocristaux de feldspaths est plus important

F. Anderson, K. Nowicki, V. Hamilton, and T. Whitaker, Portable geochronology with LDRIMS: Learning to date meteorites like Zagami with the Boulder Creek granite, Abstract #2067, 42 nd Lunar and Planetary Science, 2011.

A. L. Albee and A. A. Chodos, Microprobe investigations on Apollo 11 samples, Geochimica et Cosmochimica Acta Supplement, vol.1, p.135, 1970.

S. Amoruso, Modeling of UV pulsed-laser ablation of metallic targets, Applied Physics A: Materials Science & Processing, vol.69, issue.3, pp.323-332, 1999.
DOI : 10.1007/s003390051008

G. W. Berger and D. York, Geothermometry from dating experiments, Geochimica et Cosmochimica Acta, vol.45, issue.6, pp.795-811, 1981.
DOI : 10.1016/0016-7037(81)90109-5

J. P. Bibring, Y. Langevin, J. F. Mustard, F. Poulet, R. Arvidson et al., Global Mineralogical and Aqueous Mars History Derived from OMEGA/Mars Express Data, Science, vol.312, issue.5772, pp.312-400, 2006.
DOI : 10.1126/science.1122659

URL : https://hal.archives-ouvertes.fr/insu-00363634

A. Bogaerts and Z. Chen, Effect of laser parameters on laser ablation and laser-induced plasma formation: A numerical modeling investigation, Spectrochimica Acta Part B: Atomic Spectroscopy, vol.60, issue.9-10, pp.1280-1307, 2005.
DOI : 10.1016/j.sab.2005.06.009

G. Bastiaans and R. Mangold, The calculation of electron density and temperature in Ar spectroscopic plasmas from continuum and line spectra, Spectrochimica Acta Part B: Atomic Spectroscopy, vol.40, issue.7, pp.885-892, 1985.
DOI : 10.1016/0584-8547(85)80059-8

D. D. Bogard and D. L. Garrison, Argon-39-argon-40 ???ages??? and trapped argon in Martian shergottites, Chassigny, and Allan Hills 84001, Meteoritics & Planetary Science, vol.91, issue.Suppl., pp.451-473, 1999.
DOI : 10.1111/j.1945-5100.1999.tb01353.x

D. D. Bogard and J. Park, Ar, Meteoritics & Planetary Science, vol.46, issue.Suppl 7, pp.1113-1126, 2008.
DOI : 10.1111/j.1945-5100.2008.tb01116.x

D. D. Bogard, K-Ar dating of rocks on Mars: Requirements from Martian meteorite analyses and isochron modeling, Meteoritics & Planetary Science, vol.65, issue.1, pp.3-14, 2009.
DOI : 10.1111/j.1945-5100.2009.tb00713.x

O. V. Borisov, X. Mao, and R. E. Russo, Effects of crater development on fractionation and signal intensity during laser ablation inductively coupled plasma mass spectrometry, Spectrochimica Acta Part B: Atomic Spectroscopy, vol.55, issue.11, pp.55-1693, 2000.
DOI : 10.1016/S0584-8547(00)00272-X

J. M. Boyce, A. L. Dial, and . Jr, Relative ages of flow units in Mare Imbrium and Sinus Iridum, Lunar Science Conference, vol.3, pp.2585-2595, 1975.

W. Boynton, G. Taylor, L. Evans, R. Reedy, R. Starr et al., Concentration of H, and Th in the low-and midlatitude regions of Mars, pp.112-124, 2007.

M. H. Carr, I. Head, and J. W. , Geologic history of Mars, Earth and Planetary Science Letters, vol.294, issue.3-4, pp.185-203, 2010.
DOI : 10.1016/j.epsl.2009.06.042

C. Cassignol and P. Y. Gillot, Range and effectiveness of unspiked potassium-argon dating: Experimental groundwork and applications, pp.159-179, 1982.

