T. Tanaka, Z. Bai, Y. Srinoulprasert, and B. G. Yang, Chemokines in tumor progression and metastasis, Cancer Science, vol.62, issue.6, pp.317-322, 2005.
DOI : 10.1073/pnas.2235846100

X. Y. Liang, CXCR4, Inhibitors and Mechanisms of Action, Chemical Biology & Drug Design, vol.36, issue.2, pp.97-110, 2008.
DOI : 10.1111/j.1747-0285.2008.00681.x

J. Kuil, T. Buckle, and F. W. Van-leeuwen, Imaging agents for the chemokine receptor 4 (CXCR4), Chemical Society Reviews, vol.34, issue.Suppl 1, pp.5239-5261, 2012.
DOI : 10.1007/s1203201199900

R. Horuk, Chemokine receptors, Cytokine & Growth Factor Reviews, vol.12, issue.4, pp.313-335, 2001.
DOI : 10.1016/S1359-6101(01)00014-4

X. Q. Sun, G. C. Cheng, M. G. Hao, J. H. Zheng, X. M. Zhou et al., CXCL12 / CXCR4 / CXCR7 chemokine axis and cancer progression, Cancer and Metastasis Reviews, vol.89, issue.1, pp.709-722, 2010.
DOI : 10.1007/s10555-010-9256-x
URL : http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3175097

A. P. Vicari and C. Caux, Chemokines in cancer, Cytokine & Growth Factor Reviews, vol.13, issue.2, pp.143-154, 2002.
DOI : 10.1016/S1359-6101(01)00033-8

J. W. Murphy, Y. Cho, A. Sachpatzidis, C. P. Fan, M. E. Hodsdon et al., Structural and Functional Basis of CXCL12 (Stromal Cell-derived Factor-1??) Binding to Heparin, Journal of Biological Chemistry, vol.282, issue.13, pp.10018-10027, 2007.
DOI : 10.1074/jbc.M608796200

D. J. Scholten, M. Canals, D. Maussang, L. Roumen, M. J. Smit et al., Pharmacological modulation of chemokine receptor function, British Journal of Pharmacology, vol.106, issue.1, pp.1617-1643, 2012.
DOI : 10.1111/j.1476-5381.2011.01551.x

W. T. Choi, S. Duggineni, and Y. Xu, Drug Discovery Research Targeting the CXC Chemokine Receptor 4 (CXCR4), Journal of Medicinal Chemistry, vol.55, issue.3, pp.977-994, 2012.
DOI : 10.1021/jm200568c

F. Balkwill and . Semin, The significance of cancer cell expression of the chemokine receptor CXCR4, Seminars in Cancer Biology, vol.14, issue.3, pp.171-179, 2004.
DOI : 10.1016/j.semcancer.2003.10.003

D. Clercq and E. , HIV-chemotherapy and -prophylaxis: new drugs, leads and approaches, The International Journal of Biochemistry & Cell Biology, vol.36, issue.9, pp.1800-1822, 2004.
DOI : 10.1016/j.biocel.2004.02.015

M. J. Endres, P. R. Clapham, M. Marsh, M. Ahuja, T. J. Davis et al., CD4-Independent Infection by HIV-2 Is Mediated by Fusin/CXCR4, Cell, vol.87, issue.4, pp.745-756, 1996.
DOI : 10.1016/S0092-8674(00)81393-8

F. Baribaud, T. G. Edwards, M. Sharron, A. Brelot, N. Heveker et al., Antigenically Distinct Conformations of CXCR4, Journal of Virology, vol.75, issue.19, pp.8957-8967, 2001.
DOI : 10.1128/JVI.75.19.8957-8967.2001

P. Loetscher, J. H. Gong, B. Dewald, M. Baggiolini, and I. Clark-lewis, N-terminal Peptides of Stromal Cell-derived Factor-1 with CXC Chemokine Receptor 4 Agonist and Antagonist Activities, Journal of Biological Chemistry, vol.273, issue.35, pp.22279-22283, 1998.
DOI : 10.1074/jbc.273.35.22279

Z. W. Luo, N. M. Zhou, J. S. Luo, J. W. Hall, and . Huang, The Role of Positively Charged Residues in CXCR4 Recognition Probed with Synthetic Peptides, Biochemical and Biophysical Research Communications, vol.263, issue.3, pp.691-695, 1999.
DOI : 10.1006/bbrc.1999.1441

J. S. Luo, Z. W. Luo, N. M. Zhou, J. W. Hall, and . Huang, Attachment of C-Terminus of SDF-1 Enhances the Biological Activity of Its N-Terminal Peptide, Biochemical and Biophysical Research Communications, vol.264, issue.1, pp.42-47, 1999.
DOI : 10.1006/bbrc.1999.1476

H. Tamamura, M. Waki, M. Imai, A. Otaka, T. Ibuka et al., Downsizing of an HIV???cell fusion inhibitor, T22 ([Tyr5,12, Lys7]-Polyphemusin II), with the maintenance of anti-HIV activity and solution structure1, Bioorganic & Medicinal Chemistry, vol.6, issue.4, pp.473-479, 1998.
DOI : 10.1016/S0968-0896(97)10055-4

H. Tamamura, A. Omagari, S. Oishi, T. Kanamoto, N. Yamamoto et al., Pharmacophore identification of a specific CXCR4 inhibitor, T140, leads to development of effective anti-HIV agents with very high selectivity indexes, Bioorganic & Medicinal Chemistry Letters, vol.10, issue.23, pp.2633-2637, 2000.
DOI : 10.1016/S0960-894X(00)00535-7

H. Tamamura, K. Hiramatsu, S. Kusano, S. Terakubo, N. Yamamoto et al., Synthesis of potent CXCR4 inhibitors possessing low cytotoxicity and improved biostability based on T140 derivativesElectronic supplementary information (ESI) available: Fig. S1: behaviors of TE14005 (a), TE14011 and Ac-TE14011 (b) in mouse serum; Fig. S2: behaviors of TE14011 (a), Ac-TE14011 (b), TN14003 (c), Ac-TN14003 (d), TC14012 (e) and Ac-TC14012 (f) in rat liver homogenate; Table S1: characterization data of novel synthetic peptides; HPLC charts for synthetic compounds of TE14005, TE14011 and Ac-TE14011, and for a degraded sample of TE14011 in rat liver homogenate and its co-injection with an authentic compound des-[Arg1, Arg2, Nal3]-TE14011. See http://www.rsc.org/suppdata/ob/b3/b306473p/, Organic & Biomolecular Chemistry, vol.1, issue.21, pp.3656-3662, 2003.
DOI : 10.1039/b306473p

S. Ueda, S. Oishi, Z. X. Wang, T. Araki, H. Tamamura et al., Structure???Activity Relationships of Cyclic Peptide-Based Chemokine Receptor CXCR4 Antagonists:?? Disclosing the Importance of Side-Chain and Backbone Functionalities, Journal of Medicinal Chemistry, vol.50, issue.2, pp.192-198, 2007.
DOI : 10.1021/jm0607350

H. Tamamura, K. Hiramatsu, S. Ueda, Z. X. Wang, S. Kusano et al., )-Alkene Dipeptide Isosteres and Its Application to the Synthesis and Biological Evaluation of Pseudopeptide Analogues of the CXCR4 Antagonist FC131, Journal of Medicinal Chemistry, vol.48, issue.2, pp.380-391, 2005.
DOI : 10.1021/jm049429h

X. Y. Liang and P. Sadler, Cyclam complexes and their applications in medicine, Chemical Society Reviews, vol.33, issue.4, pp.246-266, 2004.
DOI : 10.1039/b313659k

