J. E. Mark and . B. Erman, Rubberlike elasticity: a molecular primer, 2007.
DOI : 10.1017/CBO9780511541322

F. Ignatz-hoover and B. H. To, Rubber Compounding' Brendan Rodgers, 2004.

J. H. Grobler and W. J. Mcgill, Effect of network heterogeneity on tensile and tear strengths of radiation, peroxide, efficient and conventional cured polyisoprene, Journal of Polymer Science Part B: Polymer Physics, vol.32, issue.2, pp.287-95, 1994.
DOI : 10.1002/polb.1994.090320210

S. Datta, Rubber Compounding' Chap, 2004.

P. A. Ciullo and N. Hewitt, The Rubber Formulary, 1999.

A. D1418, Standard Practice for Rubber and Rubber Latices-Nomenclature, 2006.

W. Lynch, Handbook of Silicone Rubber Fabrication', Van Nostrand Reinhold Company, 1978.

W. Endstra, Proceedings of SRC Conference on "Organic peroxides for Crosslinking applications, 1985.

A. Nobel and C. , Crosslinking Peroxides and Co-agents, pp.6-91

A. Msakni, P. Chaumont, and P. Cassagnau, Diffusion of the dicumyl peroxide in molten polymer probed by rheology, Rheologica Acta, vol.31, issue.5, pp.933-943, 2007.
DOI : 10.1007/s00397-007-0176-9
URL : https://hal.archives-ouvertes.fr/hal-00373126

J. J. Flat, Private communication. Internal report from Arkema Company, 2004.

D. R. Thomas, Siloxane polymers, p.567, 1993.

R. N. Datta and F. A. Ingham, Rubber Technologist's Handbook, Rapra Technology, 2001.

A. Sarkar, Rubber Technologist's Handbook, Rapra Technology, vol.2, issue.11, 2009.

M. R. Brooke and . In, Silicon in organic, organometallic and polymer chemistry, p.282, 2000.

P. R. Dluzneski, Peroxide Vulcanization of Elastomers, Rubber Chemistry and Technology, vol.74, issue.3, p.451, 2001.
DOI : 10.5254/1.3547647

G. Baquey, L. Moine, O. Babot, M. Degueil, and B. Maillard, Model study of the crosslinking of polydimethylsiloxanes by peroxides, Polymer, vol.46, issue.17, pp.6283-6292, 2005.
DOI : 10.1016/j.polymer.2005.05.078

F. Tanaka and S. F. Edwards, Viscoelastic properties of physically crosslinked networks. 1. Transient network theory, Macromolecules, vol.25, issue.5, pp.1516-1523, 1992.
DOI : 10.1021/ma00031a024

J. Heiner, B. Stenberg, and M. Persson, Crosslinking of siloxane elastomers, Polymer Testing, vol.22, issue.3, pp.253-257, 2003.
DOI : 10.1016/S0142-9418(02)00081-8

M. Dorn, Modification of molecular weight and flow properties of thermoplastics, Advances in Polymer Technology, vol.5, issue.2, pp.87-91, 1985.
DOI : 10.1002/adv.1985.060050203

J. V. Gulmine and L. Akcelrud, Correlations between the processing variables and morphology of crosslinked polyethylene, Journal of Applied Polymer Science, vol.10, issue.1, pp.222-230, 2004.
DOI : 10.1002/app.20863

P. Neta, J. Grodkowski, and A. B. Ross, Rate Constants for Reactions of Aliphatic Carbon???Centered Radicals in Aqueous Solution, Journal of Physical and Chemical Reference Data, vol.25, issue.3, pp.709-1050, 1996.
DOI : 10.1063/1.555978

A. L. Beckwith, V. W. Bowry, and K. U. Ingold, Kinetics of nitroxide radical trapping. 1. Solvent effects, Journal of the American Chemical Society, vol.114, issue.13, pp.4983-4992, 1992.
DOI : 10.1021/ja00039a005

C. Kroll, A. Langner, and H. H. Borchert, Nitroxide metabolism in the human keratinocyte cell line HaCaT11Dedicated to Prof. Dr. G. Heinisch, Innsbruck, Austria, on the occasion of his 60th birthday., Free Radical Biology and Medicine, vol.26, issue.7-8, pp.850-857, 1999.
DOI : 10.1016/S0891-5849(98)00268-8

H. Fischer, The persistent radical effect in controlled radical polymerizations, Journal of Polymer Science Part A: Polymer Chemistry, vol.28, issue.13, p.1885, 1999.
DOI : 10.1002/(SICI)1099-0518(19990701)37:13<1885::AID-POLA1>3.0.CO;2-1

A. Studer and T. Schulte, Nitroxide-mediated radical processes, The Chemical Record, vol.126, issue.1, pp.27-35, 2005.
DOI : 10.1002/tcr.20033