E. Coulie, X. Quidelleur, P. Y. Gillot, V. Courtillot, J. C. Lefèvre et al., Comparative K???Ar and Ar/Ar dating of Ethiopian and Yemenite Oligocene volcanism: implications for timing and duration of the Ethiopian traps, Earth and Planetary Science Letters, vol.206, issue.3-4, pp.477-492, 2003.
DOI : 10.1016/S0012-821X(02)01089-0

Y. Cho, Y. N. Miura, and S. Sugita, Development of a laser ablation Isochron K-Ar Dating Instrument for Landing planetary missions, Abstract #1093, 43 rd Lunar and Planetary Sciences Conference, 2012.

Y. Cho, Y. N. Miura, and S. Sugita, Development of an in situ K-Ar isochron dating method using LIBS-QMS configuration, Abstract #1505, 44 th Lunar and Planetary Sciences Conference, 2013.

Y. Cho, Y. N. Miura, and S. Sugita, Development of an in situ K-Ar Dating Technique Using LIBS-Qms Combination, Mineralogical Magazine, vol.878, issue.5, p.77, 2013.

B. A. Cohen, B. A. Cohen, Z. Li, J. S. Miller, W. B. Brinckerhoff et al., Development of the potassium-argon laser experiment (KARLE) instrument for in situ geochronology. Abstract #1267, 43 rd Lunar and Planetary Science Conference, Update on development of the Potassium-Argon laser experiment (KArLE) instrument for in situ geochronology. Abstract #2363, 44 th Lunar and Planetary Sciences Conference, 2012.

J. S. Cowpe and R. D. Pilkington, Swagelok Ultra-Torr based feed-through design for coupling optical fibre bundles into vacuum systems, Vacuum, vol.82, issue.11, pp.1341-1343, 2008.
DOI : 10.1016/j.vacuum.2008.03.002

D. A. Cremers, R. , and L. J. , Handbook of laser-induced breakdown spectroscopy, 2006.

A. Cousin, O. Forni, S. Maurice, O. Gasnault, C. Fabre et al., Laser induced breakdown spectroscopy library for the Martian environment, Spectrochimica Acta Part B: Atomic Spectroscopy, vol.66, issue.11-12, pp.66-805, 2011.
DOI : 10.1016/j.sab.2011.10.004

A. Cousin, LIBS (Laser-Induced Breakdown Spectroscopy) pour l'exploration martienne, Thèse de doctorat en planétologie. Toulouse, p.213, 2012.
URL : https://hal.archives-ouvertes.fr/tel-00717266

K. Danzer and L. A. Currie, Guidelines for calibration in analytical chemistry, Pure and Applied Chemistry, vol.70, issue.4, pp.993-1014, 1998.

P. T. Doran, S. M. Clifford, S. L. Forman, L. Nyquist, D. A. Papanastassiou et al., Mars chronology: assessing techniques for quantifying surficial processes, Earth-Science Reviews, vol.67, issue.3-4, pp.313-337, 2004.
DOI : 10.1016/j.earscirev.2004.04.001

P. T. Doran, S. M. Clifford, S. L. Forman, L. Nyquist, D. A. Papanastassiou et al., Mars chronology: assessing techniques for quantifying surficial processes, Earth-Science Reviews, vol.67, issue.3-4, pp.313-337, 2004.
DOI : 10.1016/j.earscirev.2004.04.001

O. Eugster, Cosmic-ray Exposure Ages of Meteorites and Lunar Rocks and Their Significance, Chemie der Erde - Geochemistry, vol.63, issue.1, 2003.
DOI : 10.1078/0009-2819-00021

A. J. Effenberger and J. R. Scott, Effect of Atmospheric Conditions on LIBS Spectra, Sensors, vol.10, issue.5, pp.4907-4925, 2010.
DOI : 10.3390/s100504907