A. R. Lam, S. Bhattacharya, K. Patel, S. E. Hall, A. Mao et al., Importance of Receptor Flexibility in Binding of Cyclam Compounds to the Chemokine Receptor CXCR4, Journal of Chemical Information and Modeling, vol.51, issue.1, pp.139-147, 2011.
DOI : 10.1021/ci1003027

D. Clercq and E. , The AMD3100 story: The path to the discovery of a stem cell mobilizer (Mozobil), Biochemical Pharmacology, vol.77, issue.11, pp.1655-1664, 2009.
DOI : 10.1016/j.bcp.2008.12.014
URL : https://hal.archives-ouvertes.fr/hal-00493482

G. C. Valks, G. Mcrobbie, E. A. Lewis, T. J. Hubin, T. M. Hunter et al., Configurationally Restricted Bismacrocyclic CXCR4 Receptor Antagonists, Journal of Medicinal Chemistry, vol.49, issue.21, pp.6162-6165, 2006.
DOI : 10.1021/jm0607810
URL : http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.497.7058

R. Smith, D. Huskens, D. Daelemans, R. E. Mewis, C. D. Garcia et al., CXCR4 chemokine receptor antagonists: nickel(ii) complexes of configurationally restricted macrocycles, Dalton Transactions, vol.186, issue.37, pp.11369-11377
DOI : 10.1039/c2dt31137b

S. Hatse, K. Princen, E. De-clercq, M. M. Rosenkilde, T. W. Schwartz et al., AMD3465, a monomacrocyclic CXCR4 antagonist and potent HIV entry inhibitor, Biochemical Pharmacology, vol.70, issue.5, pp.752-761, 2005.
DOI : 10.1016/j.bcp.2005.05.035

S. P. Kawatkar, M. C. Yan, H. Gevariya, M. Y. Lim, S. Eisold et al., Computational analysis of the structural mechanism of inhibition of chemokine receptor CXCR4 by small molecule antagonists, Experimental Biology and Medicine, vol.330, issue.7, pp.844-850, 2011.
DOI : 10.1038/382635a0

M. M. Rosenkilde, L. O. Gerlach, S. Hatse, R. T. Skerlj, D. Schols et al., Molecular Mechanism of Action of Monocyclam Versus Bicyclam Non-peptide Antagonists in the CXCR4 Chemokine Receptor, Journal of Biological Chemistry, vol.282, issue.37, pp.27354-27365, 2007.
DOI : 10.1074/jbc.M704739200

R. S. Wong, V. Bodart, M. Metz, J. Labrecque, G. Bridger et al., Comparison of the Potential Multiple Binding Modes of Bicyclam, Monocylam, and Noncyclam Small-Molecule CXC Chemokine Receptor 4 Inhibitors, Molecular Pharmacology, vol.74, issue.6, pp.1485-1495, 2008.
DOI : 10.1124/mol.108.049775

D. G. Duda, S. V. Kozin, N. D. Kirkpatrick, L. Xu, D. Fukumura et al., CXCL12 (SDF1??)-CXCR4/CXCR7 Pathway Inhibition: An Emerging Sensitizer for Anticancer Therapies?, Clinical Cancer Research, vol.17, issue.8, pp.2074-2080, 2011.
DOI : 10.1158/1078-0432.CCR-10-2636

A. Azhdarinia, P. Ghosh, S. Ghosh, N. Wilganowski, and E. M. Sevick-muraca, Dual-Labeling Strategies for Nuclear and Fluorescence Molecular Imaging: A Review and Analysis, Molecular Imaging and Biology, vol.38, issue.4, pp.261-276, 2012.
DOI : 10.1007/s11307-011-0528-9

G. Banisadr, E. Dicou, T. Berbar, W. Rostene, A. Lombet et al., Characterization and visualization of [125I] stromal cell-derived factor-1?? binding to CXCR4 receptors in rat brain and human neuroblastoma cells, Journal of Neuroimmunology, vol.110, issue.1-2, pp.151-160, 2000.
DOI : 10.1016/S0165-5728(00)00338-6

S. Nimmagadda, M. Pullambhatla, and M. G. Pomper, Immunoimaging of CXCR4 Expression in Brain Tumor Xenografts Using SPECT/CT, Journal of Nuclear Medicine, vol.50, issue.7, pp.1124-1130, 2009.
DOI : 10.2967/jnumed.108.061325

O. Aberg, F. Pisaneschi, G. Smith, Q. D. Nguyen, E. Stevens et al., 18F-labelling of a cyclic pentapeptide inhibitor of the chemokine receptor CXCR4, Journal of Fluorine Chemistry, vol.135, pp.200-206, 2012.
DOI : 10.1016/j.jfluchem.2011.11.003

O. Jacobson, I. D. Weiss, D. O. Kiesewetter, J. M. Farber, and X. Y. Chen, PET of Tumor CXCR4 Expression with 4-18F-T140, Journal of Nuclear Medicine, vol.51, issue.11, pp.1796-1804, 2010.
DOI : 10.2967/jnumed.110.079418

T. J. Wadas, E. H. Wong, G. R. Weisman, and C. Anderson, Coordinating Radiometals of Copper, Gallium, Indium, Yttrium, and Zirconium for PET and SPECT Imaging of Disease, Chemical Reviews, vol.110, issue.5, pp.2858-2902, 2010.
DOI : 10.1021/cr900325h

L. Lattuada, A. Barge, G. Cravotto, G. B. Giovenzana, and L. Tei, The synthesis and application of polyamino polycarboxylic bifunctional chelating agents, Chemical Society Reviews, vol.66, issue.4, pp.3019-3049, 2011.
DOI : 10.1039/c0cs00199f

C. L. Ferreira, E. Lamsa, M. Woods, Y. Duan, P. Fernando et al., Evaluation of Bifunctional Chelates for the Development of Gallium-Based Radiopharmaceuticals, Bioconjugate Chemistry, vol.21, issue.3, pp.531-536, 2010.
DOI : 10.1021/bc900443a

L. A. Bass, M. Wang, M. J. Welch, and C. Anderson, In Vivo Transchelation of Copper-64 from TETA-Octreotide to Superoxide Dismutase in Rat Liver, Bioconjugate Chemistry, vol.11, issue.4, pp.527-532, 2000.
DOI : 10.1021/bc990167l

C. J. Anderson and M. J. Welch, Radiometal-Labeled Agents (Non-Technetium) for Diagnostic Imaging, Chemical Reviews, vol.99, issue.9, pp.2219-2234, 1999.
DOI : 10.1021/cr980451q

M. D. Bartholoma, A. S. Louie, J. F. Valliant, and . Zubieta, Technetium and Gallium Derived Radiopharmaceuticals: Comparing and Contrasting the Chemistry of Two Important Radiometals for the Molecular Imaging Era, Chemical Reviews, vol.110, issue.5, pp.2903-2920, 2010.
DOI : 10.1021/cr1000755

S. Liu and . Adv, Bifunctional coupling agents for radiolabeling of biomolecules and target-specific delivery of metallic radionuclides, Advanced Drug Delivery Reviews, vol.60, issue.12, pp.1347-1370, 2008.
DOI : 10.1016/j.addr.2008.04.006

R. E. Mewis and S. Archibald, Biomedical applications of macrocyclic ligand complexes, Coordination Chemistry Reviews, vol.254, issue.15-16, pp.1686-1712, 2010.
DOI : 10.1016/j.ccr.2010.02.025