S. Marque, Influence of the Nitroxide Structure on the Homolysis Rate Constant of Alkoxyamines:?? A Taft???Ingold Analysis, The Journal of Organic Chemistry, vol.68, issue.20, p.7582, 2003.
DOI : 10.1021/jo030036k

K. Ingold, Rate constants for free radical reactions in solution, In Free Radicals, J. K. Kochi, pp.37-112, 1973.

S. H. Yoo, C. Cohen, and C. Hui, Mechanical and swelling properties of PDMS interpenetrating polymer networks, Polymer, vol.47, issue.17, pp.6226-6235, 2006.
DOI : 10.1016/j.polymer.2006.06.035

M. L. Dunham, D. L. Bailey, and R. Y. Mixer, New Curing System for Silicone Rubber, Industrial & Engineering Chemistry, vol.49, issue.9, pp.1373-1376, 1957.
DOI : 10.1021/ie50573a029

P. R. Dluzneski, Peroxide Vulcanization of Elastomers, Rubber Chemistry and Technology, vol.74, issue.3, pp.451-492, 2001.
DOI : 10.5254/1.3547647

P. A. Ciullo and N. Hewitt, The rubber formulary, 1999.

M. F. Vallat, F. Ruch, and M. O. David, A structural study of EPDM networks??????the influence of the crosslinking mode on their microscopic structure, European Polymer Journal, vol.40, issue.7, pp.1575-1586, 2004.
DOI : 10.1016/j.eurpolymj.2004.01.026

J. Heiner, B. Stenberg, and M. Persson, Crosslinking of siloxane elastomers, Polymer Testing, vol.22, issue.3, pp.253-257, 2003.
DOI : 10.1016/S0142-9418(02)00081-8

M. Dorn, Modification of molecular weight and flow properties of thermoplastics, Advances in Polymer Technology, vol.5, issue.2, pp.87-91, 1985.
DOI : 10.1002/adv.1985.060050203

J. R. Lizotte and T. E. Long, Stable Free-Radical Polymerization of Styrene in Combination with 2-Vinylnaphthalene Initiation, Macromolecular Chemistry and Physics, vol.204, issue.4, pp.570-576, 2003.
DOI : 10.1002/macp.200390020

I. Q. Li, B. A. Howell, R. A. Koster, and D. B. Priddy, Mono- and Dinitroxide Styrene Polymerization Initiators, Macromolecules, vol.29, issue.26, pp.8554-8555, 1996.
DOI : 10.1021/ma9610121

N. R. Langley and J. D. , Elastically Effective Strand Density in Polymer Networks, Macromolecules, vol.1, issue.4, pp.348-352, 1968.
DOI : 10.1021/ma60004a015

L. M. Dossin and W. W. Graessley, Rubber Elasticity of Well-Characterized Polybutadiene Networks, Macromolecules, vol.12, issue.1, pp.123-130, 1979.
DOI : 10.1021/ma60067a026

P. Flory, Theory of elasticity of polymer networks. The effect of local constraints on junctions, The Journal of Chemical Physics, vol.66, issue.12, pp.5720-5729, 1977.
DOI : 10.1063/1.433846

H. M. James and E. Guth, Theory of the Increase in Rigidity of Rubber during Cure, The Journal of Chemical Physics, vol.15, issue.9, pp.669-683, 1947.
DOI : 10.1063/1.1746626

D. S. Pearson and W. W. Graessley, The Structure of Rubber Networks with Multifunctional Junctions, Macromolecules, vol.11, issue.3, pp.528-533, 1978.
DOI : 10.1021/ma60063a021

D. S. Pearson and W. W. Graessley, Elastic Properties of Well-Characterized Ethylene-Propylene Copolymer Networks, Macromolecules, vol.13, issue.4, pp.1001-1009, 1980.
DOI : 10.1021/ma60076a047

D. J. Plazek, W. Dannhauser, and J. D. Ferry, Viscoelastic dispersion of polydimethyl siloxane in the rubberlike plateau zone, Journal of Colloid Science, vol.16, issue.2, pp.101-126, 1961.
DOI : 10.1016/0095-8522(61)90011-3

E. M. Valles and C. W. Macosko, Properties of Networks Formed by End Linking of Poly(dimethylsiloxane), Macromolecules, vol.12, issue.4, pp.673-679, 1979.
DOI : 10.1021/ma60070a025

A. Ballistreri, G. Montaudo, and R. W. Lenz, Mass spectral characterization and thermal decomposition mechanism of alternating silarylene-siloxane polymers, Macromolecules, vol.17, issue.9, pp.1848-1854, 1984.
DOI : 10.1021/ma00139a040