K. A. Farley, J. A. Hurowitz, P. D. Asimow, N. S. Jacobson, and J. A. Cartwright, A double-spike method for K???Ar measurement: A technique for high precision in situ dating on Mars and other planetary surfaces, Geochimica et Cosmochimica Acta, vol.110, pp.1-12, 2013.
DOI : 10.1016/j.gca.2013.02.010

M. Flisch, Potassium-argon analysis: In Numerical Dating in Stratigraphy, pp.151-158, 1982.

E. L. Garner, T. J. Murphy, J. W. Gramlich, P. J. Paulsen, and I. L. Barnes, Absolute isotopic abundance ratios and the atomic weight of a reference sample of potassium, Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry, vol.79, issue.6, pp.713-725, 1975.
DOI : 10.6028/jres.079A.028

P. Y. Gillot and Y. Cornette, The Cassignol technique for potassium ? argon dating, precision and accuracy -exemples from the late pleistocene to recent volcanics from southern Italy, Chemical Geology, vol.59, issue.2-3, pp.205-222, 1986.

P. Y. Gillot, A. Hildenbrand, J. C. Lefevre, and C. Albore-livadie, The K/Ar dating method : principle, analytical techniques, and application to Holocene volcanic eruptions in Southern Italy, Acta Vulcanologica, vol.18, pp.55-66, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00380285

R. Greeley and B. D. Schneid, Magma Generation on Mars: Amounts, Rates, and Comparisons with Earth, Moon, and Venus, Science, vol.254, issue.5034, pp.996-998, 1991.
DOI : 10.1126/science.254.5034.996

F. E. Grubbs, Procedures for Detecting Outlying Observations in Samples, Technometrics, vol.6, issue.7, pp.1-21, 1969.
DOI : 10.1080/00401706.1969.10490657

M. Guillong, I. Horn, and D. Günther, Capabilities of a homogenized 266??nm Nd:YAG laser ablation system for LA-ICP-MS, J. Anal. At. Spectrom., vol.11, issue.1, pp.8-14, 2002.
DOI : 10.1039/B107823M

R. D. Harris, D. A. Cremers, C. Khoo, and K. Benelli, Libs-based detection of geological samples at low pressures (<0,001 torr) for Moon and asteroid exploration, Abstract #2613, 36 th Lunar and Planetary Science Conference, 2005.

W. K. Hartmann and C. A. Wood, Moon: Origin and evolution of multi-ring basins, The Moon, vol.2, issue.1, pp.3-78, 1971.
DOI : 10.1007/BF00620390

W. K. Hartmann and G. Neukum, Cratering Chronology and the Evolution of Mars, Space Science Reviews, vol.96, pp.165-194, 2001.
DOI : 10.1007/978-94-017-1035-0_6

W. K. Hartmann, Martian cratering 8: Isochron refinement and the chronology of Mars, Icarus, vol.174, issue.2, pp.294-320, 2005.
DOI : 10.1016/j.icarus.2004.11.023

J. W. Head, Interplanetary correlation: themes in the geological history of terrestrial planetary bodies, p.24, 2006.

W. F. Ho, C. W. Ng, C. , and N. H. , Spectrochemical Analysis of Liquids Using Laser-Induced Plasma Emissions: Effects of Laser Wavelength, Applied Spectroscopy, vol.51, issue.1, pp.87-91, 1997.
DOI : 10.1366/0003702971938812

A. Ismaël, Une évaluation des performances analytiques de la spectroscopie sur plasma induit par laser (LIBS), Thèse de doctorat en laser. Bordeaux, p.252, 2011.