J. Notni, P. Hermann, J. Havlickova, J. Kotek, V. Kubicek et al., Ga Tracers for Positron Emission Tomography, Chemistry - A European Journal, vol.13, issue.217, pp.7174-7185, 2010.
DOI : 10.1002/chem.200903281

J. Simecek, M. Schulz, J. Notni, J. Plutnar, V. Kubicek et al., Complexation of Metal Ions with TRAP (1,4,7-Triazacyclononane Phosphinic Acid) Ligands and 1,4,7-Triazacyclononane-1,4,7-triacetic Acid: Phosphinate-Containing Ligands as Unique Chelators for Trivalent Gallium, Inorganic Chemistry, vol.51, issue.1, pp.577-590, 2012.
DOI : 10.1021/ic202103v

J. Notni, J. Simecek, P. Hermann, and H. Wester, TRAP, a Powerful and Versatile Framework for Gallium-68 Radiopharmaceuticals, Chemistry - A European Journal, vol.2, issue.52, pp.14718-14722, 2011.
DOI : 10.1002/chem.201103503

V. Kubicek, J. Havlickova, J. Kotek, G. Tircso, P. Hermann et al., Gallium(III) Complexes of DOTA and DOTA???Monoamide: Kinetic and Thermodynamic Studies, Inorganic Chemistry, vol.49, issue.23, pp.10960-10969, 2010.
DOI : 10.1021/ic101378s
URL : https://hal.archives-ouvertes.fr/hal-00602440

P. J. Riss, C. Kroll, V. Nagel, and F. Roesch, NODAPA-OH and NODAPA-(NCS)n: Synthesis, 68Ga-radiolabelling and in vitro characterisation of novel versatile bifunctional chelators for molecular imaging, Bioorganic & Medicinal Chemistry Letters, vol.18, issue.20, pp.5364-5367, 2008.
DOI : 10.1016/j.bmcl.2008.09.054

K. P. Eisenwiener, P. Powell, and H. R. Macke, A convenient synthesis of novel bifunctional prochelators for coupling to bioactive peptides for radiometal labelling, Bioorganic & Medicinal Chemistry Letters, vol.10, issue.18, pp.2133-2135, 2000.
DOI : 10.1016/S0960-894X(00)00413-3

G. Ruser, W. Ritter, and H. R. Maecke, Synthesis and evaluation of two new bifunctional carboxymethylated tetraazamacrocyclic chelating agents for protein labeling with indium-111, Bioconjugate Chemistry, vol.1, issue.5, pp.345-349, 1990.
DOI : 10.1021/bc00005a008

T. J. Wadas, M. Eiblmaier, A. Zheleznyak, C. D. Sherman, R. Ferdani et al., Preparation and Biological Evaluation of 64Cu-CB-TE2A-sst2-ANT, a Somatostatin Antagonist for PET Imaging of Somatostatin Receptor-Positive Tumors, Journal of Nuclear Medicine, vol.49, issue.11, pp.1819-1827, 2008.
DOI : 10.2967/jnumed.108.054502

S. V. Smith, Molecular imaging with copper-64, Journal of Inorganic Biochemistry, vol.98, issue.11, pp.1874-1901, 2004.
DOI : 10.1016/j.jinorgbio.2004.06.009

M. Shokeen and C. J. Anderson, Molecular Imaging of Cancer with Copper-64 Radiopharmaceuticals and Positron Emission Tomography (PET), Accounts of Chemical Research, vol.42, issue.7, pp.832-841, 2009.
DOI : 10.1021/ar800255q

T. M. Jones-wilson, K. A. Deal, C. J. Anderson, D. W. Mccarthy, Z. Kovacs et al., The in vivo behavior of copper-64-labeled azamacrocyclic complexes, Nuclear Medicine and Biology, vol.25, issue.6, pp.523-530, 1998.
DOI : 10.1016/S0969-8051(98)00017-1

M. Fani, L. Del-pozzo, K. Abiraj, R. Mansi, M. L. Tamma et al., PET of Somatostatin Receptor-Positive Tumors Using 64Cu- and 68Ga-Somatostatin Antagonists: The Chelate Makes the Difference, Journal of Nuclear Medicine, vol.52, issue.7, pp.1110-1118, 2011.
DOI : 10.2967/jnumed.111.087999

A. Y. Odendaal, A. L. Fiamengo, R. Ferdani, T. J. Wadas, D. C. Hill et al., Isomeric Trimethylene and Ethylene Pendant-armed Cross-bridged Tetraazamacrocycles and in Vitro/in Vivo Comparisions of their Copper(II) Complexes, Inorganic Chemistry, vol.50, issue.7, pp.3078-3086, 2011.
DOI : 10.1021/ic200014w

H. C. Cai, Z. B. Li, C. W. Huang, R. Park, A. H. Shahinian et al., An improved synthesis and biological evaluation of a new cage-like bifunctional chelator, 4-((8-amino-3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane-1-ylamino)methyl)benzoic acid, for 64Cu radiopharmaceuticals, Nuclear Medicine and Biology, vol.37, issue.1, pp.57-65, 2010.
DOI : 10.1016/j.nucmedbio.2009.09.001

J. Fichna and A. Janecka, Synthesis of Target-Specific Radiolabeled Peptides for Diagnostic Imaging, Bioconjugate Chemistry, vol.14, issue.1, pp.3-17, 2003.
DOI : 10.1021/bc025542f

G. Hermanson, Bioconjugate Techniques; Academic press, Tetrahedron, vol.87, issue.86, pp.61-10827, 1996.

I. Dijkgraaf, A. Y. Rijnders, A. Soede, A. C. Dechesne, G. W. Van-esse et al., Synthesis of DOTA-conjugated multivalent cyclic-RGD peptide dendrimers via 1,3-dipolar cycloaddition and their biological evaluation: implications for tumor targeting and tumor imaging purposes, Organic & Biomolecular Chemistry, vol.120, issue.6, pp.935-944, 2007.
DOI : 10.1039/b615940k

T. L. Mindt, C. Mueller, M. Melis, M. De-jong, and R. Schibli, -Labeled N(??)-Histidine Folate Derivative with Its Isostructural, Clicked 1,2,3-Triazole Analogue, Bioconjugate Chemistry, vol.19, issue.8, pp.1689-1695, 2008.
DOI : 10.1021/bc800183r

H. Struthers, B. Spingler, T. L. Mindt, and R. Schibli, ???Click???to???Chelate???: Design and Incorporation of Triazole???Containing Metal???Chelating Systems into Biomolecules of Diagnostic and Therapeutic Interest, Chemistry - A European Journal, vol.123, issue.20, pp.6173-6183, 2008.
DOI : 10.1002/chem.200702024

M. E. Martin, S. G. Parameswarappa, M. S. O-'dorisio, and F. Pigge, A DOTA???peptide conjugate by copper-free click chemistry, Bioorganic & Medicinal Chemistry Letters, vol.20, issue.16, pp.4805-4807, 2010.
DOI : 10.1016/j.bmcl.2010.06.111

P. Misra, V. Humblet, N. Pannier, W. Maison, and J. V. Frangioni, Production of Multimeric Prostate-Specific Membrane Antigen Small-Molecule Radiotracers Using a Solid-Phase 99mTc Preloading Strategy, Journal of Nuclear Medicine, vol.48, issue.8, pp.1379-1389, 2007.
DOI : 10.2967/jnumed.107.040303

P. Misra, D. Lebeche, H. Ly, M. Schwarzkopf, G. Diaz et al., Quantitation of CXCR4 Expression in Myocardial Infarction Using 99mTc-Labeled SDF-1??, Journal of Nuclear Medicine, vol.49, issue.6, pp.963-969, 2008.
DOI : 10.2967/jnumed.107.050054