N. Grassie and I. Macfarlane, The thermal degradation of polysiloxanes???I. Poly(dimethylsiloxane), European Polymer Journal, vol.14, issue.11, pp.875-884, 1978.
DOI : 10.1016/0014-3057(78)90084-8

C. Wetter, K. Jantos, K. Woithe, and A. Studer, Intermolecular Radical Addition and Addition/Cyclization Reactions of Alkoxyamines onto Nonactivated Alkenes, Organic Letters, vol.5, issue.16, pp.2899-2902, 2003.
DOI : 10.1021/ol034994k

M. R. Kamal and M. E. Ryan, Reactive polymer processing: Techniques and trends, Advances in Polymer Technology, vol.4, issue.34, pp.323-327, 1984.
DOI : 10.1002/adv.1984.060040312

K. Vollhardt and N. E. Schore, Traité de chimie organique, 2004.

M. Dorn, Modification of molecular weight and flow properties of thermoplastics, Advances in Polymer Technology, vol.5, issue.2, pp.87-91, 1985.
DOI : 10.1002/adv.1985.060050203

N. R. Langley and J. D. , Elastically Effective Strand Density in Polymer Networks, Macromolecules, vol.1, issue.4, pp.348-352, 1968.
DOI : 10.1021/ma60004a015

L. M. Dossin and W. W. Graessley, Rubber Elasticity of Well-Characterized Polybutadiene Networks, Macromolecules, vol.12, issue.1, pp.123-130, 1979.
DOI : 10.1021/ma60067a026

P. A. Ciullo and N. Hewitt, The rubber formulary, 1999.

P. R. Dluzneski, Peroxide Vulcanization of Elastomers, Rubber Chemistry and Technology, vol.74, issue.3, pp.451-492, 2001.
DOI : 10.5254/1.3547647

D. L. Kurdikar and N. A. Peppas, A Kinetic Model for Diffusion-Controlled Bulk Crosslinking Photopolymerizations, Macromolecules, vol.27, issue.15, pp.4084-4092, 1994.
DOI : 10.1021/ma00093a009

J. J. Flat, Private communication. Internal report from Arkema Company, 2004.

K. E. Russell, Free radical graft polymerization and copolymerization at higher temperatures, Progress in Polymer Science, vol.27, issue.6, pp.1007-1038, 2002.
DOI : 10.1016/S0079-6700(02)00007-2

F. Berzin, B. Vergnes, P. Dufosse, and L. Delamare, Modeling of peroxide initiated controlled degradation of polypropylene in a twin screw extruder, Polymer Engineering & Science, vol.11, issue.2, pp.344-356, 2000.
DOI : 10.1002/pen.11168
URL : https://hal.archives-ouvertes.fr/hal-00538223

C. H. Bamford and C. F. Tipper, Free-radical polymerisation-Comprehensive chemical kinetics, p.7, 1976.

C. D. Han and D. S. Lee, Curing behavior of unsaturated polyester resin with mixed initiators, Journal of Applied Polymer Science, vol.34, issue.2, pp.793-813, 1987.
DOI : 10.1002/app.1987.070340230

M. Zhang and W. H. Ray, Modeling of ?living? free-radical polymerization processes. I. Batch, semibatch, and continuous tank reactors, Journal of Applied Polymer Science, vol.31, issue.7, pp.1630-1662, 2002.
DOI : 10.1002/app.11051

H. E. Kissinger, Reaction Kinetics in Differential Thermal Analysis, Analytical Chemistry, vol.29, issue.11, pp.1702-1706, 1957.
DOI : 10.1021/ac60131a045

J. G. Drobny, Handbook of Thermoplastic Elastomers, p.179, 2007.

G. Holden, H. R. Kricheldrof, and R. P. Quirk, Thermoplastic Elastomers, p.217, 2004.

J. White, S. K. De, and K. Naskar, Rubber Technologist's Handbook Volume, p.219, 2009.

M. Bousmina and R. Muller, Rheology/morphology/flow conditions relationships for polymethylmethacrylate/rubber blend, Rheologica Acta, vol.11, issue.4, pp.369-381, 1996.
DOI : 10.1007/BF00403538

B. J. Cail and R. D. Demarco, New Heat and Oil Resistant (TPV) for Demanding Under Hood Applications, Zeon Chemicals, pp.1-0942, 2003.