B. A. Ivanov, Mars/Moon Cratering Rate Ratio Estimates, Space Sciences Reviens, vol.96, pp.87-104, 2001.
DOI : 10.1007/978-94-017-1035-0_4

S. K. Karunatillake, J. M. Keller, S. W. Squyres, W. Boynton, J. Brückner et al., Chemical compositions at Mars landing sites subject to Mars Odyssey Gamma Ray Spectrometer constraints, Journal of Geophysical Research, vol.436, issue.7047, p.112, 1991.
DOI : 10.1029/2006JE002859

A. K. Knight, N. L. Scherbarth, D. A. Cremers, and M. J. Ferris, Characterization of Laser-Induced Breakdown Spectroscopy (LIBS) for Application to Space Exploration, Applied Spectroscopy, vol.54, issue.3, pp.331-340, 2000.
DOI : 10.1366/0003702001949591

H. C. Liu, O. V. Borisov, X. Mao, S. Shuttleworth, and R. E. Russo, Pb/U Fractionation during Nd:YAG 213 nm and 266 nm Laser Ablation Sampling with Inductively Coupled Plasma Mass Spectrometry, Applied Spectroscopy, vol.54, issue.10, pp.54-1435, 2000.
DOI : 10.1366/0003702001948565

M. E. Madden, R. J. Bodnar, and J. D. Rimstidt, Jarosite as an indicator of water-limited chemical weathering on Mars, Nature, vol.14, issue.7010, pp.821-823, 2004.
DOI : 10.1016/S0016-7037(99)00401-9

A. J. Mank and P. R. Mason, A critical assessment of laser ablation ICP-MS as an analytical tool for depth analysis in silica-based glass samples, Journal of Analytical Atomic Spectrometry, vol.14, issue.8, pp.14-1143, 1999.
DOI : 10.1039/a903304a

I. Mcdougall and T. M. Harrison, Geochronology and thermochronology by the 40 Ar/ 39 Ar method, 1988.

G. G. Michael and G. Neukum, Planetary surface dating from crater size???frequency distribution measurements: Partial resurfacing events and statistical age uncertainty, Earth and Planetary Science Letters, vol.294, issue.3-4, pp.3-4, 2010.
DOI : 10.1016/j.epsl.2009.12.041

G. G. Michael, Planetary surface dating from crater size???frequency distribution measurements: Multiple resurfacing episodes and differential isochron fitting, Icarus, vol.226, issue.1, pp.885-890, 2013.
DOI : 10.1016/j.icarus.2013.07.004

R. A. Multari, L. E. Foster, D. A. Cremers, and M. J. Ferris, Effect of Sampling Geometry on Elemental Emissions in Laser-Induced Breakdown Spectroscopy, Applied Spectroscopy, vol.50, issue.12, pp.50-1483, 1996.
DOI : 10.1366/0003702963904593

G. Neukum, B. König, and J. Arkani-hamed, A study of lunar impact crater size-distributions, The Moon, vol.7, issue.Suppl. 4, pp.201-229, 1975.
DOI : 10.1007/BF00577878

G. Neukum, Meteoritenbombardement und Datierung planetarer Oberflachen. Habilitation, 1983.

G. Neukum, B. A. Ivanov, and W. K. Hartmann, Cratering Records in the Inner Solar System in Relation to the Lunar Reference System, Space Science Reviews, vol.96, pp.1-4, 2001.
DOI : 10.1007/978-94-017-1035-0_3

O. Nier, A Redetermination of the Relative Abundances of the Isotopes of Carbon, Nitrogen, Oxygen, Argon, and Potassium, Physical Review, vol.77, issue.6, pp.789-793, 1950.
DOI : 10.1103/PhysRev.77.789

G. S. Odin, Interlaboratory standards for dating purposes: In Numerical Dating in Stratigraphy, pp.123-148, 1982.

J. Park, D. W. Ming, D. H. Garrison, J. H. Jones, D. D. Bogard et al., Noble gas analysis for Mars robotic missions: evaluating K-Ar dating for Mars rock analogs and martian shergottites, 2009.