H. Hanaoka, T. Mukai, H. Tamamura, T. Mori, S. Ishino et al., Development of a 111In-labeled peptide derivative targeting a chemokine receptor, CXCR4, for imaging tumors, Nuclear Medicine and Biology, vol.33, issue.4, pp.489-494, 2006.
DOI : 10.1016/j.nucmedbio.2006.01.006

U. Hennrich, L. Seyler, M. Schafer, U. Bauder-wust, M. Eisenhut et al., Synthesis and in vitro evaluation of 68Ga-DOTA-4-FBn-TN14003, a novel tracer for the imaging of CXCR4 expression, Bioorganic & Medicinal Chemistry, vol.20, issue.4, pp.1502-1510, 2012.
DOI : 10.1016/j.bmc.2011.12.052

O. Jacobson, I. D. Weiss, L. P. Szajek, G. Niu, and Y. Ma, Improvement of CXCR4 tracer specificity for PET imaging, Journal of Controlled Release, vol.157, issue.2, pp.216-223, 2012.
DOI : 10.1016/j.jconrel.2011.09.076

E. Gourni, O. Demmer, M. Schottelius, C. D-'alessandria, S. Schulz et al., PET of CXCR4 Expression by a 68Ga-Labeled Highly Specific Targeted Contrast Agent, Journal of Nuclear Medicine, vol.52, issue.11, pp.1803-1810, 2011.
DOI : 10.2967/jnumed.111.098798

O. Jacobson, I. D. Weiss, L. Szajek, J. M. Farber, and D. O. Kiesewetter, 64Cu-AMD3100???A novel imaging agent for targeting chemokine receptor CXCR4, Bioorganic & Medicinal Chemistry, vol.17, issue.4, pp.1486-1493, 2009.
DOI : 10.1016/j.bmc.2009.01.014

I. D. Weiss, O. Jacobson, D. O. Kiesewetter, J. P. Jacobus, L. P. Szajek et al., Positron Emission Tomography Imaging of Tumors Expressing the Human Chemokine Receptor CXCR4 in Mice with the Use of 64Cu-AMD3100, Molecular Imaging and Biology, vol.39, issue.1, pp.106-114, 2012.
DOI : 10.1007/s11307-010-0466-y

J. M. Zhang, J. H. Tian, T. R. Li, H. Y. Guo, and L. Shen, 99mTc???AMD3100: A novel potential receptor-targeting radiopharmaceutical for tumor imaging, Chinese Chemical Letters, vol.21, issue.4, pp.461-463, 2010.
DOI : 10.1016/j.cclet.2009.12.018

D. Silva, R. A. Peyre, K. Pullambhatla, M. Fox, J. J. Pomper et al., Imaging CXCR4 Expression in Human Cancer Xenografts: Evaluation of Monocyclam 64Cu-AMD3465, Journal of Nuclear Medicine, vol.52, issue.6, pp.986-993, 2011.
DOI : 10.2967/jnumed.110.085613

S. L. Luo, E. L. Zhang, Y. P. Su, T. M. Cheng, and C. M. Shi, A review of NIR dyes in cancer targeting and imaging, Biomaterials, vol.32, issue.29, pp.7127-7138, 2011.
DOI : 10.1016/j.biomaterials.2011.06.024

L. D. Lavis and R. T. Raines, Bright Ideas for Chemical Biology, ACS Chemical Biology, vol.3, issue.3, pp.142-155, 2008.
DOI : 10.1021/cb700248m

H. Kobayashi, M. Ogawa, R. Alford, P. L. Choyke, and Y. Urano, New Strategies for Fluorescent Probe Design in Medical Diagnostic Imaging, Chemical Reviews, vol.110, issue.5, pp.2620-2640, 2010.
DOI : 10.1021/cr900263j

M. Meincke, S. Tiwari, K. Hattermann, H. Kalthoff, and R. Mentlein, Near-infrared molecular imaging of tumors via chemokine receptors CXCR4 and CXCR7, Clinical & Experimental Metastasis, vol.9, issue.8, pp.713-720, 2011.
DOI : 10.1007/s10585-011-9403-y

K. Nishizawa, H. Nishiyama, S. Oishi, N. Tanahara, H. Kotani et al., Fluorescent imaging of high-grade bladder cancer using a specific antagonist for chemokine receptor CXCR4, International Journal of Cancer, vol.24, issue.5, pp.1180-1187, 2010.
DOI : 10.1002/ijc.25145

W. Nomura, Y. Tanabe, H. Tsutsumi, T. Tanaka, K. Ohba et al., Fluorophore Labeling Enables Imaging and Evaluation of Specific CXCR4???Ligand Interaction at the Cell Membrane for Fluorescence-Based Screening, Bioconjugate Chemistry, vol.19, issue.9, pp.1917-1920, 2008.
DOI : 10.1021/bc800216p

A. Y. Louie, Multimodality Imaging Probes: Design and Challenges, Chemical Reviews, vol.110, issue.5, pp.3146-3195, 2010.
DOI : 10.1021/cr9003538

J. Culver, W. Akers, and S. Achilefu, Multimodality Molecular Imaging with Combined Optical and SPECT/PET Modalities, Journal of Nuclear Medicine, vol.49, issue.2, pp.169-172, 2008.
DOI : 10.2967/jnumed.107.043331

J. Kuil, A. H. Velders, and F. W. Van-leeuwen, Multimodal Tumor-Targeting Peptides Functionalized with Both a Radio- and a Fluorescent Label, Bioconjugate Chemistry, vol.21, issue.10, pp.1709-1719, 2010.
DOI : 10.1021/bc100276j

J. Kuil, T. Buckle, J. Oldenburg, H. Yuan, A. D. Borowsky et al., Hybrid Peptide Dendrimers for Imaging of Chemokine Receptor 4 (CXCR4) Expression, Molecular Pharmaceutics, vol.8, issue.6, pp.2444-2453, 2011.
DOI : 10.1021/mp200401p

F. Boschetti, F. Denat, E. Espinosa, A. Tabard, Y. Dory et al., Regioselective N-Functionalization of Tetraazacycloalkanes, The Journal of Organic Chemistry, vol.70, issue.18, pp.7042-7053, 2005.
DOI : 10.1021/jo050306u

A. Delepine, R. Tripier, H. Bernard, B. N. Le, and H. Handel, Selective mono-N-alkylation of triethylenetetraamine. A new versatile route to polylinear aza-ligands, Tetrahedron Letters, vol.50, issue.21, pp.2521-2524, 2009.
DOI : 10.1016/j.tetlet.2009.03.088

L. Baccon, M. Chuburu, F. Toupet, L. Handel, H. Soibinet et al., Bis-aminals: efficient tools for bis-macrocycle synthesis, New Journal of Chemistry, vol.25, issue.9, pp.1168-1174, 2001.
DOI : 10.1039/b103995b

G. R. Weisman, S. C. Ho, and V. Johnson, Tetracyclic tetraamines by glyoxal-macrocyclic tetraamine condensation, Tetrahedron Letters, vol.21, issue.4, pp.335-338, 1980.
DOI : 10.1016/S0040-4039(01)85466-6

C. Bucher, G. Royal, J. M. Barbe, and R. Guilard, First unequivocal synthesis of dissymmetrical trans N,N???-difunctionalized 1,4,8,11-tetraazacyclotetradecane, Tetrahedron Letters, vol.40, issue.12, pp.2315-2318, 1999.
DOI : 10.1016/S0040-4039(99)00190-2