R. Leaversuch, Super-TPVs The New Challenge to Rubber, 2009.

J. E. Dickerhoof, B. J. Cail, and S. C. Harber, 150°C Heat-and Oil-Resistant TPVs, Zeon Chemicals, 2004.

J. E. Mark, H. R. Allcock, and R. Wesr, Inorganic Polymers, Second Edition, p.172, 2005.

M. P. Munoz, M. M. Werlang, I. V. Yoshida, and R. S. Mauler, Blends of high-density polyethylene with solid silicone additive, Journal of Applied Polymer Science, vol.39, issue.11, pp.2347-2354, 2002.
DOI : 10.1002/app.10214

N. T. Mcmanus, S. H. Zhu, C. Tzoganakis, and A. Penlidis, Grafting of ethylene???ethyl acrylate???maleic anhydride terpolymer with amino-terminated polydimethylsiloxane during reactive processing, Journal of Applied Polymer Science, vol.45, issue.6, pp.4230-4237, 2006.
DOI : 10.1002/app.23890

U. Sundararaj and C. W. Macosko, Drop Breakup and Coalescence in Polymer Blends: The Effects of Concentration and Compatibilization, Macromolecules, vol.28, issue.8, pp.2647-2657, 1996.
DOI : 10.1021/ma00112a009

L. M. Robeson, Polymer blends: A comprehensive review, p.65, 2007.
DOI : 10.3139/9783446436503

S. S. Ray, M. Bousmina, and A. Maazouz, Morphology and properties of organoclay modified polycarbonate/poly(methyl methacrylate) blend, Polymer Engineering & Science, vol.14, issue.8, pp.1121-1129, 2006.
DOI : 10.1002/pen.20598

K. El-mabrouk, Phase Separation of Polystyrene/Poly(vinylmethylether)/Organoclay Nanocomposites, Journal of Nanoscience and Nanotechnology, vol.6, issue.2, pp.472-282, 2006.
DOI : 10.1166/jnn.2006.093

K. El-mabrouk, S. Vaudreuil, and A. Zeghloul, Effect of Shear on Phase-Separation in Polystyrene/Poly(vinyl methyl ether)/Organoclay Nanocomposites, Journal of Nanoscience and Nanotechnology, vol.8, issue.4, pp.1895-1900, 2008.
DOI : 10.1166/jnn.2008.0191895

G. Martin, C. Barres, and P. Sonntag, Co-continuous morphology and stress relaxation behaviour of unfilled and silica filled PP/EPDM blends, Materials Chemistry and Physics, vol.113, issue.2-3, pp.889-898, 2009.
DOI : 10.1016/j.matchemphys.2008.08.069
URL : https://hal.archives-ouvertes.fr/hal-00374481

S. Maiti, S. De, and A. K. Bhowmick, Quantitative Estimation of Filler Distribution in Immiscible Rubber Blends by Mechanical Damping Studies, Rubber Chemistry and Technology, vol.65, issue.2, pp.293-302, 1992.
DOI : 10.5254/1.3538612

P. Thareja and S. Velankar, Particle-induced bridging in immiscible polymer blends, Rheologica Acta, vol.44, issue.92, pp.405-412, 2007.
DOI : 10.1007/s00397-006-0130-2

M. Maric, N. Ashurov, and C. W. Macosko, Reactive blending of poly (dimethylsiloxane) with nylon 6 and poly (styrene):Effect of reactivity on morphology, Polymer Engineering & Science, vol.41, issue.4, pp.631-642, 2001.
DOI : 10.1002/pen.10759

M. Dorn, Modification of molecular weight and flow properties of thermoplastics, Advances in Polymer Technology, vol.5, issue.2, pp.87-91, 1985.
DOI : 10.1002/adv.1985.060050203

C. Joubert, P. Cassagnau, and A. Michel, Influence of the processing conditions on a two-phase reactive blend system: EVA/PP thermoplastic vulcanizate, Polymer Engineering & Science, vol.62, issue.11, pp.2222-2233, 2002.
DOI : 10.1002/pen.11112

C. Harrats, S. Thomas, and G. Groeninckx, Micro-and Nanostructured Multiphase Polymer Blend Systems: Phase Morphology And Interfaces, p.295, 2006.

S. Wu, Polymer interface and adhesion, 1982.

D. K. Owens and R. C. Wendt, Estimation of the surface free energy of polymers, Journal of Applied Polymer Science, vol.13, issue.8, pp.1741-1747, 1969.
DOI : 10.1002/app.1969.070130815

E. A. Guggenheim, The Principle of Corresponding States, The Journal of Chemical Physics, vol.13, issue.7, pp.253-261, 1945.
DOI : 10.1063/1.1724033

A. Bismarck and M. E. Kumru, Characterization of Several Polymer Surfaces by Streaming Potential and Wetting Measurements: Some Reflections on Acid???Base Interactions, Journal of Colloid and Interface Science, vol.217, issue.2, pp.377-387, 1999.
DOI : 10.1006/jcis.1999.6345

J. Vermant, G. Cioccolo, K. Golapan-nair, and P. Moldenaers, Coalescence suppression in model immiscible polymer blends by nano-sized colloidal particles, Rheologica Acta, vol.228, issue.5, pp.529-538, 2004.
DOI : 10.1007/s00397-004-0381-8