L. Radziemski, D. A. Cremers, K. Benelli, C. Khoo, and R. D. Harris, Use of the vacuum ultraviolet spectral region for laser-induced breakdown spectroscopy-based Martian geology and exploration, Spectrochimica Acta Part B: Atomic Spectroscopy, vol.60, issue.2, pp.237-248, 2005.
DOI : 10.1016/j.sab.2004.12.007

I. Rauschenbach, E. K. Jessberger, S. G. Pavlov, and H. Hübers, Miniaturized Laser-Induced Breakdown Spectroscopy for the in-situ analysis of the Martian surface: Calibration and quantification, Spectrochimica Acta Part B: Atomic Spectroscopy, vol.65, issue.8, pp.758-768, 2010.
DOI : 10.1016/j.sab.2010.03.018

J. Ricci, X. Quidelleur, V. Pavlov, S. Orlov, A. Shatsillo et al., New 40Ar/39Ar and K???Ar ages of the Viluy traps (Eastern Siberia): Further evidence for a relationship with the Frasnian???Famennian mass extinction, Palaeogeography, Palaeoclimatology, Palaeoecology, vol.386, pp.531-540, 2013.
DOI : 10.1016/j.palaeo.2013.06.020

URL : https://hal.archives-ouvertes.fr/hal-00839612

A. Riedo, S. Meyer, B. Heredia, M. B. Neuland, A. Bieler et al., Highly accurate isotope composition measurements by a miniature laser ablation mass spectrometer designed for in situ investigations on planetary surfaces, Planetary and Space Science, vol.87, pp.1-13, 2013.
DOI : 10.1016/j.pss.2013.09.007

S. Robbins, G. Di-achille, and B. Hynek, The volcanic history of Mars: High-resolution crater-based studies of the calderas of 20 volcanoes, Icarus, vol.211, issue.2, pp.211-1179, 2011.
DOI : 10.1016/j.icarus.2010.11.012

V. Rouchon, J. C. Lefèvre, X. Quidelleur, G. Guérin, and P. Y. Gillot, Nonspiked 40Ar and 36Ar quantification using a quadrupole mass spectrometer: A potential for K???Ar geochronology, International Journal of Mass Spectrometry, vol.270, issue.1-2, pp.52-61, 2008.
DOI : 10.1016/j.ijms.2007.11.009

URL : https://hal.archives-ouvertes.fr/hal-00375674

R. E. Russo, Laser Ablation, Applied Spectroscopy, vol.49, issue.9, pp.14-28, 1995.
DOI : 10.1366/0003702953965399

R. E. Russo, X. L. Mao, O. V. Borisov, and H. Liu, Influence of wavelength on fractionation in laser ablation ICP-MS, Journal of Analytical Atomic Spectrometry, vol.15, issue.9, pp.1115-1120, 2000.
DOI : 10.1039/b004243i

R. E. Russo, X. Mao, H. Liu, J. Gonzalez, and S. S. Mao, Laser ablation in analytical chemistry???a review, Talanta, vol.57, issue.3, pp.425-451, 2002.
DOI : 10.1016/S0039-9140(02)00053-X

B. Sallé, D. A. Cremers, S. Maurice, R. C. Wiens, and P. Fichet, Evaluation of a compact spectrograph for in-situ and stand-off Laser-Induced Breakdown Spectroscopy analyses of geological samples on Mars missions, Spectrochimica Acta Part B: Atomic Spectroscopy, vol.60, issue.6, pp.805-815, 2005.
DOI : 10.1016/j.sab.2005.05.007

D. H. Scott and M. H. Carr, Geologic map of Mars, U.S. Geological Survey Misc. Inv. Map, p.1083, 1978.

J. P. Singh and S. N. Hakur, Laser-Induced Breakdown Spectroscopy. Access Online via, 2007.

L. A. Soderblom and L. A. Lebofsky, Technique for rapid determination of relative ages of lunar areas from orbital photography, Journal of Geophysical Research, vol.12, issue.2, pp.279-296, 1972.
DOI : 10.1029/JB077i002p00279