W. C. Baker, M. J. Choi, D. C. Hill, J. L. Thompson, and P. A. Petillo, Synthesis of Lipophilic Paramagnetic Contrast Agents, The Journal of Organic Chemistry, vol.64, issue.8, pp.2683-2689, 1999.
DOI : 10.1021/jo981920r

J. Rohovec, R. Gyepes, I. Cisarova, J. Rudovsky, and I. Lukes, Nucleophilic reactivity of perhydro-3,6,9,12-tetraazacyclopenteno[1,3-f,g]acenaphthylene. A unified approach to N-monosubstituted and N,N??????-disubstituted cyclene derivatives, Tetrahedron Letters, vol.41, issue.8, pp.1249-1253, 2000.
DOI : 10.1016/S0040-4039(99)02262-5

J. Kotek, P. Hermann, and P. Vojtisek, Crystal Structures and Reactivity of 3a,5a,8a,10a-Tetraazaperhydropyrene Derivatives. An Alternative Approach to Selective Nitrogen Alkylation of 1,4,8,11-Tetraazacyclotetradecane (Cyclam), Collection of Czechoslovak Chemical Communications, vol.65, issue.2, pp.243-266, 2000.
DOI : 10.1135/cccc20000243

E. A. Lewis, C. C. Allan, R. W. Boyle, and S. J. Archibald, Efficient N- and C-functionalisation of cyclam macrocycles utilising bisaminal methodology, Tetrahedron Letters, vol.45, issue.15, pp.3059-3062, 2004.
DOI : 10.1016/j.tetlet.2004.02.108

E. H. Wong, G. R. Weisman, D. C. Hill, D. P. Reed, M. E. Rogers et al., Synthesis and Characterization of Cross-Bridged Cyclams and Pendant-Armed Derivatives and Structural Studies of Their Copper(II) Complexes, Journal of the American Chemical Society, vol.122, issue.43, pp.10561-10572, 2000.
DOI : 10.1021/ja001295j

G. Hervé, H. Bernard, N. Le-bris, J. J. Yaouanc, and H. Handel, A new route to cyclen, cyclam and homocyclen, Tetrahedron Letters, vol.39, issue.38, pp.6861-6864, 1998.
DOI : 10.1016/S0040-4039(98)01497-X

G. R. Weisman, M. E. Rogers, E. H. Wong, J. P. Jasinski, and E. S. Paight, Cross-bridged cyclam. Protonation and lithium cation (Li+) complexation in a diamond-lattice cleft, Journal of the American Chemical Society, vol.112, issue.23, pp.8604-8605, 1990.
DOI : 10.1021/ja00179a067

R. A. Kolinski and F. G. Riddell, Ring inversion in polycyclic tetraamines, Tetrahedron Letters, vol.22, issue.23, pp.2217-2220, 1981.
DOI : 10.1016/S0040-4039(01)90502-7

N. Bernier, M. Allali, R. Tripier, F. Conan, V. Patinec et al., New side-bridged bismacrocycles and cross-bridged macrotricycles. Syntheses and Cu(ii) complexation study, New Journal of Chemistry, vol.741, issue.234, pp.435-441, 2006.
DOI : 10.1039/b515150c

N. Bernier, R. Tripier, V. Patinec, M. Le-baccon, and H. Handel, Proton-sponge behaviour of new pendant armed cross-bridged bis-cyclens: Synthesis, NMR, X-ray, and potentiometric investigations, Comptes Rendus Chimie, vol.10, issue.9, pp.832-838, 2007.
DOI : 10.1016/j.crci.2007.03.016

H. Yamamoto and K. Maruoka, Regioselective carbonyl amination using diisobutylaluminum hydride, Journal of the American Chemical Society, vol.103, issue.14, pp.4186-4194, 1981.
DOI : 10.1021/ja00404a035

J. E. Richman and T. J. Atkins, Nitrogen analogs of crown ethers, Journal of the American Chemical Society, vol.96, issue.7, pp.2268-2270, 1974.
DOI : 10.1021/ja00814a056

V. Chin-quee-smith, L. Delpizzo, S. H. Jureller, J. L. Kerschner, and R. Hage, ??????-Trimethyl-1,4,7-triazacyclononane), and Its Activity toward Olefin Oxidation with Hydrogen Peroxide, Inorganic Chemistry, vol.35, issue.22, pp.6461-6465, 1996.
DOI : 10.1021/ic951522w

D. Vos, D. Bein, and T. , Intrazeolite Complexation of Transition Metal Ions by Triazacyclononane-Type Ligands:?? Control of Cluster Nuclearity and Oxygen Binding in Confined Reaction Spaces, Journal of the American Chemical Society, vol.119, issue.40, pp.9460-9465, 1997.
DOI : 10.1021/ja9629266

B. C. Gilbert, S. J. Lindsay, I. P. Mairata, and J. Oakes, A mechanistic study of the epoxidation of cinnamic acid by hydrogen peroxide catalysed by manganese l,4,7-trimethyl-l,4,7-triazacyclononane complexes, Journal of Molecular Catalysis A: Chemical, vol.219, issue.2, pp.265-272, 2004.
DOI : 10.1016/j.molcata.2004.05.012

D. L. Johnson and L. L. Martin, Controlling Protein Orientation at Interfaces Using Histidine Tags:?? An Alternative to Ni/NTA, Journal of the American Chemical Society, vol.127, issue.7, pp.2018-2019, 2005.
DOI : 10.1021/ja045084g

W. B. Tolman, Making and Breaking the Dioxygen O???O Bond:?? New Insights from Studies of Synthetic Copper Complexes, Accounts of Chemical Research, vol.30, issue.6, pp.227-237, 1997.
DOI : 10.1021/ar960052m

F. Liang, S. H. Wan, Z. Li, X. Q. Xiong, L. Yang et al., Medical Applications of Macrocyclic Polyamines, Current Medicinal Chemistry, vol.13, issue.6, pp.711-727, 2006.
DOI : 10.2174/092986706776055706

R. C. Hoye, J. E. Richman, G. A. Dantas, M. F. Lightbourne, and L. S. Shinneman, Synthesis of Polyazamacrocyclic Compounds via Modified Richman???Atkins Cyclization of ??-Trimethylsilylethanesulfonamides, The Journal of Organic Chemistry, vol.66, issue.8, pp.2722-2725, 2001.
DOI : 10.1021/jo001639o

A. E. Martin, T. M. Ford, and J. E. Bulkowski, Synthesis of selectively protected tri- and hexaamine macrocycles, The Journal of Organic Chemistry, vol.47, issue.3, pp.412-415, 1982.
DOI : 10.1021/jo00342a006

H. S. Chong and M. W. Brechbiel, A Short and Efficient Synthesis of Mono-substituted 1,4,7-Triazacyclononanes, Synthetic Communications, vol.123, issue.7, pp.1147-1154, 2003.
DOI : 10.1002/(SICI)1099-1344(200005)43:6<585::AID-JLCR343>3.0.CO;2-H

J. L. Sessler, J. W. Sibert, and V. Lynch, Model studies related to hemerythrin. Synthesis and characterization of a bridged tetranuclear iron(III) complex, Inorganic Chemistry, vol.29, issue.20, pp.4143-4146, 1990.
DOI : 10.1021/ic00345a046

Z. Kovacs and A. D. Sherry, A general synthesis of mono- and disubstituted 1,4,7-triazacyclononanes, Tetrahedron Letters, vol.36, issue.51, pp.9269-9272, 1995.
DOI : 10.1016/0040-4039(95)02009-E

J. Van-westrenen and A. D. Sherry, Sulfomethylation of di-, tri-, and polyazamacrocycles: a new route to entry of mixed-side-chain macrocyclic chelates, Bioconjugate Chemistry, vol.3, issue.6, pp.524-532, 1992.
DOI : 10.1021/bc00018a011

M. Roger, V. Patinec, M. Bourgeois, R. Tripier, S. Triki et al., exo-Diastereoisomer of 10-aryl-1,4,7-triazabicyclo[5.2.1]decane as intermediary in specific derivatisation of triazacyclononane, Tetrahedron, vol.68, issue.27-28, pp.5637-5643, 2012.
DOI : 10.1016/j.tet.2012.04.057

J. E. Scheuermann, K. F. Sibbons, D. M. Benoit, M. Motevalli, and M. Watkinson, The synthesis of unsymmetrically N-substituted chiral 1,4,7-triazacyclononanes, Org. Biomol. Chem., vol.30, issue.18, pp.2664-2670, 2004.
DOI : 10.1039/B409259G

G. Argouarch, C. L. Gibson, G. Stones, and D. C. Sherrington, The synthesis of chiral annulet 1,4,7-triazacyclononanes, Tetrahedron Letters, vol.43, issue.21, pp.3795-3798, 2002.
DOI : 10.1016/S0040-4039(02)00705-0

G. Argouarch, G. Stones, C. L. Gibson, A. R. Kennedy, and D. C. Sherrington, Bifurcated, modular syntheses of chiral annulet triazacyclononanes, Organic & Biomolecular Chemistry, vol.1, issue.24, pp.4408-4417, 2003.
DOI : 10.1039/b310492c

G. Stones, G. Argouarch, A. R. Kennedy, D. C. Sherrington, and C. L. Gibson, The synthesis of an isopropyl substituted 1,4,7-triazacyclononane via an in situ sequential macrocyclisation method, Organic & Biomolecular Chemistry, vol.1, issue.13, pp.2357-2363, 2003.
DOI : 10.1039/b302887a

J. H. Koek and E. W. Kohlen, Direct ring functionalisation of 1,4,7-trimethyl-1,4,7-triazacyclononane and its application in the preparation of functional [L2Mn2O3]-type complexes, Tetrahedron Letters, vol.47, issue.22, pp.3673-3675, 2006.
DOI : 10.1016/j.tetlet.2006.03.134

E. Rodriguez, M. Nilges, R. Weissleder, and J. W. Chen, Activatable Magnetic Resonance Imaging Agents for Myeloperoxidase Sensing: Mechanism of Activation, Stability, and Toxicity, Journal of the American Chemical Society, vol.132, issue.1, pp.168-177, 2010.
DOI : 10.1021/ja905274f

T. S. Siddiqui, A. Jani, F. Williams, R. N. Muller, L. Vander-elst et al., Lanthanide complexes on Ag nanoparticles: Designing contrast agents for magnetic resonance imaging, Journal of Colloid and Interface Science, vol.337, issue.1, pp.88-96, 2009.
DOI : 10.1016/j.jcis.2009.04.096

C. W. Tornoe, C. Christensen, and M. Meldal, Peptidotriazoles on Solid Phase:?? [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides, The Journal of Organic Chemistry, vol.67, issue.9, pp.3057-3064, 2002.
DOI : 10.1021/jo011148j

A. Bernardin, A. Cazet, L. Guyon, P. Delannoy, and F. Vinet, Metabolic Imaging, Bioconjugate Chemistry, vol.21, issue.4, pp.583-588, 2010.
DOI : 10.1021/bc900564w
URL : https://hal.archives-ouvertes.fr/hal-00521419

C. Muller, T. L. Mindt, M. De-jong, and R. Schibli, Evaluation of a novel radiofolate in tumour-bearing mice: promising prospects for folate-based radionuclide therapy, European Journal of Nuclear Medicine and Molecular Imaging, vol.22, issue.6, pp.938-946, 2009.
DOI : 10.1007/s00259-008-1058-9

V. V. Rostovtsev, L. G. Green, V. V. Fokin, and K. B. Sharpless, A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective ???Ligation??? of Azides and Terminal Alkynes, Angewandte Chemie International Edition, vol.20, issue.14, pp.2596-2599, 2002.
DOI : 10.1002/1521-3773(20020715)41:14<2596::AID-ANIE2596>3.0.CO;2-4

M. Yu, J. R. Price, P. Jensen, C. J. Lovitt, T. Shelper et al., Copper, Nickel, and Zinc Cyclam???Amino Acid and Cyclam???Peptide Complexes May Be Synthesized with ???Click??? Chemistry and Are Noncytotoxic, Inorganic Chemistry, vol.50, issue.24, pp.12823-12835, 2011.
DOI : 10.1021/ic2020012

C. Yim, O. C. Boerman, M. De-visser, M. De-jong, A. C. Dechesne et al., Versatile Conjugation of Octreotide to Dendrimers by Cycloaddition (???Click???) Chemistry to Yield High-Affinity Multivalent Cyclic Peptide Dendrimers, Bioconjugate Chemistry, vol.20, issue.7, pp.1323-1331, 2009.
DOI : 10.1021/bc900052n

S. Knoer, A. Modlinger, T. Poethko, M. Schottelius, H. Wester et al., Synthesis of Novel 1,4,7,10-Tetraazacyclodecane-1,4,7,10-Tetraacetic Acid (DOTA) Derivatives for Chemoselective Attachment to Unprotected Polyfunctionalized Compounds, Chemistry - A European Journal, vol.255, issue.21, pp.6082-6090, 2007.
DOI : 10.1002/chem.200700231

A. Y. Lebedev, J. P. Holland, and . Lewis, Clickable bifunctional radiometal chelates for peptide labeling, Chemical Communications, vol.18, issue.10, pp.1706-1708, 2010.
DOI : 10.1039/b924784j

J. Huskens and A. D. Sherry, Formation and Dissociation Kinetics of the Magnesium(II) Complex of 1,4,7-Triazacyclononane-1,4,7-tris(methylenemethylphosphinic acid), Inorganic Chemistry, vol.35, issue.18, pp.5137-5143, 1996.
DOI : 10.1021/ic9602299

J. Huskens and A. D. Sherry, H NMR Spectroscopy, Journal of the American Chemical Society, vol.118, issue.18, pp.4396-4404, 1996.
DOI : 10.1021/ja953771p

O. Picazo, I. Alkorta, J. Elguero, O. Mo, and M. Yanez, Chiral recognition in phosphinic acid dimers, Journal of Physical Organic Chemistry, vol.256, issue.6, pp.491-497, 2005.
DOI : 10.1002/poc.901

S. Kang, J. M. Llinares, V. W. Day, and K. Bowman-james, Cryptand-like anion receptors, Chemical Society Reviews, vol.41, issue.221, pp.3980-4003, 2010.
DOI : 10.1021/ic1013297

G. Ambrosi, P. Dapporto, M. Formica, V. Fusi, L. Giorgi et al., Synthesis of a Large Amino-Phenolic Cage. Synthesis, Crystal Structures, and Acid???Base and Coordination Behavior toward Cations and Anions, Inorganic Chemistry, vol.45, issue.1, pp.304-314, 2006.
DOI : 10.1021/ic051304v

H. Y. An, J. S. Bradshaw, and R. M. Izatt, Macropolycyclic polyethers (cages) and related compounds, Chemical Reviews, vol.92, issue.4, pp.543-572, 1992.
DOI : 10.1021/cr00012a004