C. B. Stipe, E. Guevara, J. Brown, and G. R. Rossman, Quantitative laser-induced breakdown spectroscopy of potassium for in-situ geochronology on Mars, Spectrochimica Acta Part B: Atomic Spectroscopy, vol.70, pp.45-50, 2012.
DOI : 10.1016/j.sab.2012.04.010

E. M. Stolper, M. B. Baker, M. E. Newcombe, M. E. Schmidt, A. H. Trieman et al., The Petrochemistry of Jake_M: A Martian Mugearite, Science, vol.341, issue.6153, p.341, 2013.
DOI : 10.1126/science.1239463

URL : https://hal.archives-ouvertes.fr/hal-01315524

T. D. Swindle, R. Bode, W. V. Boynton, D. A. Kring, M. Williams et al., AGE (Argon Geochronology Experiment): an instrument for in situ geochronology on the surface of Mars, Abstract #1488, 44 th Lunar and Planetary Sciences Conference, 2003.

K. L. Tanaka, The stratigraphy of Mars, Journal of Geophysical Research, vol.82, issue.B13, pp.91-139, 1978.
DOI : 10.1029/JB091iB13p0E139

K. L. Tanaka, T. M. Hare, and J. A. Skinner, Geologic map of the northern plains of Mars, USGS. National Aeronautics and Space Administration (electronic resource, 2005.

N. J. Tosca, S. M. Mclennan, B. C. Clark, J. P. Grotzinger, J. A. Hurowitz et al., Geochemical modeling of evaporation processes on Mars: Insight from the sedimentary record at Meridiani Planum, Earth and Planetary Science Letters, vol.240, issue.1, pp.122-148, 2005.
DOI : 10.1016/j.epsl.2005.09.042

N. J. Tosca and S. M. Mclennan, Constraints on evaporation processes at Meridiani Planum: combining theoretical and experimental data, Abstract #2278, 37 th Lunar and Planetary Sciences Conference, 2006.

J. M. Tucker, Calibrating Chemcam : preparing to probe the Red planet, Thèse de doctorat en planétologie, p.126, 2009.

G. Turner, 40Ar39Ar ages from the lunar maria, Earth and Planetary Science Letters, vol.11, issue.1-5, pp.169-191, 1971.
DOI : 10.1016/0012-821X(71)90161-0

J. M. Vadillo, J. M. Fernandez-romero, C. Rodriguez, and J. J. Laserna, Effect of plasma shielding on laser ablation rate of pure metals at reduced pressure, Surface and interface analysis, issue.11, pp.27-1009, 1999.

A. Vertes, P. Juhasz, D. Wolf, M. Gijbels, and R. , Hydrodynamic modelling of laser plasma ionization processes, International Journal of Mass Spectrometry and Ion Processes, vol.94, issue.1-2, pp.63-85, 1989.
DOI : 10.1016/0168-1176(89)80060-6

P. Z. Vroon, B. Van-der-wagt, J. M. Koornneef, and G. R. Davies, Problems in obtaining precise and accurate Sr isotope analysis from geological materials using laser ablation MC-ICPMS, Analytical and Bioanalytical Chemistry, vol.61, issue.2, pp.465-476, 2008.
DOI : 10.1007/s00216-007-1742-9

S. C. Werner and K. L. Tanaka, Redefinition of the crater-density and absolute-age boundaries for the chronostratigraphic system of Mars, Icarus, vol.215, issue.2, pp.603-607, 2011.
DOI : 10.1016/j.icarus.2011.07.024

D. E. Wilhelms, J. F. Mccauley, and N. J. Trask, The geologic history of the moon, pp.102-592, 1987.

?. Yalç?n, Y. Y. Tsui, and R. Fedosejevs, Pressure dependence of emission intensity in femtosecond laser-induced breakdown spectroscopy, J. Anal. At. Spectrom., vol.57, issue.7, pp.1295-1301, 2004.
DOI : 10.1039/B404132A