C. A. Boswell, C. A. Regino, K. E. Baidoo, K. J. Wong, A. Bumb et al., Cu Radiolabeling, Bioconjugate Chemistry, vol.19, issue.7, pp.1476-1484, 2008.
DOI : 10.1021/bc800039e

L. Broge, U. Pretzmann, N. Jensen, I. Sotofte, C. E. Olsen et al., ]Adamanzane, 1,5,9,12-Tetraazabicyclo[7.5.2]hexadecane, Inorganic Chemistry, vol.40, issue.10, pp.2323-2334, 2001.
DOI : 10.1021/ic0011157

A. Jana, S. Y. Jang, J. Shin, A. K. De, D. Goswami et al., Attachment of Different Donor Groups to a Cryptand for Modulation of Two-Photon Absorption Cross-Section, Chemistry - A European Journal, vol.12, issue.34, pp.10628-10638, 2008.
DOI : 10.1002/chem.200801396

J. Springborg, P. Kofod, C. E. Olsen, H. Toftlund, and I. Sotofte, Synthesis and Crystal Structure of a Small Bicyclic Tetraaza Proton Sponge, 1,4,7,10-Tetraazabicyclo[5.5.3]pentadecane Dibromide Perchlorate., Acta Chemica Scandinavica, vol.49, pp.547-554, 1995.
DOI : 10.3891/acta.chem.scand.49-0547

J. Springborg, U. Pretzmann, B. Nielsen, C. E. Olsen, and I. Sotofte, Synthesis of [3(5)]Adamanzane, 1,5,9,13-Tetraazabicyclo[7.7.3]nonadecane, by Oxidative C--N Cleavage of [3(6)]Adamanzane, 1,5,9,13-Tetraazatricyclo[7.7.3.3(5,13)]docosane and Crystal Structure of the Tetraprotonated Bromide Salt of [3(5)]Adamanzane., Acta Chemica Scandinavica, vol.52, pp.212-217, 1998.
DOI : 10.3891/acta.chem.scand.52-0212

J. Springborg, U. Pretzmann, and C. E. Olsen, An Inert Proton Coordinated Inside the Tetrahedral Cage [3 6]Adamanzane. Synthesis of the Inside Monoprotonated Amine 1,5,9,13-Tetraazatricyclo[7.7.3.3(5,13)]docosane., Acta Chemica Scandinavica, vol.50, pp.294-298, 1996.
DOI : 10.3891/acta.chem.scand.50-0294

J. Springborg and I. Sotofte, Synthetic, Thermodynamic and Crystallographic Studies of Pentacoordinated Copper(II) Complexes with [24.31]Adamanzane, 1,4,7,10-Tetraazabicyclo[5.5.3]pentadecane, and Bromide, Iodide, Hydroxide, Water or Ammonia., Acta Chemica Scandinavica, vol.51, pp.357-366, 1997.
DOI : 10.3891/acta.chem.scand.51-0357

L. Fabbrizzi, P. Pallavicini, L. Parodi, and A. Taglietti, Anion recognition by a dicopper (II) cryptate, Inorganica Chimica Acta, vol.238, issue.1-2, pp.5-8, 1995.
DOI : 10.1016/0020-1693(95)04751-T

J. L. Dearling, S. D. Voss, P. Dunning, E. Snay, F. Fahey et al., Imaging cancer using PET ??? the effect of the bifunctional chelator on the biodistribution of a 64Cu-labeled antibody, Nuclear Medicine and Biology, vol.38, issue.1, pp.29-38, 2011.
DOI : 10.1016/j.nucmedbio.2010.07.003

D. Bartolo, N. Sargeson, A. M. Smith, and S. V. , New 64Cu PET imaging agents for personalised medicine and drug development using the hexa-aza cage, SarAr, Organic & Biomolecular Chemistry, vol.72, issue.4, pp.3350-3357, 2006.
DOI : 10.1039/b605615f

C. A. Boswell, X. K. Sun, W. J. Niu, G. R. Weisman, E. H. Wong et al., Comparative in Vivo Stability of Copper-64-Labeled Cross-Bridged and Conventional Tetraazamacrocyclic Complexes, Journal of Medicinal Chemistry, vol.47, issue.6, pp.1465-1474, 2004.
DOI : 10.1021/jm030383m

F. Li, R. Delgado, A. Coelho, M. G. Drew, and V. Felix, New dioxadiaza-, trioxadiaza- and hexaaza-macrocycles containing dibenzofuran units, Tetrahedron, vol.62, issue.36, pp.8550-8558, 2006.
DOI : 10.1016/j.tet.2006.06.073

E. Bardazzi, M. Ciampolini, V. Fusi, M. Micheloni, N. Nardi et al., Synthetic Route To Produce Phenol-Containing Azamacropolycycles, The Journal of Organic Chemistry, vol.64, issue.4, pp.1335-1337, 1999.
DOI : 10.1021/jo980971l

Y. Habata, F. Osaka, and S. Yamada, under 1 MPa, Journal of Heterocyclic Chemistry, vol.56, issue.1, pp.157-161, 2006.
DOI : 10.1002/jhet.5570430123

D. Maffeo and J. A. Williams, Intramolecular sensitisation of europium(III) luminescence by 8-benzyloxyquinoline in aqueous solution, Inorganica Chimica Acta, vol.355, pp.127-136, 2003.
DOI : 10.1016/S0020-1693(03)00338-4

G. P. Xue, J. S. Bradshaw, N. K. Dalley, P. B. Savage, R. M. Izatt et al., The synthesis of azacrown ethers with quinoline-based sidearms as potential zinc(II) fluorophores, Tetrahedron, vol.58, issue.24, pp.4809-4815, 2002.
DOI : 10.1016/S0040-4020(02)00451-9

C. Kuehm-caubere, S. Adachbecker, Y. Fort, and P. Caubere, Expeditious and efficient syntheses of pure 4-methyl and 4,6-disubstituted dibenzothiophenes, Tetrahedron, vol.52, issue.27, pp.9087-9092, 1996.
DOI : 10.1016/0040-4020(96)00459-0

M. L. Skar and J. S. Svendsen, Conformationally restricted diamines as spacers for parallel ??-sheet formation, Tetrahedron, vol.53, issue.51, pp.17425-17440, 1997.
DOI : 10.1016/S0040-4020(97)10191-0

D. Oltmanns, S. Zitzmann-kolbe, and A. Mueller, Zn(II)-bis(cyclen) Complexes and the Imaging of Apoptosis/Necrosis, Bioconjugate Chemistry, vol.22, issue.12, pp.2611-2624, 2011.
DOI : 10.1021/bc200457b

J. Dessolin, P. Galea, P. Vlieghe, J. C. Chermann, and J. L. Kraus, New Bicyclam???AZT Conjugates:?? Design, Synthesis, Anti-HIV Evaluation, and Their Interaction with CXCR-4 Coreceptor, Journal of Medicinal Chemistry, vol.42, issue.2, pp.229-241, 1999.
DOI : 10.1021/jm980358u

V. Moret, N. Dereudre-bosquet, P. Clayette, Y. Laras, N. Pietrancosta et al., Synthesis and anti-HIV properties of new hydroxyquinoline???polyamine conjugates on cells infected by HIV-1 LAV and HIV-1 BaL viral strains, Bioorganic & Medicinal Chemistry Letters, vol.16, issue.23, pp.5988-5992, 2006.
DOI : 10.1016/j.bmcl.2006.08.114
URL : https://hal.archives-ouvertes.fr/hal-00305885

J. B. Baell, R. W. Gable, A. J. Harvey, N. Toovey, T. Herzog et al., Khellinone Derivatives as Blockers of the Voltage-Gated Potassium Channel Kv1.3:?? Synthesis and Immunosuppressive Activity, Journal of Medicinal Chemistry, vol.47, issue.9, pp.2326-2336, 2004.
DOI : 10.1021/jm030523s

S. Acherar and B. Jamart-gregoire, Efficient synthesis of N??-Me, N??-Boc-protected ??-hydrazinoacids: access to 1:1:1 [N??-Me ??-hydrazino/??/N??-Me ??-hydrazino]trimers, Tetrahedron Letters, vol.50, issue.46, pp.6377-6379, 2009.
DOI : 10.1016/j.tetlet.2009.08.095

T. W. Hudnall, T. P. Lin, and F. P. Gabbai, Substitution of hydroxide by fluoride at the boron center of a BODIPY dye, Journal of Fluorine Chemistry, vol.131, issue.11, pp.1182-1186, 2010.
DOI : 10.1016/j.jfluchem.2010.06.012

D. Kand, P. K. Mishra, T. Saha, M. Lahiri, and P. Talukdar, BODIPY based colorimetric fluorescent probe for selective thiophenol detection: theoretical and experimental studies, The Analyst, vol.83, issue.17, pp.3921-3924, 2012.
DOI : 10.1039/c2an35524h

S. Lemcke, C. Honnscheidt, G. Waschatko, A. Bopp, D. Lutjohann et al., DHEA-Bodipy???A functional fluorescent DHEA analog for live cell imaging, Molecular and Cellular Endocrinology, vol.314, issue.1, pp.31-40, 2010.
DOI : 10.1016/j.mce.2009.09.006
URL : https://hal.archives-ouvertes.fr/hal-00529009

K. M. Liu, M. S. Tsai, M. S. Jan, C. M. Chau, and W. J. Wang, Convenient one-pot procedure for synthesizing 4,4???-dimethoxy-boradiaza-s-indacene dyes and their application to cell labeling, Tetrahedron, vol.67, issue.41, pp.7919-7922, 2011.
DOI : 10.1016/j.tet.2011.08.043

J. Lee, S. Lee, D. Zhai, Y. Ahn, H. Y. Yeo et al., Bodipy-diacrylate imaging probes for targeted proteins inside live cells, Chemical Communications, vol.39, issue.15, pp.4508-4510, 2011.
DOI : 10.1039/c1cc10362h

G. Kang, H. Son, J. M. Lim, H. Kweon, I. S. Lee et al., Functionalized Fe3O4 Nanoparticles for Detecting Zinc Ions in Living Cells and Their Cytotoxicity, Chemistry - A European Journal, vol.3, issue.19, pp.5843-5847, 2012.
DOI : 10.1002/chem.201200294

A. Loudet and K. Burgess, BODIPY Dyes and Their Derivatives:?? Syntheses and Spectroscopic Properties, Chemical Reviews, vol.107, issue.11, pp.4891-4932, 2007.
DOI : 10.1021/cr078381n

R. P. Haughland, The Handbook. A Guide to Fluorescent Probes and Labeling Technologies, 2005.

G. Ulrich, R. Ziessel, and A. Harriman, The Chemistry of Fluorescent Bodipy Dyes: Versatility Unsurpassed, Angewandte Chemie International Edition, vol.107, issue.7, pp.1184-1201, 2008.
DOI : 10.1002/anie.200702070

S. Atilgan, T. Ozdemir, and E. U. Akkaya, A Sensitive and Selective Ratiometric Near IR Fluorescent Probe for Zinc Ions Based on the Distyryl???Bodipy Fluorophore, Organic Letters, vol.10, issue.18, pp.4065-4067, 2008.
DOI : 10.1021/ol801554t

M. Tasior and D. F. Shea, -Chelated Tetraarylazadipyrromethenes as NIR Fluorochromes, Bioconjugate Chemistry, vol.21, issue.7, pp.1130-1133, 2010.
DOI : 10.1021/bc100051p

S. L. Niu, C. Massif, G. Ulrich, R. Ziessel, P. Y. Renard et al., Water-solubilisation and bio-conjugation of a red-emitting BODIPY marker, Org. Biomol. Chem., vol.4, issue.1, pp.66-69, 2011.
DOI : 10.1039/C0OB00693A
URL : https://hal.archives-ouvertes.fr/hal-00991914

S. L. Niu, G. Ulrich, R. Ziessel, A. Kiss, P. Renard et al., Water-Soluble BODIPY Derivatives, Organic Letters, vol.11, issue.10, pp.2049-2052, 2009.
DOI : 10.1021/ol900302n

C. Bernhard, C. Goze, Y. Rousselin, and F. Denat, First bodipy???DOTA derivatives as probes for bimodal imaging, Chemical Communications, vol.10, issue.4, pp.8267-8269, 2010.
DOI : 10.1039/c0cc02749a

M. Brellier, G. Duportail, and R. Baati, Convenient synthesis of water-soluble nitrilotriacetic acid (NTA) BODIPY dyes, Tetrahedron Letters, vol.51, issue.9, pp.1269-1272, 2010.
DOI : 10.1016/j.tetlet.2009.12.126
URL : https://hal.archives-ouvertes.fr/hal-00450768

E. K. Barefield, New synthesis of 1,4,8,11-tetraazacyclotetradecane (Cyclam) via the nickel(II) complex, Inorganic Chemistry, vol.11, issue.9, pp.2273-2274, 1972.
DOI : 10.1021/ic50115a065

E. K. Barefield, F. Wagner, and K. D. Hodges, Synthesis of macrocyclic tetramines by metal ion assisted cyclization reactions, Inorganic Chemistry, vol.15, issue.6, pp.1370-1377, 1976.
DOI : 10.1021/ic50160a025

L. Fabbrizzi, F. Gatti, P. Pallavicini, and E. Zambarbieri, Redox-Driven Intramolecular Anion Translocation between Transition Metal Centres, Chemistry - A European Journal, vol.5, issue.2, pp.682-690, 1999.
DOI : 10.1002/(SICI)1521-3765(19990201)5:2<682::AID-CHEM682>3.0.CO;2-E

Z. M. Otwinowski, W. Carter, and C. W. Jr, [20] Processing of X-ray diffraction data collected in oscillation mode, Methods Enzymol, vol.276, pp.307-326, 1997.
DOI : 10.1016/S0076-6879(97)76066-X

R. H. Blessing, An empirical correction for absorption anisotropy, Acta Crystallographica Section A Foundations of Crystallography, vol.51, issue.1, pp.33-38, 1995.
DOI : 10.1107/S0108767394005726

A. Altomare, G. Cascarano, C. Giacovazzo, and A. Guagliardi, 92, Journal of Applied Crystallography, vol.26, issue.3, pp.343-350, 1993.
DOI : 10.1107/S0021889892010331

Y. Bernhard, F. Rousselin, F. Boschetti, and . Denat, Remarkable inertness of Copper(II) chelates of a cyclen-based rigid cryptand with two, 2012.

C. Boschetti, F. Goze, and . Denat, Young researchers days of the Therapeutical Chemistry Society, 2012.

P. Désogère, M. Fani, H. Maecke, F. Boschetti, C. Goze et al., New imaging agents for targeting chemokine receptor CXCR4 Coordination Chemistry Days, 2012.

P. Désogère, C. Goze, and F. Denat, Synthesis of new copper chelators based on reinforced cyclams Advances in the synthesis of molecularly ordered structures (ASMOS), 6 th workshop Germany France, 2010.